CN111117757A - Water-soluble volatile punching liquid and preparation method thereof - Google Patents
Water-soluble volatile punching liquid and preparation method thereof Download PDFInfo
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- CN111117757A CN111117757A CN202010035470.7A CN202010035470A CN111117757A CN 111117757 A CN111117757 A CN 111117757A CN 202010035470 A CN202010035470 A CN 202010035470A CN 111117757 A CN111117757 A CN 111117757A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/2805—Esters used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
- C10M2207/2865—Esters of polymerised unsaturated acids used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/04—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having a silicon-to-carbon bond, e.g. organo-silanes
Abstract
The embodiment of the invention provides a water-soluble volatile stamping solution and a preparation method thereof, the water-soluble volatile stamping solution is suitable for stamping various metals such as ferrous metal, aluminum material, copper material and the like, and has good rust prevention and corrosion prevention performance, the stamping solution is compounded by nontoxic raw materials, is harmless to human bodies, is compounded by low-toxicity or nontoxic raw materials, has small irritation to the bodies of operators, is suitable for stamping various metals such as ferrous metal, aluminum material, copper material and the like, has good rust prevention and corrosion prevention performance, and a stamped workpiece is clean, easy to clean and treat, low in odor and free of flash points.
Description
Technical Field
The invention belongs to the technical field of metal processing, and particularly relates to a water-soluble volatile punching liquid and a preparation method thereof.
Background
Metal stamping is a manufacturing process that uses a metal stamping die or a series of metal stamping dies to form a sheet metal into a three-dimensional shaped workpiece. In the world, 60-70% of steel products are plates, and most of the plates are punched to form finished products. The metal stamping die is mounted on a press, and each stroke of the press forms a workpiece, so that the metal plate can be efficiently formed.
The dies used for stamping generally have specificity, a complex part can be machined and formed only by a plurality of sets of dies, the manufacturing precision of the dies is high, the technical requirement is high, and therefore the die cost is very high. In the stamping process of a general workpiece, particularly in the cold forging stamping process, the temperature can be quickly raised, so that lubricating oil needs to be added for lubrication, and if the workpiece is directly stamped without lubrication, the smoothness of the workpiece is affected, the precision of a die is reduced, the service life is shortened, and the production and manufacturing cost is greatly improved. In the prior art, pressure-resistant lubricating oil is the best choice for protecting a die when producing deep-drawing or heavy-drawing workpieces, and sulfur and chlorine pressure-resistant additives are usually mixed into pure oil to prolong the service life of the die. However, with the increasingly strict environmental requirements, pressure-resistant oil-based lubricating oils have become increasingly unsuitable.
The high-strength steel is formed at high temperature, the temperature is continuously increased along with the deformation of metal in a stamping die, the pressure-resistant oil-based lubricating oil can be thinned, and the oil-based lubricating oil can reach a flash point or even burn and smoke under some conditions. According to the characteristics of metal stamping, after stamping by using a volatile lubricant, the workpiece is required to have long rust prevention period, clean surface, safety and environmental protection. The traditional volatile punching oil has the following defects: the flash point is low, generally 35-100 ℃, and the product is basically inflammable and combustible; the antirust period is short, the volatilization is fast, and the volatile stamping oil is basically and completely volatilized due to the heat generated in stamping processing and the characteristics of the product, so that the antirust oil only has a short-term antirust function; the volatile punching oil can not be mixed with water for use, so that the loss is large and the use cost is high; the cooling performance is basically absent in the processing process, the lubricating performance is general, and the environment is not protected.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. Therefore, the invention provides the water-soluble volatile stamping fluid and the preparation method thereof, the water-soluble volatile stamping fluid is suitable for stamping various metals such as ferrous metal, aluminum material, copper material and the like, has good antirust and anticorrosive properties, is prepared by compounding nontoxic raw materials, and is harmless to human bodies.
According to the embodiment of the first aspect of the invention, the water-soluble volatile punching liquid comprises the following preparation raw materials in parts by weight:
compound antirust agent: 30 to 50 parts of (a) a water-soluble polymer,
lubricant: 5 to 15 parts of (A) a water-soluble polymer,
auxiliary agent: 3 to 9 parts of (A) a water-soluble polymer,
corrosion inhibitor: 0.5 to 5 parts by weight of a stabilizer,
water: 25-50 parts.
