CN111501410A - 一种双面抗静电复合型离型纸 - Google Patents

一种双面抗静电复合型离型纸 Download PDF

Info

Publication number
CN111501410A
CN111501410A CN202010210350.6A CN202010210350A CN111501410A CN 111501410 A CN111501410 A CN 111501410A CN 202010210350 A CN202010210350 A CN 202010210350A CN 111501410 A CN111501410 A CN 111501410A
Authority
CN
China
Prior art keywords
parts
layer
antistatic
release paper
double
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010210350.6A
Other languages
English (en)
Inventor
於险峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jixiangbao Taicang Mold Material Science & Technology Development Co ltd
Original Assignee
Jixiangbao Taicang Mold Material Science & Technology Development Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jixiangbao Taicang Mold Material Science & Technology Development Co ltd filed Critical Jixiangbao Taicang Mold Material Science & Technology Development Co ltd
Priority to CN202010210350.6A priority Critical patent/CN111501410A/zh
Publication of CN111501410A publication Critical patent/CN111501410A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001—Release paper
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09J179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • C09J7/401—Adhesives in the form of films or foils characterised by release liners characterised by the release coating composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • C09J7/403—Adhesives in the form of films or foils characterised by release liners characterised by the structure of the release feature
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/28—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/30—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/32—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming a linkage containing silicon in the main chain of the macromolecule
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/28—Presence of paper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明涉及涉及一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；本发明采用科学合理的配方，各组分协同作用。具有抗静电、耐高低温、易剥离、易于模切加工的特点。应用于电子行业，防止因产生的静电而击穿线路板，烧毁电子设备。

