CN111441065A - Electrode assembly and sodium hypochlorite generator - Google Patents

Electrode assembly and sodium hypochlorite generator Download PDF

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Publication number
CN111441065A
CN111441065A CN201910041667.9A CN201910041667A CN111441065A CN 111441065 A CN111441065 A CN 111441065A CN 201910041667 A CN201910041667 A CN 201910041667A CN 111441065 A CN111441065 A CN 111441065A
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electrode
arm
power supply
arms
supply unit
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张中海
辛森森
王明
黄毅
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Wuhu Midea Kitchen and Bath Appliances Manufacturing Co Ltd
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Wuhu Midea Kitchen and Bath Appliances Manufacturing Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • C25B1/265Chlorates
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention provides an electrode assembly and a sodium hypochlorite generator. The electrode assembly includes a first electrode and a second electrode; the first electrode and the second electrode are flat sheet structures; the first electrode is communicated with the positive electrode of the power supply unit, and the second electrode is communicated with the negative electrode of the power supply unit; the first electrode comprises a plurality of first support arms, and the second electrode comprises a plurality of second support arms; the first support arms and the second support arms are arranged in a staggered mode. According to the electrode assembly, the first support arm and the second support arm are arranged in a staggered mode, so that the effective electrode areas of the first electrode and the second electrode are increased, and the electrolysis efficiency of a sodium hypochlorite solution is improved.

