CN111744532A - Method for modifying porous material by multiple elements - Google Patents

Method for modifying porous material by multiple elements Download PDF

Info

Publication number
CN111744532A
CN111744532A CN201910236257.XA CN201910236257A CN111744532A CN 111744532 A CN111744532 A CN 111744532A CN 201910236257 A CN201910236257 A CN 201910236257A CN 111744532 A CN111744532 A CN 111744532A
Authority
CN
China
Prior art keywords
molecular sieve
porous material
solution
hours
rare earth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910236257.XA
Other languages
Chinese (zh)
Inventor
郑金玉
王成强
满征
罗一斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
Original Assignee
Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinopec Research Institute of Petroleum Processing, China Petroleum and Chemical Corp filed Critical Sinopec Research Institute of Petroleum Processing
Priority to CN201910236257.XA priority Critical patent/CN111744532A/en
Publication of CN111744532A publication Critical patent/CN111744532A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

A method for modifying porous material with multiple elements is to modify a porous material with phosphorus and rare earth in sequence by combining twice cross first baking and twice cross second baking; the porous material is obtained by adding an aluminum source and an alkali solution into a NaY molecular sieve filter cake for reaction, then adding a silicon source, and recovering a product after aging treatment or further hydrothermal treatment. The method of the invention achieves the purpose of modulating the pore channel and the acid property by modifying phosphorus and rare earth, and obviously promotes the improvement of the reaction performance of the porous material.

