CN111592676A - Conductive composite colloid - Google Patents
Conductive composite colloid Download PDFInfo
- Publication number
- CN111592676A CN111592676A CN201910129207.1A CN201910129207A CN111592676A CN 111592676 A CN111592676 A CN 111592676A CN 201910129207 A CN201910129207 A CN 201910129207A CN 111592676 A CN111592676 A CN 111592676A
- Authority
- CN
- China
- Prior art keywords
- conductive
- composite colloid
- conductive composite
- omega
- conductive particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000084 colloidal system Substances 0.000 title claims abstract description 57
- 239000002131 composite material Substances 0.000 title claims abstract description 54
- 239000002245 particle Substances 0.000 claims abstract description 78
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000003190 viscoelastic substance Substances 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 4
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 4
- 238000009472 formulation Methods 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- 239000011324 bead Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 claims description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 3
- 239000004917 carbon fiber Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000011888 foil Substances 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 3
- 239000002077 nanosphere Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 229910001285 shape-memory alloy Inorganic materials 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- -1 for example Substances 0.000 abstract description 3
- 229940006076 viscoelastic substance Drugs 0.000 abstract description 3
- 239000006229 carbon black Substances 0.000 abstract description 2
- 230000008054 signal transmission Effects 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C19/00—Tyre parts or constructions not otherwise provided for
- B60C19/08—Electric-charge-dissipating arrangements
- B60C19/084—Electric-charge-dissipating arrangements using conductive carcasses
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2400/00—Characterised by the use of unspecified polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a conductive composite colloid, which comprises a macromolecule viscoelastic substance and conductive particles, wherein when the conductive composite colloid is used for grinding, the particle size of the conductive particles is between 1 nanometer and 22 micrometers, when the conductive composite colloid is used for flexing, the particle size of the conductive particles is between 20 micrometers and 60 micrometers, and the resistance of the conductive composite colloid is between 104Omega to 10‑1Omega is between. The conductive particles have a particle size and a resistance value in relation to the amount of the added conductive particles, for example, carbon nanotubes having a formula ratio (PHR) of 2 to a polymer viscoelastic material (PHR) of 28 are mixed with carbon blackA resistance value of 104Omega, relative, the pure carbon black formulation ratio (PHR) must be over 85 to reach 104Omega, the components of the invention adopt conductive particles with different formula ratios and different particle sizes to obtain the required electrical characteristics, such as being used for tire measurement, signal transmission, electric power and the like.
Description
Technical Field
The present invention relates to a conductive composite colloid, and more particularly to a colloid prepared by mixing a high molecular viscoelastic material with non-conductive particles and conductive particles to change the resistance value thereof, so that the colloid can be used for measuring the electrical characteristics of a tire, transmitting signals and transmitting power.
Background
The colloids used in tires in the early days were only pure high molecular polymers. For example, European patent No. EP2397347, "Method for making a sound absorbing material with a foam noise damper and tie with a foam noise damper", which uses a rubber compound to adhere a sound absorbing material to a tire to eliminate resonance noise generated by unevenness of a road surface during running of the tire, includes: silica gel adhesive, polyethylene, polypropylene, etc.
FOR example, U.S. Pat. No. 5,095,9284 entitled "RUBBER COMPOSITION FOR use in antistatic applications" is an electrically conductive RUBBER comprising 100 parts by mass of a RUBBER component, 1.0 to 3.5 parts by mass of sulfur having a sulfur content of 30ppm or less, 0.5 to 15 parts by mass of an electrically conductive carbon black having a DBP content of 300ml/100g or more and an iron content of 60ppm or more, and a volume resistivity of 1.0 × 10,108Omega cm or less.
Although the aforementioned patents teach the addition of carbon black to the rubber to provide a rubber having 1.0 × 108The conductivity of the rubber is controlled by adding different proportions of conductive particles to have different effects, the particle size of the conductive particles affects the surface area of the whole conduction, and further affects the proportion of the added conductive particles under the same resistance value, and the proportion of excessive conductive particles affects the viscoelasticity and rubber characteristics of the rubberThe bead portion falls off.
