CN111621371A - Polishing agent for online turbidimeter measuring system - Google Patents

Polishing agent for online turbidimeter measuring system Download PDF

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Publication number
CN111621371A
CN111621371A CN202010447769.3A CN202010447769A CN111621371A CN 111621371 A CN111621371 A CN 111621371A CN 202010447769 A CN202010447769 A CN 202010447769A CN 111621371 A CN111621371 A CN 111621371A
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CN
China
Prior art keywords
parts
turbidimeter
agent
polishing agent
cleaning
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010447769.3A
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Chinese (zh)
Inventor
杨传
王剑峰
李涛
于文涛
李晓雷
张建华
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Hebei Ji Yan Energy Science And Technology Research Institute Co ltd
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Hebei Ji Yan Energy Science And Technology Research Institute Co ltd
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Priority to CN202010447769.3A priority Critical patent/CN111621371A/en
Publication of CN111621371A publication Critical patent/CN111621371A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/34Organic compounds containing sulfur
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3272Urea, guanidine or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Cleaning In General (AREA)

Abstract

The invention discloses a polishing agent for an online turbidimeter measurement system, which comprises the following components in parts by weight: 10.0-18.0 parts of dirt dissolving agent, 2.0-4.0 parts of xylene sulfonate, 2.0-3.0 parts of deoiling agent, 0.3-0.5 part of organic silicon defoaming agent, 3.0-5.0 parts of synergist and 69.5-82.7 parts of deionized water solvent; the operation steps of the online turbidimeter measurement system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning a photocell, cleaning a bubble trap and rinsing with purified water. The polishing agent for the online turbidimeter measuring system can clean deposits such as mineral scales and the like in the turbidimeter measuring system, and solves the problem that when a low-turbidity water system is measured, the turbidimeter is inaccurate in measurement under the conditions of flow change or vibration and the like of the turbidimeter.