Description

Method for modifying porous material by multiple elements
Technical Field
The invention relates to a method for modifying a porous material, in particular to a method for modifying a porous material by multiple elements.
Background
Catalytic cracking is an important process in petroleum refining, is widely applied to the petroleum processing industry, and plays a significant role in oil refineries. In the catalytic cracking process, heavy fractions such as vacuum distillates or residues of heavier components are reacted in the presence of a catalyst to convert into gasoline, distillates and other liquid cracked products and lighter gaseous cracked products of four carbons or less. The catalytic cracking reaction process follows a carbonium ion reaction mechanism, and therefore, an acidic catalytic material, particularly a catalytic material having a strong B acid center, needs to be used. Amorphous alumino-silicate material is an acidic catalytic material, which has both B and L acid centers, is the main active component in early catalytic cracking catalysts, but is gradually replaced by crystalline molecular sieves due to its lower cracking activity and higher required reaction temperature. Crystalline molecular sieves are porous materials with a pore size of less than 2nm and a special crystalline phase structure, and materials with a pore size of less than 2nm are named as microporous materials according to the definition of IUPAC, so that crystalline molecular sieves or zeolites generally belong to microporous materials, and the microporous molecular sieve materials have stronger acidity and higher structural stability due to complete crystal structures and special framework structures, show higher catalytic activity in catalytic reactions, and are widely applied to petroleum processing and other catalytic industries.
The Y-type molecular sieve is used as a typical microporous molecular sieve material, and is applied in the fields of catalytic cracking, hydrocracking and the like on a large scale due to the regular pore channel structure, good stability and strong acidity. When the modified Y-type molecular sieve is used in a catalytic cracking catalyst, certain modification treatment is usually required to be carried out on the Y-type molecular sieve, such as skeleton dealumination inhibition through rare earth modification, the structural stability of the molecular sieve is improved, the retention degree of acid centers is increased, and the cracking activity is further improved; or the framework silicon-aluminum ratio is improved through ultra-stabilization treatment, so that the stability of the molecular sieve is improved. CN1436727A discloses a modified faujasite and a hydrocarbon cracking catalyst containing the zeolite, which adopts a one-exchange one-baking process, namely NaY firstly carries out a one-exchange reaction with a phosphorus compound and an ammonium compound, then a rare earth solution is added for continuous reaction, and the catalyst is obtained by filtering, washing and hydrothermal roasting.
CN1382631A discloses a high-silicon rare earth Y-type zeolite, which is prepared by gas phase reaction of rare earth Y-type zeolite and silicon tetrachloride, wherein the content of rare earth in crystal is 4-15 wt%, the cell constant is 2.450-2.458 nm, the collapse temperature is 1000-1056 ℃, the silica-alumina ratio is 8.3-8.8, and the content of sodium oxide is less than 1.0 wt%.
CN101823726A discloses a modified Y molecular sieve, which is prepared by a one-exchange one-baking process, namely NaY is firstly subjected to a one-exchange reaction with a rare earth solution, then a phosphorus compound is added for continuous reaction, and the modified Y molecular sieve is obtained by filtering, washing and hydrothermal roasting, wherein the content of rare earth is about 11-23 wt%, most of rare earth is positioned in a sodalite cage, the stability of the molecular sieve is improved, meanwhile, the acidity of the molecular sieve can be adjusted, and a catalyst containing the molecular sieve has the characteristics of strong heavy oil conversion capability and good coke selectivity.
CN100344374C discloses a rare earth Y molecular sieve and a preparation method thereof, the content of rare earth is 12-22 wt% calculated by rare earth oxide, and rare earth ions are all positioned in a molecular sieve small cage which is a small cage27In the Al MAS NMR spectrum, no peak was observed at a chemical shift of 0 ppm. The preparation method comprises the steps of adopting a one-way and one-way roasting process, adjusting the pH value of a solution to 8-11 by using an alkaline solution after one-way exchange, then filtering, washing, drying and roasting, or separating a molecular sieve filter cake after one-way exchange, collecting filtrate, adding the alkaline solution into the filtrate to adjust the pH value of the solution to 8-11, adding water into the obtained rare earth hydroxide filter cake and the molecular sieve filter cake, pulping, filtering, washing, drying and roasting. The process makes the excessive rare earth ions in the solution precipitate to avoid the rare earth loss and ensure that the rare earth ions are completely positioned in the molecular sieve small cage.
CN1317547A discloses an olefin reduction catalyst and a preparation method thereof, the catalyst mainly comprises REY molecular sieve with the rare earth content of 12-20 wt% and the crystallinity of more than 50% and a phosphorus and rare earth compound modified PREY molecular sieve with the rare earth content of 2-12 wt%, the phosphorus content of 0.2-3 wt% and the unit cell constant of 2.445-2.465 nm.
CN1506161A discloses a rare earth ultrastable Y molecular sieve, which adopts a double-cross double-baking process, namely, after a first-cross single-baking rare earth sodium Y is obtained, the first-cross single-baking rare earth sodium Y reacts with rare earth and phosphorus-containing substances step by step and is roasted for the second time to obtain a composite modified Y molecular sieve with the rare earth content of 8-25 wt%, the phosphorus content of 0.1-3.0 wt%, the crystallinity of 30-55% and the unit cell constant of 2.455-2.477 nm.
The molecular sieve prepared by adopting the double cross double roasting process also has other characteristics, for example, the molecular sieve which is disclosed in CN101537366A and can improve the coking performance and the preparation method thereof still adopt the double cross double roasting process, the phosphorus content of the molecular sieve is 0.05-5.0%, the rare earth content is less, only 0.05-4.0%, the unit cell constant is 2.430-2.440 nm, and the crystallinity is 35-55%.
Along with the increasing exhaustion of petroleum resources, the trend of crude oil heaving and deterioration is obvious, the slag blending proportion is continuously improved, and the requirement of the market for light oil products is not reduced, so that in recent years, the deep processing of heavy oil and residual oil is more and more emphasized in the petroleum processing industry, a plurality of refineries begin to blend vacuum residual oil, even normal pressure residual oil is directly used as a cracking raw material, the catalytic cracking of heavy oil gradually becomes a key technology for improving economic benefits of oil refining enterprises, and the macromolecular cracking capability of a catalyst therein is a focus of attention. The Y-type molecular sieve is the most main cracking active component in the conventional cracking catalyst, but due to the smaller pore channel structure, the Y-type molecular sieve shows a relatively obvious pore channel limiting effect in macromolecular reaction, and also shows a certain inhibiting effect on the cracking reaction of macromolecules such as heavy oil or residual oil and the like. Therefore, for catalytic cracking of heavy oil, it is necessary to use a material having a large pore size, no diffusion limitation to reactant molecules, and a high cracking activity.
According to the IUPAC definition, a material with a pore size of 2-50 nm is a mesoporous (mesoporous) material, and the size range of macromolecules such as heavy oil or residual oil is in the pore size range, so that the research of mesoporous materials, particularly mesoporous silicon-aluminum materials, has attracted great interest to researchers in the catalysis field. Mesoporous materials are firstly developed and succeeded by Mobil Corporation in 1992 (Beck J S, Vartuli J Z, Roth W J et al, J.Am.Chem.Comm.Soc., 1992, 114, 10834-containing 10843) and named as M41S series mesoporous molecular sieves, including MCM-41(Mobil Corporation Material-41) and MCM-48, etc., wherein the pore diameter of the molecular sieves can reach 1.6-10 nm, and the mesoporous materials are uniform and adjustable, have concentrated pore diameter distribution, large specific surface area and pore volume and strong adsorption capacity; however, the pore wall structure of the molecular sieve is an amorphous structure, so that the molecular sieve has poor hydrothermal stability and weak acidity, cannot meet the operation conditions of catalytic cracking, and is greatly limited in industrial application.
In order to solve the problem of poor hydrothermal stability of mesoporous molecular sieves, part of research work focuses on increasing the thickness of the pore walls of the molecular sieves, and if a neutral template agent is adopted, the molecular sieve with thicker pore walls can be obtained, but the defect of weaker acidity still exists. In CN1349929A, a novel mesoporous molecular sieve is disclosed, in which the primary and secondary structural units of zeolite are introduced into the pore walls of the molecular sieve, so that the molecular sieve has the basic structure of the conventional zeolite molecular sieve, and the mesoporous molecular sieve has strong acidity and ultrahigh hydrothermal stability. However, the molecular sieve has the defects that a template agent with high price is required to be used, the aperture is only about 2.7nm, the molecular sieve still has large steric hindrance effect on macromolecular cracking reaction, the structure is easy to collapse under the high-temperature hydrothermal condition, and the cracking activity is poor.
