CN111231430A - SPC-based 3D printing plate and preparation method thereof - Google Patents

SPC-based 3D printing plate and preparation method thereof Download PDF

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Publication number
CN111231430A
CN111231430A CN202010239260.XA CN202010239260A CN111231430A CN 111231430 A CN111231430 A CN 111231430A CN 202010239260 A CN202010239260 A CN 202010239260A CN 111231430 A CN111231430 A CN 111231430A
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China
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layer
spc
base material
pvc
printing
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CN202010239260.XA
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Chinese (zh)
Inventor
唐道远
邓梦德
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Anhui Sentai Wpc Technology Floor Co ltd
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Anhui Sentai Wpc Technology Floor Co ltd
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Priority to CN202010239260.XA priority Critical patent/CN111231430A/en
Priority to PCT/CN2020/084275 priority patent/WO2021196263A1/en
Publication of CN111231430A publication Critical patent/CN111231430A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/24All layers being polymeric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/536Hardness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/04Tiles for floors or walls

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to an SPC-based 3D printing plate, and belongs to the technical field of plate manufacturing. The plate comprises an SPC substrate layer, a 3D printing color layer and a UV protective layer; the base material layer comprises an SPC core layer and a background film layer which is compounded with the SPC core layer together through co-extrusion; the background film layer is also imprinted with textures in the form of wood grains, patterns or patterns; or the SPC base material layer comprises an SPC core layer and a background film layer which is laminated and compounded with the SPC core layer on line, and further comprises a resin concave-convex effect layer, wherein the resin concave-convex effect layer is arranged between the color layer and the UV protective layer. According to the invention, the background film layer which can be made of PVC is compounded on the SPC substrate layer, so that the prior art of' 1) cleaning a PVC board substrate is effectively replaced; 2) coating UV (ultraviolet) primer on the upper surface of the PVC board substrate; 3) drying and curing the UV primer; 4) coating white UV finish paint; 5) curing and drying the UV white paint; ' A series of operations simplifies the production process, thereby improving the production efficiency.

Description

SPC-based 3D printing plate and preparation method thereof
Technical Field
The invention relates to a printing plate, in particular to an SPC-based 3D printing plate and a preparation method thereof. Belongs to the technical field of SPC-based indoor floors.
Background
The process for producing SPC-based indoor floors in the prior art comprises the following steps: the extruder firstly extrudes the PVC-containing SPC base material, and then the PVC base film, the PVC color film, the PVC wear-resistant layer and the SPC base material are compounded through hot pressing by a four-roll calender. And the patterns are synchronously aligned in the pressing and pasting process, so that the effect of imitating wood textures is realized. However, this has the following disadvantages: (1) the production of the floor needs to reserve a PVC color film firstly, and the production period is too long due to the reservation of the PVC color film firstly; (2) the problem of overlong production cycle is solved by stock preparation usually, but the stock preparation leads to a large amount of color films which are not used up being accumulated in a warehouse; (3) when a PVC color film is preset, the PVC color film with a single certain pattern is restrained by the minimum amount of orders; (4) PVC color films having the customer's actual desired pattern cannot be customized and can only be selected from a limited number of PVC color films provided by upstream vendors.
The Chinese patent application with the application number of 201811628557.4 discloses a 3D effect PVC decorative plate and a 3D printing production method thereof. The manufacturing process of the plate is as follows: 1) cleaning a PVC board base material; 2) coating UV (ultraviolet) primer on the upper surface of the PVC board substrate; 3) drying and curing the UV primer; 4) coating white UV finish paint; 5) curing and drying the UV white paint; 6) printing patterns by a flat plate ink-jet printer; 7) coating UV wear-resistant paint; 8) curing and drying the UV wear-resistant paint; 9) printing a concave-convex effect layer by a flat ink-jet printer; then UV lamp irradiation curing; 10) coating UV finish paint; 11) and (5) curing and drying. The scheme subverts the traditional production mode that the color film needs to be ordered first, solves the problems of inventory, long production period, least order limitation and individual requirement at a stroke, and has remarkable effect on the production and management of SPC indoor floor production enterprises. However, the method is complicated in operation, not only the primer or the finish paint needs to be coated one time and another time, but also the coated primer or finish paint cannot be finished on one station, and the production efficiency is seriously influenced.
