CN110975319B - Zinc sulfate solution concentrating device and using method thereof - Google Patents

Zinc sulfate solution concentrating device and using method thereof Download PDF

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Publication number
CN110975319B
CN110975319B CN201911168330.0A CN201911168330A CN110975319B CN 110975319 B CN110975319 B CN 110975319B CN 201911168330 A CN201911168330 A CN 201911168330A CN 110975319 B CN110975319 B CN 110975319B
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China
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rotating
ring
fixed
rod
concentration
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Expired - Fee Related
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CN201911168330.0A
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CN110975319A (en
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张立军
李才发
张军
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Hunan Baoxiang New Material Co ltd
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Hunan Baoxiang New Material Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D9/00Crystallisation
    • B01D9/0018Evaporation of components of the mixture to be separated
    • B01D9/0031Evaporation of components of the mixture to be separated by heating

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

The invention discloses a zinc sulfate solution concentrating device which comprises a concentrating tank, four groups of supporting legs, a group of discharging holes, a group of stirring motors, a fixing frame, a heating pipe, a stirring device and a cleaning device, wherein four corners of the bottom of the concentrating tank are fixedly provided with the four groups of supporting legs, the bottom of the concentrating tank is provided with the group of discharging holes, the center of the top of the concentrating tank is provided with the group of stirring motors, one side of the top of the concentrating tank is provided with a feeding hole, the front end of a crankshaft of each stirring motor is fixedly provided with a rotating rod, the rotating rod is arranged inside the concentrating tank and penetrates through the fixing frame, the fixing frame is provided with the stirring device, the concentrating tank is divided into two groups of concentrating cavities through the fixing frame, the cleaning device is arranged on the rotating rod inside the concentrating cavities, and the top of one side edge of the concentrating tank is provided with an air guide pipe. This zinc sulfate solution enrichment facility, reasonable in design can carry out fine clearance to jar internal portion after the concentrated crystallization, is fit for using widely.

