CN111117354A - Water-based propylene marker ink and preparation method thereof - Google Patents
Water-based propylene marker ink and preparation method thereof Download PDFInfo
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- CN111117354A CN111117354A CN201911416978.5A CN201911416978A CN111117354A CN 111117354 A CN111117354 A CN 111117354A CN 201911416978 A CN201911416978 A CN 201911416978A CN 111117354 A CN111117354 A CN 111117354A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/20—Writing inks indelible
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses water-based acrylic marker ink and a preparation method thereof, and the water-based acrylic marker ink comprises 10-20% of titanium dioxide, 0-4% of pigment, 5-8% of interphase regulator, 40-50% of acrylic resin emulsion film-forming agent and 25-40% of water; the interphase regulator comprises an amphiphilic polymer and a polymer with a moisturizing effect. The ink uses titanium dioxide and pigment, uses environment-friendly nontoxic polymer as a functional interphase regulator, and is matched with film-forming emulsion to obtain the ink with stable performance, smooth water outlet, uniform distribution and high chroma fastness. The ink has the advantages of cheap and easily-obtained raw materials, simple and feasible preparation process, environment-friendly and nontoxic process and product, and no volatile organic small molecular substance.
Description
Technical Field
The invention relates to water-based acrylic Mark pen ink and a preparation method thereof, belonging to the technical field of ink manufacture.
Background
The propylene pigment is fast to dry and bright and full in color, so that the propylene pigment is popular with many painters and lovers; however, this pigment is inconvenient for many painting beginners because it needs to be prepared on site and used quickly. In recent years, various pigment acrylic marker pens have appeared, and pigment acrylic ink is filled into the pens, so that the pen is convenient to carry and use. At present, acrylic marker pens with various colors are produced by some international brands, but because organic solvents have the advantages of quick drying, better pigment solubility and better glossiness when applied to inks, volatile organic solvents and organic small molecule materials are used in the inks to different degrees, and long-term contact easily causes health influence on users. The aqueous propylene marker developed by International patent No. AU 678374B2 is claimed to contain no organic solvent, but 2-10% of alcohol solvent is added into the formula.
Disclosure of Invention
In order to solve the technical problems, the invention provides water-based acrylic Mark pen ink and a preparation method thereof. The ink uses titanium dioxide and pigment, uses an environment-friendly nontoxic polymer as a functional interphase regulator, and is matched with a film-forming emulsion to obtain the ink with stable performance, smooth water outlet, uniform distribution and high chroma fastness. The ink has the advantages of cheap and easily-obtained raw materials, simple and feasible preparation process, environment-friendly and nontoxic process and product, and no volatile organic small molecular substance.
The first purpose of the invention is to provide water-based acrylic marker ink which comprises, by mass, 10-20% of titanium dioxide, 0-4% of pigment, 5-8% of interphase regulator, 40-50% of acrylic resin emulsion film-forming agent and 25-40% of water; the interphase regulator comprises an amphiphilic polymer and a polymer with a moisturizing effect.
Further, the amphiphilic polymer comprises one or more of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sodium polyacrylate, ammonium polyacrylate, polyoxyethylene polyoxypropylene block polymer, sodium carboxymethylcellulose and polytetrahydrofuran. The amphiphilic polymer comprises oligomer, and in the formula of the ink, on one hand, the amphiphilic polymer can play a role of a surfactant, so that the ink has lower surface tension and is beneficial to fluent writing on the surfaces of different materials; on the other hand, the organic phase substance in the system is better fused with the water phase substance, and the system is more stable.
Further, the polymer with the moisturizing effect is a polymer containing hydroxyl or carbonyl, and comprises one or more of polyethylene glycol, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate and hyaluronic acid. The polymer with the moisturizing effect comprises an oligomer, and in the ink formula, on one hand, the polymer can play a moisturizing effect to prevent a pen point from being dried quickly, and on the other hand, the polymer can be better combined and dispersed with pigment particles to play a synergistic effect on an amphiphilic polymer of a surfactant.
Further, in the water-based acrylic marker ink, the using amount of the amphiphilic polymer is 2-5% by mass percent. Preferably 3 to 4%.
Further, in the water-based acrylic marker ink, the amount of the polymer with the moisturizing effect is 1-5% by mass. Preferably 2 to 4 percent.
Further, the acrylic resin emulsion film-forming agent is selected from one or more of styrene acrylic acid copolymer emulsion, Dow acrylic resin emulsion and Bassbefree acrylic resin emulsion.
Further, the particle size of the titanium dioxide is not more than 5 μm. Preferably not more than 1 μm, and further preferably not more than 500 nm.
Further, the pigment is water-based pigment, including pigment red, pigment yellow, phthalocyanine blue or pigments with different proportions.