Disclosure of Invention
The invention aims to solve the technical problems and provides an SPC-based 3D printing plate. The plate has a hierarchical structure different from any plate in the prior art, and the specific hierarchical structure ensures that the plate of the invention has the characteristic of high production efficiency on the basis of keeping the performance characteristics of the original plate.
The technical scheme for solving the problems is as follows:
an SPC based 3D printed panel, the panel comprising an SPC substrate layer, a colour layer presented on the SPC substrate layer by 3D printing and a UV protective layer overlying the colour layer; the base material layer comprises an SPC core layer and a background film layer which is compounded with the SPC core layer through co-extrusion; the background film layer is also imprinted with textures in the form of wood grains, patterns or patterns;
or the SPC base material layer comprises an SPC core layer and a background film layer which is compounded with the SPC core layer together through online laminating, and further comprises a resin concave-convex effect layer, wherein the resin concave-convex effect layer is arranged between the color layer and the UV protective layer.
In the technical scheme of the invention, the background film layer which can be made of PVC is compounded on the SPC substrate layer, so that the prior art that 1) the PVC board substrate is cleaned is effectively replaced; 2) coating UV (ultraviolet) primer on the upper surface of the PVC board substrate; 3) drying and curing the UV primer; 4) coating white UV finish paint; 5) curing and drying the UV white paint; ' A series of operations simplifies the production process, thereby improving the production efficiency.
In the technical scheme of the invention, the operation of firstly engraving and then printing the concave-convex effect layer is also subversively provided; based on the idea, a background film layer can be attached to the core layer, which is equivalent to the integration effect of steps 2) to 5) in 201811628557.4 Chinese invention patent, and the background film can be directly engraved through a printing roller, which is equivalent to the completion of steps 7) to 9), and then the concave-convex effect layer is printed through a flat ink-jet printer, which is equivalent to the completion of step 6); and finally, a UV protective layer is coated to effectively protect the printed concave-convex effect layer.
In the technical scheme of the invention, as the order of engraving and printing is inverted compared with the prior art, the UV protective layer is equivalent to simultaneously completing the steps 7) -8) and the steps 10) -11). Thus, the invention greatly shortens the process and greatly improves the operability of the process. In the prior art, since the pattern is printed firstly and then the pattern is patterned (the flat ink-jet printer prints the concave-convex effect layer), the pattern needs to be provided with a carrier, and the carrier can be a PVC white film or a paint layer, such as the integrated effect of step 2) to step 5) in the Chinese invention patent of 201811628557.4; however, in the present invention, the background film layer corresponds to the above-mentioned carrier, and in order to improve the production efficiency, the carrier is not attached by gluing or painted by painting; the PVC material is extruded on the surface of the SPC core layer through a co-extrusion technology, so that the controllability is good, the production efficiency is high, and the defects that the surface of a background film layer made of the PVC material extruded through co-extrusion is very smooth, the effect of directly printing patterns is not good, and even double images and other problems can occur; in the prior art, when the problem of poor effect of printing patterns (in the form of wood grains, patterns or textures of patterns) is solved, a layer of compatilizer is usually coated on the surface of a carrier in a rolling way, so that the problem can be relieved to a certain extent, but the problem cannot be solved effectively.
