CN111689643B - Treatment method for oily sewage of finished oil depot - Google Patents

Treatment method for oily sewage of finished oil depot Download PDF

Info

Publication number
CN111689643B
CN111689643B CN201910200042.2A CN201910200042A CN111689643B CN 111689643 B CN111689643 B CN 111689643B CN 201910200042 A CN201910200042 A CN 201910200042A CN 111689643 B CN111689643 B CN 111689643B
Authority
CN
China
Prior art keywords
oil depot
oily sewage
reactor
finished oil
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201910200042.2A
Other languages
Chinese (zh)
Other versions
CN111689643A (en
Inventor
唐晓丽
宋项宁
姚猛
张志远
郭亚逢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Safety Engineering Research Institute Co Ltd
Original Assignee
China Petroleum and Chemical Corp
Sinopec Safety Engineering Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Safety Engineering Research Institute Co Ltd filed Critical China Petroleum and Chemical Corp
Priority to CN201910200042.2A priority Critical patent/CN111689643B/en
Publication of CN111689643A publication Critical patent/CN111689643A/en
Application granted granted Critical
Publication of CN111689643B publication Critical patent/CN111689643B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • C02F2001/46138Electrodes comprising a substrate and a coating
    • C02F2001/46142Catalytic coating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to a method for treating oily sewage of a finished oil depot, which mainly solves the problems of low COD removal rate and secondary pollution in the prior art. The invention adopts a method for treating oily sewage of a finished oil depot, the oily sewage of the finished oil depot is treated by a coalescence degreaser, an iron-carbon micro-electrolysis, an electro-catalysis reactor and a BAF reactor in sequence and then is discharged, the oil content of the effluent is less than 4mg/L, and the COD is less than 70 mg/L; the technical scheme that the iron-carbon microelectrolysis is filled with the iron-carbon filler and the electrocatalysis reactor is filled with the activated carbon catalyst well solves the problems and can be used for treating oily sewage of a finished oil depot.

