CN111270445A - Manufacturing process of anti-aging water-based adhesive coating fabric - Google Patents

Manufacturing process of anti-aging water-based adhesive coating fabric Download PDF

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Publication number
CN111270445A
CN111270445A CN202010163492.1A CN202010163492A CN111270445A CN 111270445 A CN111270445 A CN 111270445A CN 202010163492 A CN202010163492 A CN 202010163492A CN 111270445 A CN111270445 A CN 111270445A
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fabric
water
manufacturing process
based adhesive
aging
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张小艳
刘惠林
韩毅
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Huamao Xiamen Special Material Co ltd
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Huamao Xiamen Special Material Co ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025Corona discharge or low temperature plasma
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/143Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethanes and other polycondensation or polyaddition products, e.g. aminoplast
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/06Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/066Silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/06Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/103Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear

Abstract

The invention discloses a manufacturing process of an anti-aging water-based adhesive coating fabric, which comprises the following steps: s1, water sprinkling, carrying out double-sided padding and water sprinkling treatment on the pretreated fabric, and then shaping and baking; s2, cleaning, namely etching the surface of the water repellent layer on the back surface of the fabric through a plasma technology to destroy the water repellent effect of the etched surface to obtain the front single-sided water repellent fabric; s3, gluing, preparing a glue stock, uniformly coating the glue stock on the reverse side of the fabric, and forming a continuous film on the reverse side of the fabric through baking and curing treatment; and S4, standing the fabric prepared in the step S3 for 24-48 h, and curing to obtain the finished fabric of the water-based adhesive coating. The water-based adhesive coating fabric manufactured by the process can resist the requirement of long-time taking under high-temperature and high-humidity environment, and has good high-temperature and high-humidity aging resistance, strong adhesive tape, water washing appearance and tearing strength.