In the preparation raw materials, the composite antirust agent and the corrosion inhibitor have synergistic action, and the synergistic action of the composite antirust agent and the corrosion inhibitor can enhance the antirust and anticorrosive performance on the surface of the processed metal. The lubricant and the auxiliary agent have synergistic action, and the synergistic action of the lubricant and the auxiliary agent can enhance the lubricity of the product.
The water-soluble volatile punching liquid provided by the embodiment of the invention has at least the following technical effects:
the formula of the water-soluble volatile stamping fluid provided by the embodiment of the invention is compounded by low-toxicity or non-toxic raw materials, has small irritation to the body of an operator, is suitable for stamping various metals such as ferrous metals, aluminum materials, copper materials and the like, and has good antirust and anticorrosive properties.
The workpiece stamped by the water-soluble volatile stamping liquid provided by the embodiment of the invention is clean and easy to clean and treat.
According to the water-soluble volatile punching liquid disclosed by the embodiment of the invention, the whole system of the product is a water-soluble additive, and the carrier of the system is water. When the stamping die is used, the stamping die can be diluted with water according to the thickness and the material of stamping, and the formula disclosed by the embodiment of the invention is low in smell and free of flash point.
According to some embodiments of the invention, the compound rust inhibitor includes a first rust inhibitor and a second rust inhibitor.
According to some embodiments of the invention, the first rust inhibitor is a mixture of a specific amine and a dicarboxylic acid.
According to some embodiments of the invention, the first rust inhibitor is a mixture of a specific amine and a tricarboxylic acid.
The special amine is 2-amino-2-methyl-1-propanol, and the organic carboxylic acid and the organic amine are subjected to saponification reaction at the temperature of 70-80 ℃, so that the optimal antirust effect can be achieved.
According to some embodiments of the invention, the second rust inhibitor is at least one of triethanol, diethanol amine, and boric acid.
According to some embodiments of the invention, the lubricant is at least one of a self-emulsifying ester and a tetrapolyricinoleate.
According to some embodiments of the invention, the adjuvant is at least one of ethanol, diethyl ether and N, N-dimethylformamide.
The auxiliary agent has the functions of improving the stability of the system and assisting the lubricant to improve the lubrication effect in the processing process.
According to some embodiments of the invention, the corrosion inhibitor is at least one of a phosphate ester corrosion inhibitor and a siloxane corrosion inhibitor.
According to some embodiments of the present invention, the corrosion inhibitor is at least one of benzotriazole, tolyltriazole and sodium mercaptobenzothiazole.
According to a second aspect of the invention, the preparation method of the water-soluble volatile punching liquid comprises the following steps: weighing the composite antirust agent, the lubricant, the auxiliary agent, the corrosion inhibitor and the water according to the proportion, and uniformly mixing to obtain the antirust agent.
The preparation method of the water-soluble volatile punching liquid provided by the embodiment of the invention at least has the following technical effects:
the preparation method of the water-soluble volatile punching liquid provided by the embodiment of the invention is simple in process and low in production cost.
Detailed Description
The following are specific examples of the present invention, and the technical solutions of the present invention will be further described with reference to the examples, but the present invention is not limited to the examples.
Example 1
The embodiment provides a water-soluble volatile punching liquid which comprises the following preparation raw materials in parts by weight:
compound antirust agent: 30-50 parts of a lubricant: 5-15 parts of an auxiliary agent: 3-9 parts of corrosion inhibitor: 0.5-5 parts of water: 25-50 parts.
The composite antirust agent comprises a first antirust agent and a second antirust agent. The first antirust agent is a mixture of special amine and dibasic acid/tribasic acid. The second antirust agent is at least one of triethanolamine, diethanolamine and boric acid. The lubricant is at least one of self-emulsifying ester and tetrapolyricinoleate. The auxiliary agent is at least one of ethanol, diethyl ether and N, N-dimethylformamide. The corrosion inhibitor is at least one of phosphate ester corrosion inhibitor and siloxane corrosion inhibitor. The corrosion inhibitor is at least one of benzotriazole, tolyltriazole and sodium mercaptobenzothiazole.
