CN111087851A - Preparation method of printer painting and calligraphy ink suitable for rice paper - Google Patents
Preparation method of printer painting and calligraphy ink suitable for rice paper Download PDFInfo
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- CN111087851A CN111087851A CN201911418992.9A CN201911418992A CN111087851A CN 111087851 A CN111087851 A CN 111087851A CN 201911418992 A CN201911418992 A CN 201911418992A CN 111087851 A CN111087851 A CN 111087851A
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- painting
- calligraphy
- deionized water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a preparation method of printer painting and calligraphy ink suitable for rice paper, which comprises the following steps: adding the pigment and the dispersing agent into deionized water at normal temperature, and continuously grinding after ultrasonic dispersion to prepare pigment dispersion liquid; adding phthalate into deionized water, stirring uniformly, heating to 70-80 ℃, adding colloid, heating to 80-100 ℃, stirring until the colloid is completely dissolved, cooling to normal temperature, slowly adding pigment dispersion, and stirring uniformly at normal temperature; then sequentially adding a surfactant, a humectant, a preservative and deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution; and cooling and standing the ink solution, and filtering to obtain the painting and calligraphy ink. The invention enables the pigment to be more uniformly dispersed in the solution, and the prepared painting and calligraphy ink has good printing fluency and high color fastness of printed picture quality.
Description
Technical Field
The invention belongs to the technical field of ink preparation, and particularly relates to a preparation method of printer painting and calligraphy ink suitable for rice paper.
Background
The painting and calligraphy is the general name of calligraphy and painting, and the Chinese painting and calligraphy art is the essence in the world culture art treasury and is a valuable art treasure worth identifying and classical preserving in human history. The Chinese painting and calligraphy paper is rice paper which is generally made from wingceltis tree as a main raw material, and the rice paper is produced in Jing county, Anhui, ancient China, so the rice paper is called as rice paper. Most of painting and calligraphy pigments are mineral pigments, and various pigments are prepared by grinding pure natural ores, such as cinnabar, rock cyan, rock green and the like. Therefore, a preparation method of the printer painting and calligraphy ink suitable for rice paper is urgently needed.
Disclosure of Invention
The invention aims to provide a preparation method of printer painting and calligraphy ink suitable for rice paper aiming at the defects of the prior art.
The invention provides the following technical scheme:
a preparation method of printer painting and calligraphy ink suitable for rice paper comprises the following steps:
s1, adding the pigment and the dispersing agent into deionized water at normal temperature, carrying out ultrasonic dispersion for 5-20min, and then continuing grinding to prepare a pigment dispersion liquid;
s2, adding phthalic acid ester into deionized water, stirring uniformly, heating to 70-80 ℃, adding colloid, heating to 80-100 ℃, stirring until the colloid is completely dissolved, cooling to normal temperature, slowly adding the pigment dispersion liquid obtained in the step S1, and stirring uniformly at normal temperature;
s3, sequentially adding a surfactant, a humectant, a preservative and deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution;
and S4, cooling and standing the ink solution obtained in the step S3, and filtering with a filter membrane to obtain the painting and calligraphy ink.
Preferably, the mass percentages of the raw materials of the painting and calligraphy ink are as follows: 5-20% of pigment, 2-10% of dispersant, 0.5-2% of phthalate, 10-15% of colloid, 0.5-5% of surfactant, 0.5-2% of humectant, 0.5-2% of preservative and the balance of deionized water.
Preferably, the mass of the deionized water adopted in the step S1 accounts for 15-20% of the total mass of the deionized water, and the mass ratio of the jelly to the deionized water in the step S2 is 1: 3-5, the deionized water in the step of S3 is the residual deionized water.
Preferably, the pigment is a natural mineral pigment or an organic pigment, the natural mineral pigment is one or more of cinnabar, red soil, stone yellow, stone green, malachite green and carbon black, and the organic pigment is one or more of azo pigments, polycyclic pigments, nitro pigments and phthalocyanine pigments.
Preferably, the median particle diameter of the pigment dispersion in the step S1 is less than 1 μm.
Preferably, the gum is gum arabic or peach gum.
Preferably, the surfactant is a cationic surfactant.
Preferably, the preservative is one of borneol, sodium benzoate and carbolic acid.
Preferably, the pore size of the filter in the step S4 is 0.1-2 μm.
The invention has the beneficial effects that:
the pigment can be uniformly and stably dispersed in the process of preparing the painting and calligraphy ink, the particle size of pigment particles can be reduced through ultrasonic treatment and grinding, so that the pigment is more uniformly dispersed in a solution, the particle size of the particles in the ink is favorably controlled by filtering with a filter membrane in the preparation process, and a printer nozzle is not easy to block.
Detailed Description
Example 1
The mass percent of each raw material of the printer painting and calligraphy ink suitable for rice paper is as follows: 15% of cinnabar, 3% of a dispersing agent, 0.5% of phthalate, 11% of Arabic gum, 1% of a cationic surfactant, 0.6% of a humectant, 0.8% of borneol and the balance of deionized water.