Description

Electrode assembly and sodium hypochlorite generator
Technical Field
The invention relates to the field of household appliances, in particular to an electrode assembly and a sodium hypochlorite generator using the electrode assembly.
Background
Sodium hypochlorite is a broad-spectrum sterilizing disinfectant, and is widely applied to disinfection in public places and household environments. In the household environment disinfection, the disinfectant can be used for soaking clothes, towels, shoes and socks to disinfect, and also can be used for cleaning floors and spraying the diluted disinfectant indoors. The sodium hypochlorite can effectively kill bacterial viruses such as escherichia coli, staphylococcus aureus, pseudomonas aeruginosa, influenza virus, hepatitis A and the like.
At present, sodium hypochlorite generators mainly adopt a mode of electrolyzing sodium hypochlorite solution. However, the electrode group has a limited area, and thus the electrolysis efficiency is low.
Therefore, it is very interesting to improve the electrolytic efficiency of sodium hypochlorite solution.
Disclosure of Invention
Embodiments of the present invention provide a sodium hypochlorite generator to solve or alleviate one or more technical problems in the prior art, and at least provide a useful choice or creation condition.
To achieve the above object, according to a first aspect of the present invention, an embodiment of the present invention provides an electrode assembly including a first electrode and a second electrode; the first electrode and the second electrode are flat sheet structures;
the first electrode is communicated with the positive electrode of the power supply unit, and the second electrode is communicated with the negative electrode of the power supply unit;
the first electrode comprises a plurality of first support arms, and the second electrode comprises a plurality of second support arms; the first support arms and the second support arms are arranged in a staggered mode.
In one embodiment, the first electrode further comprises a first stem arm, and the plurality of first arms are arranged on the first stem arm at intervals;
the second electrode further comprises a second main arm, and the plurality of second support arms are arranged on the second main arm at intervals.
In one embodiment, the first arms are disposed on the same side of the first trunk arm, and the second arms are disposed on the same side of the second trunk arm; the first electrode and the second electrode are arranged in a crossing manner.
In one embodiment, the first plurality of arms are disposed on opposite sides of the first backbone arm and the second plurality of arms are disposed on opposite sides of the second backbone arm; the first electrode and the second electrode are arranged in a crossing manner.
In one embodiment, the plurality of first arms are bent toward the first backbone arm to form a semi-circular arm; the plurality of second arms are bent toward the second backbone arm to form a semi-circular arm.
In one embodiment, the first electrode and the second electrode are respectively provided with fixing holes through which the lead and the fixing member pass.
In one embodiment, the first electrode and the second electrode are made of a titanium material, and a ruthenium-iridium plating layer or a platinum-gold plating layer is provided on the surface.
According to a second aspect of the invention, the embodiment of the invention provides a sodium hypochlorite generator, which comprises a cup body, a power supply unit and the electrode assembly; the cup body is used for containing saline solution, and the electrode assembly is arranged in the cup body;
the first electrode is communicated with the positive electrode of the power supply unit, and the second electrode is communicated with the negative electrode of the power supply unit, so that the electrode assembly forms an electrolysis loop.
In one embodiment, the power supply device further comprises a control unit, wherein the power supply unit is connected with the control unit;
the control unit is configured to switch between the positive electrode and the negative electrode of the power supply unit, so that the first electrode is conducted with the negative electrode of the power supply unit, and the second electrode is conducted with the positive electrode of the power supply unit.
In one embodiment, the cup body is provided with a water outlet, a water inlet and a handle; the water inlet is provided with a cup cover, and the cup cover is used for opening and closing the water inlet.
Some of the technical solutions have the following advantages or beneficial effects that the electrode assembly of the invention increases the effective electrode areas of the first electrode and the second electrode by staggering the first support arm and the second support arm, thereby improving the efficiency of sodium hypochlorite solution electrolysis.
The foregoing summary is provided for the purpose of description only and is not intended to be limiting in any way. In addition to the illustrative aspects, embodiments, and features described above, further aspects, embodiments, and features of the present invention will be readily apparent by reference to the drawings and following detailed description.
Drawings
In the drawings, like reference numerals refer to the same or similar parts or elements throughout the several views unless otherwise specified. The figures are not necessarily to scale. It is appreciated that these drawings depict only some embodiments in accordance with the disclosure and are therefore not to be considered limiting of its scope.
FIG. 1 is a schematic view of an electrode assembly according to one embodiment of the present invention;
FIG. 2 is a schematic view of an electrode assembly according to another embodiment of the present invention; and
fig. 3 is a schematic structural diagram of a sodium hypochlorite generator according to an embodiment of the present invention.
Detailed Description
In the following, only certain exemplary embodiments are briefly described. As those skilled in the art will recognize, the described embodiments may be modified in various different ways, all without departing from the spirit or scope of the present invention. Accordingly, the drawings and description are to be regarded as illustrative in nature, and not as restrictive.
The invention provides a sodium hypochlorite generator.
The electrode assembly and the sodium hypochlorite generator of the present invention will be described with reference to fig. 1 to 3.
Referring to fig. 1 and 2, in one embodiment, the electrode assembly 1 of the present invention comprises a first electrode 101 and a second electrode 102, wherein the first electrode 101 and the second electrode 102 are flat sheet-like structures.
The first electrode 101 may be in electrical communication with a positive electrode of a power supply unit (to be described later), and the second electrode 102 may be in electrical communication with a negative electrode of the power supply unit. Thus, the electrode assembly 1 may form an electrolysis circuit.
Further, the first electrode 101 may include a plurality of first arms 1011, and similarly, the second electrode 102 may include a plurality of second arms 1021. In addition, the first arm 1011 and the second arm 1021 can be staggered, so that the effective electrode area of the first electrode and the second electrode is increased, and the electrolysis efficiency is improved.
Preferably, the first electrode 101 and the second electrode 102 are made of a titanium material, and the surface is provided with ruthenium iridium plating or platinum gold plating.
Referring to fig. 1 and 2, in an embodiment, the first electrode 101 may further include a first stem arm 1012, and the plurality of first branch arms 1011 are disposed on the first stem arm 1012 at intervals. Similarly, the second electrode 102 may further include a second stem arm 1022, and the plurality of second arms 1021 are arranged at intervals on the second stem arm 1022. Thus, the first arms 1011 and the second arms 1021 arranged at intervals can be staggered with each other.
