CN111500160A - Solvent-free spraying low-light-level curing UV transparent primer and preparation method and application thereof - Google Patents
Solvent-free spraying low-light-level curing UV transparent primer and preparation method and application thereof Download PDFInfo
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- CN111500160A CN111500160A CN202010360955.3A CN202010360955A CN111500160A CN 111500160 A CN111500160 A CN 111500160A CN 202010360955 A CN202010360955 A CN 202010360955A CN 111500160 A CN111500160 A CN 111500160A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to the technical field of coatings, and particularly relates to a solvent-free spraying low-light-level curing UV transparent primer as well as a preparation method and application thereof. The transparent primer consists of the following components in parts by weight: 20-30 parts of modified epoxy acrylate, 10-15 parts of polyester acrylate, 5-10 parts of polyurethane acrylate, 0.5-1 part of dispersing agent, 0.1-0.5 part of defoaming agent, 0.1-0.5 part of flatting agent, 1-3 parts of anti-settling agent, 5-10 parts of photoinitiator, 10-20 parts of filler and 25-35 parts of polyfunctional group reactive diluent; wherein, the photoinitiator is a compound combination of a free radical cracking type photoinitiator, a free cationic photoinitiator and active amine. The primer disclosed by the invention can be completely cured under the condition of lower energy consumption, the initiator is almost free from residue, the ozone emission is reduced, and the odor purification effect is excellent; the primer product can achieve zero solvent addition in the whole construction process, and realize zero volatile matter in the curing process.
Description
Technical Field
The invention belongs to the technical field of coatings, and particularly relates to a solvent-free spraying low-light-level curing UV transparent primer as well as a preparation method and application thereof.
Background
In recent years, ultraviolet curing technology and coatings adopting the ultraviolet curing technology are rapidly developed and applied, and are particularly applied to furniture coatings. However, the traditional construction modes of roller coating and curtain coating are difficult to construct for special-shaped workpieces of furniture products, and the traditional construction mode of solvent-based spraying of the UV transparent primer has low solid content and large solvent release amount, so that the production environment is severe, and meanwhile, the pollution to the environment is relatively large, and the method is not suitable for large-scale production and application. Therefore, a novel spraying primer with low solvent release amount is urgently needed to meet the market demand, and meanwhile, the effects of energy conservation, emission reduction and environmental protection are achieved.
Disclosure of Invention
The invention aims to solve the problems in the prior art and provides a solvent-free spraying low-light-level curing UV transparent primer and a preparation method and application thereof, wherein the primer product can realize complete curing under the condition of low ultraviolet energy, namely under the condition of lower energy consumption, and the photoinitiator participating in the reaction has a stable structure, can effectively reduce the residue of the initiator during initiation, achieves the effects of almost no residue and complete initiation, reduces the discharge amount of ozone, and obtains a relatively excellent odor purification effect; in addition, the product can achieve zero solvent addition in the whole construction process, and realize zero volatile matter in the curing process.
The technical scheme of the invention is as follows:
a solvent-free spraying low-light-level curing UV transparent primer is composed of the following components in parts by weight:
wherein, the photoinitiator is a compound combination of a free radical cracking type photoinitiator, a free cationic photoinitiator and active amine. Preferably, the photoinitiator is CBP, PBZ and 819 of Tianjin durable new materials and 1113C of Kotian new materials. The free radical cracking type photoinitiator CBP + PBZ has an unstable structure after being irradiated by ultraviolet rays in a system to generate pinacol compounds, and the pinacol compounds react with the multifunctional groups of the resin to achieve the effect of curing the middle layer; the free cationic photoinitiator utilizes the reaction of free cations and multifunctional groups of resin to achieve the aim of deep curing; active amine such as diethanolamine provides a surface curing effect in a system, and curing is carried out from three layers of a surface layer, a middle layer and a deep layer, so that each photoinitiator is ensured to completely participate in the reaction, and the effects of high curing speed and no residue are achieved.