Description

Zinc sulfate solution concentrating device and using method thereof
Technical Field
The invention belongs to the technical field of zinc sulfate production, and particularly relates to a zinc sulfate solution concentration device and a use method of the zinc sulfate solution concentration device.
Background
Zinc sulfate is a main raw material for preparing lithopone and zinc salt, can also be used as a printing and dyeing mordant, a preservative for wood and leather, and is also an important auxiliary raw material for producing viscose fibers and vinylon fibers. In addition, it has applications in the electroplating and electrolysis industries, and can also be used to make cables.
Most of the conventional solution concentration devices cannot clean the internally bonded concentrated crystals well after use, and patent document publication No. CN209137995U discloses a zinc sulfate solution concentration device with high energy-saving, environment-friendly and concentration efficiency. The device has the problem that concentrated crystals adhered to the inner wall are inconvenient to clean after work.
Disclosure of Invention
The invention aims to provide a zinc sulfate solution concentrating device to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a zinc sulfate solution concentration device comprises a concentration tank, a stirring motor, a fixing frame, a heating pipe, a stirring device and a cleaning device, wherein four groups of supporting legs are fixed at four corners of the bottom of the concentration tank, a group of discharge ports are formed in the bottom of the concentration tank, a group of stirring motor is installed at the center of the top of the concentration tank, a feed inlet is formed in one side of the top of the concentration tank, a rotating rod is fixed at the front end of a motor shaft of the stirring motor and is arranged inside the concentration tank, the heating pipe is spirally and circularly embedded in the concentration tank, a group of cross-shaped fixing frame is fixed at the middle section of the concentration tank, an arc-shaped fixing ring is fixed on the fixing frame close to the outer edge, guide posts are fixed on the fixing ring, the rotating rod penetrates through the fixing frame, the stirring device is installed on the fixing frame, the concentration tank is divided into two groups of concentration cavities through the fixing frame, cleaning devices are arranged on the rotating rods in the concentration cavity, each cleaning device comprises a cross-shaped mounting frame, a transmission structure is arranged in the center of each mounting frame, a clamping device is arranged at the position, close to the outer edge, of each mounting frame, and an air guide pipe is arranged at the top of one side edge of each concentration tank;
cleaning device includes mounting bracket and clearance sword, the mounting bracket is the cross, and sets up on the dwang, and four groups landing legs are all established on the guide bar, the outer fringe of mounting bracket is fixed with a set of annular clearance sword, the clearance sword is hugged closely on concentrated jar inner wall, clamping device sets up in guide bar department.
The clamping device comprises a transmission ring, a clamping ring, a push rod and a lantern ring, a cavity groove is dug in the mounting frame and penetrates through the guide column, the semicircular clamping ring is arranged in the cavity groove in a sliding mode, the push rod is fixed to the outer edge of the clamping ring, the push rod is sleeved on the lantern ring, the transmission ring is rotatably arranged at the bottom of the lantern ring on the mounting frame, the top of the transmission ring is meshed with the bottom of the lantern ring, a mounting box is fixed to one side of the mounting frame, a rotating motor is installed in the mounting box, a rotating disc is arranged at the front end of a crankshaft of the rotating motor, and the rotating disc is meshed with the outer edge of the transmission ring;
the transmission structure comprises a hydraulic rod, a top plate and a rotating ring, the rotating ring is a semicircular ring, threads are arranged on the inner edge of the rotating ring, a group of top plates are fixed on the outer side edge of the rotating ring, the hydraulic rod is fixed on one side, far away from the rotating ring, of the top plate, and the two groups of rotating rings are combined and fixed on the rotating rod.
Preferably, agitating unit includes axis of rotation, first rotating disk and second rotating disk are fixed on the inside dwang of mount, the symmetry is provided with four groups of axis of rotation on the mount, is connected through the belt between two sets of axis of rotation of parallel and the first rotating disk, is connected through the belt between axis of rotation of two sets of parallels in addition and the second rotating disk, axis of rotation top and bottom all are fixed with the puddler, all be fixed with the stirring leaf on the puddler.
In addition, the invention also provides a using method of the carbon composite material flattening and forming device, which comprises the following steps:
when the concentration operation is performed, the electromagnetic valve at the discharge port is closed, zinc sulfate solution is added into the concentration tank through the feed port, the heating pipe is opened to heat the solution, the stirring motor is opened simultaneously, the rotating rod is driven to rotate when the stirring motor rotates, the first rotating disk and the second rotating disk are both rotated when the rotating rod rotates, the first rotating disk and the second rotating disk are connected with the rotating shaft through a belt, the stirring rod is further rotated to further stir the solution, the heating temperature is ensured to be concentrated under the adaptive temperature through a temperature sensor during the heating process, steam generated by concentration is discharged through an air duct, after the concentration is completed, concentrated crystals are discharged through the discharge port, crystals on the tank wall are simultaneously cleaned, when the tank wall is cleaned, the stirring motor is closed, the hydraulic rod is started, the hydraulic rod is extended, the top plate is further pushed, and then two groups of rotating rings are combined and fixed on the rotating rod, the rotation motor is started, the rotation motor rotates reversely and then enables the rotating disc to rotate, then the transmission ring rotates reversely, the lantern ring is driven to rotate reversely when the transmission ring rotates reversely, then the ejector rod is made to shrink, when the ejector rod shrinks, the clamping ring for clamping the guide post is driven to loosen, the stirring motor is opened at the moment, then the rotating rod rotates, the rotating rod is in threaded fit with the two sets of rotating rings, then the cleaning device descends, and then the crystal on the inner wall of the concentration tank is scraped by the cleaning knife, after the cleaning is finished, the cleaning device is made to recover the original position, meanwhile, the clamping device is made to clamp at the guide post, and the rotating rings loosen.
The invention has the technical effects and advantages that: the zinc sulfate solution concentration device comprises a cleaning device, a mounting frame and a cleaning knife in the cleaning device can well clean the inside of the tank wall, a clamping device in the cleaning device, a mounting box in the clamping device, a transmission ring, a clamping ring, a top rod, a lantern ring and a guide post are matched, the position of the cleaning device can be well fixed in a concentrated state, a hydraulic rod in the transmission structure, a top plate, a rotating ring and threads on the rotating rod are matched through the transmission structure in the cleaning device, the rotating ring and the rotating rod can be in threaded fit when the cleaning is needed, the cleaning device is further enabled to move, the inner wall of the concentrated tank is effectively scraped, and a rotating shaft, a first rotating disc, a second rotating disc, a rotating rod and a stirring motor in the stirring device are matched through the arranged stirring device, the solution can be heated uniformly, and the concentration effect is improved. This zinc sulfate solution enrichment facility, reasonable in design can carry out fine clearance to jar internal portion after the concentrated crystallization, is fit for using widely.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a cross-sectional view of the present invention;
FIG. 3 is a cross-sectional view taken at A-A of the cleaning apparatus of FIG. 2 in accordance with the present invention;
FIG. 4 is a cross-sectional view taken at B-B of FIG. 2 in accordance with the present invention;
FIG. 5 is an enlarged view of the invention at C of FIG. 2;
fig. 6 is an enlarged view of the invention at D in fig. 3.
In the figure: 1 concentrated jar, 2 agitator motor, 3 feed inlets, 4 dwang, 5 heating pipes, 6 mounts, 7 solid fixed rings, 8 guide posts, 9 agitating unit, 10 axis of rotation, 11 first carousel, 12 second carousel, 13 cleaning device, 14 mounting brackets, 15 clearance sword, 16 clamping device, 17 mounting box, 18 driving rings, 19 clamp rings, 20 ejector pins, 21 lantern rings, 22 transmission structure, 23 hydraulic stem, 24 roof, 25 swivel becks.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1: the invention provides a zinc sulfate solution concentration device as shown in figures 1, 2, 4 and 5, which comprises a concentration tank 1, a stirring motor 2, a fixing frame 6, a heating pipe 5 and a stirring device 9, and is characterized in that: the concentrated tank 1 bottom four corners is fixed with four groups of supporting legs, concentrated tank 1 bottom is provided with a set of discharge gate, concentrated tank 1 top center department installs a set of agitator motor 2, concentrated tank 1 top one side is provided with feed inlet 3, agitator motor 2's spindle front end is fixed with dwang 4, and dwang 4 sets up inside concentrated tank 1, the inside of concentrated tank 1 inlays to establish and installs a set of temperature sensor, temperature sensor's model is male BCZ-8, heating pipe 5 spirals to encircle to inlay and establish in concentrated tank 1, set up the display on the concentrated tank 1 outer wall, can show temperature sensor's temperature, the middle section department of concentrated tank 1 is fixed with a set of cross mount 6, be close to outer fringe department on mount 6 and be fixed with curved solid fixed ring 7, all be fixed with guide post 8 on solid fixed ring 7, the dwang 4 passes mount 6, install agitating unit 9 on the mount 6.
Specifically, agitating unit 9 includes axis of rotation 10, first rolling disc 11 and second rolling disc 12 are fixed on 6 inside dwang 4 of mount, the symmetry is provided with four sets of axis of rotation 10 on the mount 6, is connected through the belt between two sets of axis of rotation 10 of parallel and the first rolling disc 11, is connected through the belt between the axis of rotation 10 of two sets of parallels in addition and the second rolling disc 12, axis of rotation 10 top and bottom all are fixed with the puddler, all be fixed with the stirring leaf on the puddler.
