CN111454512A - Antibacterial and deodorant modified EVA shoe material and preparation method thereof - Google Patents
Antibacterial and deodorant modified EVA shoe material and preparation method thereof Download PDFInfo
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- CN111454512A CN111454512A CN202010457184.XA CN202010457184A CN111454512A CN 111454512 A CN111454512 A CN 111454512A CN 202010457184 A CN202010457184 A CN 202010457184A CN 111454512 A CN111454512 A CN 111454512A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/18—Resilient soles
- A43B13/187—Resiliency achieved by the features of the material, e.g. foam, non liquid materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/009—Use of pretreated compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof, and relates to the field of antibacterial and deodorant modified EVA shoes. The composition comprises the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel. The method comprises the following steps: 1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring; 2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, and fully stirring. The mixture of the flaky silver zeolite and the silica gel with the thickness of 1-10mm is embedded at the top of the sole by a rolling process, so that the adsorbability and the air permeability in the whole shoe can be ensured, and the antibacterial and deodorant effects of the EVA shoe are greatly improved.
Description
Technical Field
The invention relates to the field of antibacterial and deodorant modified EVA shoes, in particular to an antibacterial and deodorant modified EVA shoe material and a preparation method thereof.
Background
Shoes are as the traditional product of china, there is the history of several thousand years, be an embodiment of ancient people's wisdom, in modern society, along with the scientific and technological progress, this product that is closely related with the life of shoes, become more and more abundant, its service function also becomes abundant, not only in order to protect the foot, be convenient for walk, people pursue the travelling comfort of shoes more and more, long-time shoes of wearing, especially the hot weather in summer, can make the sweat flow of foot increase, because the inside air of shoes is not circulated, can make people's foot cover smelly again, be unfavorable for people to pursue the travelling comfort of shoes.
The existing method for deodorizing by utilizing an antibacterial agent in shoe products is characterized in that certain volatile medicines are sprayed in insoles, and odor generated in shoes is inhibited by the fragrance emitted by the volatile medicines; the other is an adsorption type substance, which utilizes the huge surface area of the substance and the inherent high surface energy to generate strong adsorption force on the surrounding substances.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an antibacterial deodorizing modified EVA shoe material and a preparation method thereof, and solves the problem that the antibacterial effect of the existing shoe product is not obvious.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: the composition comprises the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel.
Preferably comprising the steps of:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
and (3) bonding the vamp and the sole, wherein one surface of the mixture of the silver zeolite and the silica gel is positioned on the inner side of the vamp during bonding, and the bottom surface of the sole is engraved with the anti-skid lines.
Preferably, the silver zeolite and the silica gel are granular materials, and the diameter of the silver zeolite and the silica gel is not more than 5 mm.
Preferably, the finished shoe is integrally placed in a negative pressure environment for 2-5H.
Preferably, the insole is arranged inside the shoe after the finished shoe is made.
Preferably, the thickness of the mixture of the flaky silver zeolite and the silica gel is between 1 and 10 mm.
Preferably, the magnesium stearate is in the form of fine powder without sand.
Preferably, the cut flaky silver zeolite and the cut silica gel are embedded on the surface of the sole material after rolling treatment.
(III) advantageous effects
The invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof. The method has the following beneficial effects:
1. according to the invention, the mixture of the flaky silver zeolite and the silica gel with the thickness of 1-10mm is embedded on the top of the sole by a rolling process, so that the adsorbability and the air permeability in the whole shoe can be ensured, and the antibacterial and deodorant effects of the EVA shoe are greatly improved.
2. According to the invention, the finished product is placed in a negative pressure environment for 2-5h, so that the overall elasticity of the shoe can be increased, and the shoe is more comfortable to wear.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment of the invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof, wherein the material comprises the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel.
