CN111250506A - High-calcium micro powder for detoxifying, reducing and recycling coal cinder - Google Patents

High-calcium micro powder for detoxifying, reducing and recycling coal cinder Download PDF

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Publication number
CN111250506A
CN111250506A CN201910890415.3A CN201910890415A CN111250506A CN 111250506 A CN111250506 A CN 111250506A CN 201910890415 A CN201910890415 A CN 201910890415A CN 111250506 A CN111250506 A CN 111250506A
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coal
calcium
slag
micro powder
coal cinder
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张志刚
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Inner Mongolia Ruijing Yongzhi Renewable Resources Co Ltd
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Inner Mongolia Ruijing Yongzhi Renewable Resources Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • A62D3/36Detoxification by using acid or alkaline reagents
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/78Recycling of wood or furniture waste

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a high-calcium micro powder for detoxifying, reducing and recycling coal cinder, which comprises the following components in percentage by mass of 78-92% of coal cinder, 2-5% of gypsum, 2-5% of lime, 2-5% of shale, 1-2% of saccharin and 2-5% of charcoal, wherein the total mass of all the components is 100%. The preparation process comprises adding coal cinder, gypsum, lime, shale, saccharin and charcoal into a pulverizer, pulverizing to particle size of less than or equal to 30mm, and making into high calcium micropowder. The invention solves the problems of removing toxicity of coal slag, reducing acidity or alkalinity and improving calcium content of products. The industrial waste coal slag treatment method has the advantages of low cost, high speed and wide application range, not only can geometrically reduce the waste coal slag treatment cost of industrial enterprises, but also can basically meet the urgent requirements of most sewage-discharging enterprises; the downstream products have various types and wide application prospect. Greatly changes the current situation of industrial waste coal slag treatment, improves the enterprise benefit and reduces the environmental pollution.