Description

一种双面抗静电复合型离型纸
技术领域
本发明涉及文化产品印刷新材料及其制备技术领域，特别涉及一种双面抗静电复合型离型纸。
背景技术
离型纸是一种防止预浸料粘连，又可以保护预浸料不受污染的防粘纸。离型纸由涂有防粘物质的纸制成，其型号要根据材质、厚薄、伸长率、单双面的差别而区分。防粘纸，也被称为硅油纸。由三层结构组成，第一层：底纸；第二层：淋膜： 第三层：硅油。可以用在电子产品，汽车泡沫，印刷、食品、医用等等。在大多数情况下，它是与黏性物料一起使用，特别是胶粘带。
湿法生产预浸料时，在预浸料的上下均放置离型纸，其中下离型纸随着预浸料的收卷存附其中，所以预浸料表面通常有一层离型纸保护。离型纸的作用是防止预浸料被污染，又可为在其表面划线提供方便。离型纸的另一个作用是防止单向预浸料的横向开裂。
离型纸应满足：能粘住预浸料，但又易于使两者分离；不与树脂体系发生化学反应或污染树脂体系；在环境温湿度发生变化时，离型纸的长度、宽度都应保持不变，以免引起离型纸起皱而使预浸料皱折；应具有足够的致密性，能防止水分通过它进入预浸料中；离型纸受牵引后其伸长率应与纤维保持一致，以防止预浸料在制备过程中由于牵伸不同步而引起变形或扭曲；它的厚度、单位面积质量不易精确控制。
但现有的离型纸多由三层结构组成，第一层：底纸；第二层：淋膜：第三层：硅油，功能较为单一；此外，一般离型涂层表面阻抗一般大于 10 14 Ω／sq，容易产生静电，易吸附杂质，危害比较大，因为静电，电子类产品在生产、运输等过程中可能电荷积聚过大，严重的容易引起***或者着火，轻的容易造成人的触电等，给工业建设带来了很大的危害，而且防水效果不是太理想，容易发生浸湿漏电的现象，因此，电子行业所用的离型纸，需要解决抗静电问题。
发明内容
发明的目的：本发明的目的在于提供一种双面抗静电复合型离型纸。
技术方案：为了实现以上目的，本发明公开了一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；所述上淋膜层的表面涂覆第一胶粘剂层，所述第一胶粘剂层的表面涂覆有正面抗静电离型层，所述下淋膜层的表面涂覆有第二胶粘剂层，所述第二胶黏剂层的表面涂覆有反面抗静电离型层。
进一步地，所述正面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12~15份、聚四氟乙烯微粉蜡2~4份、二甲基硅油10~15份、丙烯酸环氧树脂10~14份、氧化锡5~10份、石墨烯5~10份、硬脂酸盐离型剂6~10份、有机硅消泡剂1~4份、有机溶剂9~12份。
进一步地，所述有机溶剂为乙酸乙酯和醋酸丁酯的混合物。
进一步地，所述上淋膜层包括以下重量份数的原料：PE和PET树脂35~50份、抗氧剂0.5~0.8份。
进一步地，所述下淋膜层包括以下重量份数的原料：PI和PET树脂35~50份、抗氧剂0.5~0.8份。
进一步地，所述抗氧剂为1010。
进一步地，所述第一胶粘剂层和第二胶粘剂层的胶粘剂包括以下重量份数的原料：交联型聚丙烯酸树脂25~40份、聚酰亚胺树脂25~40份、丙烯酸环氧树脂5~10份、有机硅消泡剂0.5~1份。
进一步地，所述反面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12~15份、聚四氟乙烯微粉蜡2~4份、二甲基硅油10~15份、丙烯酸环氧树脂5~10份、超细金属粉末5~8份、聚噻吩5~10份、脂肪醇聚氧乙烯醚5~8份、异丙醇10~20份、分散剂0.1~0.5份、有机硅消泡剂0.1~0.5份。
进一步地，所述超细金属粉末的粒径范围为80nm～200nm；所述超细金属粉末为金属铝、银中的一种或两种；所述分散剂为脂肪酸甲酯磺酸钠、聚丙烯酰胺中的一种或一种以上；所述有机硅消泡剂为聚醚-硅氧烷共聚物。
上述技术方案可以看出，本发明具有如下有益效果：
本发明的双面抗静电复合型离型纸，包括全正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，采用环保、无毒的原料配方，采用超细金属颗粒、氧化锡、脂肪醇聚氧乙烯醚作为抗静电剂，无机抗静电剂和有机抗静电剂协同作用，应用于电子行业，防止因产生的静电而击穿线路板，烧毁电子设备，具有抗静电、耐高低温、易剥离、易于模切加工的特点。
具体实施方式
下面将通过几个具体实施例，进一步阐明本发明，这些实施例只是为了说明问题，并不是一种限制。
实施例1：
一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；所述上淋膜层的表面涂覆第一胶粘剂层，所述第一胶粘剂层的表面涂覆有正面抗静电离型层，所述下淋膜层的表面涂覆有第二胶粘剂层，所述第二胶黏剂层的表面涂覆有反面抗静电离型层。
