Light high-strength sandwich plate and preparation method thereof
Technical Field
The invention relates to the technical field of composite boards, in particular to a light high-strength sandwich board and a preparation method thereof.
Background
The common light epoxy board is prepared by soaking glass cloth in hollow engineering plastic and then pressing. The light epoxy board adopting the method has the advantages that the hollow filler wall is thin, the compressive strength is not high, and the occupied volume of the board is larger, so that the bending strength and the bending modulus of the common light epoxy board are lower, and the hollow filler wall is more than that of the common light epoxy board which is used in the mobile phone protective case material with small forming size. For electronic products with high requirements on bending strength and compressive strength, the common light epoxy board cannot meet the corresponding requirements.
Disclosure of Invention
The invention aims to provide a light high-strength sandwich plate and a preparation method thereof, which have the advantages of high strength and light weight and solve the technical problem that the common light epoxy plate in the prior art has low bending strength and bending modulus so as to cause that the requirements of products with higher requirements cannot be met.
In order to solve the technical problems, the technical scheme provided by the invention is as follows: the utility model provides a light high strength sandwich board, includes the glass fiber layer and lays the fibrous layer on glass fiber layer two sides, the last epoxy compound that impregnates of glass fiber layer, it has hollow glass bead to fill in the epoxy compound, the fibrous layer that the epoxy compound covers two upper and lower surfaces of bonding layer is used for bonding the fibrous layer of glass as the adhesive linkage on the fibrous layer of glass.
According to the technical scheme, the carbon fiber layer has the characteristics of high strength and high temperature resistance, the carbon fiber layer covers the upper surface and the lower surface of the glass fiber layer, the glass fiber layer is effectively protected, the epoxy resin compound is used for bonding the carbon fiber layer and the glass fiber layer, the hollow glass beads are light in weight and small in specific gravity, and the sandwich plate is filled in the epoxy resin compound, so that the sandwich plate is lighter in weight; the sandwich plate has the advantages of light weight and high strength.
According to the light high-strength sandwich plate, the content of the hollow glass beads on the glass fiber layer accounts for 15-70% of the total weight of the glass fiber layer.
In the light high-strength sandwich plate, the density of the plate of the glass fiber layer is 0.5-1.5 g/cm3The thickness is 0.3 to 5.0 mm.
The epoxy resin compound comprises one or more of bisphenol A type novolac epoxy resin, o-cresol epoxy resin, phosphorus-containing epoxy resin or dicyclopentadiene epoxy resin.
In the light high-strength sandwich plate, the glass fiber layer is any one or a combination of unidirectional glass fiber yarn and glass fiber cloth.
In the light high-strength sandwich plate, the carbon fiber layers are arranged to be of a layered structure, and the number of the carbon fiber layers is 1-8.
In the light high-strength sandwich plate, the carbon fiber layer comprises any one or combination of carbon fiber unidirectional yarns and carbon fiber woven cloth.
In order to solve the above technical problems, another technical solution provided by the present invention is: a method for making a lightweight, high strength sandwich panel according to any of the above embodiments, the method comprising the steps of:
(1) preparing glue solution: uniformly mixing epoxy resin and a curing agent according to a certain mass ratio to form an epoxy resin glue solution, adding hollow glass beads accounting for 5-70% of the total weight into the glue solution, and fully dispersing the hollow glass beads into the glue solution;
(2) manufacturing an adhesive sheet: soaking glass fibers in the glue solution obtained in the step (1), and then baking to form a prepreg with the thickness of 0.1-0.3 mm;
(3) preparing a glass fiber light plate: laying a corresponding number of semi-cured bonding sheets in the step (2), and performing hot-pressing curing under high-temperature, high-pressure and vacuum conditions, wherein the temperature is 130-200 ℃, the pressure is 40-180 psi, and the vacuum degree under the vacuum condition is 20-60 torr, so as to form a fully-cured lightweight plate;
(4) laying a carbon fiber prepreg layer: laying carbon fiber prepreg layers in support areas on two sides of the glass fiber lightweight board;
(5) hot-press molding: and starting the hot press, carrying out secondary hot-pressing curing molding, and cooling to obtain the light high-strength carbon fiber and glass fiber epoxy resin composite sandwich plate, wherein the temperature of the secondary hot pressing is 130-200 ℃, the pressure is 40-180 psi, and the vacuum degree under the vacuum condition is 20-60 torr.
The beneficial effects obtained by the invention are as follows: the surface formed by the carbon fiber layer is compounded with the epoxy resin impregnated glass fiber layer containing the hollow glass beads, so that the obtained sandwich plate has lighter weight and higher strength, can be compounded with a thermoplastic material in a machining mode, and can be used as a structural member or a part of bearing parts of a tablet personal computer, a notebook computer, a high-end electronic game machine, a high-end luggage and the like.