The second purpose of the invention is to provide a preparation method of the water-based acrylic marker ink, which comprises the following steps:
s1, weighing titanium dioxide or titanium dioxide and pigment, mixing with water, and dispersing for 1-120 min to obtain a first dispersion mixture;
s2, sequentially adding the polymer with the moisturizing effect, the amphiphilic polymer and the acrylic resin emulsion film-forming agent into the dispersed mixture I obtained in S1, and uniformly stirring and mixing to obtain the water-based acrylic marker ink.
Further, the rotating speed of the stirring is 250-500 rpm.
The titanium dioxide of the invention belongs to white inorganic pigment, have non-toxic, the best opacity, best whiteness and brightness, is regarded as a kind of white pigment with the best performance in the world nowadays, in the invention, if prepare white ink, the titanium dioxide plays a role in covering the flaw and white pigment at the same time, mainly play a role in covering in the ink of other colors; the selected moisturizing polymers such as polyethylene glycol, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate, hyaluronic acid and the like have the characteristics of environmental protection and no toxicity, and have strong biological safety; the amphiphilic polymers selected by the invention, such as nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sodium polyacrylate, ammonium polyacrylate, polyoxyethylene polyoxypropylene block polymer, sodium carboxymethylcellulose, polytetrahydrofuran and other polymers, have the characteristics of environmental protection, no toxicity and compatibility with a water-based system; the acrylic resin emulsion film-forming agent, such as domestic styrene-acrylic emulsion, Dow acrylic resin emulsion, Bassburgh acrylic resin emulsion and the like, is dispersed in water, is suitable for the production of environment-friendly products, and is widely applied to various coatings, paper adhesives and the like.
The functional interphase regulator disclosed by the invention not only can respectively play the roles of a humectant and a surfactant, but also can better disperse and complex with pigment molecules by utilizing the loaded functional group of the polymer, so that the whole system is more uniform and stable; and the interphase regulator has low dosage and does not contain any volatile organic micromolecular substance.
The invention has the beneficial effects that:
① the water-based acrylic marker ink obtained by the invention has the components except purified water, adopts the raw materials which are environment-friendly polymers without any volatility or water dispersion emulsion thereof, has no volatilization of organic solvents, is cheap and easy to obtain, is safe and environment-friendly, has stable property, and can not generate health influence on users.
② the water-base acrylic ink for Mark pen is filled in Mark pen, and has smooth writing and cap-off time up to 12 hr, and can form smooth thin layer on the rough or smooth surface of glass, wood, canvas, plastic, etc. and is dried quickly.
③ the ink film has uniform pigment distribution, high chroma, glossiness, coverage and fastness, good waterproof performance after no micromolecule component, and no cleaning after wiping with dry cloth.
Detailed Description
The present invention is further described below in conjunction with specific examples to enable those skilled in the art to better understand the present invention and to practice it, but the examples are not intended to limit the present invention.
Example 1:
the white water-based acrylic marker ink comprises the following components in parts by weight:
10.0 percent of Ningbo Xinfu titanium dioxide, 1.5 percent of polyethylene glycol, 1.5 percent of polyvinyl alcohol, 2.0 percent of ammonium polyacrylate, 2.0 percent of nonylphenol polyoxyethylene ether, 50.0 percent of Basfuzhuanqiao acrylic resin emulsion, 33 percent of purified water and 100 grams of total weight.
The preparation method of the white water-based acrylic marker ink comprises the following steps:
① weighing the components according to the weight and proportion, wherein the total weight is 100 g;
② mixing Ningbo Xinfu titanium white weighed in step ① with purified water, and performing ultrasonic treatment for 30 minutes to obtain a first water dispersion mixture of titanium white;
③, adding the polyethylene glycol and the polyvinyl alcohol weighed in the step ① into the mixture I obtained in the step ②, stirring for 1 hour at 80 ℃, and controlling the rotating speed to be 250-500 rpm to obtain a mixture II;
④, adding the ammonium polyacrylate and the nonylphenol polyoxyethylene ether weighed in the step ① into the mixture II obtained in the step ③, stirring at room temperature for 1 hour, and controlling the rotating speed to be 250-500 rpm to obtain a mixture III;
⑤ adding the Bassboro acrylic resin emulsion weighed in the step ① into the mixture III obtained in the step ④, stirring for 1 hour at room temperature, controlling the rotating speed to be 250-500 rpm, and standing for 2 hours to obtain the finished product I of the white water-based acrylic marker ink.
Example 2:
the white water-based acrylic marker ink comprises the following components in parts by weight:
15.0 percent of titanium white powder in Panzhi Steel east China titanium industry, 1.5 percent of polyethylene glycol, 0.5 percent of polyvinylpyrrolidone, 2.0 percent of sodium polyacrylate, 2.0 percent of octyl phenol polyoxyethylene ether, 45.0 percent of Dow acrylic resin emulsion, 34.0 percent of purified water and 100 grams of total weight.