Description

Polishing agent for online turbidimeter measuring system
Technical Field
The invention relates to the technical field, and particularly relates to a polishing agent for an online turbidimeter measuring system.
Background
Turbidity, i.e. the degree of turbidity of water, is a measure of the reduction in water transparency caused by insoluble matter in water. The insoluble matter includes solid particles (silt, corrosive matter, floating algae, etc.) and colloidal particles suspended in water. According to international standard ISO7027, turbidity is a substitute parameter which reflects the impurity content and the particle size distribution relatively comprehensively. Common turbidity measuring methods mainly include a scattered light method, a transmitted light method and the like, and have the advantages of low detection lower limit, high sensitivity, high resolution, high accuracy and the like. The turbidity is an important index for measuring the quality of water as an important parameter for monitoring the water quality, and the monitoring of the turbidity of the water quality is widely applied to various industries.
In recent years, with the increasing importance of the state on the aspects of drinking water quality safety, industrial water discharge standards and the like, especially under the conditions that industrial sewage and domestic sewage pollute drinking water sources more and more seriously and the quality of source water deteriorates more and more, accurate measurement of turbidity is particularly important. The measurement principle of the turbidimeter is as follows: the light beam is scattered by suspended particles in the water body to be detected through the prism, and the scattered light quantity is in direct proportion to the turbidity content. However, in practical application of the turbidimeter, because a large amount of mineral deposits are deposited inside the photoelectric measuring cell, the sensor body and the bubble eliminator, the phenomenon of inaccurate measurement of the turbidimeter is easy to occur under the conditions of change or vibration of the flow of the turbidimeter and the like; especially, when a low-turbidity water system is measured, the generated measurement deviation is large, so that the accuracy is low. Therefore, the polishing treatment of the turbidity measuring system is an important measure for improving the measurement accuracy of the turbidity meter.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a polishing agent for an online turbidimeter measuring system, which is used for solving the problems of pollution of a measuring pool and low turbidity measuring accuracy caused by a large amount of mineral deposits, effectively removing the mineral deposits in the turbidimeter measuring system and improving the measuring accuracy of the turbidimeter.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows.
The polishing agent for the online turbidimeter measuring system comprises the following components in parts by weight: 10.0-18.0 parts of dirt dissolving agent, 2.0-4.0 parts of xylene sulfonate, 2.0-3.0 parts of deoiling agent, 0.3-0.5 part of organic silicon defoaming agent, 3.0-5.0 parts of synergist and 69.5-82.7 parts of deionized water solvent;
the operation steps of the online turbidimeter measurement system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning a photocell, cleaning a bubble trap and rinsing with purified water.
Further, the dirt dissolving agent comprises 5.0-8.0 parts of acetic acid and 5.0-10.0 parts of sulfamic acid.
Further, the xylene sulfonate is any one of sodium xylene sulfonate, potassium xylene sulfonate and ammonium xylene sulfonate.
Further, the degreaser is isopropanol.
Further, the organic silicon defoaming agent is a silicone glycol defoaming agent.
Further, the synergist is guanidine carbonate.
Further, the polishing agent for the on-line turbidimeter measurement system comprises the following components in parts by weight: 11.0-18.0 parts of dirt dissolvent, 2.5-4.0 parts of xylene sulfonate, 2.5-3.0 parts of degreaser, 0.4-0.5 part of organic silicon defoamer, 4.0-5.0 parts of synergist and 69.5-79.6 parts of deionized water solvent.
Due to the adoption of the technical scheme, the technical progress of the invention is as follows.
The polishing agent for the turbidimeter measuring system provided by the invention has stable physicochemical properties, does not damage a photoelectric measuring cell, a sensor body, a bubble eliminator and the like of the turbidimeter measuring system in the using process, and can be completely dissolved in a water body without influencing the turbidity value. The cleaning agent has the advantages of simple operation, high cleaning efficiency, low economic cost and the like, not only can remove mineral scale and other deposits in a turbidimeter measuring system, but also can solve the problem of inaccurate turbidimeter measurement under the conditions of change of the flow of the turbidimeter, vibration and the like; especially, the measurement deviation of the low-turbidity water system can be reduced, and the accuracy of the measurement result is improved.
Detailed Description
The polishing agent for the online turbidimeter measuring system comprises the following components in parts by weight:
10.0-18.0 parts of dirt dissolving agent, 2.0-4.0 parts of xylene sulfonate, 2.0-3.0 parts of deoiling agent, 0.3-0.5 part of organic silicon defoaming agent, 3.0-5.0 parts of synergist and 69.5-82.7 parts of deionized water solvent.
Wherein: the dirt dissolving agent comprises 5.0-8.0 parts of acetic acid and 5.0-10.0 parts of sulfamic acid; the xylene sulfonate is any one of sodium xylene sulfonate, potassium xylene sulfonate and ammonium xylene sulfonate; the deoiling agent is isopropanol; the organic silicon defoamer is silicone glycol defoamer; the synergist is guanidine carbonate.
The operation steps of the inventive online turbidimeter measuring system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning the photocell, cleaning the bubble trap, and rinsing with purified water, and the specific operation steps are as follows:
A. compounded polishing agent
a1, taking the reagents according to the parts of the components, and preparing a polishing agent solution.
B. Cleaning photovoltaic cell
b 1: the flow of sample through the body of the turbidity meter is cut off.
b 2: the head assembly and the bubble trap cover are removed from the body, and the bubble trap is lifted vertically to be removed.
b 3: the plug is screwed off from the bottom of the turbidimeter body to discharge liquid from the body.
b 4: and (4) reinstalling the drainage plug, and filling the cleaning solution into the turbidity meter body until the height of the overflow port. The wash solution may be added to dilute chlorine solution (25 mL home bleach per 3.78L wash solution) or to a laboratory cleaner such as Liqui-nox (1 mL cleaner per 1L wash solution).
b 5: the whole surface inside the body of the turbidimeter is cleaned with a soft brush.
b 6: and screwing off the drainage plug again, discharging the cleaning solution, thoroughly washing the turbidity meter body by using the ultrafiltration deionized water, and reinstalling the plug after cleaning.
C. Cleaning bubble catcher
c 1: the entire bubble trap is immersed in a cleaning solution in a container.