进一步地，所述正面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯15份、聚四氟乙烯微粉蜡4份、二甲基硅油10份、丙烯酸环氧树脂10份、氧化锡10份、石墨烯5~份、硬脂酸盐离型剂10份、有机硅消泡剂1份、有机溶剂9份。
进一步地，所述有机溶剂为乙酸乙酯和醋酸丁酯的混合物。
进一步地，所述上淋膜层包括以下重量份数的原料：PE和PET树脂35份、抗氧剂0.5份。
进一步地，所述下淋膜层包括以下重量份数的原料：PI和PET树脂35份、抗氧剂0.5份。
进一步地，所述抗氧剂为1010。
进一步地，所述第一胶粘剂层和第二胶粘剂层的胶粘剂包括以下重量份数的原料：交联型聚丙烯酸树脂25份、聚酰亚胺树脂40份、丙烯酸环氧树脂5份、有机硅消泡剂0.5份。
进一步地，所述反面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯15份、聚四氟乙烯微粉蜡4份、二甲基硅油10份、丙烯酸环氧树脂10份、超细金属粉末5份、聚噻吩5份、脂肪醇聚氧乙烯醚8份、异丙醇10份、分散剂0.1份、有机硅消泡剂0.1份。
进一步地，所述超细金属粉末的粒径范围为80nm～200nm；所述超细金属粉末为金属银；所述分散剂为脂肪酸甲酯磺酸钠和聚丙烯酰胺的混合物；所述有机硅消泡剂为聚醚-硅氧烷共聚物。
实施例2：
一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；所述上淋膜层的表面涂覆第一胶粘剂层，所述第一胶粘剂层的表面涂覆有正面抗静电离型层，所述下淋膜层的表面涂覆有第二胶粘剂层，所述第二胶黏剂层的表面涂覆有反面抗静电离型层。
进一步地，所述正面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12份、聚四氟乙烯微粉蜡3份、二甲基硅油12份、丙烯酸环氧树脂12份、氧化锡8份、石墨烯7份、硬脂酸盐离型剂8份、有机硅消泡剂2份、有机溶剂10份。
进一步地，所述有机溶剂为乙酸乙酯和醋酸丁酯的混合物。
进一步地，所述上淋膜层包括以下重量份数的原料：PE和PET树脂40份、抗氧剂0.6份。
进一步地，所述下淋膜层包括以下重量份数的原料：PI和PET树脂40份、抗氧剂0.6份。
进一步地，所述抗氧剂为1010。
进一步地，所述第一胶粘剂层和第二胶粘剂层的胶粘剂包括以下重量份数的原料：交联型聚丙烯酸树脂40份、聚酰亚胺树脂25份、丙烯酸环氧树脂8份、有机硅消泡剂0.8份。
进一步地，所述反面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12份、聚四氟乙烯微粉蜡3份、二甲基硅油13份、丙烯酸环氧树脂8份、超细金属粉末8份、聚噻吩57份、脂肪醇聚氧乙烯醚6份、异丙醇15份、分散剂0.3份、有机硅消泡剂0.3份。
进一步地，所述超细金属粉末的粒径范围为80nm～200nm；所述超细金属粉末为金属铝和银；所述分散剂为聚丙烯酰胺；所述有机硅消泡剂为聚醚-硅氧烷共聚物。
实施例3：
一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；所述上淋膜层的表面涂覆第一胶粘剂层，所述第一胶粘剂层的表面涂覆有正面抗静电离型层，所述下淋膜层的表面涂覆有第二胶粘剂层，所述第二胶黏剂层的表面涂覆有反面抗静电离型层。
进一步地，所述正面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯13份、聚四氟乙烯微粉蜡2份、二甲基硅油15份、丙烯酸环氧树脂14份、氧化锡5份、石墨烯10份、硬脂酸盐离型剂6份、有机硅消泡剂4份、有机溶剂12份。
进一步地，所述有机溶剂为乙酸乙酯和醋酸丁酯的混合物。
进一步地，所述上淋膜层包括以下重量份数的原料：PE和PET树脂50份、抗氧剂0.8份。
进一步地，所述下淋膜层包括以下重量份数的原料：PI和PET树脂50份、抗氧剂0.8份。
进一步地，所述抗氧剂为1010。
进一步地，所述第一胶粘剂层和第二胶粘剂层的胶粘剂包括以下重量份数的原料：交联型聚丙烯酸树脂30份、聚酰亚胺树脂30份、丙烯酸环氧树脂10份、有机硅消泡剂1份。
进一步地，所述反面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯13份、聚四氟乙烯微粉蜡2份、二甲基硅油15份、丙烯酸环氧树脂5份、超细金属粉末7份、聚噻吩10份、脂肪醇聚氧乙烯醚5份、异丙醇20份、分散剂0.5份、有机硅消泡剂0.5份。
进一步地，所述超细金属粉末的粒径范围为80nm～200nm；所述超细金属粉末为金属铝；所述分散剂为脂肪酸甲酯磺酸钠；所述有机硅消泡剂为聚醚-硅氧烷共聚物。
以上所述仅是本发明的实施方式，应指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进，这些改进也应视为本发明的保护范围。