In the field of catalytic cracking, silicon-aluminum materials are widely used due to their strong acid centers and good cracking properties. The proposal of the mesoporous concept provides possibility for the preparation of a novel catalyst, and the current research results mostly focus on the use of expensive organic template and organic silicon source, and mostly need to be subjected to a high-temperature hydrothermal post-treatment process. In order to reduce the preparation cost and obtain a porous material in the mesoporous range, more research efforts have been focused on the development of disordered mesoporous materials. US5,051,385 discloses a monodisperse mesoporous silicon-aluminum composite material, which is prepared by mixing acidic inorganic aluminum salt and silica sol and then adding alkali for reaction, wherein the aluminum content is 5-40 wt%, the aperture is 20-50 nm, and the specific surface area is 50-100 m2(ii) in terms of/g. In US4,708,945The method comprises the steps of loading silica particles or hydrated silica on porous boehmite, and carrying out hydrothermal treatment on the obtained compound at a temperature of over 600 ℃ for a certain time to prepare the catalyst with the silica loaded on the surface of the boehmite, wherein the silica is combined with hydroxyl of the transitional boehmite, and the surface area reaches 100-200 m2(iv) g, average pore diameter of 7 to 7.5 nm. A series of acidic cracking catalysts are disclosed in US4,440,872, some of which are supported on gamma-Al2O3Impregnating silane, and then roasting at 500 ℃ or treating with water vapor. In CN1353008A, inorganic aluminum salt and water glass are used as raw materials, stable and clear silicon-aluminum sol is formed through the processes of precipitation, washing, dispergation and the like, white gel is obtained through drying, and then the silicon-aluminum catalytic material is obtained through roasting for 1-20 hours at 350-650 ℃. CN1565733A discloses a mesoporous silicon-aluminum material which has a pseudo-boehmite structure, concentrated pore size distribution and a specific surface area of about 200-400 m2The mesoporous silicon-aluminum material has the advantages that the pore volume is 0.5-2.0 ml/g, the average pore diameter is 8-20 nm, the most probable pore diameter is 5-15 nm, an organic template agent is not needed in the preparation of the mesoporous silicon-aluminum material, the synthesis cost is low, the obtained silicon-aluminum material has high cracking activity and hydrothermal stability, and the high macromolecular cracking performance is shown in a catalytic cracking reaction.
Disclosure of Invention
The invention aims to provide a method for preparing a multi-element modified porous material different from the prior art.
Therefore, the invention provides a method for modifying a porous material with multiple elements, which comprises the following steps: (1) carrying out first contact treatment on a porous material, an ammonium salt solution and a phosphorus source, filtering, washing and drying; (2) carrying out primary roasting treatment on the obtained product in the step (1) under the condition of 0-100% of water vapor; (3) carrying out secondary contact treatment on the solution obtained in the step (2) and a rare earth solution and/or an ammonium salt solution, filtering, washing and drying, or carrying out secondary roasting treatment under the condition of 0-100% of water vapor to obtain the multi-element modified porous material; wherein, the porous material in the step (1) is obtained by the following steps: (a) configuration of synthesizable NaY moleculesUniformly mixing the raw materials of the sieve, and then performing static crystallization at the temperature of 95-105 ℃; (b) filtering and washing the slurry after the static crystallization to obtain a NaY molecular sieve filter cake; (c) adding water into the NaY molecular sieve filter cake again for pulping, uniformly dispersing, adding an aluminum source and an alkali solution into the NaY molecular sieve filter cake at the temperature of between 30 and 70 ℃ under the condition of vigorous stirring for reaction, and controlling the pH value of a slurry system in the reaction process to be between 9 and 11; (d) in terms of SiO, based on the weight of alumina contained in the added aluminum source and alkali solution2:Al2O3Adding a silicon source according to the weight ratio of (1-6), continuously aging at 30-90 ℃ for 1-8 hours and recovering the product, or aging at 30-90 ℃ for 1-4 hours after adding the silicon source, then placing the product in a closed reaction kettle, continuously crystallizing at 95-105 ℃ for 3-30 hours and recovering the product.
The mesoporous structure of the porous material in the step (1) grows on the surface of a Y-shaped molecular sieve crystal grain and coats the molecular sieve crystal grain, the grain size is 1-2 mu m, and the total specific surface area is 300-650 m2(ii) a total pore volume of 0.4 to 1.0cm3(g) in an XRD spectrum, diffraction peaks exist at 6.2 degrees, 10.1 degrees, 11.9 degrees, 15.7 degrees, 18.7 degrees, 20.4 degrees, 23.7 degrees, 27.1 degrees, 28 degrees, 31.4 degrees, 38.5 degrees, 49 degrees and 65 degrees, and the chemical composition of the mesoporous structure layer is determined by the surface chemical composition measured by an XPS method, and the chemical composition is calculated by atomic mass: 7-20% of aluminum and 5-12% of silicon; the a/b of the porous material is 1.2-9.5, wherein a represents the shift of 500cm in Raman spectrum-1B represents a Raman shift of 350cm-1Spectral peak intensity of (a).
The porous material in the step (1) has XRD spectrum with characteristic diffraction peaks at 6.2 deg., 10.1 deg., 11.9 deg., 15.7 deg., 18.7 deg., 20.4 deg., 23.7 deg., 27.1 deg., 31.4 deg. and the like corresponding to FAU crystal phase structure of Y-type molecular sieve, and characteristic diffraction peaks at 28 deg., 38.5 deg., 49 deg. and 65 deg. corresponding to pseudo-boehmite structure of mesoporous layer. The porous material can be seen in a scanning electron microscope SEM picture that the wrinkled mesoporous structure is coated on the surface of the crystal grains of the Y-shaped molecular sieve, the granularity is uniform and is between 1 and 2 mu m, and the granularity is equivalent to the size of the crystal grains of the Y-shaped molecular sieve. The low-temperature nitrogen adsorption and desorption isotherm of the mesoporous silicon dioxide is in a type IV typical form and has mesoporous characteristics; the mesoporous layer is derived on the surface of the Y-type molecular sieve crystal grain in a crystal attachment growth mode.
The porous material in the step (1) simultaneously contains a microporous structure and a mesoporous structure, and the silicon-aluminum mesoporous layer is derived from the surface of the Y-shaped molecular sieve and coated on the surface of the molecular sieve, so that the granularity is more uniform, the mesoporous structure on the surface is smooth, a continuous gradient channel structure is formed with the internal molecular sieve, and the accessibility of macromolecules is enhanced.
In the present invention, the raw materials for synthesizing NaY molecular sieve in step (a) are usually directing agent, water glass, sodium metaaluminate, aluminum sulfate and deionized water, and their addition ratio can be the charging ratio of conventional NaY molecular sieve, for example, it can be Na2O：Al2O3：SiO2：H2O is 1.5-8: 1: 5-18: 100 to 500, the charge ratio of NaY molecular sieve for preparing special performance, for example, the charge ratio of NaY molecular sieve for preparing large or small crystal grains, is not particularly limited as long as NaY molecular sieve having FAU crystal phase structure can be obtained. The guiding agent can be prepared according to the prior art (US3639099 and US3671191), and the guiding agent is prepared by mixing a silicon source, an aluminum source, alkali liquor and deionized water according to (15-18) Na2O:Al2O3:(15～17)SiO2:(280～380)H2Mixing the components according to the molar ratio of O, uniformly stirring, and standing and aging for 0.5-48 h at room temperature to 70 ℃. In the feeding proportion of the NaY molecular sieve, Al in the guiding agent2O3The content of (A) is based on the total charge Al2O33 to 15%, preferably 5 to 10% of the total amount. The static crystallization in the step (a) is carried out for 8 to 50 hours, preferably 10 to 40 hours, and more preferably 15 to 35 hours.
In the present invention, the aluminum source of step (c) is selected from one or more of aluminum nitrate, aluminum sulfate and aluminum chloride; the alkali solution is one or more selected from ammonia water, potassium hydroxide, sodium hydroxide and sodium metaaluminate. When sodium metaaluminate is used as the alkali solution, the alumina content is counted in the total alumina content. The reaction temperature in the step (c) is 30-70 ℃, preferably 35-65 ℃.
In the present invention, the silicon source in step (d) is one or more selected from the group consisting of water glass, sodium silicate, tetraethoxysilane, tetramethoxysilane and silicon oxide. The aging temperature is 30-90 ℃, preferably 40-80 ℃, and the aging time is 1-8 hours, preferably 2-7 hours.
In the invention, in the first contact treatment process of the porous material, the ammonium salt solution and the phosphorus source in the step (1), the weight ratio of the ammonium salt to the porous material is 0.3-0.8, the weight ratio of the phosphorus source to the porous material is 0.01-0.08, the contact temperature is 40-90 ℃, preferably 50-80 ℃, and the contact time is 0.5-3.0 hours, preferably 1-2 hours.
In the present invention, the first or second baking treatment in the steps (2) and (3) is performed at 500 to 700 ℃, preferably 530 to 680 ℃, under the condition of 0 to 100% steam, preferably 20 to 100% steam, for 0.5 to 4.0 hours, preferably 1 to 3 hours.