Disclosure of Invention
The invention provides a conductive composite colloid, which is used for coating a tire, and the resistance value of the composite colloid is changed by mixing a high-molecular viscoelastic substance with non-conductive particles and conductive particles, so that the composite colloid can be used for measuring the electrical characteristics of the tire, transmitting signals, transmitting electric power and the like.
In order to achieve the above object, the present invention adopts the following technical means.
A composite colloid with conductivity comprises: a high molecular viscoelastic substance mixed with a conductive particle, the particle size of the conductive particle is between 1 nanometer and 22 micrometers when the conductive particle is used for grinding, the particle size of the conductive particle is between 20 micrometers and 60 micrometers when the conductive particle is used for flexing, the hardness of the conductive composite colloid is between 50 and 75 when the conductive composite colloid is used for wearing the tire, the hardness of the conductive composite colloid is between 45 and 55 when the conductive composite colloid is used for flexing the tire, the hardness of the conductive composite colloid is between 45 and 60 when the conductive composite colloid is used for one tire bead part of the tire, and the resistance of the conductive composite colloid is between 10 and 104Omega to 10-1Omega is between.
Further, the allowable working temperature of the conductive composite colloid is between minus 80 ℃ and 220 ℃.
Further, the conductive particle comprises a non-conductive particle, and the formula ratio (PHR) of the non-conductive particle is between 0.5 and 15.
Further, the conductive particles have a formula ratio (PHR) of 2 to 110 and a resistance of 104Omega to 10-1Omega is between.
Further, the conductive particles have a formula ratio (PHR) of 3 to 150 and a resistance of 102Omega to 10-1Omega is between.
Further, the conductive particles have a composition selected from one or a combination of the following: gold, silver, copper, memory alloy, zinc, iron, cobalt, nickel, metal foil, metal powder, metal fiber, aluminum, cesium, palladium, graphite, graphene, carbon fiber, carbon nanotube, carbon cluster or nanosphere.
Further, the composition of the non-conductive particles is selected from one or a combination of the following: quartz, silicon oxide, iodine, sulfur, phosphorus and rare earth elements.
According to the technical characteristics, the following effects can be achieved:
1. the addition of the conductive particles with different formulation ratios can maintain the viscoelasticity and rubber characteristics (such as rubber elasticity, flexibility, wear resistance, etc.) of the conductive composite colloid while achieving the applicable resistance value.
2. By adding the conductive particles with different formula ratios and using different resistance values according to different electrical property requirements, excessive or insufficient conductive particles are not added, so that the rubber property of the conductive composite colloid at the corresponding part of the tire is maintained.
3. The particle size of the conductive particles affects the characteristics of the rubber, too large particle size causes large electrical change due to external force, and smaller particle size is stable, and the particle size used in the invention is a preferable range.
4. The tire material is divided into two portions, one being the tread material and one being the carcass material. The matrix material needs to be a flexible material, and the required conductive particles (such as carbon materials, micron-sized materials are used) need larger particle size. The tread material needs abrasion resistance and needs smaller particle size to meet the performance requirement.
5. The allowable working temperature of the conductive composite colloid is between minus 80 ℃ and 220 ℃, and the conductive composite colloid does not lose the conductive effect of the sizing material in the temperature range.
Detailed Description
In combination with the above technical features, the main effects of the conductive composite colloid of the present invention will be clearly demonstrated in the following examples.
The conductive composite colloid of the embodiment is rubber used for a tire and is used for coating on the tire, and the working temperature of the conductive composite colloid is preferably within the allowable range of minus 80 ℃ to 220 ℃, so that the conductive composite colloid can be used even in a severe environment with extremely low temperature or extremely high temperature, and the viscoelasticity and the conductive effect of the colloid are not lost. The conductive composite colloid comprises the following components: a polymer viscoelastic material, a conductive particle and a non-conductive particle are mixed.