Claims (10)

1.一种双面抗静电复合型离型纸，包括正面抗静电离型层、离型纸基层、淋膜层、胶黏剂层、反面抗静电离型层，其特征在于：所述离型纸基层的上表面依次设有上淋膜层、第一胶粘剂层、正面抗静电离型层，所述离型纸基层的下表面依次设有下淋膜层、第二胶粘剂层、反面抗静电离型层；所述上淋膜层的表面涂覆第一胶粘剂层，所述第一胶粘剂层的表面涂覆有正面抗静电离型层，所述下淋膜层的表面涂覆有第二胶粘剂层，所述第二胶黏剂层的表面涂覆有反面抗静电离型层。
2.根据权利要求1所述的一种双面抗静电复合型离型纸，其特征在于：所述正面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12~15份、聚四氟乙烯微粉蜡2~4份、二甲基硅油10~15份、丙烯酸环氧树脂10~14份、氧化锡5~10份、石墨烯5~10份、硬脂酸盐离型剂6~10份、有机硅消泡剂1~4份、有机溶剂9~12份。
3.根据权利要求2所述的一种双面抗静电复合型离型纸，其特征在于：所述有机溶剂为乙酸乙酯和醋酸丁酯的混合物。
4.根据权利要求1所述的一种双面抗静电复合型离型纸，其特征在于：所述上淋膜层包括以下重量份数的原料：PE和PET树脂35~50份、抗氧剂0.5~0.8份。
5.根据权利要求1所述的一种双面抗静电复合型离型纸，其特征在于：所述下淋膜层包括以下重量份数的原料：PI和PET树脂35~50份、抗氧剂0.5~0.8份。
6.根据权利要求4或5所述的一种双面抗静电复合型离型纸，其特征在于：所述抗氧剂为1010。
7.根据权利要求1所述的一种双面抗静电复合型离型纸，其特征在于：所述第一胶粘剂层和第二胶粘剂层的胶粘剂包括以下重量份数的原料：交联型聚丙烯酸树脂25~40份、聚酰亚胺树脂25~40份、丙烯酸环氧树脂5~10份、有机硅消泡剂0.5~1份。
8.根据权利要求1所述的一种双面抗静电复合型离型纸，其特征在于：所述反面抗静电离型层包括以下重量份数的原料：聚甲基丙烯酸甲酯12~15份、聚四氟乙烯微粉蜡2~4份、二甲基硅油10~15份、丙烯酸环氧树脂5~10份、超细金属粉末5~8份、聚噻吩5~10份、脂肪醇聚氧乙烯醚5~8份、异丙醇10~20份、分散剂0.1~0.5份、有机硅消泡剂0.1~0.5份。
9.根据权利要求8所述的一种双面抗静电复合型离型纸，其特征在于：所述超细金属粉末的粒径范围为80nm～200nm；所述超细金属粉末为金属铝、银中的一种或两种；所述分散剂为脂肪酸甲酯磺酸钠、聚丙烯酰胺中的一种或一种以上。
10.根据权利要求2、7、8中任意一项所述的一种双面抗静电复合型离型纸，其特征在于：所述有机硅消泡剂为聚醚-硅氧烷共聚物。
CN202010210350.6A 2020-03-24 2020-03-24 一种双面抗静电复合型离型纸 Pending CN111501410A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010210350.6A CN111501410A (zh) 2020-03-24 2020-03-24 一种双面抗静电复合型离型纸

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010210350.6A CN111501410A (zh) 2020-03-24 2020-03-24 一种双面抗静电复合型离型纸

Publications (1)

Publication Number Publication Date
CN111501410A true CN111501410A (zh) 2020-08-07

Family

ID=71865781

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010210350.6A Pending CN111501410A (zh) 2020-03-24 2020-03-24 一种双面抗静电复合型离型纸

Country Status (1)

Country Link
CN (1) CN111501410A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708358A (zh) * 2020-12-24 2021-04-27 无锡新树胶粘制品有限公司 一种防静电薄膜及其制备方法
CN113214515A (zh) * 2021-05-06 2021-08-06 吉翔宝（太仓）离型材料科技发展有限公司 一种正反双面抗静电复合型离型膜
CN113250007A (zh) * 2021-05-06 2021-08-13 吉翔宝（太仓）离型材料科技发展有限公司 一种低剥离力的耐高温离型纸及其加工工艺

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08109599A (ja) * 1994-10-03 1996-04-30 Brother Ind Ltd 帯電防止剥離紙
WO1997031294A1 (en) * 1996-02-26 1997-08-28 International Paper Company Coated paper stocks for use in electrostatic imaging applications
CN104497721A (zh) * 2014-12-02 2015-04-08 周宏亮 一种离型剂及其离型纸和离型膜
CN104943307A (zh) * 2015-06-26 2015-09-30 宝丽菲姆保护膜（苏州）有限公司 一种pvc保护膜
CN105907300A (zh) * 2016-05-09 2016-08-31 吉翔宝（太仓）离型材料科技发展有限公司 一种双面涂布的离型膜
CN206506826U (zh) * 2017-02-28 2017-09-19 广州市昌昇包装材料有限公司 一种抗静电离型纸
CN207697209U (zh) * 2017-10-30 2018-08-07 惠州市诺曼包装材料有限公司 双面抗静电离型膜
CN109098032A (zh) * 2018-07-05 2018-12-28 浙江池河科技有限公司 一种以硬脂酸盐为离型剂的离型纸
CN110746836A (zh) * 2019-11-06 2020-02-04 焦作卓立膜材料有限责任公司 一种耐高温蒸汽的热转印离型剂及其制备方法

