CN111205522A - Rubber coating composition for steel wire carcass cords of all-steel radial tires - Google Patents

Rubber coating composition for steel wire carcass cords of all-steel radial tires Download PDF

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Publication number
CN111205522A
CN111205522A CN202010109986.1A CN202010109986A CN111205522A CN 111205522 A CN111205522 A CN 111205522A CN 202010109986 A CN202010109986 A CN 202010109986A CN 111205522 A CN111205522 A CN 111205522A
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CN
China
Prior art keywords
parts
carbon black
rubber
steel
coating composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010109986.1A
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Chinese (zh)
Inventor
王�锋
李小龙
陈建平
陶晓
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Linglong Tire Co ltd
Original Assignee
Hubei Linglong Tire Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Linglong Tire Co ltd filed Critical Hubei Linglong Tire Co ltd
Priority to CN202010109986.1A priority Critical patent/CN111205522A/en
Publication of CN111205522A publication Critical patent/CN111205522A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to a rubber coating composition for steel wire carcass cords of an all-steel radial tire. The composition comprises the following raw material components in parts by weight: 70-90 parts of cis-1, 4-polyisoprene, 20-60 parts of epoxidized natural rubber ENR, 0.5-3 parts of terpene resin, 10-20 parts of silicon-aluminum carbon black, 5-10 parts of carbon black, 10-30 parts of white carbon black, 1-3 parts of cobalt salt and 0.8-1.2 parts of accelerator NS. According to the invention, the white carbon black, the epoxidized natural rubber ENR, the white carbon black and the cobalt salt are matched, so that the adhesive property of the cord thread and the rubber is improved while the performance of the rubber material is satisfied. The terpene resin can improve the adhesive force and improve the mechanical property and the aging resistance of the rubber bonding layer.

Description

Rubber coating composition for steel wire carcass cords of all-steel radial tires
Technical Field
The invention relates to a rubber coating composition for steel wire carcass cords of an all-steel radial tire.
Background
The formula of the rubber coating for the tire body cord is always a key factor influencing the performance of the all-steel radial tire, and generally needs to meet the characteristics of high strength, high adhesiveness, low heat generation and the like. With the increasing demands of the automotive industry for high speed, long distance, overload, etc., the functional demand for cord coating formulations has increased further.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides a rubber coating composition for steel wire carcass cords of all-steel radial tires.
The rubber coating composition for the steel wire carcass cord of the all-steel radial tire comprises the following raw material components in parts by weight: 70-90 parts of cis-1, 4-polyisoprene, 20-60 parts of epoxidized natural rubber ENR, 0.5-3 parts of terpene resin, 10-20 parts of silicon-aluminum carbon black, 5-10 parts of carbon black, 10-30 parts of white carbon black, 1-3 parts of cobalt salt and 0.8-1.2 parts of accelerator NS.
Further, the cobalt salt includes: 0.1-0.5 part of cobalt boroacylate and 1-2.5 parts of cobalt naphthenate.
Has the advantages that:
according to the invention, the white carbon black, the epoxidized natural rubber ENR, the white carbon black and the cobalt salt are matched, so that the adhesive property of the cord thread and the rubber is improved while the performance of the rubber material is satisfied. The terpene resin can improve the adhesive force and improve the mechanical property and the aging resistance of the rubber bonding layer.
Detailed Description
Example 1
The rubber coating composition for the steel wire carcass cord of the all-steel radial tire comprises the following raw material components in parts by weight: 90 parts of cis-1, 4-polyisoprene, 20 parts of epoxidized natural rubber ENR, 0.5 part of terpene resin, 10 parts of silicon-aluminum carbon black, 5 parts of carbon black, 10 parts of white carbon black, 0.1 part of cobalt boracylate, 1.4 parts of cobalt naphthenate and 0.8 part of accelerator NS.
Example 2
The rubber coating composition for the steel wire carcass cord of the all-steel radial tire comprises the following raw material components in parts by weight: 70 parts of cis-1, 4-polyisoprene, 60 parts of epoxidized natural rubber ENR, 3 parts of terpene resin, 20 parts of silicon-aluminum carbon black, 10 parts of carbon black, 30 parts of white carbon black, 0.5 part of cobalt boracylate, 2.5 parts of cobalt naphthenate and 0.8-1.2 parts of accelerator NS.
According to the invention, the white carbon black, the epoxidized natural rubber ENR, the white carbon black and the cobalt salt are matched, so that the adhesive property of the cord thread and the rubber is improved while the performance of the rubber material is satisfied. The terpene resin can improve the adhesive force and improve the mechanical property and the aging resistance of the rubber bonding layer.
The present invention may be embodied in other specific forms without departing from its spirit or essential characteristics. The above-described embodiments of the invention are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims, and not by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (2)