Description

Treatment method for oily sewage of finished oil depot
Technical Field
The invention relates to a method for treating oily sewage in a finished oil depot.
Background
The oil-containing sewage of the finished oil depot mainly comes from initial rainwater of the depot area, ground washing water, oil tank cutting water, tank cleaning operation drainage, loading and unloading operation drainage and the like. The water quality particularity of the oily sewage of the finished oil depot lies in that a large amount of gasoline and diesel oil additives such as methyl tert-butyl ether (MTBE) and the like which are dissolved in water are added besides petroleum, so that the COD concentration of the oily sewage of the finished oil depot is high. The existing oil depot is mainly treated by adopting an oil separation tank-coagulation air flotation-filtration process, the coagulation air flotation process in the set of process flow can remove colloid substances such as dispersed oil, emulsified oil and the like in the sewage by adding conventional coagulants such as polyaluminium chloride (PAC), Polyacrylamide (PAM) and the like and combining an air flotation device, and after the oil-containing sewage of the oil depot is subjected to oil removal treatment through water quality analysis, a large amount of benzene series substances are still contained in the water, so that the organic matter (COD) in the sewage seriously exceeds the standard.
The utility model discloses a light oil sewage integrated processing device (grant No. CN2892839Y) discloses a processing apparatus of oily sewage that light oil depot operation produced, and the device uses materialization processing as the core, realizes through processes such as swash plate separation, filtration, coalescence separation and absorption that the discharged water reaches national one-level and discharges and retrieve dispersion oil and emulsified oil simultaneously. However, the core COD removal section of the device is an adsorption section, and in order to meet the drainage requirement, the volume of the section is set to be larger, and the adsorbent is easy to saturate and lose efficacy. The invention discloses a treatment method of finished oil depot sewage (No. CN104129874B), which utilizes filtration, two-stage coalescence and electro-adsorption to achieve better treatment effect and avoid excessive use of medicaments, but the method mainly aims at the low-concentration finished oil depot oily sewage, wherein a coalescence separator mainly aims at partial dispersed oil and emulsified oil in the oily sewage and has limited COD removal effect, and an electro-adsorption reactor utilizes the principle that the adsorption capacity of activated carbon is increased under the action of an electric field, so that the treatment efficiency of COD is lower and the problem of activated carbon adsorption saturation exists.
Disclosure of Invention
The invention aims to solve the technical problems of low COD removal rate and secondary pollution in the prior art, and provides a novel method for treating oily sewage of a finished oil depot, which has the advantages of high COD removal rate and no secondary pollution.
In order to solve the problems, the technical scheme adopted by the invention is as follows: a method for treating oily sewage of a finished oil depot comprises the steps of treating the oily sewage of the finished oil depot by a coalescence degreaser, iron-carbon micro-electrolysis, an electro-catalytic reactor and a BAF reactor in sequence and then discharging, wherein the content of petroleum in effluent is less than 4mg/L, and the COD is less than 70 mg/L; wherein, iron-carbon microelectrolysis is filled with iron-carbon filler, and the electro-catalytic reactor is filled with activated carbon catalyst.
In the technical scheme, preferably, the coalescence degreaser, the iron-carbon microelectric interpretation, the electrocatalysis reactor, the BAF reactor and the electric control equipment are integrated on a skid-mounted base.
In the above technical solution, preferably, the coalescing oil remover is composed of a pre-filter, a first-stage coalescing filter, and a second-stage coalescing filter.
In the above technical scheme, preferably, the prefilter is filled with walnut shells or polypropylene fiber pellets; the first-stage coalescence filter is filled with a modified polypropylene corrugated plate or a ceramic corrugated plate; the second-stage coalescence filter is filled with stainless steel fiber or glass fiber filler, and the coalescence degreaser is provided with an oil collecting cavity.
In the technical scheme, preferably, iron in the iron-carbon filler used in the iron-carbon microelectrolysis accounts for 70-90 wt%, carbon accounts for 5-15 wt%, and metal active components Mn, Cu and Ni account for 5-15 wt%.
In the above technical solution, preferably, the electrocatalysis reactor is composed of a cathode and an anode, a catalyst filler, an aeration device, and a back-washing device; wherein, the cathode and anode are coated with Sb and Sn titanium electrodes, the catalyst particles are Mn, Cu and Ni loaded active carbon catalysts, the bottom of the reactor is provided with an aeration pipe connected with a fan, sewage enters from the bottom of the reactor and flows up uniformly through a water distribution plate to fill the whole reactor.
In the technical scheme, preferably, the voltage of the electrocatalysis reactor is 10-20V, the voltage in the regeneration process of the catalytic particles is 10-30V, and the regeneration time is 20-120 min.
In the above technical scheme, preferably, the BAF reactor is filled with hydrophilic polymer filler, and is provided with an aeration device and a back-flushing device.