When the problems are solved, the method of exchanging the sequence of the printing pattern layer and the printing concave-convex effect layer is adopted, and the printing concave-convex effect layer is replaced by the rolling concave-convex effect layer on the background film layer made of PVC material; by doing so, on one hand, the problem of poor effect of directly printing the patterns is solved, because the roller engraving of the concave-convex effect layer (displaying the wood grains or the textures of patterns or other patterns) is firstly carried out, so that the surface of the background film layer made of the PVC material is not smooth any more; on the other hand, the method effectively shortens the working procedure, directly converts the operation required to be carried out on the flat ink-jet printer into the operation of carrying out on-line roll engraving after being extruded from the extruder, so that the process becomes simple and the controllability is improved; moreover, the 'inversion' mode also has obvious influence on the subsequent process steps, so that the process is further simplified, as disclosed in the Chinese invention patent of the prior art 201811628557.4, steps 2-5 and steps 10-11 are both coated with UV paint and then cured, namely, the prior art needs to process on two stations, and the 'inversion' mode of the invention omits the operation equivalent to steps 2-5 because the concave-convex effect layer is directly engraved on the background film layer, so that the painting and curing process only needs to be carried out on one station, which is equivalent to combining the original steps 7) -8) and steps 10) -11) into a whole, thereby forming the wear-resistant layer, namely the UV protective layer, of the invention together; also, with the method of the present invention, a simple roll-engraving machine can be used to replace expensive high-precision flat ink-jet printers for "printing a relief effect layer", significantly reducing production costs.
In order to achieve better wear-resisting and protecting effects, the wear-resisting layer is upgraded on the basis of one surface of one bottom in the prior art, for example, two surfaces of five bottoms, so that a remarkable protecting effect is achieved.
However, the 3D visual effect of the invention is slightly different from the prior art, the principle of the 3D visual effect of the invention is as same as that of watching small insects in amber, the surface of the product is flat and smooth, but the stereoscopic visual effect of the product can be intuitively felt; however, in the product produced by the prior art through a complex process, the surface of the product is concave-convex because the process of printing the concave-convex effect layer is carried out later, and the 3D stereoscopic effect is more direct, but the overall 3D visual effect is slightly uncoordinated because the pattern layer in the product is planar.
More importantly, in order to achieve the effect of synchronous registration, the requirement for printing a concave-convex effect layer by a flat ink-jet printer in the prior art is very strict, when the concave-convex effect is generated by impact, the original pattern needs to be strictly contrasted, the left-right deviation and/or the front-back deviation which are 1mm or smaller cannot be generated, and once the concave-convex effect and the pattern are not matched, the 3D visual effect is seriously responded; therefore, special equipment is needed, and tens of millions of investment is needed. In the invention, because the carving is carried out firstly and then the color deposition (printing) is carried out, at the moment, because the carving is carried out firstly, the effects of depth, brightness and the like are firstly generated, and the stereoscopic vision effect can be shown even if the same color is adopted; the principle of the snow is that generally, different places in the same area have different ground surfaces, after the snow falls indifferently, due to the reasons of angle light and the like, the snow in some places looks bright, and the snow in some places looks dark, and even gray. Similarly, when the invention performs the printing based on this principle after the engraving, it is not necessary to perform the high-precision registration of the flower (different colors are printed on different portions), and the 3D visual effect unique to the invention can be realized only by performing the printing without distinction. Of course, different colors are printed on different parts accurately by adopting a plurality of colors, so that a better 3D visual effect of the invention can be embodied.
Preferably, the color of the background film layer is white or light color with covering property.
Preferably, the material of the background film layer is PVC.
Another object of the present invention is to provide a method for preparing an SPC-based 3D printing plate as described above.
A preparation method of an SPC-based 3D printing plate comprises the following steps:
a. adding the raw materials and the additives for forming the SPC core layer into a main extruder, melting the raw materials and the additives for forming the core layer through the main extruder, extruding the melted raw materials and the additives into a main runner of a mold, and extruding the melted raw materials and the additives from a die lip of the mold to form the core layer made of the SPC stone-plastic material;
b. adding a PVC raw material and an additive thereof which form a background film layer into an auxiliary extruder, melting the PVC raw material and the additive thereof which form the background film layer through the auxiliary extruder, extruding the melted PVC raw material and the additive thereof into an auxiliary flow channel of a mold, diffusing the melted PVC raw material and the additive thereof in a co-extrusion casting space of the mold after passing through the auxiliary flow channel, coating the core layer prepared in the step a, curing and shaping the core layer through the heat exchange action of a cooling flow channel plate of the mold, and finally extruding the core layer from a die orifice of the mold to obtain a precursor structure of an SPC substrate layer;
c. the precursor structure of the SPC base material layer is engraved with textures in the form of wood grains, patterns or patterns under the action of an embossing roller to obtain the SPC base material layer;
d. inputting the substrate layer into online 3D printing equipment, and printing colors corresponding to textures in the form of wood grains, patterns or patterns on the SPC substrate layer to obtain an intermediate product;
e. and sequentially coating UV primer and UV finishing paint on the intermediate product, and respectively carrying out photocuring to form a UV protective layer.
