CN110974721B - Face-repairing powder ball and preparation method thereof - Google Patents

Abstract

The invention discloses a capacity-modifying powder ball and a preparation method thereof, wherein the capacity-modifying powder ball is prepared from the following raw materials in percentage by weight: 20-50% of a filler; 20-50% of a filling material b; 3-10% of a filling material; 1-8% of ethylhexyl palmitate; 1-6% of mineral oil; 1-20% of magnesium aluminum silicate; emollient a0.1-2%; 0.3-3% of emollient b; 0-1% of tocopherol acetate; 0.2 to 2 percent of preservative; 0.1 to 30 percent of colorant; 0-10% of bismuth oxychloride. The powder ball obtained by the invention has the effect of difficult pulverization.

Description

Face-repairing powder ball and preparation method thereof

Technical Field

The invention relates to the technical field of cosmetic for repairing the appearance, in particular to a powder ball for repairing the appearance and a preparation method thereof.

Background

The face beautifying function is to decorate the face contour to make the five sense organs of the face more stereo. The light-colored face-repairing brush can brighten the narrow and small part which is not protruded enough, and the dark-colored face-repairing brush can sweep the forehead, the nose bridge and the outer contour, so that the face looks more delicate, and the face-repairing brush plays a role in face-repairing.

Today's cosmetic products, most commonly cosmetic muffins and cosmetic sticks, and also in recent years the powder balls that have been introduced by the introduction attract a large number of consumers to purchase because they contain multiple colors and are aesthetically pleasing. The powder ball is made of the face-repairing powder, the face-repairing powder can be brushed on the outer surface of the powder ball by a brush, or the face-repairing powder on the powder ball is shaken by slight shaking and then dipped by a powder puff or a brush, and the number of the powder balls with different colors can be combined according to the needs to obtain the face-repairing color suitable for the skin color of a user.

Because a plurality of mutually independent powder balls can be contained in the box, and the powder balls are greatly collided and easily broken in the express transportation process, gaps can exist on the surfaces of partial powder balls, and the appearance of a product is seriously influenced.

Disclosure of Invention

Aiming at the defects in the prior art, the invention aims to provide a cosmetic powder ball which is not easy to crush.

The second purpose of the invention is to provide a preparation method of the cosmetic powder ball.

In order to achieve the first object, the invention provides the following technical scheme: the technical purpose of the invention is realized by the following technical scheme:

the appearance-repairing powder ball is prepared from the following raw materials in percentage by weight:

20-50% of filling material;

20-50% of filling material b;

4-30% of a filling material;

1-8% of ethylhexyl palmitate;

1-6% of mineral oil;

emollient a0.1-2%;

emollient b0.3-3%;

0-1% of tocopherol acetate;

0.2 to 2 percent of preservative;

0.1 to 30 percent of colorant;

0-10% of bismuth oxychloride;

the filler a consists of 96-99 wt% of mica and 1-4 wt% of triethoxy octyl silane; the filler b consists of 98-99 wt% of talcum powder and 1-2 wt% of polydimethylsiloxane; the filler c consists of a mixture of aluminum starch octenylsuccinate and aluminum magnesium silicate or aluminum magnesium silicate.

By adopting the technical scheme, the filler a, the filler b and the filler c mainly realize the filling effect, provide carriers for other liquid components, provide fine and smooth powder and provide fine, smooth and soft skin feel and hand feeling for the powder balls; in addition to the filling function. The aluminum octenyl succinate starch can bring smooth and velvet skin feel, reduce oily skin feel of a formula, make the makeup skin feel dry and comfortable, and absorb excessive oil of the skin.