In the invention, in the step (3), the solution obtained in the step (2) and the rare earth solution and/or the ammonium salt solution are subjected to second contact treatment, the weight ratio of the rare earth solution calculated by rare earth oxide to the solution obtained in the step (2) is 0.01-0.09, the weight ratio of the ammonium salt to the solution obtained in the step (2) is 0-0.2, the contact temperature is 40-90 ℃, preferably 50-80 ℃, and the contact time is 0.5-3.0 hours, preferably 1-2 hours.
In the invention, the phosphorus source can be one or more of ammonium phosphate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate and phosphoric acid. The ammonium salt can be one or more of ammonium chloride, ammonium nitrate, ammonium carbonate and ammonium bicarbonate. The rare earth solution is well known to those skilled in the art, and may be rare earth chloride or rare earth nitrate, or rare earth chloride or rare earth nitrate composed of a single rare earth element, wherein the rare earth solution commonly includes lanthanum chloride, lanthanum nitrate, cerium chloride or cerium nitrate, or may be mixed rare earth of different rare earth element proportions, such as cerium-rich or lanthanum-rich mixed rare earth, and may have any concentration. The filtration, water washing and drying processes are well known to those skilled in the art and will not be described herein.
The invention contains Y-type molecular sieve (micropore structure) and gamma Al2O3On the basis of the porous material of the layer (mesoporous structure), a modification mode of firstly introducing phosphorus and then modifying rare earth is adopted, the introduction of a small amount of phosphorus has the effect of stabilizing framework aluminum, but can still cause unit cell shrinkage, and in the subsequent rare earth modification process, the introduction amount of the rare earth, particularly the amount of the rare earth entering a molecular sieve small cage, is not too high.
The multi-element modified porous material obtained by the method contains 1-8 wt% of phosphorus oxide and 1-9 wt% of rare earth oxide, and also contains Y-type molecular sieve (microporous structure) and gamma-Al2O3The two structures are connected with each other, the XRD spectrogram has characteristic diffraction peaks of Y-type molecular sieve at 6.2 degrees, 10.1 degrees, 11.9 degrees, 15.7 degrees, 18.7 degrees, 20.4 degrees, 23.7 degrees, 27.1 degrees, 31.4 degrees and the like, and has gamma-Al at about 20 degrees to 30 degrees and 66 degrees2O3A layer structure characteristic diffraction peak; a unit cell constant of 2.453-2.463 nm, a relative crystallinity of 20-45%, and a total specific surface area of 330-520 m2(ii) a total pore volume of 0.45 to 0.85cm3A grain size of 1 to 2 μm.
The multi-element modified porous material obtained by the method combines two different structural characteristics of micropores and mesopores, and further achieves the purpose of modulating the pore canal and the acid property by modifying phosphorus and rare earth, thereby remarkably promoting the improvement of the reaction performance of the porous material.
Drawings
FIG. 1 is a SEM photograph of the porous material SAYN-1 in example 1.
FIG. 2 is a SEM image of a typical NaY molecular sieve.
FIG. 3 is an X-ray diffraction pattern of the porous material SAYN-1 in example 1.
FIG. 4 is a low temperature nitrogen desorption isotherm of the porous material SAYN-1 of example 1.
FIG. 5 is an X-ray diffraction spectrum of the multielement modified porous material PRL-1 obtained by the preparation method of example 1.
FIG. 6 is a SEM photograph of the porous material SAY-1 of example 4.
FIG. 7 is an X-ray diffraction pattern of the porous material SAY-1 of example 4.
FIG. 8 is a pore size distribution curve of the porous material SAY-1 of example 4.
Detailed Description
The invention is further illustrated by the following examples, which are not intended to limit the scope of the invention.
The preparation process of the directing agent used in the examples was: 5700g of water glass (available from Changling catalysts, Inc., SiO)2261g/L, modulus 3.31, density 1259g/L) was placed in a beaker and 4451g of high alkali sodium metaaluminate (provided by Changling catalysts, Inc., Al) was added with vigorous stirring2O339.9g/L，Na2O279.4g/L, density 1326g/L) and aging at 30 ℃ for 18 hours to obtain 16.1Na with molar ratio2O:Al2O3:15SiO2:318.5H2A directing agent for O.
The chemical composition of the mesoporous layer of the porous material in the examples was determined by X-ray photoelectron spectroscopy. The contents of lanthanum oxide and rare earth oxide were measured by X-ray fluorescence (see "analytical methods of petrochemical industry (RIPP)", Yangcui et al, ed. scientific Press, 1990). The phase, unit cell constant, crystallinity, and the like were measured by X-ray diffraction. Wherein, the crystallinity is measured according to the industry standards SH/T0340-92 and SH/T0339-92 of China general petrochemical company, and the NaY molecular sieve crystallinity standard sample is measured: NaY molecular sieve (GS BG 75004-.
The porous material test in the examples, SEM test, was performed using a Hitachi S4800, Hitachi, Japan, field emission scanning electron microscope, acceleration voltage 5kV, and energy spectrum collected and processed by Horiba 350 software. The laser Raman spectrum adopts a LabRAM HR UV-NIR type laser confocal Raman spectrometer of HORIBA company of Japan, the wavelength of an excitation light source is 325nm, an ultraviolet 15-time objective lens, a confocal pinhole is 100 mu m, and the spectrum scanning time is 100 s.
Examples 1-8 illustrate the preparation of the multielement modified porous material provided by the present invention.
Example 1
Under the condition of vigorous stirring, water glass, aluminum sulfate, sodium metaaluminate, guiding agent and deionized water are mixed according to 7.5SiO2：Al2O3：2.15Na2O：190H2Mixing the molar ratio of O to form NaY molecular sieve gel, wherein the mass ratio of the guiding agent is 5%, continuously stirring for 1 hour at room temperature, placing the gel in a crystallization kettle for static crystallization treatment for 40 hours at 100 ℃, quickly cooling after crystallization, and filtering and washing crystallized slurry to obtain a NaY molecular sieve filter cake; adding water again to the obtained NaY molecular sieve filter cake for pulping, dispersing uniformly, and then stirring Al vigorously at 30 DEG C2(SO4)3Solution (concentration 89 gAl)2O3/L) and NaAlO2Solution (concentration 156 gAl)2O3/L) is added into the reaction kettle simultaneously to react, the pH value of a slurry system in the reaction process is controlled to be 9.5, and after a certain time of adding, the total Al content is determined according to the Al2(SO4)3 solution and the NaAlO2 solution2O3By weight, in terms of SiO2:Al2O31:2.3 weight ratio, the desired water glass solution (concentration 100g SiO)2/L) is added into the reaction system, and then aging is continued for 6 hours at 70 ℃, after the aging is finished, filtration is carried out, washing is carried out, and drying is carried out at 120 ℃, so as to obtain the porous material SAYN-1.
The comparison between the images in the FIG. 1 and the FIG. 2 shows that the SAYN-1 has a uniform particle size distribution, a particle size of 1-2 μm, and a wrinkled structure on the surface, which indicates that the SAYN-1 is a material with a wrinkled mesoporous structure grown on the surface of the crystal grains of the NaY molecular sieve, the XRD spectrum of the SAYN-1 is shown in the FIG. 3, and diffraction peaks appear at 6.2 °, 10.1 °, 11.9 °, 15.7 °, 18.7 °, 20.4 °, 23.7 °, 27.1 °, 28 °, 31.4 °, 38.5 °, 49 ° and 65 °, wherein the characteristic diffraction peak labeled ★ corresponds to the FAU crystal phase structure of the Y molecular sieve, the characteristic diffraction peak labeled ▲ corresponds to the pseudo-boehmite structure of the mesoporous layer, the nitrogen desorption isotherm of the SAYN-1 is shown in the FIG. 4, the typical IV-like surface area of the NAY molecular sieve, and the total surface area of the pseudo-like2(ii)/g, total pore volume 0.92cm3(ii) in terms of/g. By XPS methodThe surface chemical compositions measured were aluminum 13.6% and silicon 7.1% by atomic mass. Raman (Raman) spectrometry with a/b of 2.1, wherein a represents a 500cm shift in the Raman (Raman) spectrum-1B represents a Raman shift of 350cm-1Spectral peak intensity of (a).
Mixing SAYN-1 with ammonium chloride according to the proportion of 1: 0.5, in a weight ratio to phosphoric acid of 1: 0.02, performing first contact treatment at 55 ℃ for 0.5 hour, filtering, washing with water, and drying; then roasting for 2 hours at 500 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.04, weight ratio to ammonium salt 1: 0.1, carrying out secondary contact treatment at 70 ℃ for 1 hour, filtering, washing with water, and drying; and then carrying out secondary roasting treatment at 550 ℃ under the condition of 100% water vapor for 2 hours to obtain the multielement modified porous material PRL-1.
The XRD diffraction pattern of PRL-1 is shown in FIG. 5, while the Y-type molecular sieve structure and gamma-Al can be seen2O3Structure, in the figure? Diffraction peaks at 6.2 °, 10.1 °, 11.9 °, 15.7 °, 18.7 °, 20.4 °, 23.7 °, 27.1 ° and 31.4 ° corresponding to the numbers are FAU crystal phase structure characteristic peaks, and diffraction peaks at 20 ° to 30 ° and about 66 ° corresponding to parenthesis in the figure are γ -Al2O3Structural characteristic peaks.
PRL-1 contains 2 wt% of phosphorus oxide, 3.9 wt% of rare earth oxide, a unit cell constant of 2.455nm, a relative crystallinity of 33%, and a total specific surface area of 449m2G, total pore volume 0.85cm3A grain size of 1 to 2 μm.
Example 2
The preparation of the NaY molecular sieve is the same as that of the example 1, except that the crystallization treatment time is 24 hours; adding water again into the obtained NaY molecular sieve filter cake for pulping, dispersing uniformly, and then stirring Al (NO) vigorously at room temperature3)3Adding the solution and ammonia water simultaneously, controlling pH value of slurry system at 10.1, adding Al (NO) according to the amount of the solution3)3Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the required tetraethoxysilane into the reaction system according to the weight ratio of 1:1.8, continuing to age at 65 ℃ for 6 hours, filtering after the aging is finished, washing and drying at 120 ℃ to obtain the porous material SAYN-6.