Further, the modified epoxy acrylate is low-viscosity bisphenol A epoxy acrylate; the polyester acrylate is tetrafunctional low-viscosity polyester acrylate; the urethane acrylate is a hexafunctional low viscosity urethane acrylate. Wherein, the low-viscosity bisphenol A epoxy acrylate provides a better construction viscosity, and the high-functionality resins of the four-functional group low-viscosity polyester acrylate and the six-functional group low-viscosity polyurethane acrylate provide enough reaction groups to ensure a reaction activity under a low-energy condition.
Preferably, the modified epoxy acrylate is 6300 epoxy acrylate of a light new material of Jiangmen, the polyester acrylate is 8407 resin of science and technology Limited of Dibang, Hunan, and the polyurethane acrylate is 6145-100-functional polyurethane acrylate of Changxing chemistry.
Furthermore, the dispersing agent is acrylate, so that the dispersing agent can be effectively dissolved with a system, and a higher system stability is ensured; the defoaming agent is any one of an ether modified organic silicon defoaming agent and a non-organic silicon defoaming agent; the flatting agent is one or more of a fluorocarbon modified polyacrylate flatting agent, a polyether modified silicone oil flatting agent or an acrylate copolymer flatting agent.
Preferably, the dispersant is modified polyurethane dispersant EFKA4010 of Pasteur Germany; the defoaming agent is organic silicon type defoaming agent TEGO920 of TEGO company; the leveling agent is an acrylate copolymer leveling agent BYK358N of Germany BYK company or a polyether modified silicone oil leveling agent HX-3130 of Guangzhou Huaxia chemical group.
Further, the anti-settling agent is fumed silica and a dustproof auxiliary agent; the filler is one or more of talcum powder, transparent powder and zinc stearate; the polyfunctional active diluent is one or more of trimethylolpropane diacrylate, trimethylolpropane triacrylate or tripropylene glycol diacrylate.
Preferably, the anti-settling agent is A-200 of Germany Degussa, and the dustproof auxiliary agent is BYK-405; the filler is selected from 1000 mesh talcum powder of Guangxi Longsheng Huamei Talc development Co., Ltd, TP1250 mesh talcum powder of Guangxi Guilin ultra-fine powder Co., Ltd, and 1250 mesh transparent powder of Fushan monkey saint chemical Co., Ltd; the polyfunctional active diluent is TMPTA or TPGDA in Sanmu chemical engineering.
The preparation method of the solvent-free sprayed low-light-level curing UV transparent primer comprises the following steps:
firstly, adding polyurethane acrylate, polyester acrylate and epoxy acrylate into a reactor according to parts by weight, then adding 5-10 parts of polyfunctional group reactive diluent, and stirring at the speed of 600-800 r/min for 10-15 min; then, sequentially adding the defoaming agent, the flatting agent, the dispersing agent and the photoinitiator in corresponding parts by weight into the reactor, and stirring at the speed of 800-1000 r/min for 5-10 min; adding a filler and an anti-settling agent, and stirring at the speed of 800-1200 r/min for 15-30 min; and finally, adding the rest part of polyfunctional group reactive diluent into the reactor, and stirring at the speed of 600-800 r/min for 5-15 min to obtain the product.
The application of the solvent-free spraying low-light-level curing UV transparent primer is special for woodware; when the solvent-free spraying low-light-level curing UV transparent primer is used for spraying construction, firstly, the primer is heated to 40-45 ℃, spraying equipment is used for uniformly spraying the primer on the surface of wood, and then, low light level is used for curing; the spraying equipment can adopt a reciprocating type spraying machine, a vacuum spraying machine, a fixed point spraying machine and the like.
Furthermore, the wood needs to be pretreated before being sprayed with primer, namely, the surface of the wood is dedusted after the wood is deburred.
Furthermore, the low-light level is an ultraviolet lamp under the condition of low energy with single lamp power less than or equal to 3 KW.
The invention has the beneficial effects that:
(1) the solvent-free spraying low-light-level curing UV transparent primer product provided by the invention contains no volatile solvent by 100%, is solvent-free spraying construction, has the curing amount of more than or equal to 95%, can effectively control the discharge of VOC, has low VOC discharge amount, excellent environmental protection performance and simple production process; the low-light-level curing mode of the product can achieve the purpose of complete curing by using about 40% of original energy consumption, can effectively save energy, is environment-friendly and energy-saving, and responds to national policy on energy conservation and emission reduction.
