CN110937943A - Special yield-increasing and pest-preventing package fertilizer for soybeans and application method - Google Patents

Special yield-increasing and pest-preventing package fertilizer for soybeans and application method Download PDF

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Publication number
CN110937943A
CN110937943A CN201911256712.9A CN201911256712A CN110937943A CN 110937943 A CN110937943 A CN 110937943A CN 201911256712 A CN201911256712 A CN 201911256712A CN 110937943 A CN110937943 A CN 110937943A
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fertilizer
soybean
package
soybeans
application
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Inventor
高进华
张淑敏
杨恒哲
王婷婷
赵文
刘兆辉
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Stanley Agricultural Group Co Ltd
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Stanley Agricultural Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting
    • A01C21/005Following a specific plan, e.g. pattern
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00Cultivation of specific crops or plants not otherwise provided for
    • A01G22/40Fabaceae, e.g. beans or peas
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C3/00Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Botany (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention provides a package fertilizer special for soybean for increasing yield and preventing diseases and insect pests and an application method thereof, and relates to the technical field of soil fertilizers. The package fertilizer comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 is round solid particles and contains a nitrogenous fertilizer, a phosphate fertilizer, a potash fertilizer, a medium trace element fertilizer and a fertilizer filler; the fertilizer 2 is a liquid fertilizer and is formed by mixing ammonium molybdate solution, deep sea alginic acid and fulvic acid. By applying fertilizer at a specific time and a specific part, the time-space matching of fertilizer nutrient release and crop growth nutrient requirements is realized, the fertilizer utilization rate is improved, the seed germination is promoted, and the root system growth is promoted; meanwhile, foliar fertilizer spraying is carried out in the key period influencing the yield of the soybeans, the stress resistance of the soybeans is promoted, and the effects of improving the quality and increasing the yield of the soybeans are achieved.

Description

Special yield-increasing and pest-preventing package fertilizer for soybeans and application method
Technical Field
The invention relates to the technical field of soil fertilizers, in particular to a package fertilizer special for increasing yield and preventing diseases and insect pests of soybeans and an application method thereof.
Background
The soybeans originally originate from China, have a planting history of about 5000 years to date, are one of main food crops and oil crops in China, and play an important role in agricultural production. In the process of soybean production, the improvement of soybean yield and the reduction of input cost are particularly important, and not only needs to select improved varieties suitable for local natural conditions to carry out crop rotation cultivation, avoid continuous cropping and timely seeding, but also needs to carry out scientific field management and reasonable fertilization.
Molybdenum is one of essential trace elements for crop growth and development, participates in the formation of azotase, can promote the generation and development of root nodules, improves the nitrogen fixation activity and capacity of rhizobia, and is indispensable for biological nitrogen fixation of leguminous plant rhizobia and various self-growing nitrogen fixation bacteria. The content of molybdenum in soil in China is very low, generally about 2mg/Kg, and most molybdenum exists in a form of being insoluble in water, so that crops cannot absorb and utilize the molybdenum. Therefore, the development of the molybdenum-containing high-efficiency soybean special fertilizer has great significance for promoting the absorption of soybean root systems to major elements such as nitrogen, phosphorus, potassium and the like, enhancing the growth vigor of plants, promoting photosynthesis and improving the yield and quality of soybeans.
In addition, the soybean cyst nematode disease is a devastating disease in the world soybean production, when soybeans are planted in continuous cropping, the overground part shows that the leaves of soybean plants turn yellow after being damaged by the cyst nematode, the edges of the light leaves turn yellow, and the yield is obviously reduced; the soybean leaves of serious plants turn yellow completely, and some plants die, so that the root systems of the soybeans are mainly damaged in the underground part, the development of the root systems is retarded, the absorption of the root systems to nutrition and moisture is damaged, and the number of the nitrogen-fixing rhizobia of the soybeans is reduced. Meanwhile, the openness of the surface of the bean roots is increased, the damages of other soil-borne diseases such as damping off, fusarium root rot, phytophthora root rot and anthracnose are increased, and even the soybean cannot be produced before or after blooming.