The scanning electron microscope photo of SAYN-6 has the characteristics shown in figure 1, the particle size distribution is uniform, the particle size is 1-2 mu m, and the surface of the NaY molecular sieve crystal grain is coated with a wrinkled mesoporous structure. The XRD spectrum has the characteristics shown in figure 3, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. The low-temperature nitrogen adsorption and desorption isotherm of SAYN-6 has the characteristics shown in figure 4, is in the form of IV isotherms, has mesoporous characteristics and has the total specific surface area of 588m2In terms of/g, total pore volume of 0.78cm3(ii) in terms of/g. The surface chemical composition measured by the XPS method was 13.5% by atomic mass of aluminum and 9.5% by atomic mass of silicon. Raman (Raman) spectroscopy, which gave an a/b of 5.9.
Mixing SAYN-6 with ammonium chloride according to the weight ratio of 1: 0.6, in a weight ratio to ammonium dihydrogen phosphate of 1: 0.035, performing a first contact treatment at 65 ℃ for 1 hour, filtering, washing with water, and drying; then roasting for 2 hours at 580 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.06, carrying out secondary contact treatment at 65 ℃ for 1 hour, filtering, washing with water, and drying to obtain the multielement modified porous material PRL-2.
The XRD diffraction pattern of PRL-2 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-2 contains 3.3 wt% of phosphorus oxide, 5.7 wt% of rare earth oxide, 2.460nm in unit cell constant, 45% of relative crystallinity and 501m in total specific surface area2G, total pore volume 0.63cm3A grain size of 1 to 2 μm.
Example 3
The preparation of NaY molecular sieve is the same as example 1 except that the crystallization treatment time is 45 hours; adding water again to the NaY molecular sieve filter cake, pulping, dispersing uniformly, and adding AlCl under vigorous stirring at 60 deg.C3Solution and NaAlO2Adding the solution into the reaction kettle simultaneously for reaction, and controlling the slurry in the reaction processThe pH value of the system is 10.8, and after a certain time of adding, according to the AlCl used3Solution and NaAlO2Total Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the required tetraethoxysilane into the reaction system according to the weight ratio of 1:4, continuing to age at 50 ℃ for 3 hours, filtering after the aging is finished, washing and drying at 120 ℃ to obtain the porous material SAYN-7.
The scanning electron microscope photo of SAYN-7 has the characteristics shown in figure 1, the particle size distribution is uniform, the particle size is 1-2 mu m, and the surface of the NaY molecular sieve crystal grain is coated with a wrinkled mesoporous structure. The XRD spectrum has the characteristics shown in figure 3, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. The low-temperature nitrogen adsorption and desorption isotherm of SAYN-7 has the characteristics shown in figure 4, is in the form of IV isotherms, has mesoporous characteristics and has a total specific surface area of 474m2(ii)/g, total pore volume 0.81cm3(ii) in terms of/g. The surface chemical composition measured by XPS method was 16.1% aluminum and 7.7% silicon by atomic mass. Raman (Raman) spectroscopy, which gave an a/b of 9.3.
Mixing SAYN-7 with ammonium chloride according to the weight ratio of 1: 0.3, and diammonium hydrogen phosphate according to a weight ratio of 1: 0.08, performing first contact treatment at 50 ℃ for 0.5 hour, filtering, washing with water, and drying; then roasting for 1 hour at 600 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.02, weight ratio to ammonium salt 1: 0.15, carrying out secondary contact treatment at 75 ℃ for 1 hour, filtering, washing and drying; and then carrying out secondary roasting treatment at 600 ℃ under the condition of 100% water vapor for 2 hours to obtain the multielement modified porous material PRL-3.
The XRD diffraction pattern of PRL-3 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-3 contains phosphorus oxide 7.6 wt%, rare earth oxide 1.8 wt%, unit cell constant 2.460nm, relative crystallinity 22%, and total specific surface area 415m2In terms of/g, total pore volume 0.76cm3A grain size of 1 to 2 μm.
Example 4
Under the condition of vigorous stirring, water glass, aluminum sulfate, sodium metaaluminate, guiding agent and deionized water are mixed according to 8.5SiO2：Al2O3：2.65Na2O：210H2Mixing the molar ratio of O to prepare NaY molecular sieve gel, wherein the mass ratio of the guiding agent is 5%, stirring for 1 hour at room temperature, placing the gel in a crystallization kettle for static crystallization treatment for 30 hours at 100 ℃, cooling after crystallization, and filtering and washing crystallized slurry to obtain a NaY molecular sieve filter cake; adding water again into the obtained NaY molecular sieve filter cake for pulping, homogenizing, and adding AlCl at 45 deg.C under vigorous stirring3Solution (concentration 60 gAl)2O3/L) and NaAlO2Solution (concentration 102 gAl)2O3/L) adding the mixture at the same time to carry out gelling reaction, controlling the pH value of the slurry to be 10.0 in the gelling process, and adding the mixture for a certain time according to the used AlCl3Solution and NaAlO2Total Al in solution2O3By weight, in terms of SiO2:Al2O31:1.8 weight ratio, the desired water glass solution (concentration 125 gSiO)2/L) is added into the gel forming slurry, and then the gel forming slurry is aged for 3 hours at 55 ℃, after the aging, the slurry is placed into a stainless steel reaction kettle and crystallized for 20 hours at the temperature of 100 ℃, and then the filtration, the washing and the drying at the temperature of 120 ℃ are carried out, thus obtaining the porous material SAY-1.
SAY-1 SEM photograph is shown in FIG. 6, the particle size distribution is uniform, the particle size is 1-2 μm, the surface is wrinkled, it shows that the mesoporous structure grows on the NaY molecular sieve grain surface and covers it, the XRD spectrogram is shown in FIG. 7, diffraction peaks appear at 6.2 °, 10.1 °, 11.9 °, 15.7 °, 18.7 °, 20.4 °, 23.7 °, 27.1 °, 28 °, 31.4 °, 38.5 °, 49 ° and 65 °, wherein the characteristic diffraction peak marked as ★ corresponds to FAU crystal phase structure of Y-type molecular sieve, the characteristic diffraction peak marked as # corresponds to pseudo-boehmite structure, SAY-1 a/b is 6.6, wherein a is the shift of 500cm in Raman spectrum-1B is a shift of 350cm-1(ii) spectral peak intensity of; the surface silicon-aluminum atomic ratio measured by the XPS method was 0.74. SAY-1, the BJH pore size distribution curve is shown in FIG. 8, which shows the characteristic of multi-level pore distributionThe total specific surface area of the polymer is 644m2(g) the mesoporous specific surface area is 65m2/g。
SAY-1 was mixed with ammonium chloride at a ratio of 1: 0.4, and diammonium hydrogen phosphate according to a weight ratio of 1: 0.05, carrying out first contact treatment at 70 ℃ for 1 hour, filtering, washing with water, and drying; then roasting for 2 hours at 550 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.05, carrying out secondary contact treatment at 70 ℃ for 1 hour, filtering, washing with water, and drying; and then carrying out secondary roasting treatment at 550 ℃ under the condition of 100% water vapor for 2 hours to obtain the multielement modified porous material PRL-4.
The XRD diffraction pattern of PRL-4 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-4 contains phosphorus oxide 4.9 wt%, rare earth oxide 4.6 wt%, unit cell constant 2.458nm, relative crystallinity 44%, and total specific surface area 520m2G, total pore volume 0.48cm3A grain size of 1 to 2 μm.
Example 5
The preparation of NaY molecular sieve is the same as that of example 4, except that the crystallization treatment time is 26 hours; adding water again into the obtained NaY molecular sieve filter cake for pulping, homogenizing, and stirring at 60 deg.C under vigorous stirring to obtain Al2(SO4)3Adding the solution and ammonia water simultaneously to carry out gelling reaction, controlling the pH value of the slurry to be 9.4 in the gelling process, and adding Al according to the used Al after a certain time2(SO4)3Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the required water glass solution into the gel-forming slurry according to the weight ratio of 1:1.5, aging at 60 ℃ for 1.5 hours, placing the slurry into a stainless steel reaction kettle after aging, crystallizing at 100 ℃ for 25 hours, filtering, washing and drying at 120 ℃ to obtain the porous material SAY-5.
SAY-5 scanning electron micrograph has the characteristics shown in FIG. 6, uniform particle size distribution, and large particle sizeThe particle size is 1-2 mu m, and the mesoporous structure grows on the surface of NaY molecular sieve crystal grains and covers the NaY molecular sieve crystal grains. The XRD spectrum has the characteristics shown in figure 7, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. SAY-5, has an a/b of 1.5, and has a surface silicon-aluminum atomic ratio of 0.88 as measured by XPS method. SAY-5 has the characteristics shown in FIG. 8, and shows a multi-level pore distribution with a total specific surface area of 398m2(g) the mesoporous specific surface area is 285m2/g。
SAY-5 was mixed with ammonium chloride in a ratio of 1: 0.4, in a weight ratio to phosphoric acid of 1: 0.04, carrying out first contact treatment at 60 ℃ for 0.5 hour, filtering, washing with water, and drying; then roasting for 2 hours at 530 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.09, carrying out secondary contact treatment at 60 ℃ for 0.5 hour, filtering, washing with water, and drying to obtain the multielement modified porous material PRL-5.
The XRD diffraction pattern of PRL-5 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-5 contains phosphorus oxide 4.0 wt%, rare earth oxide 8.8 wt%, unit cell constant 2.461nm, relative crystallinity 25%, and total specific surface area 330m2G, total pore volume 0.80cm3A grain size of 1 to 2 μm.