In the technical scheme of the invention, because the raw material of the SPC stone-plastic base material and the PVC raw material used as the background film layer have highly similar physicochemical properties, the raw materials have good compound property after co-extrusion, and have firm connecting force without using an adhesive and by direct co-extrusion.
Preferably, the UV primer is brushed for 3-6 times, and the UV finishing paint is brushed for 1-3 times.
Preferably, the UV protection layer in step e is formed by using a UV curable coating containing silica and/or alumina, and the amount of silica and/or alumina added is controlled to be 1 to 10wt% of the mass of the UV curable coating.
In the technical scheme of the invention, the addition of the silicon dioxide and/or the aluminum oxide can obviously improve the hardness, the wear resistance and the burning resistance of the UV protective layer.
Preferably, in the above technical solution of the present invention, the step b is changed to: and (c) unwinding the PVC film forming the background film layer and the core layer of the SPC stone-plastic material obtained in the step a, and performing online rolling compounding to obtain the precursor structure of the SPC base material layer.
Preferably, in the above technical solution of the present invention, the step b is changed to: c, unwinding the PVC film forming the background film layer, and compounding the PVC film with the core layer of the SPC stone-plastic material obtained in the step a through online rolling to obtain an SPC base material layer;
changing the step c into the following steps: inputting the SPC base material layer obtained in the step b into a pattern printing area of 3D online printing equipment, and printing out planar wood grains, patterns or patterns on the SPC base material layer to obtain an intermediate product I;
changing the step d into the following steps: inputting the intermediate product I obtained in the step c into a concave-convex effect forming area of 3D online printing equipment, and printing a concave-convex effect layer to obtain an intermediate product II;
changing the step e into the following steps: and d, coating a UV primer and a UV finish on the intermediate product II obtained in the step d, and respectively carrying out photocuring to form a UV protective layer.
In conclusion, the invention has the following beneficial effects:
1. the invention discloses the operation of carving patterns and then printing, wherein the substrate layer with the background film layer is prepared by a co-extrusion method, then the carving patterns are carried out, then the printing is carried out, and finally the UV protective layer is coated, so that compared with the prior art, the invention greatly simplifies the production process, thereby greatly improving the production efficiency;
2. the product prepared by the method has the advantage of good 3D visual effect;
3. the UV protective layer of the invention is also added with some additives, such as silicon dioxide, aluminum oxide and the like; the wear resistance and burning resistance of the UV protective layer can be obviously improved. The additive is controlled to be 1-10 wt%, and the additive is uniformly dispersed in the UV photocureable coating through a high-speed dispersant when in use.
Drawings
FIG. 1 is a schematic view of the mold construction of the present invention;
FIG. 2 is a schematic view showing a cross-sectional structure of a co-extrusion casting space in the mold of the present invention;
FIG. 3 is a table showing the results of the adhesive strength and the degree of peel in dipping of a product according to an embodiment of the present invention.
In the figure, 10-main runner, 20-die lip, 30-auxiliary runner, 40-co-extrusion casting space, 50-cooling runner plate and 60-die orifice.
Detailed Description
The invention is further explained below with reference to the drawings.
This detailed description is to be construed as illustrative only and is not limiting, since any changes made by those skilled in the art after reading the present specification will be protected by the patent laws within the scope of the appended claims.