Description

High-calcium micro powder for detoxifying, reducing and recycling coal cinder
Technical Field
The invention relates to the technical field of coal cinder recycling, in particular to high-calcium micro powder for detoxifying, reducing and recycling coal cinder.
Background
The industrial coal slag is one of industrial solid wastes, and is mainly derived from coal ash produced by thermal power plants, industrial and civil boilers, slag and gas slag produced in the coal chemical industry process, and waste slag discharged by other equipment coal burning, which is also called slag. The main components of the coal cinder comprise silicon dioxide, aluminum oxide, ferric oxide, calcium oxide, magnesium oxide and the like. China is a big coal-producing country and takes coal as basic fuel for power production. In recent years, the energy industry in China is steadily developed, the power industry is rapidly developed, the emission amount of coal slag is increased sharply, the total amount of fly ash discharged by coal-fired thermal power plants every year is increased year by year, and great pressure is brought to national economic construction and ecological environment in China.
The fly ash is one of the current industrial waste residues with large discharge capacity in China, and the discharge amount of the fly ash in coal-fired power plants is increased year by year along with the development of the power industry. A large amount of fly ash can generate dust without treatment, thereby polluting the atmosphere; if discharged into a water system, the river can be silted, and toxic chemicals in the river can cause harm to human bodies and organisms. In addition, the coal slag is discarded and accumulated, so that the land is occupied, and the sulfur-containing gas is discharged to pollute the atmosphere and harm the environment. Therefore, the treatment and utilization problems of the fly ash draw wide attention, the comprehensive utilization of the coal slag, the changing of waste into valuable and the changing of harm into beneficial become an important technical and economic policy in the economic construction of China, and the fly ash is an important means for solving the contradiction between the environmental pollution and the resource shortage of the power production in China and is also one of the tasks for solving the problem of the coal production and reutilization.
The industrial coal slag is a misplaced resource, can be used as an admixture of cement, mortar and concrete, becomes a component of the cement and the concrete, and can also be used as a raw material for replacing clay to produce a raw material of cement clinker, manufacture sintered bricks, autoclaved aerated concrete, foamed concrete, hollow bricks, sintered or non-sintered ceramsite and pave roads; constructing dam bodies, and constructing backfills of ports, farmland depressed areas, coal mine subsidence areas and mines; the material may be used in separating floating bead, micro bead, fine iron powder, carbon, aluminum and other useful matter. Some of them can be used for preparing aluminium oxide or extracting rare metals of gallium and germanium, etc.
However, the components and sources of industrial coal slag are complex, toxic chemical substances in the industrial coal slag can cause harm to human bodies and organisms, particularly, slag and gas slag discharged from some coal chemical industries often contain stink and peculiar smell such as ammonia gas and the like, are hot to eyes and nose, cause people to cough and influence the health of people, are high in acidity or alkalinity, have larger influence on contact personnel and environment, are not treated and are difficult to directly recycle.
Disclosure of Invention
The invention aims to solve the technical problem of providing high-calcium micro powder for detoxifying, reducing and recycling coal cinder so as to solve the problems of detoxifying, reducing acidity or alkalinity and improving the calcium content of a product.
In order to solve the existing technical problems, the technical scheme adopted by the invention is as follows: a high calcium micro powder for detoxicating, reducing and recycling coal cinder comprises the following components in percentage by mass,
Figure RE-GDA0002463933810000021
the total mass of all the components is 100 percent.
Saccharin is commonly known as o-benzoylsulfonimide and is used as an auxiliary agent; charcoal and lime are used for removing the peculiar smell of the coal slag; lime and gypsum are used for reducing the acidity and alkalinity of the coal cinder; shale is used to increase the calcium content of the coal slag.
In general, the coal slag of the invention can adopt coal ash generated by thermal power plants, industrial and civil boilers, slag and gas slag generated by coal chemical industry processes and waste coal slag discharged by other equipment coal burning, and particularly, the coal slag of the invention is preferably one or a combination of the coal ash, the coal chemical industry slag and the coal chemical industry gas slag.
The invention also discloses a preparation method of the high-calcium micro powder, which comprises the following steps: adding coal cinder, gypsum, lime, shale, saccharin and charcoal into a grinder to be ground until the granularity is less than or equal to 30mm, and preparing the high-calcium micro powder.
In general, the pulverization particle size of the high-calcium fine powder can be selected as required, and in particular, the particle size of the high-calcium fine powder of the present invention is preferably 20 to 30 mm.
After the treatment, the industrial coal slag can be prepared into high calcium differential with different components, so that the industrial coal slag can be reduced or converted into various products required in production and life or main raw materials of important new materials, such as calcium-containing multifunctional paint, and the calcium-containing multifunctional paint is non-toxic, non-radiative, fire-resistant, acid-resistant, high-temperature-resistant, corrosion-resistant and waterproof; main materials of concrete special coagulants for highway engineering and building engineering; main materials for manufacturing special concrete anti-cracking and expansion mortar; preparing a main raw material of the solid foaming material; the main materials in sewage filtration systems; the main materials for treating saline-alkali soil and soil hardening materials; the main raw materials of the dry powder for the fire extinguishing equipment (different from the existing dry powder, the performance is better); a main coagulant material used for site treatment of debris flow and landslide disasters; reducing the domestic garbage to prepare an additive required by the high-efficiency compound fertilizer; the main material of the blue and green brick of the archaized building (the strength can reach 16 to 18 MPa, and the color can be adjusted); sponge city water permeable brick main material and the like.
Advantageous effects
The invention solves the problems of removing toxicity of coal slag, reducing acidity or alkalinity and improving calcium content of products. The industrial waste coal slag treatment method has the advantages of low cost, high speed and wide application range, not only can geometrically reduce the waste coal slag treatment cost of industrial enterprises, but also can basically meet the urgent requirements of most sewage-discharging enterprises; the downstream products have various types and wide application prospect. Greatly changes the current situation of industrial waste coal slag treatment, improves the enterprise benefit and reduces the environmental pollution.
Detailed Description
The present invention is further described in detail below with reference to specific examples so that the advantages and features of the present invention may be more readily understood by those skilled in the art, and thus the scope of the present invention is more clearly defined.
Example 1
The coal slag of the high-calcium micro powder in the embodiment adopts coal chemical industry slag of Zhongtian synthetic chemical industry Limited company, the coal chemical industry slag contains ammonia odor, stink, people have phenomena of hot eyes, nose choking and cough, the slag is alkaline, and the pH value is more than 13.
The high-calcium micro powder comprises the following components in percentage by mass:
Figure RE-GDA0002463933810000031
the total mass of all the components is 100 percent.
The preparation process of the high-calcium micro powder comprises the following steps: adding coal cinder, gypsum, lime, shale, saccharin and charcoal into a grinder to be ground until the granularity is less than or equal to 30mm, and preparing the high-calcium micro powder.
The prepared high-calcium micro powder ammonia gas and other peculiar smells disappear, no foul smell exists, eyes and nose are not hot, people have no cough, and the pH value is reduced to 7.
Example 2
The coal slag of the high-calcium micro powder in the embodiment adopts coal chemical industry slag and coal chemical industry gas slag of Zhongtian co-creation chemical industry Limited company, the coal chemical industry slag and the coal chemical industry gas slag both contain ammonia odor, stink, and people have the phenomena of eye irritation, nose irritation and cough, the coal chemical industry slag is alkaline, the pH value is larger than 13, the coal chemical industry gas slag is acidic, the pH value is smaller than 3, the coal ash adopts general boiler slag, is tasteless and is alkalescent.
The high-calcium micro powder comprises the following components in percentage by mass:
Figure RE-GDA0002463933810000032
Figure RE-GDA0002463933810000041
the total mass of all the components is 100 percent.
The preparation process of the high-calcium micro powder comprises the following steps: adding fly ash, coal chemical industry slag, coal chemical industry gas slag, gypsum, lime, shale, saccharin and charcoal into a grinder to be ground until the granularity is less than or equal to 30mm, and preparing the high-calcium micro powder.
The prepared high-calcium micro powder ammonia gas and other peculiar smells disappear, no foul smell exists, eyes and nose are not hot, people do not have cough, and the pH value reaches 7.
Example 3
The coal slag of the high-calcium micro powder in the embodiment adopts coal chemical industry slag and coal chemical industry gas slag of Zhongtian co-creation chemical industry Limited company, the coal chemical industry slag and the coal chemical industry gas slag both contain ammonia odor, stink, people have phenomena of eye irritation, nose irritation and cough, the coal chemical industry slag is alkaline, the PH value is larger than 13, the coal chemical industry gas slag is acidic, and the PH value is smaller than 3.
The high-calcium micro powder comprises the following components in percentage by mass:
Figure RE-GDA0002463933810000042
the total mass of all the components is 100 percent.
The preparation process of the high-calcium micro powder comprises the following steps: adding coal chemical industry slag, coal chemical industry gas slag, gypsum, lime, shale, saccharin and charcoal into a grinder to be ground until the granularity is less than or equal to 30mm, and preparing the high-calcium micro powder.
The prepared high-calcium micro powder ammonia gas and other peculiar smells disappear, no foul smell exists, eyes and nose are not hot, people do not have cough, and the pH value reaches 7.
The invention takes the industrial waste coal slag of the Zhongtian co-creation chemical group limited company as the raw material to establish a production line, the production of the antique big blue brick and the urban sponge water permeable brick is carried out, after the product is off-line, the product is sent to the national building material testing company for inspection, and the result shows that: the steam environment-friendly brick is a A-type decoration material, and is non-toxic and non-radiative.