The preparation method of the white water-based acrylic marker ink comprises the following steps:
① weighing the components according to the weight and proportion, wherein the total weight is 100 g;
② mixing the titanium white powder weighed in step ① with purified water, and performing ultrasonic treatment for 20 minutes to obtain a first water dispersion mixture of the titanium white powder;
③, adding the polyethylene glycol and the polyvinylpyrrolidone weighed in the step ① into the mixture I obtained in the step ②, stirring for 1 hour at 60 ℃, and controlling the rotating speed to be 250-500 rpm to obtain a mixture II;
④, adding the sodium polyacrylate and the octylphenol polyoxyethylene ether weighed in the step ① into the mixture II obtained in the step ③, stirring for 1 hour at room temperature, and controlling the rotating speed to be 250-500 rpm to obtain a mixture III;
⑤, adding the Dow acrylic resin emulsion weighed in the step ① into the mixture III obtained in the step ④, stirring for 1 hour at room temperature, controlling the rotating speed to be 250-500 rpm, and standing for 2 hours to obtain a finished product II of the white water-based acrylia ink.
Example 3:
the white water-based acrylic marker ink comprises the following components in parts by weight:
15.0% of Dupont mu titanium dioxide, 1.5% of polyethylene glycol, 1.5% of polyvinyl alcohol, 2.5% of nonylphenol polyoxyethylene ether, 2.0% of L-type polyoxyethylene polyoxypropylene block polymer, 40.0% of Basfuhuang acrylic resin emulsion, 37.5% of purified water and 100 g of total weight.
The preparation method of the white water-based acrylic marker ink comprises the following steps:
① weighing the components according to the weight and proportion, wherein the total weight is 100 g;
②, mixing the Dupont mu titanium dioxide weighed in the step ① with purified water, and carrying out ultrasonic treatment for 10 minutes to obtain a first water dispersion mixture of the titanium dioxide;
③, adding the polyethylene glycol and the polyvinylpyrrolidone weighed in the step ① into the mixture I obtained in the step ②, stirring for 1 hour at 80 ℃, and controlling the rotating speed to be 250-500 rpm to obtain a mixture II;
④, adding the alkylphenol ethoxylate and the L-type polyoxyethylene polyoxypropylene block polymer weighed in the step ① into the mixture II obtained in the step ③, stirring for 1 hour at room temperature, and controlling the rotating speed to be 250-500 rpm to obtain a mixture III;
⑤ adding the Bassbury acrylic resin emulsion weighed in the step ① into the mixture III obtained in the step ④, stirring for 1 hour at room temperature, controlling the rotating speed to be 250-500 rpm, and standing for 2 hours to obtain the finished product, three, of the white water-based acrylic marker ink.
Example 4:
the white water-based acrylic marker ink comprises the following components in parts by weight:
20.0 percent of kanois titanium dioxide, 1.5 percent of polyvinyl alcohol, 0.5 percent of polyvinylpyrrolidone, 2.0 percent of nonylphenol polyoxyethylene ether, 2.5 percent of L-type polyoxyethylene polyoxypropylene block polymer, 45.0 percent of Dow acrylic resin emulsion, 28.5 percent of purified water and 100 grams of total weight.
The preparation method of the white water-based acrylic marker ink comprises the following steps:
① weighing the components according to the weight and proportion, wherein the total weight is 100 g;
② mixing the Connous titanium white weighed in step ① with purified water, and performing ultrasonic treatment for 10 minutes to obtain a first water dispersion mixture of titanium white;
③, adding the polyvinyl alcohol and the polyvinyl pyrrolidone weighed in the step ① into the mixture I obtained in the step ②, stirring for 1 hour at 60 ℃, and controlling the rotating speed to be 250-500 rpm to obtain a mixture II;
④, adding the nonylphenol polyoxyethylene ether and the L-type polyoxyethylene polyoxypropylene block polymer weighed in the step ① into the mixture II obtained in the step ③, stirring at room temperature for 1 hour, and controlling the rotating speed to be 250-500 rpm to obtain a mixture III;
⑤, adding the Dow acrylic resin emulsion weighed in the step ① into the mixture III obtained in the step ④, stirring at room temperature for 1 hour, controlling the rotating speed to be 250-500 rpm, and standing for 2 hours to obtain a finished product of the white water-based acrylic Mark pen ink.
