CN110846549B - Metal ceramic composite material resistant to corrosion of molten aluminum - Google Patents
Metal ceramic composite material resistant to corrosion of molten aluminum Download PDFInfo
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- 238000005260 corrosion Methods 0.000 title claims abstract description 65
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 63
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 230000007797 corrosion Effects 0.000 title claims abstract description 63
- 239000002131 composite material Substances 0.000 title claims abstract description 62
- 239000000919 ceramic Substances 0.000 title claims abstract description 39
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 39
- 239000002184 metal Substances 0.000 title claims abstract description 39
- 229910020968 MoSi2 Inorganic materials 0.000 claims abstract description 40
- 239000011195 cermet Substances 0.000 claims abstract description 31
- 229910016006 MoSi Inorganic materials 0.000 claims abstract description 27
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims description 33
- 238000005245 sintering Methods 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- 238000000498 ball milling Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 8
- 238000004321 preservation Methods 0.000 claims description 5
- 238000002490 spark plasma sintering Methods 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 3
- 239000004570 mortar (masonry) Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 abstract description 9
- 229910017052 cobalt Inorganic materials 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 description 15
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 238000001878 scanning electron micrograph Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- 229910019001 CoSi Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000005258 corrosion kinetic Methods 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910005347 FeSi Inorganic materials 0.000 description 1
- 229910017305 Mo—Si Inorganic materials 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- 229910000943 NiAl Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229910001068 laves phase Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/18—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on silicides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/105—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/105—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding
- B22F2003/1051—Sintering only by using electric current other than for infrared radiant energy, laser radiation or plasma ; by ultrasonic bonding by electric discharge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
Abstract
The invention discloses a metal ceramic composite material resisting corrosion of molten aluminum, which is MoSi2-Co cermet composite, MoSi2the-Co metal ceramic composite material comprises the following components in percentage by mass: MoSi285-90% and the balance of Co; the MoSi is2The corrosion rate of the-12 Co metal ceramic composite material in molten aluminum at 700 ℃ is 4.10-7.10 microns/hour, and the microhardness is 839.2HV0.2～1384.1HM0.2. The molten aluminum corrosion resistant MoSi provided by the invention2MoSi for use in-Co cermet composites2The cobalt-based composite material has the advantages of low price, low cobalt content, low cost, simple preparation and good application prospect in the aluminum corrosion resistance industry.
Description
Technical Field
The invention belongs to the field of molten aluminum corrosion resistant materials, and particularly relates to a molten aluminum corrosion resistant metal ceramic composite material.
Background
In modern industries, corrosion caused by molten metal is quite common due to the need to transport and handle the molten metal. In the production of melting, forming (casting) and hot dip aluminizing in the aluminum industry, parts such as crucibles, molds, fixtures and the like are severely corroded, and problems such as perforation of a melting container, adhesion of the surface of a metal mold and the like are caused. Therefore, failure due to severe corrosion of the crucible and mold by molten aluminum is inevitable in the aluminum industry.
Aiming at aluminum liquid corrosion, a plurality of materials with aluminum liquid corrosion resistance are explored in the industry. Iron-based materials are the most used materials for molds and crucibles in the aluminum industry, and thus much research has been conducted on their corrosion resistance in molten aluminum. The iron-based material cannot effectively resist the strong corrosion and abrasion of aluminum in the aluminum industry at present, so that the equipment is frequently replaced and the production efficiency is reduced. In the aspect of refractory metals, compared with iron-based materials, the reaction between cobalt-based materials and liquid aluminum is more uniform and mild, but the cobalt-based materials are expensive. In the Mo-W system, the Nb-based alloy has good aluminum liquid corrosion resistance, but the hardness is higher, and the processing difficulty is high, so that the large-scale application of the Mo-W system and the Nb-based alloy is limited. In recent years, high-entropy alloy has a certain development in aluminum liquid corrosion resistance, but the aluminum liquid corrosion resistance of the existing mature AlFeNiCoCr high-entropy alloy is not good. Intermetallic compounds are a unique class of materials, Ni3Al, NiAl, FeSi and the like have good corrosion resistance in molten aluminum, but the production process of intermetallic compounds is complex and the cost is high. Ceramics possess excellent resistance to molten aluminum corrosion, like graphite, AlN, and Al2O3And the like are widely used for smelting aluminum, but ceramics have high brittleness and are difficult to process. The metal ceramic has the performance between that of ceramic and metal, has good mechanical performance and corrosion resistance, and MoSi2The metal ceramic is a high-temperature oxidation resistant metal ceramic, has good aluminum liquid corrosion resistance, but has little attention in the aluminum liquid corrosion resistance.