Description

Manufacturing process of anti-aging water-based adhesive coating fabric
Technical Field
The invention relates to the technical field of textile fabric production, in particular to a manufacturing process of an anti-aging water-based adhesive coating fabric.
Background
Along with the process of international market integration, the high quality and low pollution of products can be improved to a certain height. Under the forms of joint attack of numerous scientific research units in China and continuous intervention of scientific and technological enterprises, various high-performance environment-friendly resins are bound to become mainstream products and finally replace solvent type products. Besides the environmental protection requirements, the textile garment fabric also needs to have more functional protective properties, so that the textile garment fabric can meet the dressing requirements of various severe environments during outdoor exercises, such as better moisture permeability, vapor permeability, down resistance, water pressure protection, wear resistance and the like. The water gel is water-based resin, belongs to a solvent-free environment-friendly material, mainly uses water as a carrier, and has no pollution to the environment, so that the water gel is considered to endow the fabric with better protective performance. However, the water-based adhesive has poor washing resistance, adhesion fastness and other functions, and the functions of the water-based adhesive and other functions applied to the fabric are not as good as those of the oil-based adhesive, so that the development of a manufacturing process of the water-based adhesive functional fabric with good functional application effect is required.
Disclosure of Invention
In view of the above problems, the present invention aims to provide a process for manufacturing an anti-aging water-based adhesive coated fabric, which can improve the aging performance of the manufactured water-based adhesive functional fabric in a high temperature and high humidity environment.
In order to achieve the purpose, the technical scheme adopted by the invention is as follows:
a manufacturing process of an anti-aging water-based adhesive coating fabric comprises the following steps:
and S1, water splashing, carrying out double-sided padding and water splashing treatment on the pretreated fabric, and then shaping and baking the fabric.
And S2, cleaning, namely etching the surface of the water repellent layer on the back surface of the fabric by using a plasma technology to destroy the water repellent effect of the etched surface, thereby obtaining the single-sided water repellent fabric on the front surface.
S3, gluing, preparing a glue stock, uniformly coating the glue stock on the reverse side of the fabric, and forming a continuous film on the reverse side of the fabric through baking and curing treatment.
And S4, standing the fabric prepared in the step S3 for 24-48 h, and curing to obtain the anti-aging water-based adhesive coating fabric.
Further, the water-splashing formula in the step S1 is: 0.5-3 g/L of penetrating agent, 90-140 g/L of water-sprinkling agent, 3-12 g/L of softening agent and 5-10 g/L of cross-linking agent.
Wherein the water-sprinkling agent comprises the following raw materials in percentage by weight: 50-80 g/L of fluorine-containing polymer dispersion liquid and 40-60 g/L of fluorine-containing acrylic ester copolymer dispersing agent.
The penetrant is a phosphate ester emulsion, the softener is modified organic silicon, and the crosslinking agent is isocyanate.
Further, in the step S1, the fabric subjected to the double-sided water sprinkling treatment is pre-baked at 110-120 ℃, and then is baked and shaped in a baking room at 150-180 ℃, wherein the baking speed is 15-30 m/min.
Further, in step S2, the plasma processing conditions are: the current is 3-6A, the power is 110-160 w, and the processing time is 90-120 s.
Further, the rubber material in the step S3 is prepared from the following raw materials in parts by mass: 100 parts of polyether type waterborne polyurethane water gel, 5-10 parts of waterborne organic silicon, 2-5 parts of isocyanate crosslinking agent and 1-2 parts of aziridine crosslinking agent.
Firstly, mixing polyether type waterborne polyurethane water gel, waterborne organic silicon, an isocyanate crosslinking agent and an aziridine crosslinking agent, mixing at the rotating speed of 400-800 RPM, sealing the mixed glue stock, and adjusting the glue stock to 10 RPM-9And (4) carrying out vacuum bubbling under the Kpa air pressure condition until bubbles with the diameter larger than 0.3cm in the sizing material are completely removed.
Further, in step S4, the ripening conditions of the fabric are: the temperature is 30-35 ℃, and the humidity is 65-85%.
The invention has the following beneficial effects: 1. the high-temperature-resistant, high-humidity-resistant and aging-resistant rubber has good high-temperature-resistant, high-humidity-resistant and aging-resistant performance, and can reach 5-grade standard EN12280-3-2002 when tested under the conditions of 70 ℃ for 14 days and 95% humidity; 2. the PU strip is 516rpm at 590 ℃, the wheel pressure of hot air is 1.1-1.4 kg/cm and 3.0kg/cm2,300mm/min) is more than or equal to 7N; 3. the washing appearance can meet the GB/T8629-2017,4N 10 times, A hanging airing 5-grade standard; 4. due to the addition of the water-based organic silicon, the tear strength of the fabric is improved, and the adhesive strength is ensured while the requirement of GB/T3917.1-2009 (warp/weft) is more than or equal to 7N is met.
Detailed Description
The present invention will be further described with reference to the following embodiments.
A manufacturing process of an anti-aging water-based adhesive coating fabric comprises the following steps:
step 1: selecting cloth (shown in table 1), preparing desizing for the code-tested gray cloth, controlling the pH value of desizing liquid to be 9-11.5, keeping the temperature of a desizing groove to be 85-95 ℃, and controlling the speed of the desizing machine to be 25-60/MIN, so that the size on the surface of the fiber is better dispersed, and the cleaning and the coloring performance avoidance are facilitated. Desizing formula conditions are as follows: 8-12g/L of NaOH, 8-15g/L of fatty alcohol polyglycol ether and 6-8g/L of fatty alcohol polyoxyethylene ether degreaser. And (3) desizing, and dyeing by an overflow or open width dyeing machine, wherein the dyeing temperature is 95-130 ℃, and the holding time is 30-45 min. And (3) taking the cloth dyed with the color OK, and baking the cloth in a baking room with a speed of 40-60M/MIN and a temperature of 150 (145-180) 9 so as to effectively dry the dyed sample.
Step 2: and (2) carrying out double-sided water splashing treatment on the dyed fabric to enable the surface to have a good waterproof effect, wherein the water splashing formula is shown in table 1, the fabric after water splashing is pre-dried at 120 ℃, and then the fabric is placed into a 9-section drying room at 150-180 ℃ for baking, and the baking speed is 15-30 m/min.
And step 3: the treated base fabric is divided into front and back surfaces, and the surface of the back surface is selected to be treated so as to improve the adhesion of deep processing and ensure the adhesion fastness. And etching the surface of the water repellent layer on the reverse side of the fabric by using a plasma technology to destroy the water repellent effect of the etched surface. The plasma processing current is 3-6A, the power is 110-160W, and the processing time is 90-120 s. The fabric is originally treated by double-sided water splashing, the single-sided water splashing performance is damaged by plasma treatment, and the next process is operated as soon as possible within 4 hours after the plasma treatment, so that the water splashing agent after the treatment is prevented from possibly generating copolymerization effect again and influencing the treatment effect. The plasma technology treatment aims to ensure that the fabric is easy to be better adhered with polyurethane rubber and enhance the adhesive force between the coating and the fabric.
And 4, step 4: the preparation of the sizing material selects a ceiling fan with best shape and few teeth (2-4 teeth), so that too fast air can not enter too much, a large amount of bubbles are generated, and the film forming property of the water gel is influenced. The glue mixing rotating speed is kept at about 400-800 RPM for uniform operation, the stability of the aqueous emulsion is guaranteed not to be damaged, and good film forming property is kept. Defoaming, the above sizing material is prepared well and sealed, vacuum foam pumping is adopted, and the conditions are as follows: air pressure 10-9KPA, the diameter of bubbles on the liquid surface cannot be larger than 0.3cm, bubbles in the sizing material are eliminated, and the viscosity is kept at 10000-70000 CPS.
And 5: one or more layers of waterborne polyurethane are uniformly coated on the plasma treatment surface of the fabric through a scraper, and a continuous film is formed on the surface of the fabric, so that the hand feeling, the appearance and the style of the fabric are improved.
Step 6: and (3) aging the fabric subjected to gluing after being placed for 24-28h, wherein the aging temperature is 30-35 ℃, and the humidity is 65-85%.
And 7: and baking the semi-finished fabric in a baking oven with the speed of 40-60M/MIN (120-150) by 9 sections at the planned speed, so that the hand feeling and the dimensional stability of the fabric are well guaranteed.
The water-based adhesive fabric prepared by the steps has good high-temperature-resistant, high-humidity-resistant and aging-resistant performance, can be subjected to heat sealing, has an excellent adhesion effect, and is durable and washable. The specific performance test results are shown in table 1:
Figure BDA0002406616520000031
Figure BDA0002406616520000041
table 1: results of Performance testing
As can be seen from the experimental results in Table 1, the water-based adhesive coating fabric prepared by the method has the advantages of high temperature resistance, high humidity resistance, strip sticking, and capability of meeting the effect of high tearing strength while ensuring the bonding strength.
While the invention has been particularly shown and described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (9)