At present, a one-shot fertilization mode is adopted in soybean production, so that excessive fertilizer application is caused, the utilization rate of the fertilizer is low, and diseases and insect pests are frequent. In order to solve the outstanding problems, domestic soybean related scientific research personnel also provide soybean recommended fertilization methods, such as soil testing formula fertilization, a fertilizer effect function method, nutrient precise management and the like, and particularly, the traditional recommended fertilization method based on the soil testing formula plays an important role in soybean yield increase. However, soil testing assays are time consuming, labor intensive, and require some financial investment; in addition, the soil nutrient test value cannot completely reflect the soil nutrient supply condition under the influence of the limitations of the current test method. Therefore, the soybean fertilizer which has the advantages of small fertilizer consumption and high fertilizer application efficiency, can promote the yield and income increase of soybeans and improve the pest and disease resistance of soybeans is urgently needed to be developed to make up for the defects of the prior art.
Disclosure of Invention
Aiming at the problems of excessive fertilization, low fertilizer utilization rate, frequent occurrence of diseases and insect pests and the like in the soybean fertilization process, the invention develops a special package fertilizer for soybeans and an application method thereof by researching the development characteristics of soybean root development, pod setting growth and different growth periods and combining indexes such as soybean nutrient demand, fertilizer nutrient content, agricultural efficiency and the like, and has obvious effects on reducing the fertilizer consumption, improving the fertilizer utilization rate, slowing down soil-borne diseases and improving the soybean yield.
The invention provides a package fertilizer special for soybean, which comprises a fertilizer 1 and a fertilizer 2,
wherein the fertilizer 1 is a solid fertilizer and contains a nitrogenous fertilizer, a phosphate fertilizer, a potash fertilizer, a medium trace element fertilizer and a fertilizer filler; is prepared by a common roller production process.
The fertilizer 2 is a liquid fertilizer and is formed by uniformly mixing an ammonium molybdate solution, a deep sea alginic acid solution and a fulvic acid solution, and the solvents of the three solutions are water.
Further, in the package fertilizer of the invention, the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000021
preferably, the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000031
in the embodiment of the invention, the nitrogen fertilizer is humic acid urea; and/or the phosphate fertilizer is diammonium phosphate;
and/or the potash fertilizer is potassium sulfate;
and/or the medium trace element fertilizer is formed by mixing two or more of borax, calcium sulfate and zinc sulfate in equal mass fraction;
and/or the fertilizer filler comprises clay, moisture and a plate prevention agent which are mixed according to equal mass fractions.
In research and development, the invention discovers that the round solid granular fertilizer prepared by processing the components of the fertilizer 1 has better slow release effect when being used as a soybean fertilizer, can improve the utilization rate of nitrogen fertilizer, potassium fertilizer and calcium fertilizer, improve soil environment and improve crop yield. Particularly, by arranging the humic acid urea, the diammonium phosphate, the potassium sulfate, the borax, the calcium sulfate, the zinc sulfate and the fertilizer filler which contain the humic acid urea, the diammonium phosphate, the potassium sulfate and the fertilizer filler in the specific proportion, the fertilizer nutrients can be increased, the absorption of soybeans on the fertilizer nutrients can be promoted, the components in the fertilizer 1 can play a better role, and the effect of slowly releasing and controlling the fertilizer can be realized; meanwhile, the method can also improve the quantity of soil bacteria, inhibit the propagation of harmful fungi and parasites, relieve the occurrence of plant diseases and insect pests in the soil, enhance the stress resistance of crops and create a good environment for the growth and development of the crops.
More preferably, in the set of fertilizers of the present invention, the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000032
Figure BDA0002310466440000041
in the package fertilizer, the fertilizer 2 is formed by mixing 5% of ammonium molybdate solution, 5% of deep sea alginic acid solution and 5% of fulvic acid solution, and the mixing volume ratio of the ammonium molybdate solution to the deep sea alginic acid solution to the fulvic acid solution is 2: 1: 2. the percentage is mass percent.
Molybdenum is a synthetic raw material of molybdenum protein in rhizobia, and the nitrogen fixation effect of nitrogen-fixing bacteria in soil can be well promoted through the compounding.
Furthermore, the deep sea alginic acid and the fulvic acid are added for compounding, so that the functions of fertilizer synergism, soil improvement, soybean growth stimulation, agricultural product quality improvement and the like can be better exerted, sufficient nutrients are provided for the growth and development of the soybeans, and the growth condition of the soybeans in the whole growth period is stably maintained.
In a preferred embodiment of the invention, the prepared package fertilizer comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 comprises the following raw materials in parts by weight:
Figure BDA0002310466440000042
the fertilizer 2 is formed by mixing a 5% ammonium molybdate solution, a 5% deep sea alginic acid solution and a 5% fulvic acid solution, and the dosage of the three solutions is 40ml, 20ml and 40ml in sequence.