Specific, this zinc sulfate solution enrichment facility, concentrated during operation, close the solenoid valve of discharge gate department, through feed inlet 3 to 1 inside zinc sulfate solution that adds of concentrated jar, open heating pipe 5 and heat solution, open agitator motor 2 simultaneously, drive dwang 4 when agitator motor 2 rotates and rotate, dwang 4 rotates and then make first rolling disk 11 and second rolling disk 12 all rotate, be connected through the belt between first rolling disk 11 and second rolling disk 12 and the axis of rotation 10, and then make the puddler rotate, and then stir solution, guarantee through temperature sensor among the heating process that heating temperature concentrates under adaptation temperature, the vapour that the concentration produced passes through the air duct and discharges, after the concentration finishes, pass through discharge gate discharge with concentrated crystallization. This zinc sulfate solution enrichment facility, it is even to enable zinc sulfate solution afterheat, carries out fine concentration, improves concentration efficiency.
Example 2: the invention provides a zinc sulfate solution concentration device as shown in figures 1, 2, 3 and 6, which comprises a concentration tank 1, a stirring motor 2, a fixing frame 6, a heating pipe 5 and a stirring device 9, and is characterized in that: 1 bottom four corners of concentrated jar is fixed with four groups of supporting legs, 1 bottom of concentrated jar is provided with a set of discharge gate, 1 top center department of concentrated jar installs a set of agitator motor 2, 1 top one side of concentrated jar is provided with feed inlet 3, agitator motor 2's spindle front end is fixed with dwang 4, the middle part department of concentrated jar 1 is fixed with a set of cross mount 6, be close to outer fringe department on the mount 6 and be fixed with curved solid fixed ring 7, gu all be fixed with guide post 8 on 7, concentrated jar 1 divide into two sets of concentrated chambeies through mount 6, all is provided with cleaning device 13 on the dwang 4 of concentrated intracavity, the top is provided with the air duct on one side of concentrated jar 1, the end of giving vent to anger of air duct is provided with vapour eduction gear (can be suction fan etc.).
Specifically, cleaning device 13 includes mounting bracket 14, clearance sword 15, clamping device 16 and drive structure 22, mounting bracket 14 is the cross, mounting bracket 14 is installed on guide post 8, and then staggers with the mount, and sets up on dwang 4, and four groups of landing legs all overlap and establish on the guide bar, mounting bracket 14's outer fringe is fixed with a set of annular clearance sword 15, clearance sword 15 hugs closely on 1 inner wall of concentrated jar, mounting bracket 14 is close to the outer fringe department and is provided with clamping device 16, and clamping device 16 sets up in the guide bar department, the inside drive structure 22 that is provided with is located at the center of mounting bracket 14.
Specifically, transmission structure 22 includes hydraulic stem 23, roof 24 and swivel becket 25, swivel becket 25 is semi-circular ring, the inner edge of swivel becket 25 is provided with the screw thread, swivel becket 25 outside limit department is fixed with a set of roof 24, one side that swivel becket 25 was kept away from to roof 24 is fixed with hydraulic stem 23, and two sets of swivel becket 25 encloses into solid fixed ring 7 and with the dwang 4 between the screw-thread fit.
Specifically, the clamping device 16 comprises a transmission ring 18, a clamping ring 19, a top rod 20 and a sleeve ring 21, a cavity groove is dug in the mounting frame 14 and penetrates through the guide post 8, the semicircular clamping ring 19 is slidably arranged in the cavity groove, a rubber pad is arranged on the inner side wall of the clamping ring 19, the top rod 20 is fixed on the outer edge of the clamping ring 19, the top rod 20 is sleeved on the sleeve ring 21, the transmission ring 18 is rotatably arranged at the bottom of the sleeve ring 21 on the mounting frame 14, the transmission ring 18 is staggered with the stirring blades, the top of the transmission ring 18 is meshed with the bottom of the sleeve ring 21, a mounting box 17 is fixed on one side of the mounting frame 14, a rotating motor is installed in the mounting box 17, a rotating disc is arranged at the front end of a crankshaft of the rotating motor, and the rotating disc is meshed with the outer edge of the transmission ring 18.
Specifically, when the zinc sulfate solution concentrating device is used for cleaning the wall of a tank, the stirring motor 2 is turned off, the hydraulic rod 23 is started, the hydraulic rod 23 extends, the top plate 24 is further pushed, the two groups of rotating rings 25 are combined and fixed on the rotating rod 4, the rotating motor is started, the rotating motor rotates reversely, the rotating disc rotates, the driving ring 18 rotates reversely, the lantern ring 21 is driven to rotate reversely when the driving ring 18 rotates, the ejector rod 20 contracts, the clamping ring 19 clamping the guide post 8 is driven to loosen when the ejector rod 20 contracts, the stirring motor 2 is turned on at the moment, the rotating rod 4 rotates, the rotating rod 4 is in threaded fit with the two groups of rotating rings 25, the cleaning device 13 descends, the crystal on the inner wall of the concentrating tank 1 is scraped by the cleaning knife 15, the cleaning device 13 is restored to the original position after cleaning is finished, and the clamping device 16 is clamped at the guide post 8, and the rotating ring 25 is released. This zinc sulfate solution enrichment facility enables zinc sulfate solution and carries out fine clearance at concentrated crystallization discharge back to jar internal wall.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.