In the technical scheme, preferably, the oil class of the oily sewage of the finished oil depot is 10-100 mg/L, and the COD is 1000-3000 mg/L.
In the technical scheme, preferably, the effluent petroleum is less than 4mg/L, and the COD is less than 70 mg/L.
According to the invention, the finished product oil depot sewage is treated by the coalescence degreaser, the iron-carbon micro-electrolysis, the electro-catalytic reactor and the BAF reactor in sequence and then discharged, the effluent oil content is less than 4mg/L, and the COD is less than 50mg/L, a physicochemical method and a biological method are combined, and meanwhile, the method has a good removal rate on the oil content and the COD, can ensure that the finished product oil depot oil-containing sewage is discharged after reaching the standard, and achieves a good technical effect.
Drawings
FIG. 1 is a schematic flow diagram of the process of the present invention.
In fig. 1, a centrifugal pump; 2. a pre-filter; 3. a first stage coalescing filter; 4. a secondary coalescing filter; 5. iron-carbon micro-electrolysis; 6. an electrocatalytic reactor; 7. a direct current power supply; 8. a cathode and an anode; 9. a catalyst filler; 10. a blower; BAF reactor.
The present invention will be further illustrated by the following examples, but is not limited to these examples.
Detailed Description
Example one
As shown in figure 1, the mixed oil product (gasoline and diesel oil) finished product oil depot drainage is treated, and the drainage sequentially passes through a coalescence degreaser, an iron-carbon micro-electrolysis, an electro-catalytic reactor and a BAF reactor. The coalescence degreaser consists of a prefilter, a first-stage coalescence filter and a second-stage coalescence filter, wherein the prefilter is filled with walnut shells or polypropylene fiber pellets; the first-stage coalescence filter is filled with a modified polypropylene corrugated plate or a ceramic corrugated plate; the second-stage coalescence filter is filled with fillers such as stainless steel fibers or glass fibers. The coalescence degreaser is provided with an oil collecting cavity. The coalescence degreaser, the iron-carbon microelectric interpretation, the electrocatalysis reactor, the BAF reactor and the electric control equipment are integrated on a skid-mounted base. The electro-catalytic reactor consists of a negative electrode, a positive electrode, a negative electrode, catalyst filler, an aeration device and a back washing device; wherein, the cathode and anode are coated with Sb and Sn titanium electrodes, the catalyst particles are Mn, Cu and Ni loaded active carbon catalysts, the bottom of the reactor is provided with an aeration pipe connected with a fan, sewage enters from the bottom of the reactor and flows up uniformly through a water distribution plate to fill the whole reactor.
Removing floating oil and dispersed oil from sewage through a coalescence degreaser, then performing iron-carbon micro-electrolysis to break bonds of macromolecular substances to decompose the macromolecular substances into micromolecular substances and remove part of COD, then entering an electro-catalytic reactor to finish removing most of COD, and then entering a BAF reactor to perform biodegradation. In the iron-carbon filler used in the iron-carbon microelectrolysis, 20 wt% of iron, 75 wt% of carbon and 5 wt% of metal active components of Mn, Cu and Ni are contained.
The method is utilized to drain a mixed oil product (gasoline and diesel oil) finished oil depot with 50mg/L, COD content of oil and 1600mg/L content of oil, the voltage applied to the electrocatalysis reactor is adjusted to be 10V, the oil is less than or equal to 10mg/L after the treatment by the coalescence degreaser, the oil in the final effluent is less than or equal to 4mg/L, and the COD is less than or equal to 50 mg/L.
Example two
According to the procedure described in example 1, the iron-carbon filler used in iron-carbon microelectrolysis contains 20 wt% of iron, 75 wt% of carbon and 5 wt% of metal active components Mn, Cu and Ni. The high-efficiency integrated treatment device for the sewage of the finished oil depot is used for draining the finished oil depot of the mixed oil product (gasoline and diesel oil) with the petroleum content of 92mg/L, COD of 2650mg/L, the voltage applied to the electrocatalysis reactor is adjusted to be 20V, the petroleum is less than or equal to 20mg/L after the treatment of the coalescence degreaser, the final effluent petroleum is less than or equal to 4mg/L, and the COD is less than or equal to 50 mg/L.
EXAMPLE III
According to the procedure described in example 1, the iron-carbon filler used in iron-carbon microelectrolysis contains 20 wt% of iron, 75 wt% of carbon and 5 wt% of metal active components Mn, Cu and Ni. The high-efficiency integrated treatment device for the sewage of the finished oil depot is utilized to drain the finished oil depot of the mixed oil products (gasoline and diesel oil) with the petroleum content of 93mg/L, COD and the content of 2683mg/L, the applied voltage of the electro-catalytic reactor is adjusted to 10V, the petroleum is less than or equal to 20mg/L after the treatment of the coalescence degreaser, the final effluent petroleum is less than or equal to 4mg/L, and the COD is less than or equal to 70 mg/L.
[ COMPARATIVE EXAMPLES ]
The method utilizes the air flotation and the contact oxidation method to treat the mixed oil product (gasoline and diesel oil) finished product oil depot drainage with the petroleum content of 93mg/L, COD and the petroleum content of 2683mg/L, the treated sewage is 10mg/L of petroleum and the COD is 210 mg/L.