The method comprises the following steps:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
bonding the vamp and the sole, wherein one side of the mixture of silver zeolite and silica gel is positioned at the inner side of the vamp during bonding, anti-skid lines are engraved on the bottom surface of the sole, the silver zeolite and the silica gel are made of granular materials, the diameter of the silver zeolite and the silica gel is not more than 5mm, the mixture of the silver zeolite and the silica gel is integrally placed in a negative pressure environment for 2-5H after being made into a finished shoe, an insole is arranged inside the shoe after the finished shoe is made, the thickness of the mixture of the flaky silver zeolite and the silica gel is 1-10mm, the magnesium stearate is sand-free fine powder, the cut flaky silver zeolite and the silica gel are inlaid on the surface of the sole material after rolling treatment.
Preferably, the cut flaky silver zeolite and the cut silica gel are embedded on the surface of the sole material after rolling treatment. .
Example two:
the embodiment of the invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof, wherein the material comprises the following raw materials in parts by weight: 200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel.
The method comprises the following steps:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 150-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
bonding the vamp and the sole, wherein one side of the mixture of silver zeolite and silica gel is positioned at the inner side of the vamp during bonding, anti-skid lines are engraved on the bottom surface of the sole, the silver zeolite and the silica gel are made of granular materials, the diameter of the silver zeolite and the silica gel is not more than 5mm, the mixture of the silver zeolite and the silica gel is integrally placed in a negative pressure environment for 2-5H after being made into a finished shoe, an insole is arranged inside the shoe after the finished shoe is made, the thickness of the mixture of the flaky silver zeolite and the silica gel is 4-10mm, the magnesium stearate is sand-free fine powder, the cut flaky silver zeolite and the silica gel are inlaid on the surface of the sole material after rolling treatment.
Example three:
the embodiment of the invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof, wherein the material comprises the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-4 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel.
The method comprises the following steps:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
bonding the vamp and the sole, wherein one side of the mixture of silver zeolite and silica gel is positioned at the inner side of the vamp during bonding, anti-skid lines are engraved on the bottom surface of the sole, the silver zeolite and the silica gel are made of granular materials, the diameter of the silver zeolite and the silica gel is not more than 5mm, the mixture of the silver zeolite and the silica gel is integrally placed in a negative pressure environment for 3-5H after being made into a finished shoe, an insole is arranged inside the shoe after the finished shoe is made, the thickness of the mixture of the flaky silver zeolite and the silica gel is 1-10mm, the magnesium stearate is sand-free fine powder, the cut flaky silver zeolite and the silica gel are inlaid on the surface of the sole material after rolling treatment.
Example four:
the embodiment of the invention provides an antibacterial and deodorant modified EVA shoe material and a preparation method thereof, wherein the material comprises the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 3-5 parts of silver zeolite and 6-10 parts of silica gel.
The method comprises the following steps:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
bonding the vamp and the sole, wherein one side of the mixture of silver zeolite and silica gel is positioned at the inner side of the vamp during bonding, anti-skid lines are engraved on the bottom surface of the sole, the silver zeolite and the silica gel are made of granular materials, the diameter of the silver zeolite and the silica gel is not more than 5mm, the mixture of the silver zeolite and the silica gel is integrally placed in a negative pressure environment for 3-5H after being made into a finished shoe, an insole is arranged inside the shoe after the finished shoe is made, the thickness of the mixture of the flaky silver zeolite and the silica gel is 1-10mm, the magnesium stearate is sand-free fine powder, the cut flaky silver zeolite and the silica gel are inlaid on the surface of the sole material after rolling treatment.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (8)
1. The antibacterial and deodorant modified EVA shoe material is characterized by comprising the following raw materials in parts by weight: 100-200 parts of ethylene-vinyl acetate copolymer, 2-5 parts of magnesium stearate, 3-5 parts of foaming agent, 0.5-1.5 parts of accelerant, 2-3 parts of antioxidant, 2-5 parts of silver zeolite and 4-10 parts of silica gel.