Example 6
Under the condition of vigorous stirring, water glass, aluminum sulfate, sodium metaaluminate, guiding agent and deionized water are mixed according to 7.5SiO2：Al2O3：2.15Na2O：190H2Mixing the molar ratio of O to prepare NaY molecular sieve gel, wherein the mass ratio of the directing agent is 5%, stirring for 1 hour at room temperature, and then placing the gel in a crystallization kettle for static crystallization treatment for 30 hours at 100 ℃; adding water again into the obtained NaY molecular sieve filter cake for pulping, homogenizing, and then stirring Al vigorously at 40 DEG C2(SO4)3Solution and NaAlO2Adding the solution at the same time to carry out gelling reaction, controlling the pH value of the slurry to be 10.2 in the gelling process, and adding Al according to the used Al after a certain time2(SO4)3Solution and NaAlO2Total Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the required water glass solution into the gel-forming slurry according to the weight ratio of 1:2.6, aging at 75 ℃ for 3 hours, placing the slurry into a stainless steel reaction kettle after aging, crystallizing at 100 ℃ for 4 hours, filtering, washing and drying at 120 ℃ to obtain the porous material SAY-6.
SAY-6 has the characteristics shown in figure 6, the particle size distribution is uniform, the particle size is 1-2 μm, and the mesoporous structure grows on the surface of NaY molecular sieve crystal grains and covers the NaY molecular sieve crystal grains. The XRD spectrum has the characteristics shown in figure 7, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. SAY-6, has an a/b of 2.6, and has a surface silicon-aluminum atomic ratio of 0.50 as measured by XPS method. SAY-6 has the characteristics shown in FIG. 8, presents a multistage pore distribution, and has a total specific surface area of 532m2(iv)/g, mesoporous specific surface area is 209m2/g。
SAY-6 was mixed with ammonium chloride at a ratio of 1: 0.5 in a weight ratio to ammonium dihydrogen phosphate according to a weight ratio of 1: 0.06 weight ratio, carrying out first contact treatment at 65 ℃ for 1 hour, filtering, washing with water, and drying; then roasting for 1 hour at 650 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.07, carrying out secondary contact treatment at 55 ℃ for 1 hour, filtering, washing with water, and drying to obtain the multielement modified porous material PRL-6.
The XRD diffraction pattern of PRL-6 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-6 contains 5.9 wt% of phosphorus oxide, 6.5 wt% of rare earth oxide, 2.457nm in unit cell constant, 35% in relative crystallinity and 429m in total specific surface area2In terms of/g, total pore volume 0.66cm3A grain size of 1 to 2 μm.
Example 7
The preparation of NaY molecular sieve is the same as example 4, except that the crystallization treatment time is 40 hours; adding water again to the obtained NaY molecular sieve filter cake for pulping, homogenizing, and then violently stirring at room temperatureStirring, adding Al (NO)3)3Solution and NaAlO2Adding the solution at the same time to carry out gelling reaction, controlling the pH value of the slurry to be 10.5 in the gelling process, and adding Al (NO) according to the use after a certain time3)3Solution and NaAlO2Total Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the needed tetraethoxysilane into the gel-forming slurry according to the weight ratio of 1:5.2, aging at 65 ℃ for 4 hours, placing the slurry into a stainless steel reaction kettle after aging, crystallizing at 100 ℃ for 30 hours, filtering, washing and drying at 120 ℃ to obtain the porous material SAY-7.
SAY-7 scanning electron microscope photo has the characteristics shown in figure 6, the particle size distribution is uniform, the particle size is 1-2 μm, and the mesoporous structure grows on the surface of NaY molecular sieve crystal grains and covers the NaY molecular sieve crystal grains. The XRD spectrum has the characteristics shown in figure 7, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. SAY-7, has an a/b of 1.4, and has a surface silicon-aluminum atomic ratio of 0.29 as measured by XPS method. SAY-7 has the characteristics shown in FIG. 8, presents a multistage pore distribution, and has a total specific surface area of 457m2Per g, the mesoporous specific surface area is 381m2/g。
SAY-7 was mixed with ammonium chloride in a ratio of 1: 0.3, and diammonium hydrogen phosphate according to a weight ratio of 1: 0.03, performing first contact treatment at 55 ℃ for 1 hour, filtering, washing with water, and drying; then roasting for 2 hours at 600 ℃ under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.08, performing second contact treatment at 55 ℃ for 1 hour, filtering, washing with water, and drying; and then carrying out secondary roasting treatment at 600 ℃ under the condition of 100% water vapor for 2 hours to obtain the multielement modified porous material PRL-7.
The XRD diffraction pattern of PRL-7 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-7 contains 3.0 wt% of phosphorus oxide, 8.0 wt% of rare earth oxide, 2.462nm in unit cell constant, 20% in relative crystallinity and 382m in total specific surface area2Per g, total poreVolume 0.77cm3A grain size of 1 to 2 μm.
Example 8
Under the condition of vigorous stirring, water glass, aluminum sulfate, sodium metaaluminate, guiding agent and deionized water are mixed according to 7.5SiO2：Al2O3：2.15Na2O：190H2Mixing the molar ratio of O to prepare NaY molecular sieve gel, wherein the mass ratio of the guiding agent is 5%, stirring for 1 hour at room temperature, placing the gel in a crystallization kettle for static crystallization treatment for 35 hours at 100 ℃, cooling after crystallization, and filtering and washing crystallized slurry to obtain a NaY molecular sieve filter cake; adding water again into the obtained NaY molecular sieve filter cake for pulping, homogenizing, and stirring at 55 deg.C under vigorous stirring to obtain Al2(SO4)3Solution (concentration 90 gAl)2O3/L) and ammonia water are added simultaneously to carry out gelling reaction, the pH value of slurry in the gelling process is controlled to be 9.0, and after a certain time, Al is added according to the use2(SO4)3Al of solution2O3By weight, in terms of SiO2:Al2O3Adding the required tetraethoxysilane into the gel-forming slurry according to the weight ratio of 1:2.2, aging at 80 ℃ for 2 hours, placing the slurry into a stainless steel reaction kettle after aging, crystallizing at 100 ℃ for 9 hours, filtering, washing and drying at 120 ℃ to obtain the porous material SAY-3.
SAY-3 scanning electron microscope photo has the characteristics shown in figure 6, the particle size distribution is uniform, the particle size is 1-2 μm, and the mesoporous structure grows on the surface of NaY molecular sieve crystal grains and covers the NaY molecular sieve crystal grains. The XRD spectrum has the characteristics shown in figure 7, and simultaneously contains an FAU crystal phase structure and a pseudo-boehmite structure. SAY-3, has an a/b of 3.4, and has a surface silicon to aluminum atomic ratio of 0.52 as measured by XPS. The BJH pore size distribution curve has the characteristics shown in FIG. 8, presents a multistage pore distribution characteristic, and has a total specific surface area of 542m2Per g, the mesoporous specific surface area is 154m2/g。
SAY-3 was mixed with ammonium chloride in a ratio of 1: 0.4, and diammonium hydrogen phosphate according to a weight ratio of 1: 0.07, performing first contact treatment at 75 ℃ for 0.5 hour, filtering, washing with water, and drying; then roasting for 2 hours at the temperature of 620 ℃ and under the condition of 100 percent of water vapor; mixing the obtained mixture with a rare earth solution according to the weight ratio of 1: 0.03, weight ratio to ammonium salt 1: 0.1, carrying out secondary contact treatment at 75 ℃ for 1 hour, filtering, washing with water, and drying to obtain the multielement modified porous material PRL-8.
The XRD diffraction pattern of PRL-8 has the characteristics shown in figure 5, and the FAU crystal phase structure and gamma-Al of the Y-type molecular sieve can be seen2O3And (5) structure.
PRL-8 contains 6.7 wt% of phosphorus oxide, 2.9 wt% of rare earth oxide, 2.461nm unit cell constant, 43% relative crystallinity and 440m total specific surface area2In terms of/g, total pore volume 0.62cm3A grain size of 1 to 2 μm.
Examples 9 to 16
Examples 9-16 illustrate the microreflective activity of the multielement modified porous material of the invention after aging at 800 c for 8 hours with 100% water vapor.
The multielement modified porous materials PRL-1 to PRL-8 in the embodiments 1 to 8 are exchanged by ammonium chloride solution until the content of sodium oxide is lower than 0.3 weight percent, and after drying, the materials are tableted and sieved into particles of 20 to 40 meshes, and the particles are aged for 8 hours at the temperature of 800 ℃ under the condition of 100 percent of water vapor, and then the micro-inversion activity index MA is tested on a light oil micro-inversion evaluation device.
Light oil micro-reverse evaluation conditions: the raw oil is Dagang straight run light diesel oil, the sample loading is 2g, the oil inlet is 1.56g, and the reaction temperature is 460 ℃.
The microreflective index is shown in Table 1.
TABLE 1
Sample (I) MA Sample (I) MA
PRL-1 58 PRL-5 57
PRL-2 61 PRL-6 61
PRL-3 56 PRL-7 58
PRL-4 63 PRL-8 58
As can be seen from the test results of the micro-inversion activity index MA shown in Table 1, the MA of the multi-element modified porous materials PRL-1 to PRL-8 obtained in examples 1 to 8 can basically reach 56 to 63 after aging treatment with 100% steam at 800 ℃ for 8 hours, and the cracking activity is relatively high.
The multi-element modified porous material prepared by the method respectively modifies micropores and mesoporous channels in a composite structure through different modification effects of phosphorus and rare earth, obtains a special modification effect, and effectively improves the cracking activity of the material.