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08109599A (ja) * 1994-10-03 1996-04-30 Brother Ind Ltd 帯電防止剥離紙
WO1997031294A1 (en) * 1996-02-26 1997-08-28 International Paper Company Coated paper stocks for use in electrostatic imaging applications
CN104497721A (zh) * 2014-12-02 2015-04-08 周宏亮 一种离型剂及其离型纸和离型膜
CN104943307A (zh) * 2015-06-26 2015-09-30 宝丽菲姆保护膜（苏州）有限公司 一种pvc保护膜
CN105907300A (zh) * 2016-05-09 2016-08-31 吉翔宝（太仓）离型材料科技发展有限公司 一种双面涂布的离型膜
CN206506826U (zh) * 2017-02-28 2017-09-19 广州市昌昇包装材料有限公司 一种抗静电离型纸
CN207697209U (zh) * 2017-10-30 2018-08-07 惠州市诺曼包装材料有限公司 双面抗静电离型膜
CN109098032A (zh) * 2018-07-05 2018-12-28 浙江池河科技有限公司 一种以硬脂酸盐为离型剂的离型纸
CN110746836A (zh) * 2019-11-06 2020-02-04 焦作卓立膜材料有限责任公司 一种耐高温蒸汽的热转印离型剂及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
董晨空等: "《塑料新型加工助剂应用技术》", 30 June 1999 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708358A (zh) * 2020-12-24 2021-04-27 无锡新树胶粘制品有限公司 一种防静电薄膜及其制备方法
CN113214515A (zh) * 2021-05-06 2021-08-06 吉翔宝（太仓）离型材料科技发展有限公司 一种正反双面抗静电复合型离型膜
CN113250007A (zh) * 2021-05-06 2021-08-13 吉翔宝（太仓）离型材料科技发展有限公司 一种低剥离力的耐高温离型纸及其加工工艺

Similar Documents

Publication Publication Date Title
CN111501410A (zh) 一种双面抗静电复合型离型纸
CN202390357U (zh) 一种抗刮防静电保护膜
CN205800372U (zh) 一种抗静电硅胶保护膜
CN113250007A (zh) 一种低剥离力的耐高温离型纸及其加工工艺
CN114015368A (zh) 一种胶带用bopp基膜及应用其的锂电池保护胶带
CN205133491U (zh) 一种无基材易拉可剥除双面粘合固定胶带
CN102555381A (zh) Bopp涂布热封膜
CN205291765U (zh) 铝基覆铜板
US20170233613A1 (en) Adhesive tapes and heat spreader assemblies
CN207277094U (zh) 一种pe防静电网格离型纸
CN215799293U (zh) 一种粘附硅油离型涂层薄膜的垫高防滑保护胶带
KR20020074448A (ko) 전자 케이블용 부식방지 코팅 및 테이프
CN202809395U (zh) 防静电雾面离型纸
CN103264554A (zh) 一种防静电pet材料膜及其制作方法和应用
CN110628350A (zh) 用于保护处于加工状态的工件的保护膜及其应用
CN204097388U (zh) 一种白色超薄单面胶带
CN109466143A (zh) 一种适用于电子产品的多功能保护膜
CN204097391U (zh) 一种黑色超薄单面胶带
CN211719170U (zh) 导热耐高温标签
CN204058341U (zh) 均匀散热贴片
CN102101994A (zh) 一种用于保护膜的低粘丙烯酸酯胶粘剂
CN202809394U (zh) 防静电离型纸
CN203381288U (zh) 一种防静电pet材料膜
CN204625526U (zh) 一种抗静电异差保护膜
CN104616844B (zh) 一种阻燃耐磨的彩色绝缘片

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20200807