Claims (3)

1. The utility model provides a zinc sulfate solution enrichment facility, includes concentrated jar (1), agitator motor (2), mount (6), heating pipe (5), agitating unit (9) and cleaning device (13), its characterized in that: concentrated jar (1) bottom four corners is fixed with four groups of supporting legs, concentrated jar (1) bottom is provided with a set of discharge gate, concentrated jar (1) top center department installs a set of agitator motor (2), concentrated jar (1) top one side is provided with feed inlet (3), the spindle front end of agitator motor (2) is fixed with dwang (4), and dwang (4) set up inside concentrated jar (1), heating pipe (5) circle to encircle to inlay in concentrated jar (1), the well department of concentrated jar (1) is fixed with mount (6) of a set of cross, be close to the periphery department on mount (6) and be fixed with curved solid fixed ring (7), all be fixed with guide post (8) on solid fixed ring (7), dwang (4) pass mount (6), install agitating unit (9) on mount (6), the concentration tank (1) is divided into two groups of concentration cavities through a fixing frame (6), cleaning devices (13) are arranged on rotating rods (4) in the concentration cavities, and an air guide pipe is arranged at the top of one side edge of the concentration tank (1);
the cleaning device (13) comprises a mounting frame (14), a cleaning knife (15), a clamping device (16) and a transmission structure (22), the mounting frame (14) is cross-shaped and is arranged on the rotating rod (4), four groups of supporting legs are sleeved on the guide rod, a group of annular cleaning knives (15) are fixed on the outer edge of the mounting frame (14), the cleaning knives (15) are tightly attached to the inner wall of the concentration tank (1), the clamping device (16) is arranged at a position, close to the outer edge, of the mounting frame (14), the clamping device (16) is arranged at the position of the guide rod, and the transmission structure (22) is arranged inside the center of the mounting frame (14);
the clamping device (16) comprises a transmission ring (18), a clamping ring (19), a top rod (20) and a sleeve ring (21), a cavity groove is dug in the mounting frame (14) and penetrates through the guide column (8), a semicircular clamping ring (19) is arranged in the cavity groove in a sliding mode, the top rod (20) is fixed to the outer edge of the clamping ring (19), the top rod (20) is sleeved on the sleeve ring (21), the transmission ring (18) is rotatably arranged at the bottom of the sleeve ring (21) on the mounting frame (14), the top of the transmission ring (18) is meshed with the bottom of the sleeve ring (21), a mounting box (17) is fixed to one side of the mounting frame (14), a rotating motor is installed in the mounting box (17), a rotating disc is arranged at the front end of a crankshaft of the rotating motor, and the rotating disc is meshed with the outer edge of the transmission ring (18);
drive structure (22) include hydraulic stem (23), roof (24) and swivel becket (25), swivel becket (25) are semi-circular ring, the inner edge of swivel becket (25) is provided with the screw thread, swivel becket (25) outside limit department is fixed with a set of roof (24), one side that swivel becket (25) were kept away from in roof (24) is fixed with hydraulic stem (23), and is two sets of swivel becket (25) are merged and are fixed on dwang (4).
2. The zinc sulfate solution concentrating device of claim 1, characterized in that: agitating unit (9) are including axis of rotation (10), first rotating disk (11) and second rotating disk (12) are fixed on dwang (4) of mount (6) inside, the symmetry is provided with four sets of axis of rotation (10) on mount (6), is connected through the belt between two sets of axis of rotation (10) of parallel and first rotating disk (11), is connected through the belt between axis of rotation (10) of two sets of parallels in addition and second rotating disk (12), axis of rotation (10) top and bottom all are fixed with the puddler, all be fixed with the stirring leaf on the puddler.
3. The use method of the zinc sulfate solution concentrating device according to claim 2, characterized in that: the method comprises the following steps:
when the concentration operation is performed, the electromagnetic valve at the discharge port is closed, zinc sulfate solution is added into the concentration tank (1) through the feed port (3), the heating pipe (5) is opened to heat the solution, the stirring motor (2) is opened simultaneously, the stirring motor (2) drives the rotating rod (4) to rotate when rotating, the rotating rod (4) further enables the first rotating disk (11) and the second rotating disk (12) to rotate when rotating, the first rotating disk (11), the second rotating disk (12) and the rotating shaft (10) are connected through a belt, the stirring rod is further enabled to rotate, the solution is further stirred, the heating temperature is guaranteed to be concentrated at the adaptive temperature through a temperature sensor in the heating process, steam generated by concentration is discharged through an air duct, after the concentration is completed, concentrated crystals are discharged through the discharge port, crystals on the tank wall are simultaneously cleaned, and when the tank wall is cleaned, turning off the stirring motor (2), starting the hydraulic rod (23), extending the hydraulic rod (23), further pushing the top plate (24), further combining and fixing two groups of rotating rings (25) on the rotating rod (4), starting the rotating motor, rotating the rotating motor reversely to further rotate the rotating disc, further rotating the transmission ring (18), driving the lantern ring (21) to reversely rotate when the transmission ring (18) reversely rotates, further contracting the ejector rod (20), driving the clamping ring (19) clamping the guide post (8) to loosen when the ejector rod (20) contracts, opening the stirring motor (2) at the moment, further rotating the rotating rod (4), matching the rotating rod (4) with the two groups of rotating rings (25) through threads, further lowering the cleaning device (13), further scraping crystals on the inner wall of the concentration tank (1) through the cleaning knife (15), and after cleaning, restoring the cleaning device (13), at the same time, the clamping device (16) is clamped at the guide column (8) and the rotary ring (25) is released.
CN201911168330.0A 2019-11-26 2019-11-26 Zinc sulfate solution concentrating device and using method thereof Expired - Fee Related CN110975319B (en)