2. The preparation method of the antibacterial and deodorant modified EVA shoes is characterized by comprising the following steps: the method comprises the following steps:
1) firstly, fully mixing and stirring a foaming agent, an accelerator and an antioxidant in raw materials according to the proportion of a formula to form a blending mixture, and ensuring the temperature to be 60-80 ℃ during stirring;
2) mixing 100-200 parts of ethylene-vinyl acetate copolymer and 2-5 parts of magnesium stearate in the raw materials, then adding the blending mixture, fully stirring, then pouring into a mold, standing and forming into a sheet shape to form the sole material;
3) then, mechanically rolling the sheet sole material, and cutting the sole material into the size of a common sole;
4) vulcanizing the cut sole;
5) mixing silver zeolite and silica gel according to a formula ratio, and bonding the mixed silver zeolite and silica gel into a sheet by an adhesive;
6) cutting the flaky silver zeolite and silica gel, wherein the cutting area is smaller than that of the sole;
7) placing the cut mixture of the flaky silver zeolite and the silica gel on one side of the cut sole, and performing rolling treatment to enable the two sides to be flat;
8) and (3) bonding the vamp and the sole, wherein one surface of the mixture of the silver zeolite and the silica gel is positioned on the inner side of the vamp during bonding, and the bottom surface of the sole is engraved with the anti-skid lines.
3. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 1 are characterized in that: the silver zeolite and the silica gel are granular materials, and the diameter of the silver zeolite and the silica gel is not more than 5 mm.
4. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 2 are characterized in that: the finished product of the shoe is integrally placed in a negative pressure environment for 2-5H.
5. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 2 are characterized in that: after the finished product shoes are manufactured, insoles are arranged inside the shoes.
6. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 2 are characterized in that: the thickness of the mixture of the flaky silver zeolite and the silica gel is between 1 and 10 mm.
7. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 1 are characterized in that: the magnesium stearate is in the form of fine powder without sand.
8. The antibacterial deodorant modified EVA shoe material and the preparation method thereof according to claim 2 are characterized in that: the cut flaky silver zeolite and the cut silica gel are embedded on the surface of the sole material after rolling treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010457184.XA CN111454512A (en) | 2020-05-26 | 2020-05-26 | Antibacterial and deodorant modified EVA shoe material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010457184.XA CN111454512A (en) | 2020-05-26 | 2020-05-26 | Antibacterial and deodorant modified EVA shoe material and preparation method thereof |
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| CN111454512A true CN111454512A (en) | 2020-07-28 |
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| CN202010457184.XA Pending CN111454512A (en) | 2020-05-26 | 2020-05-26 | Antibacterial and deodorant modified EVA shoe material and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101291982A (en) * | 2005-10-12 | 2008-10-22 | 西巴特殊化学品控股有限公司 | Material having antibacterial and antifungal properties |
| CN107522937A (en) * | 2017-09-28 | 2017-12-29 | 鹤山市亿田路鞋业有限公司 | EVA shoe bottom expanded material of antibacterial and deodouring and preparation method thereof |
| CN109181088A (en) * | 2018-09-04 | 2019-01-11 | 泉州市正域数码科技有限公司 | Damping EVA shoe bottom material and preparation method thereof |
| CN110372950A (en) * | 2019-07-24 | 2019-10-25 | 温州市宜和鞋材有限公司 | A kind of antibacterial and mouldproof footwear material and preparation method of shoe pads |
-
2020
- 2020-05-26 CN CN202010457184.XA patent/CN111454512A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101291982A (en) * | 2005-10-12 | 2008-10-22 | 西巴特殊化学品控股有限公司 | Material having antibacterial and antifungal properties |
| CN107522937A (en) * | 2017-09-28 | 2017-12-29 | 鹤山市亿田路鞋业有限公司 | EVA shoe bottom expanded material of antibacterial and deodouring and preparation method thereof |
| CN109181088A (en) * | 2018-09-04 | 2019-01-11 | 泉州市正域数码科技有限公司 | Damping EVA shoe bottom material and preparation method thereof |
| CN110372950A (en) * | 2019-07-24 | 2019-10-25 | 温州市宜和鞋材有限公司 | A kind of antibacterial and mouldproof footwear material and preparation method of shoe pads |
Non-Patent Citations (1)
| Title |
|---|
| 杨建忠 主编: "《新型纺织材料及应用》", 31 October 2011, 东华大学出版社 * |
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Application publication date: 20200728 |
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