(2) The solvent-free sprayed low-light-level cured UV transparent primer prepared by the invention can realize complete curing under the condition of low ultraviolet energy, and simultaneously achieves zero solvent addition in the whole construction process and zero volatile matter in the curing process; the photoinitiator participating in the reaction has a stable structure, and simultaneously, due to the effect of the self-curing system structure, the initiator can completely participate in the reaction, and the paint film has a stable structure and a smell removal effect.
(3) Because this priming paint product does not contain volatile solvent and volatile matter during the construction, can make production operational environment obtain a great promotion, compare in traditional solvent type spraying UV product, this product obtains a great promotion to the protection of construction workman's health, is an environment-friendly coating.
Detailed Description
The technical solutions of the present invention will be described in detail and fully with reference to the following specific embodiments, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention. In the examples, the means used are conventional in the art, unless otherwise specified.
For a further understanding of the present invention, reference will now be made in detail to the following examples.
Example 1
The components in parts by weight of the solvent-free sprayed low-light-cured UV transparent primer are shown in Table 1, and the preparation method comprises the following steps:
(1) accurately weighing 20 parts of 6300 epoxy acrylate, 10 parts of 8407 resin, 5 parts of 100 hexafunctional polyurethane acrylate 6145-one and 13 parts of TPGDA, then putting into a reactor, and stirring at the speed of 800r/min for 10 min;
(2) slowly adding 0.1 part of defoaming agent TEGO920, 0.1 part of flatting agent BYK358N, 0.5 part of dispersing agent EFKA4010, 2 parts of photoinitiator CBP and 3 parts of photoinitiator 1113C into the reactor, and stirring at the speed of 800r/min for 10 min;
(3) slowly adding 3 parts of transparent powder TM-2500, 7 parts of 1000-mesh talcum powder and 1 part of fumed silica anti-settling agent A-200, and stirring at the speed of 1200r/min for 30min until the fineness is less than or equal to 50 mu m;
(4) slowly adding 14 parts of polyfunctional active diluent TMPTA into the reactor, and dispersing for 5min at the speed of 600 r/min;
(5) slowly adding the rest 6 parts of polyfunctional active diluent TPGDA into the reactor, and stirring at the speed of 600r/min for 10min to obtain the product.
Example 2
The components in parts by weight of the solvent-free sprayed low-light-cured UV transparent primer are shown in Table 1, and the preparation method comprises the following steps:
(1) accurately weighing 30 parts of 6300 epoxy acrylate, 15 parts of 8407 resin, 10 parts of 100 hexafunctional polyurethane acrylate 6145-one and 15 parts of TPGDA, then putting into a reactor, and stirring at the speed of 800r/min for 10 min;
(2) slowly adding 0.5 part of defoaming agent TEGO920, 0.5 part of flatting agent HX-3130, 1.0 part of dispersing agent EFKA4010, 4 parts of photoinitiator OMB and 6 parts of photoinitiator 1113C into the reactor, and stirring at the speed of 800r/min for 10 min;
(3) slowly adding 20 parts of TP 1250-mesh talcum powder and 3 parts of fumed silica anti-settling agent A-200, and stirring at the speed of 1200r/min for 30min until the fineness is less than or equal to 50 mu m;
(4) slowly adding 14 parts of polyfunctional active diluent TMPTA into the reactor, and dispersing for 5min at the speed of 600 r/min;
(5) slowly adding the rest 2 parts of polyfunctional active diluent TPGDA into the reactor, and stirring at the speed of 600r/min for 10min to obtain the product.