The preparation method of the painting and calligraphy ink comprises the following specific preparation steps according to the mixture ratio:
s1, adding a pigment and a dispersing agent into deionized water at normal temperature, wherein the mass of the deionized water accounts for 20% of the total mass of the deionized water, performing ultrasonic dispersion for 15min, and then continuing grinding to prepare a pigment dispersion liquid, wherein the particle size of medium particles of the pigment dispersion liquid is less than 1 μm;
s2, adding phthalic acid ester into deionized water, stirring uniformly, heating to 70-80 ℃, adding Arabic gum, heating to 80-100 ℃, stirring to dissolve completely, cooling to normal temperature, slowly adding the pigment dispersion liquid obtained in the step S1, and stirring uniformly at normal temperature, wherein the mass ratio of the Arabic gum to the deionized water is 1: 4;
s3, sequentially adding the cationic surfactant, the humectant, the borneol and the rest deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution;
and S4, cooling and standing the ink solution obtained in the step S3, and filtering the ink solution by using a filter membrane of 0.2 mu m to obtain the painting and calligraphy ink.
Example 2
The mass percent of each raw material of the printer painting and calligraphy ink suitable for rice paper is as follows: 12% of cinnabar, 3% of a dispersing agent, 0.8% of phthalate, 12% of Arabic gum, 0.8% of cationic surfactant, 0.6% of a humectant, 1.2% of borneol and the balance of deionized water.
The preparation method of the painting and calligraphy ink comprises the following specific preparation steps according to the mixture ratio:
s1, adding a pigment and a dispersing agent into deionized water at normal temperature, wherein the mass of the deionized water accounts for 20% of the total mass of the deionized water, performing ultrasonic dispersion for 15min, and then continuing grinding to prepare a pigment dispersion liquid, wherein the particle size of medium particles of the pigment dispersion liquid is less than 1 μm;
s2, adding phthalic acid ester into deionized water, stirring uniformly, heating to 70-80 ℃, adding Arabic gum, heating to 80-100 ℃, stirring to dissolve completely, cooling to normal temperature, slowly adding the pigment dispersion liquid obtained in the step S1, and stirring uniformly at normal temperature, wherein the mass ratio of the Arabic gum to the deionized water is 1: 3;
s3, sequentially adding the cationic surfactant, the humectant, the borneol and the rest deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution;
and S4, cooling and standing the ink solution obtained in the step S3, and filtering the ink solution by using a filter membrane of 0.2 mu m to obtain the painting and calligraphy ink.
Example 3
The mass percent of each raw material of the printer painting and calligraphy ink suitable for rice paper is as follows: 18% of pigment red 176, 5% of dispersing agent, 1% of phthalate, 11% of Arabic gum, 0.8% of cationic surfactant, 0.6% of humectant, 1.2% of borneol and the balance of deionized water, wherein the pigment red 176 is an azo pigment.
The preparation method of the painting and calligraphy ink comprises the following specific preparation steps according to the mixture ratio:
s1, adding a pigment and a dispersing agent into deionized water at normal temperature, wherein the mass of the deionized water accounts for 15% of the total mass of the deionized water, performing ultrasonic dispersion for 15min, and then continuing grinding to prepare a pigment dispersion liquid, wherein the particle size of medium particles of the pigment dispersion liquid is less than 1 μm;
s2, adding phthalic acid ester into deionized water, stirring uniformly, heating to 70-80 ℃, adding Arabic gum, heating to 80-100 ℃, stirring to dissolve completely, cooling to normal temperature, slowly adding the pigment dispersion liquid obtained in the step S1, and stirring uniformly at normal temperature, wherein the mass ratio of the Arabic gum to the deionized water is 1: 4;
s3, sequentially adding the cationic surfactant, the humectant, the borneol and the rest deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution;
and S4, cooling and standing the ink solution obtained in the step S3, and filtering the ink solution by using a filter membrane of 0.2 mu m to obtain the painting and calligraphy ink.
Evaluation of ink Properties of painting and calligraphy
1) Ink storage stability of painting and calligraphy
The inks prepared in the embodiments 1 to 3 were sealed, placed in a 50 ℃ oven and a-20 ℃ refrigerator, and stored for 100 days, the inks were free from delamination, did not deteriorate, had uniform color, and could be printed normally, and the maximum particle size change in the inks before and after the test was not significant, and the change range of the ink viscosity was within ± 15%, indicating that the inks prepared by the present invention still have good storage stability in high temperature and low temperature environments.
2) Painting and calligraphy ink intermittent printing effect
The inks prepared in examples 1 to 3 were printed normally after 7 days of pause, with the same effect as the standards, indicating that the inks prepared in the present invention have good printing stability.