In the filling material c, the magnesium aluminum silicate is used as a substance with a very large specific surface area and a very developed micropore system to provide a rigid structure for the powder ball, and liquid substances in the formula are adsorbed, so that the liquid can be adhered to the surfaces of other filling materials, the adsorption between the magnesium aluminum silicate and other filling materials is realized, the adsorption force between the materials is provided, and the strength of the powder ball is provided; on the other hand, after the aluminum octenylsuccinate starch is mixed with a liquid formula, a soft and glutinous mixture can be obtained and can be adhered to and filled in pores of aluminum magnesium silicate to obtain a compact rigid aluminum magnesium silicate framework, and then residual filling materials and liquid components are adhered to the surface and the rest pores to ensure that the obtained powder balls are not easy to crush.

The filler b and the filler c both contain a certain amount of liquid substances, the content of the liquid substances can be improved, and the adhesive strength among the components is improved by matching with ethylhexyl palmitate and mineral oil, so that the components are better adsorbed in magnesium aluminum silicate micropores. Tocopherol acetate can reduce lipid peroxidation and prevent free radical damage to skin. Bismuth oxychloride can provide a shiny pearlescent effect.

More preferably: the weight part ratio of aluminum starch octenylsuccinate to aluminum magnesium silicate in the filler c is 1:2.

by adopting the technical scheme, experiments show that the use ratio of aluminum octenylsuccinate starch to aluminum magnesium silicate is 1: and 2, the powder balls are not easy to crush, so that the transportation is guaranteed.

More preferably: the emollient b comprises the following components in parts by weight (1-2): (0.5-1): 2, sodium riboflavin phosphate and panthenol.

By adopting the technical scheme, experiments show that the emollient b consisting of the three substances has good moisturizing effect, is not easy to remove makeup and has low anaphylactic reaction. Meanwhile, as the panthenol is viscous liquid, the panthenol can be well adhered to the aluminum magnesium silicate framework, and the bonding strength of powder and the aluminum magnesium silicate in the formula is further improved.

More preferably: the weight part ratio of the ascorbyl palmitate, the riboflavin sodium phosphate and the panthenol is 1:1:2.

by adopting the technical scheme, experiments show that the emollient with the weight portion ratio can achieve a good moisturizing effect and is not easy to remove makeup, and meanwhile, the obtained powder balls are high in strength and not easy to break.

More preferably: the emollient a is prepared from the following components in percentage by mass of 1.5:1 and retinol palmitate.

By adopting the technical scheme, the almond oil has good oxidation resistance and stability, can be used as a bonding agent, improves the bonding among powder materials, can be adsorbed by magnesium aluminum silicate, further improves the bonding strength of powder balls, and reduces the occurrence of powder crumbs. The retinol palmitate is vitamin A, and can improve skin roughness and cornification, and make skin more delicate.

More preferably: the preservative consists of 65 weight percent of phenoxyethanol and 35 weight percent of octoglycol.

By adopting the technical scheme, the antiseptic effect is achieved, and the possibility of bacterial breeding is reduced.

In order to achieve the second object, the invention provides the following technical scheme: a preparation method of a cosmetic powder ball comprises the following steps:

s1: weighing the filler a, the filler b, the filler c, the coloring agent and the bismuth oxychloride, and uniformly mixing at the temperature of 45-55 ℃ to obtain a mixture A;

s2: adding the rest raw materials into the mixture A, and uniformly mixing at the temperature of 45-55 ℃ to obtain a mixture B;

s3: adding the mixture B into a granulator at a feeding speed of 48-51g/min, adding 75% alcohol by mass, wherein the mass ratio of the alcohol to the mixture B is 1; starting the ball forming machine at the rotating speed of 45r/min, forming the balls to the diameter of 5 +/-0.2 mm, and discharging to obtain powder balls;

s4: standing the powder ball for 24h at 20-28 deg.C, standing at 85 deg.C for 5h, and cooling to room temperature.

By adopting the technical scheme, the raw materials are uniformly mixed, and are formed into balls, and finally, the balls are baked at high temperature to obtain stable powder balls.