Example 3
The components in parts by weight of the solvent-free sprayed low-light-cured UV transparent primer are shown in Table 1, and the preparation method comprises the following steps:
(1) accurately weighing 22 parts of 6300 parts of epoxy acrylate, 13 parts of 8407 resin, 7 parts of 100 hexafunctional polyurethane acrylate 6145-one and 10 parts of TPGDA, then putting into a reactor, and stirring at the speed of 800r/min for 10 min;
(2) slowly adding 0.2 part of defoaming agent TEGO920, 0.3 part of flatting agent BYK358N, 0.5 part of dispersing agent EFKA4010, 2 parts of photoinitiator 819 and 4 parts of photoinitiator 1113C into the reactor, and stirring at the speed of 800r/min for 10 min;
(3) slowly adding 15 parts of 1250-mesh talcum powder and 2 parts of fumed silica anti-settling agent A-200, and stirring at the speed of 1200r/min for 30min until the fineness is less than or equal to 50 mu m;
(4) slowly adding 14 parts of polyfunctional active diluent TMPTA into the reactor, and dispersing for 5min at the speed of 600 r/min;
(5) slowly adding the rest 2 parts of polyfunctional active diluent TPGDA into the reactor, and stirring at the speed of 600r/min for 10min to obtain the product.
TABLE 1 Components and parts by weight compositions of the primers of examples 1-3
Test example 1
According to the detection standard HG/T3655-2012, the solvent-free spray micro-light curing UV transparent primer products prepared in the embodiments 1-3 are subjected to the performance parameter detection, and the detection results are shown in the following table 2:
TABLE 2 Performance parameters and test results for the products of examples 1-3
| Test items | Example 1 product | EXAMPLE 2 product | EXAMPLE 3 product |
| State parameter in container | Uniformly stirred without hard lumps | Uniformly stirred without hard lumps | Uniformly stirred without hard lumps |
| The fineness is less than or equal to 50 mu m | 45μm | 45μm | 45μm |
| Storage stability (50 ℃, 7d) | No abnormality | No abnormality | No abnormality |
| Non-volatile fraction of% | 100％ | 100％ | 100％ |
| Appearance of coating film | Smooth and flat | Smooth and flat | Smooth and flat |
| ≥H | ≥H | ≥H | ≥H |
| Adhesive force (space 2mm) | Grade 2 or below | Grade 2 or below | Grade 2 or below |
Test example 2
The primers prepared in examples 1-3 were tested in comparison with a conventional UV-curable clear primer.
The bottom plate is a fraxinus mandshurica board, the solvent-free sprayed low-light-level cured UV transparent primer prepared in the embodiment 1-3 and the common ultraviolet cured transparent primer are sprayed on the fraxinus mandshurica bottom plate simultaneously, and the curing energy is set to be 60mj/cm2。
The conventional ultraviolet curing energy range is 200-240 mj/cm260mj/cm as used in this test example2Energy belongs to the energy which can not be solidified by conventional products in the field of ultraviolet light solidification.
The process comprises the following steps: base plate → dust removal by sanding → sample oil (100 g/m)2) → curing energy (60 mj/cm)2) → sanding dust removal → sample oil (100 g/m)2) → curing energy (60 mj/cm)2) → sanding dust removal → sample oil (100 g/m)2) → curing energy (60 mj/cm)2) After spraying, the detection is respectively carried out, and the detection results are shown in table 3:
table 3 test results of examples 1-3 after roller coating of primers and general uv curable clear primer
According to the test result, the common ultraviolet curing transparent primer is 60mj/cm2The curing is carried out under the condition of (1), the aim of integrally curing a paint film cannot be achieved, the panel is poorly cured and cannot be polished, and deep curing is insufficient, so that the adhesive force is poor; the novel low-light-level curing primer provided by the invention can completely achieve the curing effect under the low-energy condition, namely, the curing effect of a conventional product under the energy condition of 240mj can be achieved under the energy condition of 60 mj.
The above description is only for the preferred embodiment of the present invention and should not be taken as limiting the invention, and any modifications, equivalents, improvements and the like made within the scope of the present invention should be included in the patent protection scope of the present invention. It is intended that all such modifications and variations be included within the scope of the invention as claimed, without departing from the spirit thereof.
Claims (8)
1. The solvent-free spraying low-light-level curing UV transparent primer is characterized by comprising the following components in parts by weight:
wherein, the photoinitiator is a compound combination of a free radical cracking type photoinitiator, a free cationic photoinitiator and active amine.