Claims (4)

1. A high calcium micro powder for detoxication, reduction and reutilization of coal cinder comprises the following components in percentage by mass,
Figure RE-FDA0002463933800000011
the total mass of all the components is 100 percent.
2. The high-calcium micropowder according to claim 1, characterized in that: the coal slag is one or a combination of fly ash, coal chemical industry slag and coal chemical industry gas slag.
3. The method for producing a high-calcium fine powder according to claim 1 or 2, comprising the steps of: adding coal cinder, gypsum, lime, shale, saccharin and charcoal into a grinder to be ground until the granularity is less than or equal to 30mm, and preparing the high-calcium micro powder.
4. The method of claim 6, wherein: the granularity of the high-calcium micro powder is 20-30 mm.
CN201910890415.3A 2019-09-20 2019-09-20 High-calcium micro powder for detoxifying, reducing and recycling coal cinder Pending CN111250506A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60238609A (en) * 1984-05-11 1985-11-27 Mitsubishi Heavy Ind Ltd Ash treatment apparatus
CN1034355A (en) * 1988-07-27 1989-08-02 石家庄钢铁厂 Concrete made of slag aggregate
JPH081130A (en) * 1994-06-17 1996-01-09 Nippon Dia Com Kogyo Kk Industrial material and its manufacture
CN102731003A (en) * 2012-06-29 2012-10-17 酒钢(集团)宏达建材有限责任公司 Method for producing S95-grade slag micro-powder by using low-activity acidic slag
CN105271630A (en) * 2015-09-24 2016-01-27 葛洲坝中固科技股份有限公司 Energy-saving and environment-protection sludge modified material and preparation method thereof
CN105694510A (en) * 2016-03-21 2016-06-22 安徽以诺木塑板材科技有限公司 Charcoal dust added base material layer of environment-friendly wood-plastic floor
CN107377365A (en) * 2017-08-30 2017-11-24 梁溪区昊星工业设计工作室 A kind of industrial residue collection device

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60238609A (en) * 1984-05-11 1985-11-27 Mitsubishi Heavy Ind Ltd Ash treatment apparatus
CN1034355A (en) * 1988-07-27 1989-08-02 石家庄钢铁厂 Concrete made of slag aggregate
JPH081130A (en) * 1994-06-17 1996-01-09 Nippon Dia Com Kogyo Kk Industrial material and its manufacture
CN102731003A (en) * 2012-06-29 2012-10-17 酒钢(集团)宏达建材有限责任公司 Method for producing S95-grade slag micro-powder by using low-activity acidic slag
CN105271630A (en) * 2015-09-24 2016-01-27 葛洲坝中固科技股份有限公司 Energy-saving and environment-protection sludge modified material and preparation method thereof
CN105694510A (en) * 2016-03-21 2016-06-22 安徽以诺木塑板材科技有限公司 Charcoal dust added base material layer of environment-friendly wood-plastic floor
CN107377365A (en) * 2017-08-30 2017-11-24 梁溪区昊星工业设计工作室 A kind of industrial residue collection device

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Application publication date: 20200609