The conductive particles have the particle size which affects the characteristics of the colloid, so that the electrical property change is large due to external force caused by the large particle size, the smaller particle size is stable, and the tire material is mainly divided into two parts, namely a tread material and a carcass material. The matrix material needs to be a large-deflection material, and the required conductive particles need to have a large particle size (for example, a micron-sized carbon material is used); the tread material needs wear resistance, so that smaller particle size is needed to meet the performance requirement. Thus, when the conductive particles are used for grinding, particle sizes between 1 nm and 22 microns are used, and when the conductive particles are suitable for flexing, particle sizes between 20 microns and 60 microns are used. Specifically, the hardness of the conductive composite colloid is required to be between 50 and 75 shore d when used for abrasion of the tire, between 45 and 55 shore d when used for flexure of the tire, and between 45 and 60 shore d when used for a bead portion of the tire. The Shore hardness is only the test standard used in the present embodiment, but not limited thereto, and other hardness test standards, such as Shore hardness 50 approximately equal to Rockwell hardness 36.6, can be used, so that the hardness of the gel will have different data according to the test standard used.
The purpose of the non-conductive particles is to maintain the wear resistance, viscoelasticity and dry and wet grabbing performance of the rubber material and reduce the influence of the conductive particles on the physical properties of the rubber body. Wherein the formulation ratio (PHR) of the non-conductive particles is between 0.5 and 15.
In one embodiment, the conductive composite colloid is formed by mixing the base of the polymer viscoelastic material and the conductive particles in a formula ratio (PHR) of 1-150, such that the resistance of the conductive composite colloid is 104Omega to 10-1Omega is between. Wherein, the conductive particles comprise one or a combination of the following components: gold, silver, copper, memory alloy, zinc, iron, cobalt, nickel, metal foil, metal powder, metal fiber, aluminum, cesium, palladium, graphite, graphene, carbon fiber, carbon nanotube, carbon cluster or nanosphere, the composition of the non-conductive particles is selected from one or a combination of the following: quartz, silicon oxide, iodine, sulfur, phosphorus and rare earth elements.
But to be specifically noted: when the conductive composite colloid is used for measuring the physical properties of a tire, the formula ratio (PHR) of the conductive particles in the conductive composite colloid is between 2 and 110, and the resistance is between 104Omega to 10-1Omega is between. When the conductive composite colloid is used for signal transmission and power transmission of tires, the formula ratio (PHR) of the conductive particles in the conductive composite colloid is between 3 and 150, and the resistance is between 102Omega to 10-1Omega is between.
The conductive particles with different formula ratios (PHR) are added according to different purposes, so that the applicable resistance value can be achieved, and the usable viscoelasticity of the conductive composite colloid and the rubber characteristic of the use part can be still maintained. And the resistance values are respectively provided according to different electric signals transmitted, so that excessive or too little conductive particles are not added, and the rubber characteristics of the corresponding part when the conductive composite colloid is used in the tire are not influenced.
The operation, use and efficacy of the present invention will be fully understood from the description of the embodiments, which are given by way of illustration only, and the scope of the invention should not be limited thereby, and all changes and modifications that come within the spirit of the invention, including the scope of the claims and the description thereof, are deemed to be covered thereby.
Claims (7)
1. A conductive composite gel for coating on a tire, the conductive composite gel comprising: a polymer viscoelastic material mixed with a conductive particle, the conductive particle has a particle size in the range ofThe particle size of the conductive particles is between 20 and 60 micrometers when the conductive composite colloid is used for flexing, the hardness of the conductive composite colloid is between 50 and 75 Shore hardness when the conductive composite colloid is used for wearing the tire, the hardness of the conductive composite colloid is between 45 and 55 Shore hardness when the conductive composite colloid is used for flexing the tire, the hardness of the conductive composite colloid is between 45 and 60 Shore hardness when the conductive composite colloid is used for one bead part of the tire, and the resistance of the conductive composite colloid is between 104Omega to 10-1Omega is between.