Drawings
FIG. 1 is a schematic view of a layered structure of a sandwich panel according to the invention;
FIG. 2 is a schematic cross-sectional view of the sandwich panel of FIG. 1.
Description of reference numerals: 1 glass fiber layer and 2 carbon fiber layer.
Detailed Description
The invention is further described with reference to the following figures and detailed description.
Referring to fig. 1 and 2, the invention discloses a light high-strength sandwich plate, which comprises a glass fiber layer 1 and carbon fiber layers 2 laid on two surfaces of the glass fiber layer 1, wherein epoxy resin compounds are impregnated on the glass fiber layer 2, hollow glass beads are filled in the epoxy resin compounds, the hollow glass beads are dispersed in the epoxy resin compounds to play a role of reducing weight, and the epoxy resin compounds are covered on the glass fiber layer 1 to serve as bonding layers for bonding the carbon fiber layers 2 on the upper surface and the lower surface of the glass fiber layer 1, so that the carbon fiber layers 2 are firmly connected with the glass fiber layer 1.
In this embodiment, the content of the hollow glass beads in the glass fiber layer 1 is 15% to 70% of the total weight of the glass fiber layer 1. In other embodiments, the hollow glass microspheres are present in an amount of 30% to 50% by weight.
The density of the glass fiber layer 1 is 0.5-1.5 g/cm3The thickness is 0.3 to 5.0 mm. In other embodiments, the density of the glass fiber layer 1 may be 0.5-1.0 g/cm 3.
The epoxy resin compound comprises one or more of bisphenol A novolac epoxy resin, o-cresol epoxy resin, phosphorus-containing epoxy resin or dicyclopentadiene epoxy resin. Further, the glass fiber layer 1 is any one of unidirectional glass fiber yarn and glass fiber cloth or a combination thereof.
In the present embodiment, the carbon fiber layer 2 is provided as a layered structure, and the number of layers is 1 to 8. Further, the carbon fiber layer 2 includes any one of carbon fiber unidirectional yarn, carbon fiber woven cloth, or a combination thereof.
The invention also discloses a preparation method of the light high-strength sandwich plate, which comprises the following steps:
(1) preparing glue solution: uniformly mixing epoxy resin and a curing agent according to a certain mass ratio to form an epoxy resin glue solution, adding hollow glass beads accounting for 5-70% of the total weight into the glue solution, and fully dispersing the hollow glass beads into the glue solution;
(2) manufacturing an adhesive sheet: soaking glass fibers in the glue solution obtained in the step (1), and then baking to form a prepreg with the thickness of 0.1-0.3 mm;
(3) preparing a glass fiber light plate: laying a corresponding number of semi-cured bonding sheets in the step (2), and performing hot-pressing curing under high-temperature, high-pressure and vacuum conditions, wherein the temperature is 130-200 ℃, the pressure is 40-180 psi, and the vacuum degree under the vacuum condition is 20-60 torr, so as to form a fully-cured lightweight plate;
(4) laying a carbon fiber prepreg layer: laying carbon fiber prepreg layers in support areas on two sides of the glass fiber lightweight board;
(5) hot-press molding: and starting the hot press, carrying out secondary hot-pressing curing molding, and cooling to obtain the light high-strength carbon fiber and glass fiber epoxy resin composite sandwich plate, wherein the temperature of the secondary hot pressing is 130-200 ℃, the pressure is 40-180 psi, and the vacuum degree under the vacuum condition is 20-60 torr.
The invention is further illustrated by the following examples of the invention and comparative examples:
the first embodiment is as follows: the light high-strength sandwich plate with the thickness of 1.0mm prepared by the preparation method is used for testing the density, the bending strength and the bending modulus of the plate.
The first comparative example is as follows: pure light epoxy boards with the same thickness of 1.0mm are taken and tested for board density, bending strength and bending modulus in a comparison manner.
Comparative example two: and taking a common density epoxy glass fiber board with the same thickness of 1.0mm, and comparing and testing the density, the bending strength and the bending modulus of the board.
The test results of example one are compared with those of comparative examples one and two as follows:
table 1 comparison of performance tests between examples and comparative examples
Compared with a pure light epoxy plate, the light high-strength sandwich plate has the advantages that the strength is obviously increased, and the light high-strength sandwich plate can play a good role in supporting and fully protecting a tablet computer, a notebook computer, a high-end game machine or a high-end case.
Compared with the common density epoxy glass fiber board, the light high-strength sandwich board has the advantages of obviously reduced density, obviously increased strength and light weight and high strength.
In summary, the actual samples of the present invention are prepared according to the description and the drawings, and after a plurality of usage tests, the effect of the usage tests proves that the present invention can achieve the expected purpose, and the practical value is undoubted. The above-mentioned embodiments are only for convenience of illustration and not intended to limit the invention in any way, and those skilled in the art will be able to make equivalents of the features of the invention without departing from the technical scope of the invention.