Example one
An SPC based 3D printed panel comprising a stone-plastic (SPC) substrate layer, a colour layer presented on the stone-plastic (SPC) substrate layer by 3D printing and a UV protective layer overlying the colour layer; the Stone Plastic (SPC) substrate layer comprises a Stone Plastic (SPC) core layer and a background film layer compounded with the Stone Plastic (SPC) core layer; the background film layer is made of PVC; the background film layer is also embossed with a wood grain texture. The color of the background film layer is white with covering property.
Referring to fig. 1 and 2, a method for preparing an SPC-based 3D printing plate includes the steps of:
a. adding raw materials and additives for forming a Stone Plastic (SPC) core layer into a main extruder, melting the raw materials and the additives for forming the core layer through the main extruder, extruding the melted raw materials and the additives into a main runner 10 of a mold, and extruding the melted raw materials and the additives from a die lip 20 of the mold to form the core layer made of the Stone Plastic (SPC);
b. adding a PVC raw material and an additive thereof which form the background film layer into an auxiliary extruder, melting the PVC raw material and the additive thereof which form the background film layer through the auxiliary extruder, extruding the melted PVC raw material and the additive thereof into an auxiliary runner 30 of a mold, diffusing the melted PVC raw material and the additive thereof in a co-extrusion casting space 40 of the mold after passing through the auxiliary runner 30, coating the core layer prepared in the step a, solidifying and shaping the core layer through the heat exchange action of a cooling runner plate 50 of the mold, and finally extruding the core layer from a mold opening 60 of the mold to obtain a precursor structure of the SPC substrate layer;
c. carving wood grains on the precursor structure of the SPC base material layer under the action of a knurling roller to obtain the SPC base material layer;
d. inputting the SPC base material layer into online 3D printing equipment, and printing a color corresponding to wood grains on the SPC base material layer to obtain an intermediate product;
e. performing primary coating on the intermediate product for 5 times, then performing photocuring, then performing surface coating for 2 times, and performing photocuring to form a UV protective layer; the UV protective layer is formed by using a UV light curing coating containing silicon dioxide and aluminum oxide, and the total adding amount of the silicon dioxide and the aluminum oxide is controlled to be 5wt% of the mass of the UV light curing coating.
Example two
The difference from the first embodiment is that: changing the step b into the following steps: and (c) unwinding the PVC film forming the background film layer and the core layer of the SPC stone-plastic material obtained in the step a, and performing online rolling compounding to obtain the precursor structure of the SPC base material layer. In this example, the PVC film is a preformed film; in the first embodiment, the PVC film is formed by co-extruding the PVC material with the core layer formed of the Stone Plastic (SPC) material through an extruder.
EXAMPLE III
The difference from the first embodiment is that: changing the step b into the following steps: c, unwinding the PVC film forming the background film layer, and compounding the PVC film with the core layer of the SPC stone-plastic material obtained in the step a through online rolling to obtain an SPC base material layer;
changing the step c into the following steps: inputting the SPC base material layer obtained in the step b into a pattern printing area of 3D online printing equipment, and printing out planar wood grains, patterns or patterns on the SPC base material layer to obtain an intermediate product I;
changing the step d into the following steps: inputting the intermediate product I obtained in the step c into a concave-convex effect forming area of 3D online printing equipment, and printing a concave-convex effect layer to obtain an intermediate product II;
changing the step e into the following steps: and d, coating a UV primer and a UV finish on the intermediate product II obtained in the step d, and respectively carrying out photocuring to form a UV protective layer.
The bonding strength and the degree of impregnation peeling of the product of the first example were tested according to the relevant contents of GB/T17657-2013 physicochemical property test methods for artificial boards and veneered artificial boards and GB/T18103-20136.3.2 solid wood composite floors, and the results are shown in FIG. 3.

Claims (8)

1. The utility model provides a panel is printed to SPC base 3D which characterized in that: the panel comprises an SPC base material layer, a color layer displayed on the SPC base material layer through 3D printing and a UV protection layer covered on the color layer;
the SPC base material layer comprises an SPC core layer and a background film layer which is compounded with the SPC core layer together through co-extrusion, and textures in the form of wood grains, patterns or patterns are also stamped on the background film layer;
or the SPC base material layer comprises an SPC core layer and a background film layer which is compounded with the SPC core layer together through online laminating, and further comprises a resin concave-convex effect layer, wherein the resin concave-convex effect layer is arranged between the color layer and the UV protective layer.