More preferably: in the step S1 and the step S2, the components are mixed by stirring, the stirring speed is 2300-2600r/min, the stirring time is 1-3min, and the temperature is 50-55 ℃.

By adopting the technical scheme, the aluminum starch octenylsuccinate adhered to the liquid component is gradually gelatinized when heated and stirred at the temperature, and the aluminum starch octenylsuccinate is converted into colloid adsorbing the liquid component after standing, so that the obtained powder has certain elasticity, the overall toughness of the powder ball is improved, the brittleness of the powder ball is improved, and the possibility of crushing the powder is reduced.

In conclusion, the invention has the following beneficial effects:

1. the aluminum magnesium silicate is mixed with a liquid component in the filling material and aluminum octenylsuccinate starch in a liquid formula to obtain a soft and glutinous mixture which can be adhered to and filled in pores of the aluminum magnesium silicate to obtain a compact rigid aluminum magnesium silicate framework, and then the rest filling material and liquid components are adhered to the surface and the rest pores to ensure that the obtained powder balls are not easy to crush;

2. by adopting ascorbyl palmitate, riboflavin sodium phosphate and panthenol, a good moisturizing effect can be achieved, makeup is not easy to remove, and the obtained powder balls are high in strength and not easy to pulverize;

3. by adopting the stirring temperature of 50-55 ℃, the aluminum octenyl succinate starch can be converted into colloid which absorbs liquid components, so that the obtained powder has certain elasticity, the integral toughness of the powder ball is improved, the brittleness of the powder ball is improved, and the possibility of crushing is reduced.

Detailed Description

Examples 1-5A cosmetic powder ball comprising the components and corresponding masses shown in Table 1, based on 100kg of total weight, was prepared by the following steps

S1: weighing the filler a, the filler b, the filler c, the aluminum magnesium silicate, the colorant and the bismuth oxychloride, putting the weighed materials into a powder grinding machine, and stirring the materials for 1min at a stirring speed of 2500r/min and a temperature of 55 ℃ to obtain a mixture A;

s2: weighing the rest raw materials, putting into a powder grinding machine of the mixture A, and stirring at a stirring speed of 2500r/min and a temperature of 55 ℃ for 1min to obtain a mixture B;

s3: adding the mixture B into a ball forming mill at a feeding speed of 50g/min, and adding alcohol with the mass concentration of 75% and the same mass as that of the mixture B; setting the rotating speed of the ball forming machine at 45r/min, starting the ball forming machine, taking the balls out of the pot after the balls are formed and reach the size of 5 +/-0.2 mm in diameter, and obtaining powder balls;

s4: standing the powder balls for 24h in an environment at 25 ℃, then putting the powder balls into an oven at 85 ℃ for standing for 5h, taking out the powder balls, and cooling to 25 ℃.

TABLE 1 examples 1-5 compositions and corresponding masses (kg)

In the above examples, the particle size of mica is 6 to 10 μm, the particle size of talc is 6 to 10 μm, the particle size of aluminum starch octenylsuccinate is 6 to 10 μm, the particle size of magnesium aluminum silicate is 6 to 10 μm, and the particle size of bismuth oxychloride is 6 to 15 μm; the colorant is a mixture of CI 15850 and CI 77891 in a weight part ratio of 1. The preservative consists of 65 weight percent of phenoxyethanol and 35 weight percent of octoglycol.

In example 1, the filler a was composed of 96% by weight of mica and 4% by weight of triethoxyoctylsilane; the filler b consists of 99 percent of talcum powder and 1 percent of polydimethylsiloxane; the filling material c consists of 1 part by weight of aluminum octenyl succinate starch and aluminum magnesium silicate. The emollient a consists of almond oil and retinol palmitate with the mass ratio of 0.5; the emollient b is composed of 1.

In example 2, the compositions of the filler a, the filler b, the filler c and the emollient a were the same as those of example 1; the emollient b is composed of 1.5 parts by weight of ascorbyl palmitate, sodium riboflavin phosphate and panthenol.