Referring to FIG. 1, in one embodiment, the first arms 1011 are disposed on the same side of the first backbone arm 1012, and similarly, the second arms 1021 are disposed on the same side of the second backbone arm 1022. Also, the first electrode 101 and the second electrode 102 are disposed to intersect, so that the plurality of first arms 1011 and the plurality of second arms 1021 can be staggered.
Referring to fig. 2, in another embodiment, a plurality of first arms 1011 are disposed on both sides of the first backbone arm 1012, and similarly, a plurality of second arms 1021 are disposed on both sides of the second backbone arm 1022. Also, the first electrode 101 and the second electrode 102 are disposed to intersect, so that the plurality of first arms 1011 and the plurality of second arms 1021 can be staggered.
Preferably, the plurality of first leg arms 1011 may be bent toward the first stem arm 1012 to form a semi-circular arm. Similarly, the second plurality of arms 1021 may be curved toward the second spine arm 1022 to form a semi-circular arm. Thus, the plurality of first arms 1011 and the plurality of second arms 1021 can be staggered and wrapped around each other, thereby further increasing the effective electrode area of the first electrode 101 and the second electrode 102.
Referring to fig. 1 and 2, in one embodiment, the first electrode 101 and the second electrode 102 are provided with fixing holes 103, respectively. The fixing hole 103 is used for a wire (not shown) to pass through, and the wire can be further connected to a power supply unit. Thus, the first electrode 101 can be electrically connected to the positive electrode of the power feeding unit, and the second electrode 102 can be electrically connected to the negative electrode of the power feeding unit.
Referring to figure 3, in one embodiment, the sodium hypochlorite generator of the invention comprises an electrode assembly 1 and a cup 2 of any of the embodiments described above. Wherein, the cup body 2 is used for containing saline solution, and the electrode component 1 is arranged in the cup body 2.
Preferably, the electrode assembly 1 is disposed at a low water level of the cup body 2 so that the saline solution can completely soak the electrode assembly 1. Thus, chlorine gas (to be described later) generated by the electrolysis reaction can be sufficiently mixed with the salt solution to react, and the utilization rate of the electrode assembly can be improved.
Further, a power supply unit (not shown) is provided on the control unit 3, and a positive electrode and a negative electrode of the power supply unit are connected to the electrode assembly 1, respectively, so that the electrode assembly 1 forms an electrolysis circuit.
Thus, when the saline solution is injected into the cup body 2, chlorine ions in the solution are electrolyzed at the anode of the electrode assembly 1 to generate chlorine gas, and hydrogen ions are electrolyzed at the cathode of the electrode assembly 1 to generate hydrogen gas. Chlorine is dissolved in salt solution and reacts to generate sodium hypochlorite. The chemical reaction equation is as follows:
anode: 2Cl--2e→Cl2
Anode: 2H6++2e→H2
And (3) hydrolysis reaction: cl2+H2O→HClO+HCl
And (3) total reaction: NaCl + H2O=NaClO+H2
Preferably, the control unit 3 may control the power supply voltage, the power supply current and the power supply time of the power supply unit to generate sodium hypochlorite solutions of different concentrations.
The sodium hypochlorite generator can generate sodium hypochlorite by applying voltage and current to the electrode group to electrolyze a salt solution by the electrode group. And sodium hypochlorite solutions with different concentrations can be generated by controlling parameters of voltage and current applied to the electrode group so as to meet different use requirements of users.
Meanwhile, the sodium hypochlorite generator can be used for preparing sodium hypochlorite at any time without storing the sodium hypochlorite. And the sodium hypochlorite is safe to prepare, has no other unknown chemical impurity residues, and is harmless to human bodies. The sodium hypochlorite aqueous solution can meet the requirements of body disinfection, kitchen disinfection, vegetable and fruit disinfection, clothes disinfection and the like. Meanwhile, the sodium hypochlorite aqueous solution can also be used for disinfection of nonmetal houses and floors and spray disinfection and sterilization of household daily environments.
During the actual use of the generator, scale may be generated on the first electrode 101 and the second electrode 102, which affects the electrolysis efficiency. Further, the control unit 3 may periodically switch the positive electrode and the negative electrode of the power supply unit, and adjust the cathode-anode characteristics of the first electrode 101 and the second electrode 102, that is, the first electrode 101 is electrically connected to the negative electrode of the power supply unit, and the second electrode 102 is electrically connected to the positive electrode of the power supply unit. Thus, the scale formed on the first electrode 101 and the second electrode 102 automatically falls off and is washed away by the water flow. Therefore, the influence of the water scale on the electrolysis efficiency can be effectively relieved.
In one embodiment, the control unit 3 is connected to a control panel (not shown). The control panel can be used for interacting with a user, and the user can set parameters of power supply voltage, power supply current and power supply time through the control panel. The user can also manipulate the control unit 3 to switch the positive and negative poles of the power supply unit through the control panel.
In one embodiment, the cup body 2 may be provided with a water inlet 201 and a water outlet 202, so that the saline solution can be injected into the cup body 2 from the water inlet 201, and the sodium hypochlorite solution (to be described later) is poured out from the water outlet 201 after the sodium hypochlorite solution is generated. Of course, it is also possible to provide only one water inlet for both filling and pouring out the solution.
Preferably, a cap 203 may be provided on the water inlet 201 to open and close the water inlet 201 to prevent dust from entering the cup body 2.
Preferably, the cup body 2 may be provided with a handle 204 to facilitate access to the sodium hypochlorite generator.
It should be noted that the directions "front", "rear", "upper", "lower", and the like are provided for convenience of description, and do not necessarily correspond to the front, rear, upper, and lower in space in actual operation.
In the experiment, the cup body is set to be 2.3L, can contain saline solution 2.0L, and the electrode group selects spiral electrode, and single electrode area is 40cm2, and saline solution concentration is 0.5%, tests show that effective residual chlorine content and bactericidal effect see the following table:
Figure BDA0001947763480000061
through above-mentioned embodiment, we can conclude, common escherichia coli and staphylococcus aureus can effectively be killed to the hypochlorite generator, can effectively protect user's health safety, have fine practical value to the user.
In the description herein, reference to the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples" or the like means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
The above description is only for the specific embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive various changes or substitutions within the technical scope of the present invention, and these should be covered by the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.