Example 2
This example provides a method for preparing a water-soluble volatile punching fluid, comprising: weighing the composite antirust agent, the lubricant, the auxiliary agent, the corrosion inhibitor and the water according to the proportion, and uniformly mixing to obtain the antirust agent.
Example 3
In this example, a water-soluble volatile punching fluid a was prepared by using the preparation method of example 2 and the formulation of example 1, and the punching fluid included the following raw materials in parts by weight:
c20 (Nanjing Cutian specialty amine) (first rust inhibitor reagent): 10 parts, diethanolamine (second rust inhibitor agent): 15 parts, sebacic acid (first rust inhibitor agent): 5 parts, boric acid (second rust inhibitor agent): 5 parts of tetrapolyricinoleic acid ester (lubricant): 5 parts, ethanol (adjuvant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 0.8 parts, NEUF815 (siloxane corrosion inhibitor): 0.5 part of BTA (sodium mercaptobenzothiazole corrosion inhibitor): 0.2 part, water: 53.5 parts.
Example 4
In this example, a water-soluble volatile punching fluid B was prepared by using the preparation method of example 2 and the formulation of example 1, and the punching fluid included the following raw materials in parts by weight:
DGA (wu xi chen special amine) (first rust inhibitor reagent): 10 parts, diethanolamine (second rust inhibitor): 15 parts, TAT730 (triorganic polycarboxylic acid, first rust inhibitor agent): 5 parts, boric acid (second rust inhibitor agent): 5 parts, Priolube3955Croda (lubricant): 5 parts, ethanol (adjuvant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 0.8 parts, NEUF815 (siloxane corrosion inhibitor): 0.5 part of MBT (sodium mercaptobenzothiazole as corrosion inhibitor): 0.2 part, water: 53.5 parts.
Example 5
In this example, a water-soluble volatile punching fluid C was prepared by using the preparation method of example 2 and the formulation of example 1, and the punching fluid included the following raw materials in parts by weight:
AMP-95 (specialty amine) (first rust inhibitor reagent): 10 parts, diethanolamine (second rust inhibitor agent): 10 parts, triethanolamine (second rust inhibitor agent): 5 parts, CP-50 (tribasic acid, first rust inhibitor agent): 5 parts, boric acid (second rust inhibitor agent): 5 parts, Priolube3955Croda (lubricant): 5 parts, ethanol (adjuvant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 0.8 parts, NEUF815 (siloxane corrosion inhibitor): 0.5 part of BTA (sodium mercaptobenzothiazole as corrosion inhibitor): 0.2 part of TTA (methyl benzotriazole as corrosion inhibitor): 0.1 part, water: 53.4 parts.
COMPARATIVE EXAMPLE 1 (Explanation: this example does not contain the specialty amine C20)
In this example, using the preparation method of example 2 and the formulation of example 1, a water-soluble volatile punching liquid a1 was prepared, which is different from the punching liquid a of example 3 in that it does not contain the special amine C20, and specifically includes the following raw materials in parts by weight:
diethanolamine (second rust inhibitor agent): 15 parts, sebacic acid (first rust inhibitor agent): 15 parts, boric acid (second rust inhibitor agent): 5 parts of tetrapolyricinoleic acid ester (lubricant): 5 parts, ethanol (adjuvant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 0.8 parts, NEUF815 (siloxane corrosion inhibitor): 0.5 part of BTA (sodium mercaptobenzothiazole corrosion inhibitor): 0.2 part, water: 53.5 parts.
Comparative example 2 (the example does not contain a built sustained release agent)
In this example, the preparation method of example 2 and the formulation of example 1 were used to prepare a water-soluble volatile punching liquid a2, which is different from the punching liquid a of example 3 in that it does not contain a compound sustained-release agent, and specifically includes the following preparation raw materials in parts by weight:
c20 (Nanjing Cutian specialty amine) (first rust inhibitor reagent): 10 parts, diethanolamine (second rust inhibitor agent): 15 parts, sebacic acid (first rust inhibitor agent): 5 parts, boric acid (second rust inhibitor agent): 5 parts of tetrapolyricinoleic acid ester (lubricant): 5 parts, ethanol (adjuvant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 1.5 parts, water: 53.5 parts.