c 2: each surface of the bubble trap was cleaned using a test tube brush.
c 3: the bubble trap was thoroughly rinsed with ultra-filtered deionized water and reinstalled in the turbidity meter body.
c 4: the bubble trap cover is reinstalled and the header assembly is installed on top of the body.
D. Rinsing with purified water
d 1: the turbidity meter was rinsed with secondary deionized water after filtration through a 0.2 micron filter.
d 2: the sample flow through the body of the turbidity meter is restored.
The present invention will be described in further detail with reference to specific examples.
Example 1:
the polishing agent for the online turbidimeter measuring system comprises the following components in parts by weight:
5.0 parts of acetic acid, 5.0 parts of sulfamic acid, 4.0 parts of sodium xylene sulfonate, 2.0 parts of isopropanol, 0.5 part of silicone glycol defoamer, 3 parts of synergist and 82.7 parts of deionized water solvent.
The operation steps of the inventive online turbidimeter measuring system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning the photocell, cleaning the bubble trap, and rinsing with purified water, and the specific operation steps are as follows:
A. compounded polishing agent
a1, taking the reagents according to the parts of the components, and preparing a polishing agent solution.
B. Cleaning photovoltaic cell
b 1: the flow of sample through the body of the turbidity meter is cut off.
b 2: the head assembly and the bubble trap cover are removed from the body, and the bubble trap is lifted vertically to be removed.
b 3: the plug is screwed off from the bottom of the turbidimeter body to discharge liquid from the body.
b 4: the drain plug was reinstalled and the wash solution was mixed as described in 756: 5, adding the household bleaching liquid, and then pouring the mixed liquid into the turbidity meter body until the height of the overflow gap.
b 5: the whole surface inside the body of the turbidimeter is cleaned with a soft brush.
b 6: and screwing off the drainage plug again, discharging the cleaning solution, thoroughly washing the turbidity meter body by using the ultrafiltration deionized water, and reinstalling the plug after cleaning.
C. Cleaning bubble catcher
c 1: the entire bubble trap is immersed in a cleaning solution in a container.
c 2: each surface of the bubble trap was cleaned using a test tube brush.
c 3: the bubble trap was thoroughly rinsed with ultra-filtered deionized water and reinstalled in the turbidity meter body.
c 4: the bubble trap cover is reinstalled and the header assembly is installed on top of the body.
D. Rinsing with purified water
d 1: the turbidity meter was rinsed with secondary deionized water after filtration through a 0.2 micron filter.
d 2: the sample flow through the body of the turbidity meter is restored.
Example 2:
the polishing agent for the online turbidimeter measuring system comprises the following components in parts by weight:
7.0 parts of acetic acid, 10.0 parts of sulfamic acid, 2.0 parts of potassium xylene sulfonate, 2.5 parts of isopropanol, 0.3 part of silicone glycol defoamer, 5 parts of synergist and 69.5 parts of deionized water solvent.
The operation steps of the inventive online turbidimeter measuring system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning the photocell, cleaning the bubble trap, and rinsing with purified water, and the specific operation steps are as follows:
A. compounded polishing agent
a1, taking the reagents according to the parts of the components, and preparing a polishing agent solution.
B. Cleaning photovoltaic cell
b 1: the flow of sample through the body of the turbidity meter is cut off.
b 2: the head assembly and the bubble trap cover are removed from the body, and the bubble trap is lifted vertically to be removed.
b 3: the plug is screwed off from the bottom of the turbidimeter body to discharge liquid from the body.
b 4: and (3) reinstalling a drainage plug, and adding 1000 parts of cleaning solution: adding Liqui-nox according to the volume ratio of 1, and then pouring the mixed liquid into a turbidimeter body until the height of the overflow gap.
b 5: the whole surface inside the body of the turbidimeter is cleaned with a soft brush.
b 6: and screwing off the drainage plug again, discharging the cleaning solution, thoroughly washing the turbidity meter body by using the ultrafiltration deionized water, and reinstalling the plug after cleaning.
C. Cleaning bubble catcher
c 1: the entire bubble trap is immersed in a cleaning solution in a container.
c 2: each surface of the bubble trap was cleaned using a test tube brush.
c 3: the bubble trap was thoroughly rinsed with ultra-filtered deionized water and reinstalled in the turbidity meter body.
c 4: the bubble trap cover is reinstalled and the header assembly is installed on top of the body.
D. Rinsing with purified water
d 1: the turbidity meter was rinsed with secondary deionized water after filtration through a 0.2 micron filter.
d 2: the sample flow through the body of the turbidity meter is restored.
Example 3:
the polishing agent for the online turbidimeter measuring system comprises the following components in parts by weight:
8.0 parts of acetic acid, 7.0 parts of sulfamic acid, 3.0 parts of ammonium xylene sulfonate, 3.0 parts of isopropanol, 0.4 part of silicone glycol defoamer, 4.0 parts of synergist and 74.6 parts of deionized water solvent.
The operation steps of the inventive online turbidimeter measuring system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning the photocell, cleaning the bubble trap, and rinsing with purified water, and the specific operation steps are as follows:
A. compounded polishing agent
a1, taking the reagents according to the parts of the components, and preparing a polishing agent solution.
B. Cleaning photovoltaic cell
b 1: the flow of sample through the body of the turbidity meter is cut off.
b 2: the head assembly and the bubble trap cover are removed from the body, and the bubble trap is lifted vertically to be removed.
b 3: the plug is screwed off from the bottom of the turbidimeter body to discharge liquid from the body.
b 4: and (3) reinstalling a drainage plug, and adding 1000 parts of cleaning solution: adding Liqui-nox according to the volume ratio of 1, and then pouring the mixed liquid into a turbidimeter body until the height of the overflow gap.
b 5: the whole surface inside the body of the turbidimeter is cleaned with a soft brush.
b 6: and screwing off the drainage plug again, discharging the cleaning solution, thoroughly washing the turbidity meter body by using the ultrafiltration deionized water, and reinstalling the plug after cleaning.
C. Cleaning bubble catcher
c 1: the entire bubble trap is immersed in a cleaning solution in a container.
c 2: each surface of the bubble trap was cleaned using a test tube brush.
c 3: the bubble trap was thoroughly rinsed with ultra-filtered deionized water and reinstalled in the turbidity meter body.
c 4: the bubble trap cover is reinstalled and the header assembly is installed on top of the body.
D. Rinsing with purified water
d 1: the turbidity meter was rinsed with secondary deionized water after filtration through a 0.2 micron filter.
d 2: the sample flow through the body of the turbidity meter is restored.