Claims (10)

1. An electrode assembly comprising a first electrode and a second electrode; the first electrode and the second electrode are flat sheet structures;
the first electrode is communicated with the positive electrode of the power supply unit, and the second electrode is communicated with the negative electrode of the power supply unit;
the first electrode comprises a plurality of first support arms, and the second electrode comprises a plurality of second support arms; the first support arms and the second support arms are arranged in a staggered mode.
2. The electrode assembly of claim 1, wherein the first electrode further comprises a first stem arm, the plurality of first arms being spaced apart on the first stem arm;
the second electrode further comprises a second main arm, and the plurality of second support arms are arranged on the second main arm at intervals.
3. The electrode assembly of claim 2, wherein the first plurality of arms are disposed on a same side of the first backbone arm and the second plurality of arms are disposed on a same side of the second backbone arm; the first electrode and the second electrode are arranged in a crossing manner.
4. The electrode assembly of claim 2, wherein the first plurality of arms are disposed on opposite sides of the first backbone arm and the second plurality of arms are disposed on opposite sides of the second backbone arm; the first electrode and the second electrode are arranged in a crossing manner.
5. The electrode assembly of claim 4, wherein the plurality of first arms are bent toward the first backbone arm to form a semi-circular arm; the plurality of second arms are bent toward the second backbone arm to form a semi-circular arm.
6. The electrode assembly according to any one of claims 1 to 5, wherein the first electrode and the second electrode are respectively provided with fixing holes through which a lead and a fixing member pass.
7. The electrode assembly according to any one of claims 1 to 5, wherein the first electrode and the second electrode are made of a titanium material, and a surface is provided with ruthenium iridium plating or platinum gold plating.
8. A sodium hypochlorite generator comprising a cup, a power supply unit and an electrode assembly according to any one of claims 1 to 7; the cup body is used for containing saline solution, and the electrode assembly is arranged in the cup body;
the first electrode is communicated with the positive electrode of the power supply unit, and the second electrode is communicated with the negative electrode of the power supply unit, so that the electrode assembly forms an electrolysis loop.
9. A sodium hypochlorite generator as claimed in claim 8, further comprising a control unit, the power supply unit being connected to the control unit;
the control unit is configured to switch between the positive electrode and the negative electrode of the power supply unit, so that the first electrode is conducted with the negative electrode of the power supply unit, and the second electrode is conducted with the positive electrode of the power supply unit.
10. A sodium hypochlorite generator as claimed in claim 8 or claim 9 wherein the cup body is provided with a water outlet, a water inlet and a handle; the water inlet is provided with a cup cover, and the cup cover is used for opening and closing the water inlet.
CN201910041667.9A 2019-01-16 2019-01-16 Electrode assembly and sodium hypochlorite generator Pending CN111441065A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200812918A (en) * 2006-06-12 2008-03-16 Dolki Korea Ltd Portable manufacturing apparatus of sterilized isotonic saline solution
CN104047018A (en) * 2014-06-20 2014-09-17 深圳市好美水科技开发有限公司 Hydrogen-rich electrolysis method
TWM502689U (en) * 2015-02-17 2015-06-11 Jin Yuan Heng Entpr Co Ltd Generation apparatus for sodium hypochlorite disinfectant blanching water
TWM505932U (en) * 2015-04-10 2015-08-01 Jin Yuan Heng Entpr Co Ltd Sterilizing water/blanching water manufacturer
CN209602643U (en) * 2019-01-16 2019-11-08 芜湖美的厨卫电器制造有限公司 Electrode assembly and sodium hypochlorite generator

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200812918A (en) * 2006-06-12 2008-03-16 Dolki Korea Ltd Portable manufacturing apparatus of sterilized isotonic saline solution
CN104047018A (en) * 2014-06-20 2014-09-17 深圳市好美水科技开发有限公司 Hydrogen-rich electrolysis method
TWM502689U (en) * 2015-02-17 2015-06-11 Jin Yuan Heng Entpr Co Ltd Generation apparatus for sodium hypochlorite disinfectant blanching water
TWM505932U (en) * 2015-04-10 2015-08-01 Jin Yuan Heng Entpr Co Ltd Sterilizing water/blanching water manufacturer
CN209602643U (en) * 2019-01-16 2019-11-08 芜湖美的厨卫电器制造有限公司 Electrode assembly and sodium hypochlorite generator

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