Comparative example 3 (example containing no auxiliary)
In this example, using the preparation method of example 2 and the formulation of example 1, a water-soluble volatile punching liquid a3 was prepared, which is different from the punching liquid a of example 3 in that it contains no auxiliary agent and specifically comprises the following raw materials in parts by weight:
c20 (Nanjing Cutian specialty amine) (first rust inhibitor reagent): 10 parts, diethanolamine (second rust inhibitor agent): 15 parts, sebacic acid (first rust inhibitor agent): 5 parts, boric acid (second rust inhibitor agent): 5 parts of tetrapolyricinoleic acid ester (lubricant): 5 parts, ASI-80 (phosphate ester corrosion inhibitor): 0.8 parts, NEUF815 (siloxane corrosion inhibitor): 0.5 part of BTA (sodium mercaptobenzothiazole corrosion inhibitor): 0.2 part, water: 58.5 parts.
Detection example 1
In this example, the antirust performance of the punching liquids A, B and C prepared in examples 3-5 was tested according to GB/T6144, and the test results are shown in Table 1.
TABLE 1 antirust property test results
Detection example 2
In this example, the lubricating wear properties of the punching liquids A, B and C prepared in examples 3 to 5 were tested, and the lubricating wear properties of the volatile punching liquids were tested by an AW lubricating wear tester developed and produced by the mechanical research institute in hunan province, and the obtained test results of the wear scar areas are shown in table 2.
TABLE 2 lubricating wear performance test results
Claims (10)
1. The water-soluble volatile punching liquid is characterized by comprising the following preparation raw materials in parts by weight:
compound antirust agent: 30 to 50 parts of (a) a water-soluble polymer,
lubricant: 5 to 15 parts of (A) a water-soluble polymer,
auxiliary agent: 3 to 9 parts of (A) a water-soluble polymer,
corrosion inhibitor: 0.5 to 5 parts by weight of a stabilizer,
water: 25-50 parts.
2. The water-soluble volatile punching fluid of claim 1, wherein the compound rust inhibitor comprises a first rust inhibitor and a second rust inhibitor.
3. The water-soluble volatile punching fluid of claim 2, wherein the first rust inhibitor is a mixture of a specific amine and a dicarboxylic acid.
4. The water soluble volatile punching fluid according to claim 3, wherein said first rust inhibitor further comprises a tricarboxylic acid.
5. The water-soluble volatile punching liquid according to claim 2, wherein the second rust inhibitor is at least one of triethanol, diethanol amine and boric acid.
6. The water-soluble volatile punching liquid according to claim 1, wherein said lubricant is at least one of a self-emulsifying ester and a tetrapolyricinoleate.
7. The water-soluble volatile punching liquid according to claim 1, wherein the auxiliary agent is at least one of ethanol, diethyl ether and N, N-dimethylformamide.
8. The water soluble volatile punching fluid of claim 1, wherein the corrosion inhibitor is at least one of a phosphate ester corrosion inhibitor and a siloxane corrosion inhibitor.
9. The water-soluble volatile punching liquid according to claim 8, wherein the corrosion inhibitor further comprises at least one of benzotriazole, tolyltriazole and sodium mercaptobenzothiazole.
10. The method for preparing the water-soluble volatile punching liquid according to any one of claims 1 to 9, characterized in that the method comprises: weighing the composite antirust agent, the lubricant, the auxiliary agent, the corrosion inhibitor and the water according to the proportion, and uniformly mixing to obtain the antirust agent.
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Cited By (5)
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| CN112048358A (en) * | 2020-09-30 | 2020-12-08 | 武汉市华中特种油有限公司 | Formula of fully-synthesized magnesium alloy cutting fluid |
| CN113481041A (en) * | 2021-07-22 | 2021-10-08 | 东莞市卓骏润滑科技有限公司 | Water-based cooling lubricating liquid for stamping thick plates of automobiles, preparation method and use method thereof |
| CN113736551A (en) * | 2021-09-08 | 2021-12-03 | 长沙艾森设备维护技术有限公司 | Metal extrusion tapping liquid |
| CN116024038A (en) * | 2022-12-28 | 2023-04-28 | 长沙艾森设备维护技术有限公司 | Environment-friendly metal cold heading paste and preparation method and application thereof |
| CN116554948A (en) * | 2023-05-16 | 2023-08-08 | 清华大学天津高端装备研究院 | Deep hole drilling oil with low viscosity and preparation method thereof |
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