Claims (12)

1. A method of multielement modification of a porous material, comprising: (1) carrying out first contact treatment on a porous material, an ammonium salt solution and a phosphorus source, filtering, washing and drying; (2) 0 to E obtained in the step (1)Carrying out first roasting treatment under the condition of 100% water vapor; (3) carrying out secondary contact treatment on the solution obtained in the step (2) and a rare earth solution and/or an ammonium salt solution, filtering, washing and drying, or carrying out secondary roasting treatment under the condition of 0-100% of water vapor to obtain the multi-element modified porous material; wherein, the porous material in the step (1) is obtained by the following steps: (a) preparing raw materials capable of synthesizing a NaY molecular sieve, uniformly mixing, and then performing static crystallization at the temperature of 95-105 ℃; (b) filtering and washing the slurry after the static crystallization to obtain a NaY molecular sieve filter cake; (c) adding water into the NaY molecular sieve filter cake again for pulping, uniformly dispersing, adding an aluminum source and an alkali solution into the NaY molecular sieve filter cake at the temperature of between 30 and 70 ℃ under the condition of vigorous stirring for reaction, and controlling the pH value of a slurry system in the reaction process to be between 9 and 11; (d) in terms of SiO, based on the weight of alumina contained in the added aluminum source and alkali solution2:Al2O3Adding a silicon source according to the weight ratio of (1-6), continuously aging at 30-90 ℃ for 1-8 hours and recovering the product, or aging at 30-90 ℃ for 1-4 hours after adding the silicon source, then placing the product in a closed reaction kettle, continuously crystallizing at 95-105 ℃ for 3-30 hours and recovering the product.
2. The method of claim 1, wherein the raw materials for synthesizing NaY molecular sieve in step (a) are directing agent, water glass, sodium metaaluminate, aluminum sulfate and deionized water.
3. The method of claim 1 wherein the aluminum source in step (c) is selected from one or more of aluminum nitrate, aluminum sulfate and aluminum chloride.
4. The method according to claim 1, wherein the alkali solution in the step (c) is one or more selected from the group consisting of aqueous ammonia, potassium hydroxide, sodium hydroxide and sodium metaaluminate.
5. The process according to claim 1, wherein in the case of sodium metaaluminate as the alkali solution in the step (c), the alumina content is calculated from the alumina content in the step (d).
6. The method according to claim 1, wherein the silicon source in step (d) is one or more selected from the group consisting of water glass, sodium silicate, tetraethoxysilane, tetramethoxysilane, and silicon oxide.
7. The preparation method according to claim 1, wherein the porous material in the step (1) is subjected to a first contact treatment with an ammonium salt solution and a phosphorus source, the weight ratio of the ammonium salt to the porous material is 0.3 to 0.8, the weight ratio of the phosphorus source to the porous material is 0.01 to 0.08, the contact temperature is 40 to 90 ℃, preferably 50 to 80 ℃, and the contact time is 0.5 to 3.0 hours, preferably 1 to 2 hours.
8. The process according to claim 1, wherein the first or second calcination treatment in steps (2) and (3) is carried out at a temperature of 500 to 700 ℃, preferably 530 to 680 ℃, under the condition of 0 to 100% steam, preferably 20 to 100% steam, for 0.5 to 4.0 hours, preferably 1 to 3 hours.
9. The process according to claim 1, wherein in the step (3), in the second contact treatment of the solution of rare earth and/or ammonium salt obtained in the step (2), the weight ratio of the rare earth solution to the solution of rare earth and/or ammonium salt obtained in the step (2) is 0.01 to 0.09 in terms of rare earth oxide, the weight ratio of ammonium salt to the solution of ammonium salt obtained in the step (2) is 0 to 0.2, the contact temperature is 40 to 90 ℃, preferably 50 to 80 ℃, and the contact time is 0.5 to 3.0 hours, preferably 1 to 2 hours.
10. The method according to claim 1, wherein the phosphorus source in step (1) is one or more selected from the group consisting of ammonium phosphate, diammonium phosphate, monoammonium phosphate, and phosphoric acid.
11. The method according to claim 1, wherein the ammonium salt in the steps (1) and (3) is one or more of ammonium chloride, ammonium nitrate, ammonium carbonate and ammonium bicarbonate.
12. The preparation method according to claim 1, wherein the multi-element modified porous material prepared by the method contains 1-8 wt% of phosphorus oxide and 1-9 wt% of rare earth oxide, and also contains Y-type molecular sieve and gamma-Al2O3A layer, the two structures are connected with each other, the cell constant is 2.453-2.463 nm, the relative crystallinity is 20-45%, and the total specific surface area is 330-520 m2(ii) a total pore volume of 0.45 to 0.85cm3A grain size of 1 to 2 μm.
CN201910236257.XA 2019-03-27 2019-03-27 Method for modifying porous material by multiple elements Pending CN111744532A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910236257.XA CN111744532A (en) 2019-03-27 2019-03-27 Method for modifying porous material by multiple elements