Therefore, there is a need for a new method for preparing a cermet composite material that is resistant to corrosion by molten aluminum.
Disclosure of Invention
The technical problem to be solved by the invention is to provide the metal ceramic composite material with molten aluminum corrosion resistance, which has the advantages of low cost, easy preparation and obvious molten aluminum corrosion resistance.
The technical solution of the invention is as follows:
a metal ceramic composite material resisting corrosion of molten aluminum, wherein the metal ceramic composite material is MoSi2-Co cermet composite, MoSi2the-Co metal ceramic composite material comprises the following components in percentage by mass:
MoSi285-90% and the balance of Co;
the MoSi is2The corrosion rate of the-12 Co metal ceramic composite material in molten aluminum at 700 ℃ is 4.10-7.10 microns/hour, and the microhardness is 839.2HV0.2～1384.1HV0.2。
Adopts industrial pure MoSi2Powder and cobalt powder as raw materials, MoSi2The purity of the powder is 99.9 percent, the purity of the cobalt powder is 99.9 percent, and the purity is percent by mass.
MoSi2The content of the powder is 85%, 88% or 90%.
MoSi2-Co cermet composite material via MoSi2The powder and cobalt powder are mixed by ball milling and sintered by discharge plasma.
In ball milling and mixing, the ball-material ratio is between 3:1 and 10:1, the rotating speed is between 180r/min and 220r/min, the ball milling time is 2h to 5h, and the ball-material ratio is the mass ratio.
And after ball milling, placing the ball milling tank in a vacuum drying oven for drying for 7-9 h, wherein the drying temperature is 80-100 ℃. Preferably 8 hours and 90 ℃.
And after the dry powder is cooled, grinding the powder by using a mortar to reduce the hardening of the powder, wherein the grain size of the ground powder ranges from 1 micron to 2 microns.
In the discharge plasma sintering process, the sintering temperature is 1200-1250 ℃.
In the discharge plasma sintering process, the applied pressure value is 20-40 MPa, the heat preservation time is 3-10 min, the preferred pressure value is 30MPa, and the heat preservation time is 5 min.
Description of technical route:
MoSi with higher performance through aluminum corrosion resistance2The metal ceramic realizes the molten aluminum corrosion resistance, and simultaneously, in order to improve the mechanical property of the sintered ceramic, a certain amount of cobalt is added to improve the plasticity and toughness of the sintered ceramic. MoSi was found after sintering2Co reacts to generate a CoMoSi ternary phase, and the CoMoSi ternary phase belongs to laves phases, so that MoSi is generated2The corrosion resistance of the-Co metal ceramic composite material is more excellent. As the sintering process of the cermet which is widely used in the current practical industrial application and is 90 percent WC-10 percent Co, 88 percent WC-12 percent Co and 85 percent WC-15 percent Co is mature, a similar sintering process is selected, and the component proportion selected in the embodiment is made according to a Co-Mo-Si ternary phase diagram.
Has the advantages that:
the invention discloses a metal ceramic composite material resisting corrosion of molten aluminum, which is MoSi2-Co cermet composite material, said MoSi2-Co cermet composite material having corrosion rate of 4.10 to 7.10 microns per hour in 700 ℃ molten aluminum and microhardness of 839.2HV0.2-1384.1HV0.2. The embodiment of the invention provides molten aluminum corrosion resistant MoSi2MoSi for use in-Co cermet composites2The cobalt-based composite material has the advantages of low price, low cobalt content, low cost, simple preparation and good application prospect in the aluminum corrosion resistance industry.
Drawings
FIG. 1 is 88% MoSi2-XRD pattern after sintering of 12% Co cermet composite.
FIG. 2 shows MoSi after sintering2-12Co cermet composite texture map.
FIG. 3 is 88% MoSi2SEM image of interface structure after 1 day corrosion of-12% Co in 700 ℃ aluminum liquid.
FIG. 4 is 88% MoSi2SEM image of interface structure of-12% Co after 2 days of corrosion in aluminum liquid at 700 ℃.
FIG. 5 is 88% MoSi2SEM image of interface structure of-12% Co after 3 days of corrosion in 700 ℃ aluminum liquid.
FIG. 6 is 88% MoSi2SEM image of interface structure of-12% Co after 4 days of corrosion in 700 ℃ aluminum liquid.
FIG. 7 is 88% MoSi2SEM image of interface structure of-12% Co after 5 days of corrosion in 700 ℃ aluminum liquid.
FIG. 8 is a graph showing the corrosion kinetics of three examples in a 700 ℃ aluminum liquid.
FIG. 9 is the 90% MoSi after sintering2Texture map of 10% Co cermet composite.
FIG. 10 is the 85% MoSi after sintering2-texture map of 15% Co cermet composite.
Detailed Description
In order to facilitate an understanding of the invention, the invention will be described more fully and in detail below with reference to the accompanying drawings and preferred embodiments, but the scope of the invention is not limited to the following specific embodiments.
Unless otherwise defined, all terms of art used hereinafter have the same meaning as commonly understood by one of ordinary skill in the art. The terminology used herein is for the purpose of describing particular embodiments only and is not intended to limit the scope of the present invention.
The preparation method of the metal ceramic composite material resisting molten aluminum corrosion comprises the following steps:
(1) material preparation
Adopts industrial pure MoSi2Powder and cobalt powder are used as raw materials. Wherein, MoSi2The purity of the cobalt is 99.9 percent, and the particle sizes are all 1-2 microns.
(2) Ball milling mixed powder
Weighing pure MoSi2Pouring the powder and cobalt powder into a 250ml hard alloy tank, adding hard alloy balls with the diameter of 2-5mm (the average diameter of the alloy balls in the hard alloy tank is the same, and the diameter is 2-5mm, such as 2mm or 5mm) according to the ball material ratio of 3:1 to 10:1, and then pouring a proper amount of alcohol for wet mixing, wherein the alcohol is just submerged in the powder; after the steps are completed, sealing the tank body and filling argon into the tank body so as to avoid the oxidation of the materials in the powder mixing process; after the powder is filled, filling the ball mill tank into a ball mill and setting a program, wherein the rotating speed is between 180r/min and 220r/min, and the time is 2-5 h; after ball milling, the ball milling tank is placed in a vacuum drying oven for drying for 8 hours, the drying temperature is 90 degrees, the heating rate is 3 degrees, and the vacuum degree is 1.0 multiplied by 10-3MPaMPa; and after the powder is cooled, grinding the powder by using a mortar to reduce the hardening of the powder, and finally obtaining the powder before sintering, wherein the particle size of the powder is 1-2 microns.
(3) Spark plasma sintering
The pre-powder was placed in a cylindrical graphite mold with a diameter of 40mm and a length of 100 mm. The hot-pressing sintering temperature is 1200-1250 ℃, the applied pressure value is 30MPa, the heat preservation time is 5min, and after the sintering is finished, the sample is taken out after the temperature is cooled to the room temperature.
Example 1:
the MoSi is2-a Co cermet composite material consisting of the following components in mass percent: 90% MoSi210% Co, the corresponding mass is 45 g and 5 g respectively, the powder-mixing ball material ratio is 3:1, the diameter of the hard alloy ball is 5mm, then a proper amount of alcohol is poured for wet mixing, and the amount of the alcohol is just over the powder; after the steps are completed, sealing the tank body and filling argon into the tank body so as to avoid the oxidation of the materials in the powder mixing process; the powder mixing speed is 180r/min, and the time is 2 h; after ball milling, the ball milling tank is placed in a vacuum drying oven for drying for 8 hours, the drying temperature is 90 ℃, the heating rate is 3 ℃/min, the vacuum degree is 1.0 multiplied by 10-3MPa. The sintering temperature is 1230 ℃, the applied pressure value is 30MPa, and the heat preservation time is 5 min.
Example 2:
the MoSi is2-a Co cermet composite material consisting of the following components in mass percent: 88% MoSi212% Co, corresponding to a mass of 44 g, 6 g, respectively. The difference from the first embodiment is that the ratio of the mixed powder to the ball material is 5: 1, the sintering temperature is 1240 ℃, the powder mixing speed is 200r/min, the time is 4h, and the rest are the same.
Example 3:
the MoSi is2-a Co cermet composite material consisting of the following components in mass percent: 85% MoSi215% Co, corresponding to a mass of 42.5 g, 7.5 g, respectively. The difference between the first and second embodiments is that the ratio of powder mixing and ball material is 10:1, the sintering temperature is 1250 ℃, the powder mixing speed is 220r/min, the time is 5h, and the rest are the same.
MoSi provided by three embodiments of the invention2the-Co metal ceramic composite material only contains three elements of Mo, Si and Co, and is industrially pure MoSi2Adding Co as alloy element, wherein Co element reacts with M in sintering processoSi2React to generate ternary CoMoSi phase, thereby enhancing MoSi2-corrosion resistance of Co cermet composite.
To verify MoSi2The resistance of-Co metal ceramic composite material to molten aluminum corrosion, the invention also relates to MoSi2the-Co metal ceramic composite material is subjected to a molten aluminum corrosion resistance test.
Before a molten aluminum corrosion resistance experiment is carried out, an oxide film on the surface of a sample is removed, a picture is taken under a scanning electron microscope, and the accurate thickness of each sample is measured by utilizing smileview. And then placing the materials into different graphite crucibles containing molten aluminum respectively, heating the graphite crucibles by using a shaft furnace to keep the temperature of the molten aluminum at 700 ℃, corroding the molten aluminum for 1 day, 2 days, 3 days, 4 days and 5 days respectively, and then taking out the samples. Analysis of MoSi by scanning Electron microscopy2Texture morphology of a corrosion interface between the-Co metal ceramic composite material and the molten aluminum, and MoSi is measured by an energy spectrometer and an X-ray energy spectrometer2-chemical composition of Co cermet composite.
MoSi2The molten aluminum corrosion resistance of the-Co metal ceramic composite material can be embodied by the corrosion rate. The embodiment of the invention adopts a depth method to calculate the corrosion rate v, and the formula is as follows:
V＝(a+b)/2t
wherein a and b are the thicknesses of the sample before and after corrosion, and t is the corrosion time. The thickness of the sample before etching was measured ten times and then averaged to maintain accuracy. And observing the corroded cross section of the corroded sample under a scanning electron microscope to take a photo, measuring the accurate thickness of each sample by utilizing smileview, calculating the average value, and measuring the number of times of ten times. The measuring method comprises the following steps: one measurement point was taken every 0.3mm interval, 10 points were taken for each sample, and the average value was calculated.
MoSi obtained in the above three examples2-performing performance detection and analysis on the Co metal ceramic composite material:
FIG. 1 is 88% MoSi2XRD pattern of sintered-12% Co metal ceramic composite material, from which it can be seen that metal Co and MoSi after sintering2Reaction to generate CoMoSi ternary phase and CoSi phase. 88% MoSi after sintering from FIG. 22The back scattering diffraction pattern of the-12% Co metal ceramic composite material can be known as 88% MoSi2-12% Co cermet composite material consisting of three phases. 88% MoSi was determined by the spectral composition of Table 1 and the XRD pattern of FIG. 12-12% Co cermet composite material made of MoSi2Phase, a CoMoSi ternary phase and a CoSi phase.
FIG. 3 to FIG. 7 are 88% MoSi, respectively2Scanning electron microscope images of the interface structure of the-12% Co metal ceramic composite material after being corroded in aluminum liquid at 700 ℃ for 1, 2, 3, 4 and 5 days. As can be seen from the corrosion kinetics curves of the three examples in FIG. 8 in the molten aluminum at 700 ℃ and Table 1, the corrosion rates are approximately uniform.
TABLE 1 MoSi2-12Co cermet composite average Corrosion Rate (micrometer/hour)
To better embody MoSi2Corrosion resistance of Co cermet composite this example also illustrates the aluminum corrosion resistance test data of cast iron in patent CN 103938050A. The corrosion rate of the molten aluminum at 700 ℃ of the cast iron is 8.5 multiplied by 10 compared with that of the cast iron-1mm/h，MoSi2The corrosion resistance of the-Co metal ceramic composite material is improved by 140-207 times. By the pair of MoSi2Analysis of-Co cermet composite materials revealed that Co and MoSi were present during spark plasma sintering2The reaction produces a CoMoSi ternary phase which results in MoSi2The corrosion resistance of the-Co metal ceramic composite material is more excellent.
In addition, the invention also uses Vickers hardness meter to MoSi2the-Co cermet composite was subjected to microhardness testing. Wherein the load is 200g, the loading time is 15 seconds, three points are selected in total, and the obtained average hardness is 839.2HV0.2-1384.1HM0.2In the meantime.
In summary, in the embodiments of the present invention, MoSi is obtained by spark plasma sintering2-Co cermet composite of Co and MoSi during sintering2The reaction produces CoMoSiTernary phase ordered MoSi2the-Co metal ceramic composite material has more excellent corrosion resistance and MoSi2The price is cheap, the content of cobalt is less, and the cost is lower. The preparation is simple, and the method has good application prospect in the aluminum corrosion resistant industry.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (5)
1. The metal ceramic composite material resisting molten aluminum corrosion is characterized in that the metal ceramic composite material is MoSi2-Co cermet composite, MoSi2the-Co metal ceramic composite material comprises the following components in percentage by mass:
MoSi285-90% and the balance of Co;
MoSi2the corrosion rate of the-12% Co metal ceramic composite material in the molten aluminum at 700 ℃ is 4.10-7.10 microns/hour, and the microhardness is 839.2HV0.2～1384.1HV0.2；
The MoSi is2-Co cermet composite material via MoSi2The powder and cobalt powder are mixed by ball milling and sintered by discharge plasma, and the method specifically comprises the following steps:
after the dry powder is cooled, the hardening of the powder is reduced by grinding the powder through a mortar, and the particle size of the ground powder ranges from 1 micron to 2 microns;
in the spark plasma sintering process, the sintering temperature is 1200-1250 ℃; the applied pressure value is 20-40 MPa, and the heat preservation time is 3-10 min.
2. The fused aluminum corrosion resistant cermet composite of claim 1, in which commercially pure MoSi is used2Powder and cobalt powder as raw materials, MoSi2The purity of the powder was 99.9%, and the purity of the cobalt powder was 99.9%.
3. The fused aluminum corrosion resistant cermet composite of claim 1, wherein MoSi2The content of the powder is 85%, 88% or 90%.
4. The fused aluminum corrosion resistant cermet composite material of claim 1 wherein the ball-milling mixing is performed at a ball-to-material ratio of 3:1 to 10:1, a rotational speed of 180r/min to 220r/min, and a ball-milling time of 2h to 5 h.
5. The fused aluminum corrosion resistant cermet composite material of claim 1, wherein the ball milling jar is placed in a vacuum drying oven for drying for 7-9 hours after ball milling, and the drying temperature is 80-100 ℃.
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