Claims (9)

1. A treatment method of oily sewage of a finished oil depot is characterized in that the oily sewage of the finished oil depot is treated by a coalescence degreaser, iron-carbon micro-electrolysis, an electro-catalytic reactor and a BAF reactor in sequence and then discharged, the content of petroleum in effluent is less than 4mg/L, and the COD is less than 70 mg/L; wherein, iron-carbon microelectrolysis is filled with iron-carbon filler, and an electro-catalytic reactor is filled with an activated carbon catalyst;
the electro-catalytic reactor consists of a negative electrode, a positive electrode, a negative electrode, catalyst filler, an aeration device and a back washing device; wherein, the cathode and anode are coated with Sb and Sn titanium electrodes, the catalyst particles are Mn, Cu and Ni loaded active carbon catalysts, the bottom of the reactor is provided with an aeration pipe connected with a fan, sewage enters from the bottom of the reactor and flows up uniformly through a water distribution plate to fill the whole reactor.
2. The method for treating oily sewage in a finished oil depot according to claim 1, wherein the coalescence degreaser, the iron-carbon micro-electrolysis, the electro-catalytic reactor, the BAF reactor and the electric control equipment are integrated on a skid-mounted base.
3. The method for treating oily sewage of a finished oil depot according to claim 1, wherein the coalescence degreaser is composed of a prefilter, a first-stage coalescence filter and a second-stage coalescence filter.
4. The method for treating oily sewage of a finished oil depot according to claim 3, wherein the prefilter is filled with walnut shells or polypropylene fiber pellets; the first-stage coalescence filter is filled with a modified polypropylene corrugated plate or a ceramic corrugated plate; the second-stage coalescence filter is filled with stainless steel fiber or glass fiber filler, and the coalescence degreaser is provided with an oil collecting cavity.
5. The method for treating oily sewage of a finished oil depot according to claim 1, wherein iron in the iron-carbon filler used in iron-carbon microelectrolysis accounts for 70-90 wt%, carbon accounts for 5-15 wt%, and metal active components Mn, Cu and Ni account for 5-15 wt%.
6. The method for treating oily sewage of a finished oil depot according to claim 1, wherein the voltage of the electro-catalytic reactor is 10-20V, the voltage in the regeneration process of catalytic particles is 10-30V, and the regeneration time is 20-120 min.
7. The method for treating oily sewage in a finished oil depot according to claim 1, wherein the BAF reactor is filled with hydrophilic polymer filler and is provided with an aeration device and a back-flushing device.
8. The method for treating oily sewage of a finished oil depot according to claim 1, wherein the oil content of the oily sewage of the finished oil depot is 10-100 mg/L, and the COD is 1000-3000 mg/L.
9. The method for treating oily sewage in a finished oil depot according to claim 1, wherein the petroleum content in the effluent is less than 4mg/L and the COD is less than 50 mg/L.
CN201910200042.2A 2019-03-15 2019-03-15 Treatment method for oily sewage of finished oil depot Active CN111689643B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910200042.2A CN111689643B (en) 2019-03-15 2019-03-15 Treatment method for oily sewage of finished oil depot

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910200042.2A CN111689643B (en) 2019-03-15 2019-03-15 Treatment method for oily sewage of finished oil depot

Publications (2)

Publication Number Publication Date
CN111689643A CN111689643A (en) 2020-09-22
CN111689643B true CN111689643B (en) 2022-07-05

Family

ID=72475567

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910200042.2A Active CN111689643B (en) 2019-03-15 2019-03-15 Treatment method for oily sewage of finished oil depot

Country Status (1)

Country Link
CN (1) CN111689643B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116332297B (en) * 2023-05-29 2023-08-22 四川省生态环境科学研究院 Skid-mounted combined sewage treatment device

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012055263A1 (en) * 2010-10-28 2012-05-03 波鹰(厦门)科技有限公司 Apparatus and method for treating and recycling tannery wastewater based on nano catalytic electrolysis technology and membrane technology
CN102849878A (en) * 2012-10-10 2013-01-02 南京农业大学 Pretreatment method for industrial wastewater of pyrethroid
CN104129874A (en) * 2014-05-30 2014-11-05 中国石油化工股份有限公司 Method for treating sewage in refined oil store
CN104176798A (en) * 2014-09-11 2014-12-03 江国平 Method and device for performing electrocatalytic oxidation treatment on high-concentration wastewater
CN105084648A (en) * 2015-07-21 2015-11-25 昆山美淼环保科技有限公司 Treatment method for hardly biodegraded sewage
CN105174657A (en) * 2015-10-20 2015-12-23 波鹰(厦门)科技有限公司 Treatment device and method for oil extraction wastewater
CN105293790A (en) * 2015-12-01 2016-02-03 安洁士环保(上海)股份有限公司 Comprehensive treatment method for oily sewage in oil field
CN205616727U (en) * 2016-04-19 2016-10-05 江苏丽天石化码头有限公司 Petrochemical industry pier effluent disposal system
CN108017236A (en) * 2017-12-26 2018-05-11 湖南千幻科技有限公司 A kind of High Strength Organic Pharmaceutical Wastewater processing method
CN108033601A (en) * 2017-12-05 2018-05-15 中国石油集团安全环保技术研究院 The method of operation wastewater in oil field processing
CN109081479A (en) * 2018-09-20 2018-12-25 中石化(洛阳)科技有限公司 Coking is vented tower oil-containing waste water treating device and method