1. The rubber coating composition for the steel wire carcass cord of the all-steel radial tire is characterized by comprising the following raw material components in parts by weight: 70-90 parts of cis-1, 4-polyisoprene, 20-60 parts of epoxidized natural rubber ENR, 0.5-3 parts of terpene resin, 10-20 parts of silicon-aluminum carbon black, 5-10 parts of carbon black, 10-30 parts of white carbon black, 1-3 parts of cobalt salt and 0.8-1.2 parts of accelerator NS.
2. The all-steel radial tire steel carcass cord skim composition according to claim 1, wherein the cobalt salt comprises: 0.1-0.5 part of cobalt boroacylate and 1-2.5 parts of cobalt naphthenate.
CN202010109986.1A 2020-02-23 2020-02-23 Rubber coating composition for steel wire carcass cords of all-steel radial tires Pending CN111205522A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010109986.1A CN111205522A (en) 2020-02-23 2020-02-23 Rubber coating composition for steel wire carcass cords of all-steel radial tires

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010109986.1A CN111205522A (en) 2020-02-23 2020-02-23 Rubber coating composition for steel wire carcass cords of all-steel radial tires

Publications (1)

Publication Number Publication Date
CN111205522A true CN111205522A (en) 2020-05-29

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010109986.1A Pending CN111205522A (en) 2020-02-23 2020-02-23 Rubber coating composition for steel wire carcass cords of all-steel radial tires

Country Status (1)

Country Link
CN (1) CN111205522A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048108A (en) * 2020-09-17 2020-12-08 山东玲珑轮胎股份有限公司 Low-odor belt rubber composition of novel bonding system

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07102115A (en) * 1993-10-08 1995-04-18 Bridgestone Corp Rubber composition
CN101314652A (en) * 2007-06-01 2008-12-03 住友橡胶工业株式会社 Rubber composition for coating tire cord
CN103717662A (en) * 2011-08-23 2014-04-09 住友橡胶工业株式会社 Pneumatic tire
CN105860162A (en) * 2016-06-13 2016-08-17 青岛双星轮胎工业有限公司 Environment-friendly rubber composition for belted layer of all-steel truck tire
CN106397848A (en) * 2015-08-04 2017-02-15 天津国际联合轮胎橡胶股份有限公司 Formula for belt coating rubber of all-steel engineering radial tire
CN107674250A (en) * 2016-08-02 2018-02-09 天津国际联合轮胎橡胶股份有限公司 A kind of full steel engineering radial-type tyre steel wire cord tire line covers glue formula

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07102115A (en) * 1993-10-08 1995-04-18 Bridgestone Corp Rubber composition
CN101314652A (en) * 2007-06-01 2008-12-03 住友橡胶工业株式会社 Rubber composition for coating tire cord
CN103717662A (en) * 2011-08-23 2014-04-09 住友橡胶工业株式会社 Pneumatic tire
CN106397848A (en) * 2015-08-04 2017-02-15 天津国际联合轮胎橡胶股份有限公司 Formula for belt coating rubber of all-steel engineering radial tire
CN105860162A (en) * 2016-06-13 2016-08-17 青岛双星轮胎工业有限公司 Environment-friendly rubber composition for belted layer of all-steel truck tire
CN107674250A (en) * 2016-08-02 2018-02-09 天津国际联合轮胎橡胶股份有限公司 A kind of full steel engineering radial-type tyre steel wire cord tire line covers glue formula

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112048108A (en) * 2020-09-17 2020-12-08 山东玲珑轮胎股份有限公司 Low-odor belt rubber composition of novel bonding system

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Application publication date: 20200529