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910236257.XA CN111744532A (en) 2019-03-27 2019-03-27 Method for modifying porous material by multiple elements

Publications (1)

Publication Number Publication Date
CN111744532A true CN111744532A (en) 2020-10-09

Family

ID=72671868

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910236257.XA Pending CN111744532A (en) 2019-03-27 2019-03-27 Method for modifying porous material by multiple elements

Country Status (1)

Country Link
CN (1) CN111744532A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5051385A (en) * 1988-07-05 1991-09-24 Exxon Research And Engineering Company Monodispersed mesoporous catalyst matrices and FCC catalysts thereof
CN1353086A (en) * 2000-11-13 2002-06-12 中国石油化工股份有限公司 Process for preparing Y-type molecular sieve
CN102173436A (en) * 2011-01-04 2011-09-07 卓润生 Preparation method of rare earth (RE) yttrium (Y) molecular sieve
CN103449471A (en) * 2012-06-01 2013-12-18 中国石油天然气股份有限公司 Phosphorus-containing super stable rare earth Y-type molecular sieve and preparation method thereof
CN104588054A (en) * 2013-10-31 2015-05-06 中国石油化工股份有限公司 Mesoporous catalysis material containing phosphorus and rare earth
CN106268919A (en) * 2015-06-29 2017-01-04 中国石油化工股份有限公司 A kind of containing rare earth with the modified Y catalyst of phosphorus
CN108927207A (en) * 2017-05-26 2018-12-04 中国石油化工股份有限公司 A kind of porous catalyst material and preparation method thereof of surface richness aluminium

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5051385A (en) * 1988-07-05 1991-09-24 Exxon Research And Engineering Company Monodispersed mesoporous catalyst matrices and FCC catalysts thereof
CN1353086A (en) * 2000-11-13 2002-06-12 中国石油化工股份有限公司 Process for preparing Y-type molecular sieve
CN102173436A (en) * 2011-01-04 2011-09-07 卓润生 Preparation method of rare earth (RE) yttrium (Y) molecular sieve
CN103449471A (en) * 2012-06-01 2013-12-18 中国石油天然气股份有限公司 Phosphorus-containing super stable rare earth Y-type molecular sieve and preparation method thereof
CN104588054A (en) * 2013-10-31 2015-05-06 中国石油化工股份有限公司 Mesoporous catalysis material containing phosphorus and rare earth
CN106268919A (en) * 2015-06-29 2017-01-04 中国石油化工股份有限公司 A kind of containing rare earth with the modified Y catalyst of phosphorus
CN108927207A (en) * 2017-05-26 2018-12-04 中国石油化工股份有限公司 A kind of porous catalyst material and preparation method thereof of surface richness aluminium

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
WENLIN LI ET AL.: "Effect of hierarchical porosity and phosphorus modification on thecatalytic properties of zeolite Y", 《APPLIED SURFACE SCIENCE》 *
张剑秋等: "磷改性Y型分子筛的氢转移性能考察", 《石油学报》 *

Similar Documents

Publication Publication Date Title
CN109967117B (en) Preparation method of modified Y-type molecular sieve
CN109569697B (en) Silicon-aluminum catalytic material and preparation method thereof
CN108927123B (en) Porous catalytic material and preparation method thereof
CN111744528B (en) Preparation method of multi-metal modified composite material
CN111744532A (en) Method for modifying porous material by multiple elements
CN111744531B (en) Preparation method of hierarchical porous material
CN110871108B (en) Preparation method of porous catalytic material containing Y-type molecular sieve
CN111747424B (en) Preparation method of rare earth and phosphorus-containing porous material
CN109970076B (en) Y-type molecular sieve with surface coated with silicon-aluminum mesoporous layer and preparation method thereof
CN109833900B (en) Preparation method of micro-mesoporous composite material
CN111617798A (en) Preparation method of rare earth modified composite material
CN110871104B (en) Porous catalytic material and preparation method thereof
CN111744536A (en) Catalytic material containing rare earth and magnesium and preparation method thereof
CN111747425B (en) Porous catalytic material containing mesopores and micropores
CN111744535A (en) Catalytic material jointly modified by rare earth and phosphorus and preparation method thereof
CN109569713B (en) Catalytic material and preparation method thereof
CN111744529A (en) Method for modifying composite catalytic material by rare earth
CN111085246B (en) Composite catalytic material and preparation method thereof
CN110090660B (en) Composite material containing Y-type molecular sieve and preparation method thereof
CN111617797A (en) Preparation method of rare earth type composite catalytic material
CN110871103B (en) Composite material containing gamma-alumina structure and preparation method thereof
CN109833899B (en) Silicon-aluminum composite material and preparation method thereof
CN110871102B (en) Preparation method of micro-mesoporous composite material containing Y-type molecular sieve
CN111086999A (en) Preparation method of composite material containing Y-type molecular sieve
CN110092392B (en) Preparation method of composite material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination