CN110951123B - Manufacturing process of super-wear-resistant belt - Google Patents

Manufacturing process of super-wear-resistant belt Download PDF

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CN110951123B
CN110951123B CN201911277578.0A CN201911277578A CN110951123B CN 110951123 B CN110951123 B CN 110951123B CN 201911277578 A CN201911277578 A CN 201911277578A CN 110951123 B CN110951123 B CN 110951123B
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wear
belt
parts
resistant
weight
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CN110951123A (en
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陈露
黄凯军
余佳政
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Zhejiang Weiger Transmission Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

The invention relates to a manufacturing process of a super wear-resistant belt, which relates to the technical field of belts and comprises the following process steps: s1: the raw materials are put into an extruder in proportion for mixing, and after mixing is finished, the raw materials are extruded to obtain a mixed rubber material; s2: introducing the mixed rubber material into a calender for calendering to obtain a formed belt; s3: and (5) coiling and packaging the formed belt to obtain a finished belt product. The invention has the effect of improving the wear resistance of the belt.

Description

Manufacturing process of super-wear-resistant belt
Technical Field
The invention relates to the technical field of belts, in particular to a manufacturing process of a super-wear-resistant belt.
Background
The belt is also called a transmission belt, which is a main body component of the belt transmission. Belt drives are one form of drive that is important in mechanical drives.
The prior transmission belt manufacturing process, for example, Chinese patent with publication No. CN100418744C, discloses a preparation process of an elastic rubber transmission belt. The process for preparing the elastic rubber transmission belt comprises the following steps: firstly, mixing rubber materials and other auxiliary materials, mixing, thinly passing and cutting into rubber sheets, then wrapping the cut rubber sheets on a cylindrical blank-making mould with certain elasticity, sequentially winding high-elasticity bone threads on the rubber sheets and wrapping the rubber sheets to obtain cylindrical rubber blanks, thirdly, sleeving the cylindrical rubber blanks on a vulcanization inner mould, placing the cylindrical rubber blanks in a vulcanization outer mould for vulcanization, and finally demoulding, cutting and packaging the formed transmission belt blanks. The elastic rubber transmission belt prepared by the method provided by the invention has the deformation of more than 20% and the service life of 15 years.
The above prior art solutions have the following drawbacks: for the aforesaid drive belt in actual practical process, the friction between drive belt and the drive wheel can cause the wearing and tearing on drive belt surface, and is especially obvious in some high-speed moving equipment, and wearing and tearing are more quick, the drive belt receives wearing and tearing back, and its driven performance can receive the influence, need change the drive belt immediately, and the change makes the work efficiency who uses this equipment obtain the reduction of certain degree.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a manufacturing process of a super wear-resistant belt, and the wear resistance of the manufactured belt is greatly improved.
The above object of the present invention is achieved by the following technical solutions:
a manufacturing process of an ultra-wear-resistant belt comprises the following process steps:
s1: the raw materials are put into an extruder in proportion for mixing, and after mixing is finished, the raw materials are extruded to obtain a mixed rubber material, wherein the raw materials comprise the following components in parts by weight:
Figure BDA0002312986680000011
Figure BDA0002312986680000021
s2: introducing the mixed rubber material into a calender for calendering to obtain a formed belt;
s3: and (5) coiling and packaging the formed belt to obtain a finished belt product.
By adopting the technical scheme, the super wear-resistant belt is mixed according to the raw material proportion, then the mixture is subjected to mixing extrusion to obtain a mixed material, all components in the mixed material are uniformly mixed by an extruder, then the mixed material is introduced into a calender for calendering and molding, the belt is obtained after molding, and then the belt is rolled and packaged. The production process of the super wear-resistant belt is simple and rapid, the working procedures are few, and the efficiency is high.
The raw materials of the super wear-resistant belt comprise butadiene rubber, natural rubber, styrene-butadiene rubber and wear-resistant resin which are used as main matrix resin of the super wear-resistant belt, so that the wear resistance of the super wear-resistant belt is enhanced. The addition of the wear-resistant filler and the filler reinforces the belt and reduces the volume cost. The stearic acid can soften and plasticize the matrix resin, fully disperse the filler and the wear-resistant filler, and promote the vulcanization of the rubber. The anti-aging agent is mainly used for prolonging the practical service life of the belt, reaches the surface of the belt through the migration effect and reacts with substances such as ozone and the like which cause aging, thereby achieving the purpose of prolonging the service life. The accelerator and the sulfur enable the rubber to be vulcanized, the reaction between the sulfur and the rubber is slow, the vulcanization is activated after the accelerator is added, the vulcanization time is shortened, and the efficiency is improved. By adding short fibers, the rubber is reinforced, and the rigidity of the belt in the length direction is enhanced by controlling the orientation of the fibers.
The present invention in a preferred example may be further configured to: the wear-resistant resin comprises the following components in percentage by weight:
20-50% of polyvinylidene fluoride;
15-40% of polyether-ether-ketone
10-40% of ultra-high molecular weight polyethylene.
By adopting the technical scheme, the polyvinylidene fluoride is a polymer of vinylidene fluoride, has the characteristics of both fluororesin and general resin, and has the characteristics of good chemical corrosion resistance, oxidation resistance and high strength; the polyether-ether-ketone is a special high polymer material, has better corrosion resistance and high temperature resistance, and has fatigue resistance under alternating stress which is comparable with that of an alloy material; the ultra-high molecular weight polyethylene is a thermoplastic engineering material with a linear structure, has very high strength and super wear resistance. Therefore, when the wear-resistant resin obtained by mixing polyvinylidene fluoride, polyether-ether-ketone and ultra-high molecular weight polyethylene is combined with other matrix resins in the raw materials, the wear-resistant performance of the belt is greatly enhanced, and the weather resistance and the corrosion resistance of the belt to the environment are enhanced. The present invention in a preferred example may be further configured to: according to the weight percentage, 2-3% of an auxiliary agent is also added into the wear-resistant resin, and the auxiliary agent comprises the following components in percentage by weight:
30-60% of sucrose ester;
20-30% of fluorocarbon surfactant;
20-40% of pentaerythritol ester.
By adopting the technical scheme, the sucrose ester, the fluorocarbon surfactant and the pentaerythritol ester are taken as the surfactants, and have the effect of promoting dispersion of all components in the wear-resistant resin, so that when all components in the wear-resistant resin are mixed with other matrix resins in the raw materials, the components are mixed more uniformly, all parts of the belt have uniform and stable performance, and the wear-resistant strength is excellent. The sucrose ester and the pentaerythritol ester contain a large amount of hydroxyl, and the oxygen in fluorine in polyvinylidene fluoride in the wear-resistant resin and the oxygen in carbonyl in polyether ether ketone in the wear-resistant resin are easy to form hydrogen bonds with hydroxyl hydrogen in the sucrose ester and the pentaerythritol ester, and the hydrogen bonds are less formed when the raw materials are mixed, so that the components in the auxiliary agent play a main role of a surfactant to disperse materials, and when extrusion, calendering and shaping are carried out, the hydrogen bonds are more formed, so that the auxiliary agent is used for connecting the components of the wear-resistant resin, a similar net structure is formed in the belt after calendering, the strength of the belt is improved, and the wear resistance of the wear-resistant resin to the belt is enhanced. The fluorocarbon surfactant has good compatibility, and can make sucrose ester and pentaerythritol ester well compatible. The present invention in a preferred example may be further configured to: the wear-resistant filler comprises the following components in percentage by weight:
50-60% of porous ceramic microspheres;
40-50% of nano magnesium oxide.
By adopting the technical scheme, the porous ceramic microspheres and the nano magnesium oxide have higher strength, wherein the size of the porous ceramic microspheres is equivalent to the fineness of common coating, the porous ceramic microspheres can be dispersed in a resin matrix, and the dispersed porous ceramic microspheres can improve the strength and the wear resistance of the belt. On one hand, the nano magnesium oxide can improve the mechanical strength of the belt and the wear resistance of the belt, and meanwhile, the flame retardant property of the belt can be improved by adding a large amount of nano magnesium oxide, so that the belt can be prevented from being burnt to be broken, and the safety is improved.
The present invention in a preferred example may be further configured to: the anti-aging agent comprises the following components in percentage by weight:
20-40% of N-phenyl-2-naphthylamine;
20-30% of N-phenyl-N' -isopropyl-p-phenylenediamine;
30-50% of N- (1, 3-dimethyl) butyl-N' -phenyl p-phenylenediamine;
by adopting the technical scheme, the N-phenyl-2-naphthylamine, the N-phenyl-N '-isopropyl-p-phenylenediamine and the N- (1, 3-dimethyl) butyl-N' -phenyl-p-phenylenediamine can play an anti-aging role in rubber components in the belt, and can migrate to the surface of the belt, so that substances which can generate oxidation action with the belt on the surface of the belt are reacted, and the service life of the belt is prolonged. The N-phenyl-N '-isopropyl-p-phenylenediamine and the N- (1, 3-dimethyl) butyl-N' -phenyl-p-phenylenediamine belong to p-phenylenediamine antioxidants, and can be complexed with stearic acid in raw materials to form a part of p-phenylenediamine antioxidants, and the stearic acid is used as a slow release agent, so that the antioxidants can be released and migrated to the surface to be supplemented after the antioxidants on the surface of the belt react, and the service life of the antioxidants is prolonged.
The belt generates heat due to friction in the using process, the more the generated heat is, the more the antioxidant complexed by stearic acid is released, the higher the concentration of the antioxidant on the surface of the belt is, so that the anti-aging capability of the belt is enhanced under the condition of higher temperature, and the service life of the belt is prolonged. And the nano magnesium oxide and the porous ceramic microspheres in the wear-resistant filler have good heat conductivity, so that heat generated in the moving process of the belt can be quickly transferred, the antioxidant complexed by stearic acid in the belt is quickly released in response, and the aging resistance of the belt is improved.
The present invention in a preferred example may be further configured to: the filler comprises the following components in percentage by weight:
70-80% of carbon black;
10-20% of white carbon black;
5-10% of a coupling agent.
By adopting the technical scheme, the filler is added to modify the carbon black and the white carbon black into the dual-phase filler for the belt, and the white carbon black is dispersed in the carbon black phase, so that the interaction between the filler and the filler is reduced, the action between the filler and the rubber is improved, and the wear resistance of the matrix resin is improved. The addition of the coupling agent causes a small amount of gel to be generated during the mixing of the raw materials in the extruder, and the gel helps to increase the viscosity of the matrix resin, thereby causing a tighter bond between the matrix resin and the filler.
The present invention in a preferred example may be further configured to: the temperature of a feeding section in the extruder is controlled to be 55-65 ℃, the temperature of a screw of the extruder is controlled to be 80-90 ℃, and the temperature of a machine head of the extruder is controlled to be 90-100 ℃.
The present invention in a preferred example may be further configured to: the upper roll temperature of the calender is controlled to be 60-70 ℃, the middle roll temperature of the calender is controlled to be 55-65 ℃, and the cooling roll temperature of the calender is controlled to be 20-30 ℃.
In summary, the invention includes at least one of the following beneficial technical effects:
1. the wear-resistant resin and the auxiliary agent are added into the raw materials for manufacturing the belt, so that the wear-resistant capability of the belt obtained by production is greatly improved;
2. the wear-resistant filler is added to assist in improving the strength and the wear resistance of the belt, and meanwhile, the migration of the anti-aging agent is promoted, so that the surface of the belt is not easy to age, and the service life of the belt is prolonged.
Detailed Description
The present invention will be described in further detail below.
Example 1:
the invention discloses a manufacturing process of a super wear-resistant belt, which comprises the following process steps:
s1: 60 parts of butadiene rubber, 20 parts of natural rubber, 20 parts of styrene-butadiene rubber, 15 parts of wear-resistant resin, 1 part of wear-resistant filler, 60 parts of filler, 1 part of stearic acid, 2 parts of anti-aging agent, 2 parts of accelerator, 2 parts of sulfur and 8 parts of short fiber are put into an extruder in proportion for mixing, the temperature of a feeding section in the extruder is controlled at 55 ℃, the temperature of a screw rod of the extruder is controlled at 80 ℃, the temperature of a machine head of the extruder is controlled at 90 ℃, and after mixing is completed, the mixed rubber material is obtained by extrusion.
S2: introducing the mixed rubber material into a calender for calendering, controlling the temperature of an upper roll of the calender at 60 ℃, the temperature of a middle roll of the calender at 55 ℃, controlling the temperature of a cooling roll of the calender at 20 ℃, and obtaining a forming belt after calendering treatment;
s3: and (5) coiling and packaging the formed belt to obtain a finished belt product.
In the raw materials, the wear-resistant resin comprises the following components in percentage by weight:
Figure BDA0002312986680000051
Figure BDA0002312986680000061
the auxiliary agent comprises the following components in percentage by weight:
60% of sucrose ester;
20% of fluorocarbon surfactant;
20 percent of pentaerythritol ester.
In the raw materials, the wear-resistant filler comprises the following components in percentage by weight:
50% of porous ceramic microspheres;
50 percent of nano magnesium oxide.
In the raw materials, the anti-aging agent comprises the following components in percentage by weight:
40% of N-phenyl-2-naphthylamine;
30% of N-phenyl-N' -isopropyl-p-phenylenediamine;
30% of N- (1, 3-dimethyl) butyl-N' -phenyl-p-phenylenediamine;
in the raw materials, the filler comprises the following components in percentage by weight:
80% of carbon black;
10% of white carbon black;
10% of coupling agent.
The difference between the examples 2-5 and the example 1 is that the raw materials are shown in the following table 1 in terms of parts by weight.
Examples 6 to 12 are different from example 1 in that the components in the abrasion resistant resin are shown in the following table 2 in percentage by weight.
Examples 13 to 16 are different from example 1 in that the components in the adjuvant are in the following table 3 in weight percentage.
Examples 17 to 20 differ from example 1 in that the components in the wear-resistant filler are in the following table 4 in weight percent.
Examples 21 to 28 are different from example 1 in that the components in the antioxidant are in the following Table 5 in terms of weight percent.
Examples 29 to 36 are different from example 1 in that the respective components in the filler are in the following table 6 in weight percentage.
Examples 37 to 40 are different from example 1 in that the operating temperatures of the respective portions in the extruder are shown in Table 7 below.
Examples 41 to 44 are different from example 1 in that the working temperature of each part in the calender is shown in the following Table 8.
TABLE 1
Figure BDA0002312986680000062
Figure BDA0002312986680000071
TABLE 2
Figure BDA0002312986680000072
TABLE 3
Figure BDA0002312986680000073
TABLE 4
Figure BDA0002312986680000074
Figure BDA0002312986680000081
TABLE 5
Figure BDA0002312986680000082
TABLE 6
Figure BDA0002312986680000083
Figure BDA0002312986680000091
TABLE 7
Examples Feed section (. degree.C.) Screw (° c) Head (. degree. C.)
Example 37 57.5 82.5 92.5
Example 38 60 85 95
Example 39 62.5 87.5 97.5
Example 40 65 90 100
TABLE 8
Examples Upper roll (. degree. C.) Middle roller (DEG C) Chill roll (. degree. C.)
EXAMPLE 41 62.5 57.5 22.5
Example 42 65 60 25
Example 43 67.5 62.5 27.5
Example 44 70 65 30
Comparative example
Comparative example 1 differs from example 1 in that no abrasion resistant resin was added to the raw materials;
comparative example 2 differs from example 1 in that no adjuvant was added to the raw materials;
comparative example 3 differs from example 1 in that no abrasion-resistant resin and no adjuvant are added to the raw materials;
comparative example 4 differs from example 1 in that no abrasion resistant filler is added to the feed.
Detection method
1. Abrasion resistance test
The belts were tested using GB/T9867-2008/ISO 4649:2002 "determination of abrasion resistance of vulcanized or thermoplastic rubber (rotating drum abrader method)", the results of which are given in the table below.
Figure BDA0002312986680000101
Figure BDA0002312986680000102
Figure BDA0002312986680000111
And (4) conclusion: from the above test results, it can be seen that the belt of example 1 has the smallest volume wear, indicating that the wear resistance of the resulting belt of example 1 is the best. The comparison of the comparative examples 1 to 4 with the example 1 and the volume abrasion loss of the standard rubber shows that the abrasion-resistant resin has the greatest influence on the abrasion resistance of the belt, the auxiliary agent and the abrasion-resistant filler have the lowest frequency, and the auxiliary agent and the abrasion-resistant resin have the best effect on enhancing the abrasion resistance of the belt when added together.
2. The belts were tested by the test method of GB 6037-85 determination of high temperature tensile strength and elongation at break of vulcanized rubber, and the test results are shown in the following table.
Figure BDA0002312986680000112
And (4) conclusion: from the data in the above table, it can be seen that the elongation of the belt obtained in example 1 is the highest, and the corresponding tensile strength at break and tensile strength at 100% are smaller, which indicates that the elongation of the belt obtained in example 1 is larger, and that the addition of the auxiliary and the abrasion resistant resin has a larger effect on the tensile strength of the belt by comparison of comparative examples 1 to 4.
The embodiments of the present invention are preferred embodiments of the present invention, and the scope of the present invention is not limited by these embodiments, so: all equivalent changes made according to the structure, shape and principle of the invention are covered by the protection scope of the invention.

Claims (5)

1. A manufacturing process of a super wear-resistant belt is characterized by comprising the following steps: the method comprises the following process steps:
s1: the raw materials are put into an extruder in proportion for mixing, and after mixing is finished, the raw materials are extruded to obtain a mixed rubber material, wherein the raw materials comprise the following components in parts by weight:
60 parts of butadiene rubber;
20 parts of natural rubber;
20 parts of styrene butadiene rubber;
15-20 parts of wear-resistant resin;
1-3 parts of wear-resistant filler;
60-80 parts of a filler;
1-2 parts of stearic acid;
2-4 parts of an anti-aging agent;
2-3 parts of an accelerator;
2-3 parts of sulfur;
8-12 parts of short fibers;
s2: introducing the mixed rubber material into a calender for calendering to obtain a formed belt;
s3: coiling and packaging the formed belt to obtain a finished belt product;
the wear-resistant resin comprises the following components in percentage by weight:
20-50% of polyvinylidene fluoride;
15-40% of polyether-ether-ketone;
10-40% of ultra-high molecular weight polyethylene;
according to the weight percentage, 2-3% of an auxiliary agent is also added into the wear-resistant resin, and the auxiliary agent comprises the following components in percentage by weight:
30-60% of sucrose ester;
20-30% of fluorocarbon surfactant;
20-40% of pentaerythritol ester;
the wear-resistant filler comprises the following components in percentage by weight:
50-60% of porous ceramic microspheres;
40-50% of nano magnesium oxide.
2. The manufacturing process of the super wear-resistant belt according to claim 1, characterized in that: the anti-aging agent comprises the following components in percentage by weight:
20-40% of N-phenyl-2-naphthylamine;
20-30% of N-phenyl-N' -isopropyl-p-phenylenediamine;
30-50% of N- (1, 3-dimethyl) butyl-N' -phenyl-p-phenylenediamine.
3. The manufacturing process of the super wear-resistant belt according to claim 1, characterized in that: the filler comprises the following components in percentage by weight:
70-80% of carbon black;
10-20% of white carbon black;
5-10% of a coupling agent.
4. The manufacturing process of the super wear-resistant belt according to claim 1, characterized in that: the temperature of a feeding section in the extruder is controlled to be 55-65 ℃, the temperature of a screw of the extruder is controlled to be 80-90 ℃, and the temperature of a machine head of the extruder is controlled to be 90-100 ℃.
5. The manufacturing process of the super wear-resistant belt according to claim 1, characterized in that: the upper roll temperature of the calender is controlled to be 60-70 ℃, the middle roll temperature of the calender is controlled to be 55-65 ℃, and the cooling roll temperature of the calender is controlled to be 20-30 ℃.
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020530A (en) * 2007-03-23 2007-08-22 无锡市宝通带业有限公司 Anti-tearing and wear-resistant conveying belt
DE102008053888A1 (en) * 2008-10-30 2010-05-06 Lanxess Deutschland Gmbh New process for the production of polybutadiene-containing moldings
CN104662349A (en) * 2012-08-03 2015-05-27 泰克尼普法国公司 Flexible underwater pipe including a layer including a polyethylene having enhanced heat resistance
CN107189147A (en) * 2017-06-05 2017-09-22 薛念念 A kind of high-elastic conductive abrasion-resistant rubber roller sizing material
CN107383691A (en) * 2017-08-17 2017-11-24 安徽卓越电力设备有限公司 A kind of Heavy-duty cables protective cover material
CN110283367A (en) * 2019-07-16 2019-09-27 无锡宝通科技股份有限公司 Super abrasive conveyer belt coating rubber and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020530A (en) * 2007-03-23 2007-08-22 无锡市宝通带业有限公司 Anti-tearing and wear-resistant conveying belt
DE102008053888A1 (en) * 2008-10-30 2010-05-06 Lanxess Deutschland Gmbh New process for the production of polybutadiene-containing moldings
CN104662349A (en) * 2012-08-03 2015-05-27 泰克尼普法国公司 Flexible underwater pipe including a layer including a polyethylene having enhanced heat resistance
CN107189147A (en) * 2017-06-05 2017-09-22 薛念念 A kind of high-elastic conductive abrasion-resistant rubber roller sizing material
CN107383691A (en) * 2017-08-17 2017-11-24 安徽卓越电力设备有限公司 A kind of Heavy-duty cables protective cover material
CN110283367A (en) * 2019-07-16 2019-09-27 无锡宝通科技股份有限公司 Super abrasive conveyer belt coating rubber and preparation method thereof

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