CN111235721A - Anti-electric arc fabric and preparation method thereof - Google Patents

Anti-electric arc fabric and preparation method thereof Download PDF

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Publication number
CN111235721A
CN111235721A CN201911405679.1A CN201911405679A CN111235721A CN 111235721 A CN111235721 A CN 111235721A CN 201911405679 A CN201911405679 A CN 201911405679A CN 111235721 A CN111235721 A CN 111235721A
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China
Prior art keywords
parts
fiber
fabric
arc
flame
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Pending
Application number
CN201911405679.1A
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Chinese (zh)
Inventor
邵新平
申亚欣
窦倩
王冻洋
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Ningbo Taipingniao Fashion Clothing Originality Research Institute Co ltd
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Ningbo Taipingniao Fashion Clothing Originality Research Institute Co ltd
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Priority to CN201911405679.1A priority Critical patent/CN111235721A/en
Publication of CN111235721A publication Critical patent/CN111235721A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/04Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons
    • D10B2321/042Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of halogenated hydrocarbons polymers of fluorinated hydrocarbons, e.g. polytetrafluoroethene [PTFE]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/06Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated alcohols, e.g. polyvinyl alcohol, or of their acetals or ketals
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Woven Fabrics (AREA)

Abstract

The invention relates to the technical field of textile, and discloses an arc-proof fabric, which comprises: warp yarn: the composition is characterized by comprising the following raw materials in parts by weight: 20-30 parts of modal fiber, 15-25 parts of nylon fiber, 13-20 parts of bamboo fiber, 10-15 parts of aramid fiber and 2-5 parts of conductive fiber; weft yarn: the composition is characterized by comprising the following raw materials in parts by weight: 25-35 parts of vinylon fiber, 20-30 parts of flame-retardant PTFE fiber, 15-25 parts of polysulfonamide fiber, 13-20 parts of bamboo charcoal fiber and 8-15 parts of polyurethane fiber. According to the invention, through various fiber content ratios, the synergistic effect among materials is exerted, the compatibility design is reasonable, on the basis of meeting the electric arc protection performance of the fabric, the fabric has excellent characteristics of soft hand feeling, wear resistance, antibacterial property, no melting and dripping when meeting fire and the like, the antistatic property of the fabric is long-acting, lasting and stable, the mechanical strength and toughness of the fabric are increased, the flame-retardant and antistatic effect is not influenced after multiple times of washing, the fabric can be worn more comfortably by a wearer, and the comprehensive performance is strong.

Description

Anti-electric arc fabric and preparation method thereof
Technical Field
The invention relates to the technical field of textiles, in particular to an arc-proof fabric and a preparation method thereof.
Background
The electric power industry is an important industry related to the national civilization, the safety is the first task of the electric power industry, and the personal safety is the personal benefits of related staff and the development of enterprises and even the social stability. An arc event is an unpredictable event. Thousands of workers are exposed to the risk of arcing every day, including not only electric power workers, but also workers in the petroleum, chemical industry, gas, water utility companies, oil refineries and other enterprises;
because the electric arc burns (electric arc burns) are always a big killer threatening the personal safety of electric power industry workers, particularly electric power line maintenance and constructors, and because the electric arc-proof clothes with excellent materials have permanent electric arc-proof characteristics, the electric arc-proof clothes cannot decline due to the prolonging of wearing time and the increasing of washing times, and can remarkably reduce or even effectively avoid the damage to human bodies when exposed to flashover, sudden electric arc attacks and high-temperature threats, thereby becoming an important protective article in an electric power system;
although many aramid fabrics with excellent performance are available, because aramid fibers are not high in comfort and air permeability and are easy to generate static electricity, how to further improve the flame retardance, comfort and antistatic property of the aramid fabrics is always a focus of research in the field of protective clothing.
Disclosure of Invention
The invention aims to provide an arc-proof fabric and a preparation method thereof, so as to prepare the arc-proof fabric which has high flame-retardant protection performance, high comfort and good comprehensive performance and can effectively prevent static electricity from being generated.
In order to achieve the purpose, the invention provides the following technical scheme: an arc-resistant fabric comprising:
warp yarn: the composition is characterized by comprising the following raw materials in parts by weight: 20-30 parts of modal fiber, 15-25 parts of nylon fiber, 13-20 parts of bamboo fiber, 10-15 parts of aramid fiber and 2-5 parts of conductive fiber;
weft yarn: the composition is characterized by comprising the following raw materials in parts by weight: 25-35 parts of vinylon fiber, 20-30 parts of flame-retardant PTFE fiber, 15-25 parts of polysulfonamide fiber, 13-20 parts of bamboo charcoal fiber and 8-15 parts of polyurethane fiber.
The preparation method of the fabric comprises the following steps;
step one, weighing warp yarn raw materials and weft yarn raw materials according to the weight parts;
step two, carrying out blowing, cotton carding, three-pass drawing, roving and spinning on the warp yarn raw material and the weft yarn raw material to obtain warp yarn and weft yarn through blending;
thirdly, weaving the warps and the wefts on a loom through spooling, warping, sizing and reeding processes to obtain grey cloth;
step four, preparing a flame-retardant antistatic agent;
s1, mixing ATP, antistatic modified liquid, hydrophilic soft finishing agent and deionized water, fully dissolving the mixture with a nonionic surfactant, and dropwise adding 5-10% NaOH solution until the pH value of the solution is 6-6.5;
s2, adding the cross-linking agent, the halogen salt and the dimethyl sulfoxide, stirring, diluting with water, and stirring at a high speed for emulsification for 1-1.5h to obtain the flame-retardant antistatic agent;
fifthly, placing the grey cloth into the flame-retardant antistatic agent for two-time soaking and two-time rolling, wherein the mangle ratio is 55-70%;
and step six, drying the obtained grey cloth → baking → washing → steam drying to obtain the finished fabric.
Preferably, in the second step, the density of the warp yarns is 190-200 yarns/10 cm, and the density of the weft yarns is 180-195/10 cm.
Preferably, in the third step, the bobbin winder adjusts the tension ring of the bobbin winder to 21-23 g; the warping adopts a high-speed warping machine, and the parameters are as follows: the number of the yarn is 500-; weaving adopts a rapier type loom to weave, and the parameters are as follows: the speed is 450 DEG and 500m/min, the opening time is 280-310 DEG, and the opening height is 25-30 mm.
Preferably, in the fourth step, the halogen salt is a mixture of three of lithium chloride, lithium bromide and calcium bromide.
Preferably, the following components: in the sixth step, the baking temperature is 90-100 ℃ and the baking time is 1-2min, the baking temperature is 185-195 ℃ and the baking time is 1.5-2 min.
The invention provides an arc-proof fabric and a preparation method thereof, and the arc-proof fabric has the beneficial effects that: according to the invention, through various fiber content ratios, the synergistic effect among materials is exerted, the compatibility design is reasonable, on the basis of meeting the electric arc protection performance of the fabric, the fabric has excellent characteristics of soft hand feeling, wear resistance, antibacterial property, no melting and dripping when meeting fire and the like, the antistatic property of the fabric is long-acting, lasting and stable, the mechanical strength and toughness of the fabric are increased, the flame-retardant and antistatic effect is not influenced after multiple times of washing, the fabric can be worn more comfortably by a wearer, and the comprehensive performance is strong.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Embodiment 1, the present invention provides a technical solution: an arc-resistant fabric comprising:
warp yarn: the composition is characterized by comprising the following raw materials in parts by weight: 30 parts of modal fiber, 25 parts of nylon fiber, 15 parts of bamboo fiber, 13 parts of aramid fiber and 3 parts of conductive fiber;
weft yarn: the composition is characterized by comprising the following raw materials in parts by weight: 28 parts of vinylon fiber, 25 parts of flame-retardant PTFE fiber, 20 parts of polysulfonamide fiber, 17 parts of bamboo charcoal fiber and 11 parts of polyurethane fiber.
Also discloses a preparation method of the anti-electric arc fabric, which comprises the following steps;
step one, weighing warp yarn raw materials and weft yarn raw materials according to the weight parts;
step two, carrying out blowing, cotton carding, three-pass drawing, roving and spinning on the warp yarn raw material and the weft yarn raw material to obtain warp yarn and weft yarn through blending;
the density of warp yarns is 190 yarns/10 cm, and the density of weft yarns is 195/10 cm;
thirdly, weaving the warps and the wefts on a loom through spooling, warping, sizing and reeding processes to obtain grey cloth;
the bobbin winder adjusts the tension ring of the bobbin winder to 22 g; the warping adopts a high-speed warping machine, and the parameters are as follows: the number of the yarn turns is 520m/min, and the yarn pressing pressure is 0.3 Mpa; weaving adopts a rapier type loom to weave, and the parameters are as follows: the speed is 500m/min, the opening time is 290 degrees, and the opening height is 28 mm.
Step four, preparing a flame-retardant antistatic agent;
s1, mixing ATP, antistatic modified liquid, hydrophilic soft finishing agent and deionized water, fully dissolving the mixture with a nonionic surfactant, and dropwise adding 8% NaOH solution until the pH value of the solution is 6.2;
s2, adding a cross-linking agent, three mixtures of lithium chloride, lithium bromide and calcium bromide as halogen salt and dimethyl sulfoxide, stirring, diluting with water, and emulsifying at high speed for 1.5h to obtain the flame-retardant antistatic agent;
placing the grey cloth into the flame-retardant antistatic agent for two-time soaking and two-time rolling, wherein the mangle rolling rate is 65%;
and step six, drying the obtained grey cloth → baking → washing → steam drying to obtain the finished fabric, wherein the baking temperature is 100 ℃ and the baking time is 2min, and the baking temperature is 195 ℃ and the baking time is 1.8 min.
Embodiment 2, the present invention provides a technical solution: an arc-resistant fabric comprising:
warp yarn: the composition is characterized by comprising the following raw materials in parts by weight: 28 parts of modal fiber, 23 parts of nylon fiber, 17 parts of bamboo fiber, 12 parts of aramid fiber and 4 parts of conductive fiber;
weft yarn: the composition is characterized by comprising the following raw materials in parts by weight: 28 parts of vinylon fiber, 21 parts of flame-retardant PTFE fiber, 22 parts of polysulfonamide fiber, 17 parts of bamboo charcoal fiber and 13 parts of polyurethane fiber.
Also discloses a preparation method of the anti-electric arc fabric, which is characterized by comprising the following steps: comprises the following steps;
step one, weighing warp yarn raw materials and weft yarn raw materials according to the weight parts;
step two, carrying out blowing, cotton carding, three-pass drawing, roving and spinning on the warp yarn raw material and the weft yarn raw material to obtain warp yarn and weft yarn through blending;
the density of warp yarns is 195 pieces/10 cm, and the density of weft yarns is 192/10 cm;
thirdly, weaving the warps and the wefts on a loom through spooling, warping, sizing and reeding processes to obtain grey cloth;
the bobbin winder adjusts the tension ring of the bobbin winder to 23 g; the warping adopts a high-speed warping machine, and the parameters are as follows: the number of the yarn turns is 530m/min, and the yarn pressing pressure is 0.25 MPa; weaving adopts a rapier type loom to weave, and the parameters are as follows: the speed is 480m/min, the opening time is 285 degrees, and the opening height is 27 mm.
Step four, preparing a flame-retardant antistatic agent;
s1, mixing ATP, antistatic modified liquid, hydrophilic soft finishing agent and deionized water, fully dissolving the mixture with a nonionic surfactant, and dropwise adding 7% NaOH solution until the pH value of the solution is 6.5;
s2, adding a cross-linking agent, three mixtures of lithium chloride, lithium bromide and calcium bromide as halogen salt and dimethyl sulfoxide, stirring, diluting with water, and emulsifying at high speed for 1.2h to obtain the flame-retardant antistatic agent;
placing the grey cloth into the flame-retardant antistatic agent, and soaking and rolling the grey cloth twice, wherein the mangle rolling rate is 60%;
and step six, drying the obtained grey cloth → baking → washing → steam drying to obtain the finished fabric, wherein the baking temperature is 98 ℃, the baking time is 1.4min, the baking temperature is 192 ℃, and the baking time is 1.6 min.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (6)