The white water-based acrylic marker inks prepared in examples 1, 2, 3 and 4 were loaded into marker pens, respectively, and written on a smooth glass plate at room temperature of 25 ℃ to observe the smoothness of writing, odor, drying film formation time, whiteness coverage and pigment fastness, and to examine the ink stability. The specific test results are shown in table 1:
table 1: results of Performance testing
As can be seen from Table 1, the environment-friendly water-based acrylic marker ink obtained by the various formulas of the invention has the advantages of smooth writing, no organic solvent and odor, and excellent chroma, coverage, fine degree of pigment and film forming fastness in the optimized formula.
The above-mentioned embodiments are merely preferred embodiments for fully illustrating the present invention, and the scope of the present invention is not limited thereto. The equivalent substitution or change made by the technical personnel in the technical field on the basis of the invention is all within the protection scope of the invention. The protection scope of the invention is subject to the claims.
Claims (10)
1. The water-based acrylic marker ink is characterized by comprising 10-20% of titanium dioxide, 0-4% of pigment, 5-8% of interphase regulator, 40-50% of acrylic resin emulsion film-forming agent and 25-40% of water by mass percent; the interphase regulator comprises an amphiphilic polymer and a polymer with a moisturizing effect.
2. The water-based acrylic marker ink according to claim 1, wherein the amphiphilic polymer comprises one or more of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, sodium polyacrylate, ammonium polyacrylate, polyoxyethylene polyoxypropylene block polymer, sodium carboxymethylcellulose, and polytetrahydrofuran.
3. The water-based acrylic marker ink as claimed in claim 1, wherein the polymer with moisture retention effect is a polymer containing hydroxyl or carbonyl groups, and comprises one or more of polyethylene glycol, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate and hyaluronic acid.
4. The water-based acrylic marker ink according to claim 1, wherein the amount of the amphiphilic polymer is 2 to 5% by mass of the water-based acrylic marker ink.
5. The water-based acrylic marker ink according to claim 1, wherein the amount of the polymer having a moisturizing effect in the water-based acrylic marker ink is 1 to 5% by mass.
6. The water-based propylene marker ink as claimed in claim 1, wherein the acrylic resin emulsion film former is selected from one or more of styrene acrylic copolymer emulsion, Dow acrylic resin emulsion, and Bassburgh acrylic resin emulsion.
7. The water-based acrylic marker ink according to claim 1, wherein the titanium dioxide has a particle size of not more than 5 μm.
8. The water-based acrylic marker ink as claimed in claim 1, wherein the pigment is water-based pigment, including pigment red, pigment yellow, phthalocyanine blue or their mixture ratio.
9. A method for preparing the water-based acrylic marker ink as claimed in any one of claims 1 to 8, which comprises the following steps:
s1, weighing titanium dioxide or titanium dioxide and pigment, mixing with water, and dispersing for 1-120 min to obtain a first dispersion mixture;
s2, sequentially adding the polymer with the moisturizing effect, the amphiphilic polymer and the acrylic resin emulsion film-forming agent into the dispersed mixture I obtained in S1, and uniformly stirring and mixing to obtain the water-based acrylic marker ink.
10. The method according to claim 9, wherein the stirring speed is 250-500 rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911416978.5A CN111117354A (en) | 2019-12-31 | 2019-12-31 | Water-based propylene marker ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911416978.5A CN111117354A (en) | 2019-12-31 | 2019-12-31 | Water-based propylene marker ink and preparation method thereof |
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| Publication Number | Publication Date |
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| CN111117354A true CN111117354A (en) | 2020-05-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911416978.5A Pending CN111117354A (en) | 2019-12-31 | 2019-12-31 | Water-based propylene marker ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115304978A (en) * | 2022-08-17 | 2022-11-08 | 恒昌涂料（惠阳）有限公司 | Paint with effect of dissolving paint film in water and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319955A (en) * | 2013-05-24 | 2013-09-25 | 贝碧欧美术颜料(昆山)有限公司 | High cover up low viscosity textile hand drawing mark pen ink, preparation method and application thereof |
| CN105623380A (en) * | 2014-11-26 | 2016-06-01 | 天津单渡科技开发有限公司 | White board dry-cleaning ink and preparation method thereof |
-
2019
- 2019-12-31 CN CN201911416978.5A patent/CN111117354A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319955A (en) * | 2013-05-24 | 2013-09-25 | 贝碧欧美术颜料(昆山)有限公司 | High cover up low viscosity textile hand drawing mark pen ink, preparation method and application thereof |
| CN105623380A (en) * | 2014-11-26 | 2016-06-01 | 天津单渡科技开发有限公司 | White board dry-cleaning ink and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李竖 主编: "《轻稀贵金属冶金学》", 31 March 2018, 冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115304978A (en) * | 2022-08-17 | 2022-11-08 | 恒昌涂料（惠阳）有限公司 | Paint with effect of dissolving paint film in water and preparation method and application thereof |
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