2. The solventless spray micro-photocuring UV clear primer of claim 1 wherein the modified epoxy acrylate is a low viscosity bisphenol a type epoxy acrylate; the polyester acrylate is tetrafunctional low-viscosity polyester acrylate; the urethane acrylate is a hexafunctional low viscosity urethane acrylate.
3. The solventless spray micro-photocuring UV transparent primer as claimed in claim 1, wherein the dispersant is an acrylate dispersant; the defoaming agent is any one of an ether modified organic silicon defoaming agent and a non-organic silicon defoaming agent; the flatting agent is one or more of a fluorocarbon modified polyacrylate flatting agent, a polyether modified silicone oil flatting agent or an acrylate copolymer flatting agent.
4. The solvent-free spray micro-light cured UV transparent primer according to claim 1, wherein the anti-settling agent is fumed silica and a dust-proof auxiliary agent; the filler is one or more of talcum powder, transparent powder and zinc stearate; the polyfunctional active diluent is one or more of trimethylolpropane diacrylate, trimethylolpropane triacrylate or tripropylene glycol diacrylate.
5. The method for preparing the solvent-free spray micro-photocuring UV transparent primer as claimed in any one of claims 1 to 4, wherein the preparation method comprises the following steps:
firstly, adding polyurethane acrylate, polyester acrylate and epoxy acrylate into a reactor according to parts by weight, then adding 5-10 parts of polyfunctional group reactive diluent, and stirring at the speed of 600-800 r/min for 10-15 min; then, sequentially adding the defoaming agent, the flatting agent, the dispersing agent and the photoinitiator in corresponding parts by weight into the reactor, and stirring at the speed of 800-1000 r/min for 5-10 min; adding a filler and an anti-settling agent, and stirring at the speed of 800-1200 r/min for 15-30 min; and finally, adding the rest part of polyfunctional group reactive diluent into the reactor, and stirring at the speed of 600-800 r/min for 5-15 min to obtain the product.
6. The use of the solvent-free spray micro-light cured UV transparent primer according to any one of claims 1 to 4, wherein the solvent-free spray micro-light cured UV transparent primer is specific to woodware; when the solvent-free low-light-level-curing UV transparent primer is sprayed, firstly, the primer is heated to 40-45 ℃, spraying equipment is used for uniformly spraying the primer on the surface of the wood, and then, low light level is used for curing.
7. Use according to claim 6, characterised in that the wood is pretreated before the primer is sprayed, i.e. the wood surface is dedusted after being deburred.
8. The use according to claim 6, characterized in that the dim light is a UV lamp at low energy with a single lamp power of 3KW or less.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409297A (en) * | 2020-11-17 | 2021-02-26 | 肇庆市名洋涂料有限公司 | Free radical-cation hybrid photo-curing monomer, preparation method thereof, radiation-curing coating and application |
| CN113174189A (en) * | 2021-05-11 | 2021-07-27 | 澳达树熊涂料(惠州)有限公司 | Ultraviolet-curing microparticle spray primer and preparation method thereof |
| CN113604149A (en) * | 2021-06-07 | 2021-11-05 | 君子兰涂料（天津）有限公司 | UV (ultraviolet) spraying white-bottom woodware coating for mechanical arm and preparation method thereof |
| CN114213944A (en) * | 2021-12-27 | 2022-03-22 | 濮阳展辰新材料有限公司 | Long-wave cured woodware coating and preparation method thereof |
| CN114292572A (en) * | 2021-12-28 | 2022-04-08 | 濮阳展辰新材料有限公司 | UV (ultraviolet) photocuring woodware coating and preparation method thereof |
| CN114763450A (en) * | 2021-10-20 | 2022-07-19 | 上海君子兰新材料股份有限公司 | UV roller coating transparent primer applied to calcium silicate board and preparation method thereof |