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that changes may be made in the embodiments and/or equivalents thereof without departing from the spirit and scope of the invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (9)
1. A preparation method of printer painting and calligraphy ink suitable for rice paper is characterized by comprising the following steps:
s1, adding the pigment and the dispersing agent into deionized water at normal temperature, carrying out ultrasonic dispersion for 5-20min, and then continuing grinding to prepare a pigment dispersion liquid;
s2, adding phthalic acid ester into deionized water, stirring uniformly, heating to 70-80 ℃, adding colloid, heating to 80-100 ℃, stirring until the colloid is completely dissolved, cooling to normal temperature, slowly adding the pigment dispersion liquid obtained in the step S1, and stirring uniformly at normal temperature;
s3, sequentially adding a surfactant, a humectant, a preservative and deionized water, heating to 80-100 ℃, and stirring for reaction to obtain an ink solution;
and S4, cooling and standing the ink solution obtained in the step S3, and filtering with a filter membrane to obtain the painting and calligraphy ink.
2. The preparation method of the printer painting and calligraphy ink suitable for rice paper as claimed in claim 1, wherein the painting and calligraphy ink comprises the following raw materials in percentage by mass: 5-20% of pigment, 2-10% of dispersant, 0.5-2% of phthalate, 10-15% of colloid, 0.5-5% of surfactant, 0.5-2% of humectant, 0.5-2% of preservative and the balance of deionized water.
3. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 2, wherein the mass of deionized water used in the step S1 accounts for 15-20% of the total mass of deionized water, and the mass ratio of the jelly to the deionized water used in the step S2 is 1: 3-5, the deionized water in the step of S3 is the residual deionized water.
4. The method for preparing printer, painting and calligraphy ink suitable for rice paper according to claim 1, wherein the pigment is a natural mineral pigment or an organic pigment, the natural mineral pigment is one or more of cinnabar, red earth, yellow stone, green stone, malachite green and carbon black, and the organic pigment is one or more of azo pigments, polycyclic pigments, nitro pigments and phthalocyanine pigments.
5. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 1, wherein the particle size of the pigment dispersion in step S1 is less than 1 μm.
6. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 1, wherein the colloid substance is acacia gum or peach gum.
7. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 1, wherein the surfactant is a cationic surfactant.
8. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 1, wherein the preservative is one of borneol, sodium benzoate and carbolic acid.
9. The method for preparing printer calligraphy and painting ink suitable for rice paper as claimed in claim 1, wherein the pore size of the filter membrane in step S4 is 0.1-2 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911418992.9A CN111087851A (en) | 2019-12-31 | 2019-12-31 | Preparation method of printer painting and calligraphy ink suitable for rice paper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911418992.9A CN111087851A (en) | 2019-12-31 | 2019-12-31 | Preparation method of printer painting and calligraphy ink suitable for rice paper |
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| CN111087851A true CN111087851A (en) | 2020-05-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201911418992.9A Pending CN111087851A (en) | 2019-12-31 | 2019-12-31 | Preparation method of printer painting and calligraphy ink suitable for rice paper |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552743A (en) * | 2020-12-23 | 2021-03-26 | 南京柚香创意文化产业有限公司 | Quick-drying printer painting and calligraphy ink |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143386A (en) * | 2002-10-28 | 2004-05-20 | Seiko Epson Corp | Water-based ink |
| CN101914325A (en) * | 2010-08-19 | 2010-12-15 | 苏州世名科技股份有限公司 | Pseudoplastic water-based pigment type ink composition for ball pen and production process thereof |
| CN108948864A (en) * | 2018-07-02 | 2018-12-07 | 中稷油服(北京)科技有限公司 | A kind of aqueous pigment ink and its manufacturing method for high speed ink jet printer |
| CN110105808A (en) * | 2019-04-09 | 2019-08-09 | 中南大学 | A kind of Chinese painting ink and preparation method thereof with transparent ink trace |
-
2019
- 2019-12-31 CN CN201911418992.9A patent/CN111087851A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143386A (en) * | 2002-10-28 | 2004-05-20 | Seiko Epson Corp | Water-based ink |
| CN101914325A (en) * | 2010-08-19 | 2010-12-15 | 苏州世名科技股份有限公司 | Pseudoplastic water-based pigment type ink composition for ball pen and production process thereof |
| CN108948864A (en) * | 2018-07-02 | 2018-12-07 | 中稷油服(北京)科技有限公司 | A kind of aqueous pigment ink and its manufacturing method for high speed ink jet printer |
| CN110105808A (en) * | 2019-04-09 | 2019-08-09 | 中南大学 | A kind of Chinese painting ink and preparation method thereof with transparent ink trace |
Non-Patent Citations (2)
| Title |
|---|
| 中国纺织工程学会: "《第一届广东纺织助剂行业年会论文集》", 28 February 2009 * |
| 薛朝华等: "《纺织品数码喷墨印花技术》", 29 February 2008, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112552743A (en) * | 2020-12-23 | 2021-03-26 | 南京柚香创意文化产业有限公司 | Quick-drying printer painting and calligraphy ink |
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Application publication date: 20200501 |