Claims (7)

1. The polishing agent for the online turbidimeter measuring system is characterized by comprising the following components in parts by weight: 10.0-18.0 parts of dirt dissolving agent, 2.0-4.0 parts of xylene sulfonate, 2.0-3.0 parts of deoiling agent, 0.3-0.5 part of organic silicon defoaming agent, 3.0-5.0 parts of synergist and 69.5-82.7 parts of deionized water solvent;
the operation steps of the online turbidimeter measurement system when the polishing agent is used comprise the steps of preparing the polishing agent, cleaning a photocell, cleaning a bubble trap and rinsing with purified water.
2. The on-line turbidimeter measurement system finish of claim 1, wherein: the dirt dissolving agent comprises 5.0-8.0 parts of acetic acid and 5.0-10.0 parts of sulfamic acid.
3. The on-line turbidimeter measurement system finish of claim 1, wherein: the xylene sulfonate is any one of sodium xylene sulfonate, potassium xylene sulfonate and ammonium xylene sulfonate.
4. The on-line turbidimeter measurement system finish of claim 1, wherein: the degreaser is isopropanol.
5. The on-line turbidimeter measurement system finish of claim 1, wherein: the organic silicon defoaming agent is a silicone glycol defoaming agent.
6. The on-line turbidimeter measurement system finish of claim 1, wherein: the synergist is guanidine carbonate.
7. The composition of claim 1, comprising in parts by weight: 11.0-18.0 parts of dirt dissolvent, 2.5-4.0 parts of xylene sulfonate, 2.5-3.0 parts of degreaser, 0.4-0.5 part of organic silicon defoamer, 4.0-5.0 parts of synergist and 69.5-79.6 parts of deionized water solvent.
CN202010447769.3A 2020-05-25 2020-05-25 Polishing agent for online turbidimeter measuring system Pending CN111621371A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010447769.3A CN111621371A (en) 2020-05-25 2020-05-25 Polishing agent for online turbidimeter measuring system

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Application Number Priority Date Filing Date Title
CN202010447769.3A CN111621371A (en) 2020-05-25 2020-05-25 Polishing agent for online turbidimeter measuring system

Publications (1)

Publication Number Publication Date
CN111621371A true CN111621371A (en) 2020-09-04

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2528006Y (en) * 2002-01-09 2002-12-25 吉林市光大电力设备有限责任公司 Self-cleaning device for on-line water quality turbidity measurer detector
CN1566304A (en) * 2003-06-13 2005-01-19 李小平 Full automatic biochemical analyzer cleaning agent
EP1736533A1 (en) * 2005-06-23 2006-12-27 Kabushiki Kaisha Toshiba Alkaline detergent and washing method for automatic analyzer
CN101498628A (en) * 2009-03-16 2009-08-05 刘宪武 Door-based calibration method for water turbidometer and its sample collection system
CN108251227A (en) * 2018-02-11 2018-07-06 山东佳星环保科技有限公司 A kind of Military Electronic Equipment detergent and preparation method thereof
CN111088125A (en) * 2019-12-31 2020-05-01 南京市检捷生物信息科技有限公司 Cleaning agent for laboratory optical instrument and cleaning method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2528006Y (en) * 2002-01-09 2002-12-25 吉林市光大电力设备有限责任公司 Self-cleaning device for on-line water quality turbidity measurer detector
CN1566304A (en) * 2003-06-13 2005-01-19 李小平 Full automatic biochemical analyzer cleaning agent
EP1736533A1 (en) * 2005-06-23 2006-12-27 Kabushiki Kaisha Toshiba Alkaline detergent and washing method for automatic analyzer
CN1891806A (en) * 2005-06-23 2007-01-10 株式会社东芝 Alkaline detergent for an automatic analysing apparatus, process for cleaning an automatic analysing apparatus, and an automatic analysing apparatus
CN101498628A (en) * 2009-03-16 2009-08-05 刘宪武 Door-based calibration method for water turbidometer and its sample collection system
CN108251227A (en) * 2018-02-11 2018-07-06 山东佳星环保科技有限公司 A kind of Military Electronic Equipment detergent and preparation method thereof
CN111088125A (en) * 2019-12-31 2020-05-01 南京市检捷生物信息科技有限公司 Cleaning agent for laboratory optical instrument and cleaning method thereof

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Application publication date: 20200904