1. The manufacturing process of the anti-aging water-based adhesive coating fabric is characterized by comprising the following steps of:
s1, water sprinkling, carrying out double-sided padding and water sprinkling treatment on the pretreated fabric, and then shaping and baking;
s2, cleaning, namely etching the surface of the water repellent layer on the back surface of the fabric through a plasma technology to destroy the water repellent effect of the etched surface to obtain the front single-sided water repellent fabric;
s3, gluing, preparing a glue stock, uniformly coating the glue stock on the reverse side of the fabric, and forming a continuous film on the reverse side of the fabric through baking and curing treatment;
and S4, standing the fabric prepared in the step S3 for 24-48 h, and curing to obtain the anti-aging water-based adhesive coating fabric.
2. The process for manufacturing the aging-resistant water-based adhesive coated fabric according to claim 1, wherein the water splashing formula in the step S1 is as follows: 0.5-3 g/L of penetrating agent, 90-140 g/L of water-sprinkling agent, 3-12 g/L of softening agent and 5-10 g/L of cross-linking agent.
3. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 2, wherein the water repellent agent comprises the following raw materials: 50-80 g/L of fluorine-containing polymer dispersion liquid and 40-60 g/L of fluorine-containing acrylic ester copolymer dispersing agent.
4. The manufacturing process of the anti-aging water-based adhesive coating fabric as claimed in claim 2, wherein the manufacturing process comprises the following steps: the penetrant is a phosphate ester emulsion, the softener is modified organic silicon, and the cross-linking agent is isocyanate.
5. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 1, wherein the manufacturing process comprises the following steps: in the step S1, the fabric subjected to the double-sided water splashing treatment is pre-baked at 110-120 ℃, and then is baked and shaped in a baking room at 150-180 ℃, wherein the baking speed is 15-30 m/min.
6. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 1, wherein the manufacturing process comprises the following steps: in step S2, the plasma processing conditions are: the current is 3-6A, the power is 110-160 w, and the processing time is 90-120 s.
7. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 1, wherein the manufacturing process comprises the following steps: the rubber material in the step S3 is prepared from the following raw materials in parts by mass: 100 parts of polyether type waterborne polyurethane water gel, 5-10 parts of waterborne organic silicon, 2-5 parts of isocyanate crosslinking agent and 1-2 parts of aziridine crosslinking agent.
8. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 7, wherein the manufacturing process comprises the following steps: the method for adjusting the rubber material comprises the following steps of mixing polyether type waterborne polyurethane water gel, waterborne organic silicon, an isocyanate crosslinking agent and an aziridine crosslinking agent, mixing the mixture at the rotating speed of 400-800 RPM, sealing the rubber material after mixing, and sealing the rubber material at 10 RPM-9And (4) carrying out vacuum bubbling under the Kpa air pressure condition until bubbles with the diameter larger than 0.3cm in the sizing material are completely removed.
9. The manufacturing process of the anti-aging water-based adhesive coated fabric as claimed in claim 1, wherein the manufacturing process comprises the following steps: in the step S4, the fabric ripening conditions are as follows: the temperature is 30-35 ℃, and the humidity is 65-85%.
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CN101538802A (en) * 2009-04-23 2009-09-23 朱守诚 High-performance fiber reinforced film composite material
CN101538800A (en) * 2009-04-23 2009-09-23 合肥市东方美捷分子材料技术有限公司 Thermoplastic resin coating film material and preparation method thereof
CN109137550A (en) * 2018-08-20 2019-01-04 福建省向兴纺织科技有限公司 A kind of PU coating fabric manufacture craft of high water pressure resistance height tearing
CN110126427A (en) * 2019-05-17 2019-08-16 福建省向兴纺织科技有限公司 A kind of low denier nylon facing material combination process

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