2. The conductive composite colloid according to claim 1, wherein: the allowable working temperature of the conductive composite colloid is between minus 80 ℃ and 220 ℃.
3. The conductive composite colloid according to claim 1, wherein: further comprises a non-conductive particle, and the formulation ratio of the non-conductive particle is between 0.5 and 15.
4. The conductive composite colloid according to claim 1, wherein: the conductive particles have a formula ratio of 2-110 and a resistance of 104Omega to 10-1Omega is between.
5. The conductive composite colloid according to claim 1, wherein: the conductive particles have a formula ratio of 3-150 and a resistance of 102Omega to 10-1Omega is between.
6. The conductive composite colloid according to claim 1, wherein: the conductive particles have a composition selected from one or a combination of the following: gold, silver, copper, memory alloy, zinc, iron, cobalt, nickel, metal foil, metal powder, metal fiber, aluminum, cesium, palladium, graphite, graphene, carbon fiber, carbon nanotube, carbon cluster or nanosphere.
7. The conductive composite colloid according to claim 3, wherein: the non-conductive particles have a composition selected from one or a combination of the following: quartz, silicon oxide, iodine, sulfur, phosphorus and rare earth elements.
Priority Applications (1)
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CN201910129207.1A CN111592676A (en) | 2019-02-21 | 2019-02-21 | Conductive composite colloid |
Applications Claiming Priority (1)
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CN201910129207.1A CN111592676A (en) | 2019-02-21 | 2019-02-21 | Conductive composite colloid |
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CN111592676A true CN111592676A (en) | 2020-08-28 |
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Family Applications (1)
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CN201910129207.1A Pending CN111592676A (en) | 2019-02-21 | 2019-02-21 | Conductive composite colloid |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102050973A (en) * | 2009-10-30 | 2011-05-11 | 中国石油化工股份有限公司 | Tread rubber composite material and preparation method thereof |
CN104130478A (en) * | 2014-07-15 | 2014-11-05 | 北京化工大学 | Low-hysteresis antistatic tread rubber material for fuel-efficient tires, and preparation method thereof |
JP2015124258A (en) * | 2013-12-26 | 2015-07-06 | 横浜ゴム株式会社 | Rubber composition for tire sidewall and pneumatic tire using the same |
CN106146920A (en) * | 2015-04-22 | 2016-11-23 | Samo技术有限公司 | The retreads rubber composition that recaps that thermal conductivity and wearability improve |
CN109134981A (en) * | 2018-08-13 | 2019-01-04 | 中策橡胶集团有限公司 | The rubber composition and its mixing method and tire of a kind of tire tread for high-performance tire |
-
2019
- 2019-02-21 CN CN201910129207.1A patent/CN111592676A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102050973A (en) * | 2009-10-30 | 2011-05-11 | 中国石油化工股份有限公司 | Tread rubber composite material and preparation method thereof |
JP2015124258A (en) * | 2013-12-26 | 2015-07-06 | 横浜ゴム株式会社 | Rubber composition for tire sidewall and pneumatic tire using the same |
CN104130478A (en) * | 2014-07-15 | 2014-11-05 | 北京化工大学 | Low-hysteresis antistatic tread rubber material for fuel-efficient tires, and preparation method thereof |
CN106146920A (en) * | 2015-04-22 | 2016-11-23 | Samo技术有限公司 | The retreads rubber composition that recaps that thermal conductivity and wearability improve |
CN109134981A (en) * | 2018-08-13 | 2019-01-04 | 中策橡胶集团有限公司 | The rubber composition and its mixing method and tire of a kind of tire tread for high-performance tire |
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