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CN201911168330.0A CN110975319B (en) 2019-11-26 2019-11-26 Zinc sulfate solution concentrating device and using method thereof

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CN110975319B true CN110975319B (en) 2022-04-26

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000135406A (en) * 1998-11-02 2000-05-16 Ishigaki:Kk Flocculating and concentrating device
CN107596721A (en) * 2017-10-30 2018-01-19 蔡素真 A kind of chemical crystallization kettle
CN208373089U (en) * 2018-05-23 2019-01-15 宿迁久巨环保科技有限公司 A kind of production zinc sulfate agitating device
CN208809973U (en) * 2018-08-03 2019-05-03 河北建设集团装饰工程有限公司 A kind of interior decoration coating tempering tank
CN109699795A (en) * 2019-01-12 2019-05-03 刘恒铄 A kind of coffee effective component extraction element
CN110115946A (en) * 2019-04-04 2019-08-13 朱振尧 A kind of industrial chemicals is mixed with storage device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000135406A (en) * 1998-11-02 2000-05-16 Ishigaki:Kk Flocculating and concentrating device
CN107596721A (en) * 2017-10-30 2018-01-19 蔡素真 A kind of chemical crystallization kettle
CN208373089U (en) * 2018-05-23 2019-01-15 宿迁久巨环保科技有限公司 A kind of production zinc sulfate agitating device
CN208809973U (en) * 2018-08-03 2019-05-03 河北建设集团装饰工程有限公司 A kind of interior decoration coating tempering tank
CN109699795A (en) * 2019-01-12 2019-05-03 刘恒铄 A kind of coffee effective component extraction element
CN110115946A (en) * 2019-04-04 2019-08-13 朱振尧 A kind of industrial chemicals is mixed with storage device

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