1. An arc-proof fabric, comprising:
warp yarn: the composition is characterized by comprising the following raw materials in parts by weight: 20-30 parts of modal fiber, 15-25 parts of nylon fiber, 13-20 parts of bamboo fiber, 10-15 parts of aramid fiber and 2-5 parts of conductive fiber;
weft yarn: the composition is characterized by comprising the following raw materials in parts by weight: 25-35 parts of vinylon fiber, 20-30 parts of flame-retardant PTFE fiber, 15-25 parts of polysulfonamide fiber, 13-20 parts of bamboo charcoal fiber and 8-15 parts of polyurethane fiber.
2. The method for preparing the arc-proof fabric according to claim 1, characterized in that: comprises the following steps;
step one, weighing warp yarn raw materials and weft yarn raw materials according to the weight parts;
step two, carrying out blowing, cotton carding, three-pass drawing, roving and spinning on the warp yarn raw material and the weft yarn raw material to obtain warp yarn and weft yarn through blending;
thirdly, weaving the warps and the wefts on a loom through spooling, warping, sizing and reeding processes to obtain grey cloth;
step four, preparing a flame-retardant antistatic agent;
s1, mixing ATP, antistatic modified liquid, hydrophilic soft finishing agent and deionized water, fully dissolving the mixture with a nonionic surfactant, and dropwise adding 5-10% NaOH solution until the pH value of the solution is 6-6.5;
s2, adding the cross-linking agent, the halogen salt and the dimethyl sulfoxide, stirring, diluting with water, and stirring at a high speed for emulsification for 1-1.5h to obtain the flame-retardant antistatic agent;
fifthly, placing the grey cloth into the flame-retardant antistatic agent for two-time soaking and two-time rolling, wherein the mangle ratio is 55-70%;
and step six, drying the obtained grey cloth → baking → washing → steam drying to obtain the finished fabric.
3. The method for preparing the arc-proof fabric according to claim 2, characterized in that: in the second step, the density of the warp yarns is 190-200 yarns/10 cm, and the density of the weft yarns is 180-195/10 cm.
4. The method for preparing the arc-proof fabric according to claim 2, characterized in that: in the third step, the bobbin winder adjusts the tension ring of the bobbin winder to 21-23 g; the warping adopts a high-speed warping machine, and the parameters are as follows: the number of the yarn is 500-; weaving adopts a rapier type loom to weave, and the parameters are as follows: the speed is 450 DEG and 500m/min, the opening time is 280-310 DEG, and the opening height is 25-30 mm.
5. The method for preparing the arc-proof fabric according to claim 2, characterized in that: in the fourth step, the halide salt is a mixture of lithium chloride, lithium bromide and calcium bromide.
6. The method for preparing the arc-proof fabric according to claim 2, characterized in that: in the sixth step, the baking temperature is 90-100 ℃ and the baking time is 1-2min, the baking temperature is 185-195 ℃ and the baking time is 1.5-2 min.
CN201911405679.1A 2019-12-31 2019-12-31 Anti-electric arc fabric and preparation method thereof Pending CN111235721A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911405679.1A CN111235721A (en) 2019-12-31 2019-12-31 Anti-electric arc fabric and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201911405679.1A CN111235721A (en) 2019-12-31 2019-12-31 Anti-electric arc fabric and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111235721A true CN111235721A (en) 2020-06-05

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113584780A (en) * 2021-08-05 2021-11-02 思迈(青岛)防护科技有限公司 Flame-retardant and molten metal impact-resistant fabric and preparation system and preparation method thereof
CN114541018A (en) * 2020-11-11 2022-05-27 中国石油化工股份有限公司 Durable comfortable flame-retardant fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114541018A (en) * 2020-11-11 2022-05-27 中国石油化工股份有限公司 Durable comfortable flame-retardant fabric
CN113584780A (en) * 2021-08-05 2021-11-02 思迈(青岛)防护科技有限公司 Flame-retardant and molten metal impact-resistant fabric and preparation system and preparation method thereof

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Application publication date: 20200605