| CN115558385A (en) * | 2022-11-07 | 2023-01-03 | 上海立邦长润发涂料有限公司 | UV primer preparation and coating method for UV bottom water surface process |
| CN115651502A (en) * | 2022-11-08 | 2023-01-31 | 青岛展辰新材料有限公司 | Ultraviolet light curing woodware primer, preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371543A (en) * | 2014-08-20 | 2015-02-25 | 昆山博益鑫成高分子材料有限公司 | Solvent-free cationic light-curable release coating and preparation method thereof |
| CN105733415A (en) * | 2016-04-14 | 2016-07-06 | 湖南省金海科技有限公司 | Full-solid-content low-energy curing sector-shaped shower coating UV coating and preparation method thereof |
| CN107513344A (en) * | 2017-09-05 | 2017-12-26 | 史海生 | A kind of LED UV ultraviolet cured woodware nano paints and preparation method thereof |
| CN108977049A (en) * | 2018-06-27 | 2018-12-11 | 江苏宏泰高分子材料有限公司 | A kind of environment-friendly type photocuring thermostable high humidity PVD finishing coat and preparation method thereof |
| CN109897529A (en) * | 2019-02-25 | 2019-06-18 | 江苏宏泰高分子材料有限公司 | It is painted in a kind of solidification gradient color plating of ultraviolet light |
-
2020
- 2020-04-30 CN CN202010360955.3A patent/CN111500160A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371543A (en) * | 2014-08-20 | 2015-02-25 | 昆山博益鑫成高分子材料有限公司 | Solvent-free cationic light-curable release coating and preparation method thereof |
| CN105733415A (en) * | 2016-04-14 | 2016-07-06 | 湖南省金海科技有限公司 | Full-solid-content low-energy curing sector-shaped shower coating UV coating and preparation method thereof |
| CN107513344A (en) * | 2017-09-05 | 2017-12-26 | 史海生 | A kind of LED UV ultraviolet cured woodware nano paints and preparation method thereof |
| CN108977049A (en) * | 2018-06-27 | 2018-12-11 | 江苏宏泰高分子材料有限公司 | A kind of environment-friendly type photocuring thermostable high humidity PVD finishing coat and preparation method thereof |
| CN109897529A (en) * | 2019-02-25 | 2019-06-18 | 江苏宏泰高分子材料有限公司 | It is painted in a kind of solidification gradient color plating of ultraviolet light |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409297A (en) * | 2020-11-17 | 2021-02-26 | 肇庆市名洋涂料有限公司 | Free radical-cation hybrid photo-curing monomer, preparation method thereof, radiation-curing coating and application |
| CN112409297B (en) * | 2020-11-17 | 2023-06-20 | 肇庆市名洋涂料有限公司 | Free radical-cation hybrid photo-curing monomer, preparation method thereof, radiation-curing coating and application |
| CN113174189A (en) * | 2021-05-11 | 2021-07-27 | 澳达树熊涂料(惠州)有限公司 | Ultraviolet-curing microparticle spray primer and preparation method thereof |
| CN113604149A (en) * | 2021-06-07 | 2021-11-05 | 君子兰涂料（天津）有限公司 | UV (ultraviolet) spraying white-bottom woodware coating for mechanical arm and preparation method thereof |
| CN114763450A (en) * | 2021-10-20 | 2022-07-19 | 上海君子兰新材料股份有限公司 | UV roller coating transparent primer applied to calcium silicate board and preparation method thereof |
| CN114213944A (en) * | 2021-12-27 | 2022-03-22 | 濮阳展辰新材料有限公司 | Long-wave cured woodware coating and preparation method thereof |
| CN114292572A (en) * | 2021-12-28 | 2022-04-08 | 濮阳展辰新材料有限公司 | UV (ultraviolet) photocuring woodware coating and preparation method thereof |
| CN115558385A (en) * | 2022-11-07 | 2023-01-03 | 上海立邦长润发涂料有限公司 | UV primer preparation and coating method for UV bottom water surface process |
| CN115558385B (en) * | 2022-11-07 | 2023-09-08 | 上海立邦长润发涂料有限公司 | UV primer preparation and coating method for UV base water surface process |
| CN115651502A (en) * | 2022-11-08 | 2023-01-31 | 青岛展辰新材料有限公司 | Ultraviolet light curing woodware primer, preparation method and application thereof |
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