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012055263A1 (en) * 2010-10-28 2012-05-03 波鹰(厦门)科技有限公司 Apparatus and method for treating and recycling tannery wastewater based on nano catalytic electrolysis technology and membrane technology
CN102849878A (en) * 2012-10-10 2013-01-02 南京农业大学 Pretreatment method for industrial wastewater of pyrethroid
CN104129874A (en) * 2014-05-30 2014-11-05 中国石油化工股份有限公司 Method for treating sewage in refined oil store
CN104176798A (en) * 2014-09-11 2014-12-03 江国平 Method and device for performing electrocatalytic oxidation treatment on high-concentration wastewater
CN105084648A (en) * 2015-07-21 2015-11-25 昆山美淼环保科技有限公司 Treatment method for hardly biodegraded sewage
CN105174657A (en) * 2015-10-20 2015-12-23 波鹰(厦门)科技有限公司 Treatment device and method for oil extraction wastewater
CN105293790A (en) * 2015-12-01 2016-02-03 安洁士环保(上海)股份有限公司 Comprehensive treatment method for oily sewage in oil field
CN205616727U (en) * 2016-04-19 2016-10-05 江苏丽天石化码头有限公司 Petrochemical industry pier effluent disposal system
CN108033601A (en) * 2017-12-05 2018-05-15 中国石油集团安全环保技术研究院 The method of operation wastewater in oil field processing
CN108017236A (en) * 2017-12-26 2018-05-11 湖南千幻科技有限公司 A kind of High Strength Organic Pharmaceutical Wastewater processing method
CN109081479A (en) * 2018-09-20 2018-12-25 中石化(洛阳)科技有限公司 Coking is vented tower oil-containing waste water treating device and method

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
三维电极法深度处理成品油库含油污水;唐晓丽等;《化工环保》;20171215(第06期);全文 *
电镀废水膜分离浓液达标处理技术分析;王驭龙等;《电镀与涂饰》;20141115(第21期);全文 *

Also Published As

Publication number Publication date
CN111689643A (en) 2020-09-22

Similar Documents

Publication Publication Date Title
CN101481186B (en) Process and apparatus for treating oil-gas field wastewater
US10150685B2 (en) Water reclamation method integrating magnetic resin adsorption and electrosorption
CN1141263C (en) Method for controlling oil-bearing waste water
CN108238689B (en) Method for treating polymer flooding sewage
CN105417839B (en) A kind of processing system and method for pre-electroplating treatment waste water
CN110510808A (en) Metal cutting waste liquid environment protection emission processing system
CN111689643B (en) Treatment method for oily sewage of finished oil depot
CN210974231U (en) A processing apparatus for high concentration organic and heavy metal pollution's waste water
CN210620528U (en) High concentration cutting fluid emulsion effluent disposal system
CN106587447B (en) Electric induction coagulation ozone air flotation-catalytic oxidation multi-element coupling water treatment system and method
CN110577337A (en) Domestic sewage treatment method
CN104129874A (en) Method for treating sewage in refined oil store
CN105347580B (en) A kind of method of suitable polymer flooding water processing standard discharge
CN217077108U (en) Sewage treatment system based on ozone catalytic oxidation air supporting integration
CN216890540U (en) High-suspended solid high-concentration organic wastewater treatment device
CN1724397A (en) Treater of sewage by electrochemistr catalyzing oxidizing
CN212269731U (en) Treatment system for sewage of spray tower in automobile paint spraying workshop
CN1226205C (en) Method of treating oil field waste water using flocculation electro multiphase catalysis and special flocculation equipment
CN106517676A (en) Biomass gasification wastewater treatment method and device
CN108751573B (en) BAME treatment and recycling method for printing and dyeing wastewater
CN107311360A (en) The method that catalytic ozonation coupling three-diemsnional electrode handles product oil storage field oil-polluted water
CN203474558U (en) Tail end system for treating wastewater so as to realize emission on standard
CN111392926A (en) Treatment system and treatment method for sewage of spray tower in automobile paint spraying workshop
CN110776166A (en) Advanced treatment method and device for oil extraction sewage in oil field
CN111362478A (en) Deep treatment method for oily sewage of finished oil depot

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20220615

Address after: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen

Applicant after: CHINA PETROLEUM & CHEMICAL Corp.

Applicant after: Sinopec Safety Engineering Research Institute Co.,Ltd.

Address before: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen

Applicant before: CHINA PETROLEUM & CHEMICAL Corp.

Applicant before: Qingdao Safety Engineering Research Institute of Sinopec

GR01 Patent grant
GR01 Patent grant