In example 3, the filler a was composed of 99% by weight of mica and 1% by weight of triethoxyoctylsilane; the filling material b consists of 98 percent of talcum powder and 2 percent of polydimethylsiloxane; the filler c is aluminum magnesium silicate. The emollient a consists of almond oil and retinol palmitate with the mass ratio of 1; the emollient b is composed of ascorbyl palmitate, riboflavin sodium phosphate and panthenol in a weight ratio of 2.8.

In example 4, filler a consisted of 97% by weight of mica and 3% by weight of triethoxyoctylsilane; the filling material b consists of 98 percent of talcum powder and 2 percent of polydimethylsiloxane; the filling material c consists of 2 parts by weight of aluminum octenyl succinate starch and aluminum magnesium silicate. The emollient a consists of almond oil and retinol palmitate with the mass ratio of 1; the emollient b is composed of 1.5 parts by weight of ascorbyl palmitate, 1.2 parts by weight of riboflavin sodium phosphate and panthenol.

In example 5, filler a was composed of 98% by weight of mica and 2% by weight of triethoxyoctylsilane; the filling material b consists of 98 percent of talcum powder and 2 percent of polydimethylsiloxane; the filling material c consists of 1 part by weight of aluminum octenyl succinate starch and 1 part by weight of aluminum magnesium silicate. Emollient a had the same composition as example 4; the emollient b is composed of 1.5 parts by weight of ascorbyl palmitate, 1 part by weight of riboflavin sodium phosphate and panthenol, and the weight ratio of the ascorbyl palmitate to the riboflavin sodium phosphate to the panthenol is.

Example 6 a cosmetic powder ball, which is different from example 5 in that the filler c is composed of 1 part by weight of aluminum octenylsuccinate starch and 2 parts by weight of magnesium aluminum silicate.

Example 7 a cosmetic powder ball, which differs from example 6 in that emollient b consists of ascorbyl palmitate, sodium riboflavin phosphate and panthenol in the weight ratio of 1.

Example 8 a cosmetic powder ball different from example 7 in that emollient a is prepared from a mixture of 1.5:1 and retinol palmitate.

Example 9A method of making a cosmetic powder ball comprising the steps of

S1: weighing the filler a, the filler b, the filler c, the colorant and the bismuth oxychloride, putting the weighed materials into a powder grinding machine, and stirring the materials for 2min at the stirring speed of 2300r/min and the temperature of 50 ℃ to obtain a mixture A;

s2: weighing the rest raw materials, adding into a powder grinding machine of the mixture A, and stirring at a stirring speed of 2300r/min and at a temperature of 50 ℃ for 2min to obtain a mixture B;

s3: adding the mixture B into a ball forming mill at a feeding speed of 51g/min, and adding alcohol with the mass concentration of 75% and the same mass as that of the mixture B; setting the rotating speed of the ball forming machine at 45r/min, starting the ball forming machine, taking the balls out of the pan after the balls are formed and reach the size of 5 +/-0.2 mm, and obtaining powder balls;

s4: standing the powder balls for 24h at 20 ℃, then putting the powder balls into an oven at 85 ℃ for standing for 5h, taking out the powder balls, and cooling to 25 ℃.

Example 10A method of making a cosmetic powder ball comprising the steps of

S1: weighing the filler a, the filler b, the filler c, the colorant and the bismuth oxychloride, putting the materials into a powder grinding machine, and stirring the materials for 3min at the stirring speed of 2600r/min and the temperature of 45 ℃ to obtain a mixture A;

s2: weighing the rest raw materials, putting into a powder grinding machine of the mixture A, and stirring at a stirring speed of 2600r/min and a temperature of 45 ℃ for 3min to obtain a mixture B;

s3: adding the mixture B into a ball forming mill at a feeding speed of 48g/min, and adding alcohol with the mass concentration of 75% and the mass of the mixture B; setting the rotating speed of the ball forming machine at 45r/min, starting the ball forming machine, taking the balls out of the pan after the balls are formed and reach the size of 5 +/-0.2 mm, and obtaining powder balls;

s4: standing the powder balls for 24h in an environment at 28 ℃, then putting the powder balls into an oven at 85 ℃ for standing for 5h, taking out the powder balls, and cooling to 25 ℃.