2. An SPC based 3D printed board according to claim 1, characterized in that: the color of the background film layer is white or light color with covering performance.
3. An SPC based 3D printing plate according to claim 1 or 2, characterized in that: the background film layer is made of PVC.
4. The method for preparing an SPC based 3D printed board according to claim 1, comprising the steps of:
a. adding the raw materials and the additives for forming the SPC core layer into a main extruder, melting the raw materials and the additives for forming the core layer through the main extruder, extruding the melted raw materials and the additives into a main runner (10) of a mold, and extruding the melted raw materials and the additives from a die lip (20) of the mold to form the core layer made of the SPC stone-plastic material;
b. adding a PVC raw material and an additive thereof which form a background film layer into an auxiliary extruder, melting the PVC raw material and the additive thereof which form the background film layer through the auxiliary extruder, extruding the melted PVC raw material and the additive thereof into an auxiliary runner (30) of a die, diffusing the melted PVC raw material and the additive thereof in a co-extrusion casting space (40) of the die after passing through the auxiliary runner (30), coating the core layer prepared in the step a, curing and shaping the core layer through the heat exchange action of a cooling runner plate (50) of the die, and finally extruding the core layer from a die orifice (60) of the die to obtain a precursor structure of an SPC substrate layer;
c. the precursor structure of the SPC base material layer is carved with textures in the form of wood grains, patterns or patterns under the action of a knurling roller to obtain the SPC base material layer;
d. inputting the SPC substrate layer into 3D online printing equipment, and printing colors corresponding to textures in the form of wood grains, patterns or patterns on the SPC substrate layer to obtain an intermediate product;
e. and sequentially coating UV primer and UV finishing paint on the intermediate product, and respectively carrying out photocuring to form a UV protective layer.
5. The method for preparing an SPC based 3D printed plate according to claim 4, wherein the method comprises the following steps: and e, brushing the UV primer for 3-6 times, and brushing the UV finish paint for 1-3 times.
6. The method for preparing an SPC based 3D printed plate according to claim 4, wherein the method comprises the following steps: and e, forming the UV protective layer by using a UV photocuring coating containing silicon dioxide and/or aluminum oxide, wherein the adding amount of the silicon dioxide and/or aluminum oxide is controlled to be 1-10 wt% of the mass of the UV photocuring coating.
7. The method for preparing an SPC based 3D printed plate according to claim 4, wherein the method comprises the following steps: changing the step b into the following steps: and (c) unwinding the PVC film forming the background film layer and the core layer of the SPC stone-plastic material obtained in the step a, and performing online rolling compounding to obtain the precursor structure of the SPC base material layer.
8. The method for preparing an SPC based 3D printed plate according to claim 4, wherein the method comprises the following steps: changing the step b into the following steps: c, unwinding the PVC film forming the background film layer, and compounding the PVC film with the core layer of the SPC stone-plastic material obtained in the step a through online rolling to obtain an SPC base material layer;
changing the step c into the following steps: inputting the SPC base material layer obtained in the step b into a pattern printing area of 3D online printing equipment, and printing out planar wood grains, patterns or patterns on the SPC base material layer to obtain an intermediate product I;
changing the step d into the following steps: inputting the intermediate product I obtained in the step c into a concave-convex effect forming area of 3D online printing equipment, and printing a concave-convex effect layer to obtain an intermediate product II;
changing the step e into the following steps: and d, coating a UV primer and a UV finish on the intermediate product II obtained in the step d, and respectively carrying out photocuring to form a UV protective layer.
CN202010239260.XA 2020-03-30 2020-03-30 SPC-based 3D printing plate and preparation method thereof Pending CN111231430A (en)

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PCT/CN2020/084275 WO2021196263A1 (en) 2020-03-30 2020-04-28 Spc-based 3d printed plate and preparation method therefor

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