The second purpose of the invention is to provide the application method of the package fertilizer special for soybeans, and specifically, the fertilizer 1 is applied below or just below the seed side when the soybeans are sowed, and the application amount is 600-2(ii) a Spraying fertilizer 2 in the flowering pod period of the soybeans, wherein the application amount is 700-2
The application method further comprises dressing seeds with rhizobia before soybean sowing; and preferably, fertilizer 1 is applied 4-5cm below or just below the seed side; ensuring the appropriate water content in the field.
The invention provides any one of the following applications of the soybean meal fertilizer,
(1) the application of the fertilizer in improving the utilization rate of the fertilizer for soybean;
(2) application in promoting soybean seed germination;
(3) the application in promoting the growth and development of soybean root systems;
(4) the application in increasing the number of the soybean single plant node pods;
(5) the application in promoting the yield and income increase of the soybean or improving the yield of the soybean;
(6) application in improving stress resistance of soybean.
In the application, the fertilizer 1 in the package fertilizer is applied to the lower side or right below the seed side when the soybeans are sowed, and the application amount is 600-750kg/hm2(ii) a Spraying fertilizer 2 in the flowering pod period of the soybeans, wherein the application amount is 700-2
The technical innovation of the invention is that the package fertilizer special for the soybeans is provided, the package fertilizer contains two fertilizers which are respectively in a solid particle state and a liquid state, the fertilizers are applied at specific parts and specific periods of the growth of the soybeans, and the solid particles of the fertilizer 1 are deeply applied during sowing to provide nutrients for the whole growth period of the soybeans; the liquid fertilizer of the fertilizer 2 is subjected to foliage spraying (spraying in a pod stage) in a key period influencing the soybean yield, through the cooperative regulation and control effect between nutrients, the stress resistance can be improved through the coupling of the two fertilizers, the incidence rate of soybean cyst nematode is reduced, the space-time matching of the fertilizer nutrient release and the crop growth nutrient demand is realized, the fertilizer utilization rate is improved, the seed germination is promoted, the soybean pod formation is promoted, the root growth is promoted, and the yield and the quality are improved. The set of fertilizer is cooperated with each other to promote the growth and development of the soybean and improve the maturing rate and stress resistance of the soybean. The nutrient elements required by the growth of the soybeans can be met, the stress resistance of the soybeans can be improved, the using amount of fertilizers and pesticides can be reduced, and the purposes of losing weight and improving the effect can be achieved.
Detailed Description
Preferred embodiments of the present invention will be described in detail with reference to the following examples. It is to be understood that the following examples are given for illustrative purposes only and are not intended to limit the scope of the present invention. Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the spirit and scope of this invention.
The experimental procedures used in the following examples are all conventional procedures unless otherwise specified.
Materials, reagents and the like used in the following examples are commercially available unless otherwise specified. Fertilizer to be tested: the rhizobium inoculant is purchased from advanced biological agriculture companies, the number of effective viable bacteria is more than or equal to 20 hundred million/mL, and the seed dressing dosage is 300mL/hm2(ii) a The common compound fertilizer used in the examples is a commercial agricultural large compound fertilizer 600kg/hm2(15-15-15). Humic acid urea is purchased from Shandong Pongsheng agricultural production data Co., Ltd, ammonium molybdate is purchased from Borui Metal products Co., Ltd, Henan province, and deep sea alginic acid and fulvic acid are purchased from Mobei (Shanghai) Biotech Co., Ltd.
Example 1
The embodiment provides a package fertilizer special for soybeans, which comprises a fertilizer 1 and a fertilizer 2,
the fertilizer 1 comprises the following raw materials in parts by weight:
Figure BDA0002310466440000061
the fertilizer filler is formed by mixing clay, water and a plate prevention agent in a mass ratio of 1:1: 1.
The fertilizer 2 is formed by mixing 5% ammonium molybdate solution, 5% deep sea alginic acid solution and 5% fulvic acid solution, and the mixing volume ratio of the three is 2: 1: 2.
example 2
The embodiment provides a special package fertilizer for soybeans, which comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000062
Figure BDA0002310466440000071
the fertilizer filler is formed by mixing clay, water and a plate prevention agent in a mass ratio of 1:1: 1.
Fertilizer 2 was the same as in example 1.
Example 3
The embodiment provides a special package fertilizer for soybeans, which comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000072
fertilizer 2 was prepared as in example 1.
Example 4
The embodiment provides a special package fertilizer for soybeans, which comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000073
fertilizer 2 was prepared as in example 1.
Example 5
The embodiment provides a special package fertilizer for soybeans, which comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000081
fertilizer 2 was prepared as in example 1.
Example 6
The embodiment provides a special package fertilizer for soybeans, which comprises a fertilizer 1 and a fertilizer 2, wherein the fertilizer 1 contains the following raw materials in parts by weight:
Figure BDA0002310466440000082
fertilizer 2 was prepared according to the same method as in example 1.
Example 7 methods of administration and Effect (1)
The test varieties are: summer soybean (Glycine max (L.) Merr.) is very early-maturing variety Ludou No. 1, which has limited pod bearing habit and is planted in summer for 90-95 days.
The test was carried out in 2018, 6 and 25 months, and the test was carried out in a pot culture. The height of the basin is 23cm, and the diameter of the upper opening is 26 cm; the soil layer is 20cm, and the fertilizer is folded according to the area. 6 seeds are sown in each pot, after the 3 rd compound leaf is completely unfolded, the seedlings are set, 3 plants are reserved in each pot, 5 different treatments are set, and each treatment is repeated for 3 times, and the total number of soybean plants is 45 pots. Wherein CK represents no fertilization treatment; SF1-SF6 show the treatment with the Standyley solid particulate fertilizer (fertilizer 1) prepared in examples 1-6; ST represents the application of Standby solid granular fertilizer prepared in example 1 (Fertilizer 1, application rate is 600-2) And spraying fertilizer 2 between the flowering pod period and the prophase of the drumming, wherein the application amount is 750ml/hm2Processing; PF represents the application of common compound fertilizer treatment; PT represents that common compound fertilizer is applied, and liquid fertilizer treatment is sprayed between the flowering pod period and the prophase of grain swelling.
As can be seen from Table 1, the agronomic traits can be improved by applying the package fertilizer special for soybean, and the plant heights in the flowering pod stage and the harvesting stage are shown as follows: ST > PT > SF > PF > CK, the number of soybean branches is shown in the pod stage and the harvest stage as follows: ST > PT > SF ═ PF > CK; the number of leaves in the pod stage is shown as follows: ST > PT > SF ═ PF > CK, and it can be seen that the application of the package fertilizers prepared in examples 1-6 of the present invention at a determined period of time in an appropriate amount can effectively improve the growth and development conditions of soybean.
At the same density, soybean yield constituents include the number of effective pods per plant, the number of seeds per plant, the weight of the hundreds of grains, and the like. As can be seen from Table 2, the number of pods per plant, the number of seeds per plant, the weight of seeds per plant and the weight of seeds per plant of ST soybean were significantly increased as compared with CK, and the number of pods per plant, the number of seeds per plant, the weight of seeds per plant and the weight of seeds per plant were relatively high when PT treatment was performed on the liquid fertilizer of the present invention.
TABLE 1 Effect of different fertilization modes on the agronomic traits of Soybean
Figure BDA0002310466440000091
TABLE 2 Effect of different fertilization regimes on soybean yield constituents
Treatment of Pod bearing number per plant Number of seeds per plant Hundred grain weight/g Seed weight per gram of individual plant
CK 25.4 55.0 14.1 9.4
SF1 31.3 75.0 15.0 11.2
SF2 30.8 70.4 14.9 10.5
SF3 30.9 72.4 14.9 10.8
SF4 31.0 72.5 14.9 10.8
SF5 31.0 73.3 15.0 11.0
SF6 30.8 69.8 14.9 10.4
ST 42.0 95.3 16.5 16.7
PF 30.7 62.0 14.9 10.3
PT 33.2 66.2 16.0 12.3
Example 8 methods of administration and Effect (2)
The test varieties are: summer soybean (Glycine max (L.) Merr.) is very early-maturing variety Ludou No. 11, which has limited pod bearing habit and is planted in summer for 90-95 days.
The test was carried out 24.6.2019, the test site was located in the Tech-Tech demonstration park in Shu county, Shandong province, and the test site was a low-and-medium-yield field. The trial was planted 5 soybean plots (5 trial treatments), with 3 rows of soybeans planted per plot. Wherein CK represents no fertilization treatment; SF represents the treatment with the Standby solid particulate fertilizer (Fertilizer 1) prepared in example 1; ST represents the treatment of applying the Standyley solid particulate fertilizer (fertilizer 1) prepared in example 1 and spraying the liquid fertilizer (fertilizer 2) prepared in example 1 between the pod stage and the pre-granulation stage; PF represents the application of common compound fertilizer treatment; PT represents that common compound fertilizer is applied, and liquid fertilizer treatment is sprayed between the flowering pod period and the prophase of grain swelling.
As can be seen from Table 3, the emergence rate, the single plant satiety rate and the yield of ST treatment were the highest, with the lowest incidence. Therefore, the soybean emergence can be effectively promoted by applying the Strobilanthus spinosus soybean package fertilizer, the stress resistance of the soybeans is improved, the incidence of soybean cyst nematodes is inhibited, and the soybean fructification is promoted, so that the yield and income of the soybeans are increased.
TABLE 3 Effect of different fertilization patterns on the growth and development of soybeans
Figure BDA0002310466440000111
In conclusion, the special yield-increasing and disease and pest preventing package fertilizer for soybeans provided by the invention comprises a solid fertilizer combination product and a liquid fertilizer combination product, and the coordinated application can improve the fertilizer utilization rate, promote the soybean fructification, improve the stress resistance of soybeans and is beneficial to boosting the development of the soybean planting industry.
Although the invention has been described in detail hereinabove by way of general description, specific embodiments and experiments, it will be apparent to those skilled in the art that many modifications and improvements can be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. A package fertilizer special for increasing yield and preventing plant diseases and insect pests of soybeans is characterized by comprising a fertilizer 1 and a fertilizer 2,
wherein the fertilizer 1 is a solid fertilizer and contains a nitrogenous fertilizer, a phosphate fertilizer, a potash fertilizer, a medium trace element fertilizer and a fertilizer filler; the fertilizer 2 is a liquid fertilizer and is prepared by mixing ammonium molybdate solution, deep sea alginic acid and fulvic acid solution.
2. The package fertilizer of claim 1, wherein fertilizer 1 comprises the following raw materials in parts by weight:
Figure FDA0002310466430000011
3. the package fertilizer of claim 2, wherein fertilizer 1 comprises the following raw materials in parts by weight:
Figure FDA0002310466430000012
4. the package fertilizer of claim 2, wherein the nitrogen fertilizer is humic acid urea; and/or the phosphate fertilizer is diammonium phosphate;
and/or the potash fertilizer is potassium sulfate;
and/or the medium trace element fertilizer is formed by mixing two or more of borax, calcium sulfate and zinc sulfate in equal mass fraction;
and/or the fertilizer filler comprises clay, moisture and a plate prevention agent which are mixed according to equal mass fractions.
5. The package fertilizer of claim 4, wherein fertilizer 1 comprises the following raw materials in parts by weight:
Figure FDA0002310466430000021
6. the package fertilizer of any one of claims 1 to 5, wherein the fertilizer 2 is prepared from a 5% ammonium molybdate solution, a 5% deep sea alginic acid solution and a 5% fulvic acid solution in a volume ratio of 2: 1: 2, mixing the components.
7. The method for applying a package fertilizer as set forth in any one of claims 1 to 6, wherein the fertilizer 1 is applied to the seed side or just under the seed side at the time of soybean sowing in an amount of 600-750kg/hm2(ii) a Spraying fertilizer 2 in the flowering pod period of the soybeans, wherein the application amount is 700-2
8. The method of application of a set of fertilizers as claimed in any of claims 1 to 6, characterized in that before soybean sowing, rhizobia is used for dressing seeds; applying the fertilizer 1 to the lower side or right below the seed by 4-5 cm; ensuring the appropriate water content in the field.
9. The use of any one of the set of fertilizers of claims 1-6,
(1) the application of the fertilizer in improving the utilization rate of the fertilizer for soybean;
(2) application in promoting soybean seed germination;
(3) the application in promoting the growth and development of soybean root systems;
(4) the application in increasing the number of the soybean single plant node pods;
(5) the application in promoting the yield and income increase of the soybean or improving the yield of the soybean;
(6) application in improving stress resistance of soybean.
10. Use according to claim 9, characterized in that the use according to any of claims 1-6 is usedThe fertilizer 1 in the package fertilizer is applied to the lower side or the right lower side of the seed during the soybean sowing, and the application amount is 600-plus-one 750kg/hm2(ii) a Spraying fertilizer 2 in the flowering and pod period of soybean in an application amount of 750ml/hm2
CN201911256712.9A 2019-12-06 2019-12-06 Special yield-increasing and pest-preventing package fertilizer for soybeans and application method Pending CN110937943A (en)

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Cited By (1)

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CN1498879A (en) * 2002-11-04 2004-05-26 天津市福升肥料有限公司 Envirconmental protection typed dedicated fertilizer for soybean in coming crop
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