Comparative example 1: a difference from example 1 is that the amount of the filler c used is 0.

Comparative example 2: the difference between the repair powder ball and the embodiment 1 is that the filler a is mica, the filler b is talcum powder, and the usage amount of the filler c is 0.

Comparative example 3: the difference of the cosmetic powder ball from the example 1 is that the filler a is mica, the filler b is talcum powder, and the usage amount of the filler c, the emollient a and the emollient b is 0.

Comparative example 4: a method for preparing a cosmetic powder ball, which is different from the method of example 10 in that the temperature during stirring in steps S1 and S2 is 20 ℃.

Comparative example 5: a method for preparing a cosmetic powder ball, which is different from the method of example 10 in that the temperature during stirring in steps S1 and S2 is 60 ℃.

Characterization experiment:

1. transportation simulation experiment

(1) Effect of powder ball formulation on powder ball Strength

Subject: examples 1-8 and comparative examples 1-3, for a total of 11 experimental groups.

The experimental method comprises the following steps: the obtained examples 1 to 8 and comparative examples 1 to 3 are respectively filled into product packaging boxes according to the product specification, and the weight of all the powder balls is weighed to be accurate to 0.01g before packaging; after being put into a packaging box, the product packaging box is covered with a layer of bubble bag, and then the product packaging box is put into a corrugated paper box and finally sealed by an adhesive tape. A simulated transportation vibration experiment table is prepared, the time of a timer is 10min, and the rotating speed is set to be 100. After the simulation is finished, the corrugated paper box and the bubble bag are detached, the powder balls and the crushed powder in the product packaging box are poured into a grid plastic cloth with the grid size of 3 x 3mm, the crushed powder and the crushed particles are filtered, then the powder balls are weighed, the total weight difference of the powder balls before and after each sample is recorded, the surface crack stripping condition of the powder balls is observed, the crack is marked from serious to no by 5-0 minutes, 0 is no crack, and 5 is crack stripping serious.

The experimental results are as follows: the results of the transport simulation experiments are reported in table 2.

TABLE 2 recording of powder ball transportation simulation experiment results (powder ball formula)

And (3) data analysis: as can be seen from the data in Table 2, the weight differences of examples 1 to 8 are smaller than those of comparative examples 1 to 3, which indicates that the appearance of the examples is better in the transportation experiment, and cracks and peeling appear on the surfaces of the comparative examples, which indicates that the powder balls of the examples show better strength and adhesion between the raw materials, and are not easy to crumble and fall off.

The filler c, the emollient a and the emollient b are combined in the optimal proportion in the example 8, the powder falling amount of the obtained powder ball is also minimum, the emollient b in the examples 2 and 4-7 is in the limited proportion range, the liquid-solid component proportion in the formula promotes the bonding with the magnesium aluminum silicate, the bonding among the raw materials is improved, and the crushed powder can be reduced. In example 3, the filler c only uses magnesium aluminum silicate, and the weight difference is slightly larger than that of the mixture of the magnesium aluminum silicate and aluminum octenylsuccinate starch, which shows that the aluminum octenylsuccinate starch can ensure that the obtained powder has certain elasticity, improve the overall toughness of the powder ball, improve the brittleness of the powder ball and reduce the possibility of powder crushing.

In the comparative example 1, no filler c is adopted, and the powder falling condition of the powder balls is serious; comparative example 2 of the filler a and the filler b on the basis of the comparative example 1, triethoxyoctylsilane and polydimethylsiloxane are not used, so that the powder falling condition of powder balls is more serious, and cracks are formed on the outer surface; comparative example 3 based on comparative example 2, the solid-liquid ratio of the whole formula is damaged without using the emollient a and the emollient b, the powder falling of the powder balls is serious, and the outer surface has cracks and peeling.

(2) Influence of preparation method of powder ball on strength of powder ball

Subjects: the formulation of example 8 was prepared corresponding to the preparation of examples 1, 9-10 and comparative examples 4-5 to obtain a total of 5 experimental samples of examples 1, 9-10 and comparative examples 4-5.

The experimental method comprises the following steps: the same experimental procedure as for "(1) the effect of powder ball formulation on powder ball strength".

The experimental results are as follows: the results of the transport simulation are reported in table 3.

TABLE 3 simulation of powder transportation results record (powder ball preparation method)

And (3) data analysis: as can be seen from the data in Table 3, the reasonable heating and stirring temperature can promote the formation of aluminum octenylsuccinate starch colloid, so that the obtained powder has certain elasticity, the overall toughness of the powder ball is improved, the brittleness of the powder ball is improved, and the possibility of powder crushing is reduced.

The above-mentioned embodiments are merely illustrative and not restrictive, and those skilled in the art can modify the embodiments without inventive contribution as required after reading this specification, but only fall within the scope of the claims of the present invention.

Claims (5)

1. The face-repairing powder ball is characterized by being prepared from the following raw materials in percentage by weight:

20-50% of a filler;

20-50% of filling material b;

4-30% of a filling material;

1-8% of ethylhexyl palmitate;

1-6% of mineral oil;

emollient a0.1-2%;

emollient b0.3-3%;

0-1% of tocopherol acetate;

0.2 to 2 percent of preservative;

0.1 to 30 percent of colorant;

0-10% of bismuth oxychloride;

the filler a consists of 96-99% by weight of mica and 1-4% by weight of triethoxyoctylsilane;

the filler b consists of 98-99 wt% of talcum powder and 1-2 wt% of polydimethylsiloxane;

the filling material c is a mixture of aluminum octenylsuccinate starch and aluminum magnesium silicate, and the weight part ratio of the aluminum octenylsuccinate starch to the aluminum magnesium silicate is 1;

the emollient a is prepared from the following components in percentage by mass of 1.5:1 almond oil and retinol palmitate;

the emollient b comprises the following components in parts by weight (1-2): (0.5-1): 2, sodium riboflavin phosphate and panthenol.

2. The face beautifying powder ball as claimed in claim 1, wherein the weight part ratio of the ascorbyl palmitate, the riboflavin sodium phosphate and the panthenol is 1:1:2.

3. the face powder ball of claim 1, wherein the preservative is comprised of 65% by weight phenoxyethanol and 35% by weight caprylyl glycol.

4. A method of making a cosmetic powder ball according to any one of claims 1 to 3, comprising the steps of:

s1: weighing the filler a, the filler b, the filler c, the coloring agent and the bismuth oxychloride, and uniformly mixing at the temperature of 45-55 ℃ to obtain a mixture A;

s2: adding the rest raw materials into the mixture A, and uniformly mixing at the temperature of 45-55 ℃ to obtain a mixture B;

s3: adding the mixture B into a ball forming mill at a feeding speed of 48-51g/min, adding 75% alcohol by mass, wherein the mass ratio of the alcohol to the mixture B is 1; starting the ball forming machine at a rotating speed of 45r/min, forming the balls until the diameter of the balls is 5 +/-0.2 mm, and discharging to obtain powder balls;

s4: standing the powder ball for 24h at 20-28 deg.C, standing at 85 deg.C for 5h, and cooling to room temperature.

5. The method for preparing the cosmetic powder ball as claimed in claim 4, wherein the mixing in the steps S1 and S2 is carried out by stirring at a speed of 2300-2600r/min for 1-3min at a temperature of 50-55 ℃.