CN110759662A - Building material additive and preparation method thereof - Google Patents

Building material additive and preparation method thereof Download PDF

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Publication number
CN110759662A
CN110759662A CN201910924127.5A CN201910924127A CN110759662A CN 110759662 A CN110759662 A CN 110759662A CN 201910924127 A CN201910924127 A CN 201910924127A CN 110759662 A CN110759662 A CN 110759662A
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CN
China
Prior art keywords
building material
polyvinyl alcohol
material additive
parts
water
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910924127.5A
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Chinese (zh)
Inventor
孙新坡
毕钰璋
郭毅
司马卫平
刘文方
叶建兵
张应迁
陈艳丹
郭海燕
钟言
王寒梅
王磊
王毅恒
江凯
赵朴
韩昌霖
丁泽浩
李佳欣
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Sichuan University of Science and Engineering
Original Assignee
Sichuan University of Science and Engineering
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Publication date
Application filed by Sichuan University of Science and Engineering filed Critical Sichuan University of Science and Engineering
Priority to CN201910924127.5A priority Critical patent/CN110759662A/en
Publication of CN110759662A publication Critical patent/CN110759662A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a building material additive and a preparation method thereof, wherein the building material additive comprises styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible latex powder, an alkali activator and an auxiliary agent. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.

Description

Building material additive and preparation method thereof
Technical Field
The invention relates to the field of building materials, in particular to a building material additive and a preparation method thereof.
Background
In the field of existing building materials, steel slag and volcanic ash are used for replacing cement clinker to prepare cement cementing materials to produce mortar with stable product performance and good workability, because the chemical composition and the phase composition of the steel slag and the volcanic ash are close to the quantity of common silicon cement, the steel slag can be recycled, and the utilization rate of the steel slag is improved.
However, in the prior art, when the cement clinker is replaced by the steel powder slag, the slag and the volcanic ash, a large amount of slag powder and a small amount of steel slag powder are needed to make the mortar meet the specification, so that the utilization rate of the steel slag is low, and the actual production cost is increased.
And when the slag powder and the steel slag powder are used, the water retention of concrete is poor, however, various building materials need certain water retention and mortar with poor water retention, and the building materials are easy to bleed and segregate in the transportation and storage processes, namely, water floats on the surface, sand and cement sink on the bottom, and the building materials need to be stirred again before use.
Various base layers needing mortar for construction have certain water absorption, if the water retention of the mortar is poor, in the smearing process of the mortar, as long as the premixed mortar is in contact with the block or the base layer, the premixed mortar can absorb water, and the outer surface of the mortar evaporates water to the atmosphere, so that the mortar is insufficient in water due to dehydration, further hydration of cement is influenced, normal development of the strength of the mortar is influenced, the strength, particularly the interface strength between a mortar hardened body and the base layer is reduced, and the mortar is cracked and falls off. The mortar with good water retention property has sufficient cement hydration, can normally develop the strength and can be well bonded with the base layer.
The ready-mixed mortar is usually built among water-absorbing blocks or coated on a base layer, and forms an integral body together with a matrix. The influence of poor water retention of the mortar on the engineering quality is as follows:
1. the normal setting and hardening of the mortar are influenced due to excessive water loss of the mortar, the binding force between the mortar and an object surface is reduced, the construction operation is not convenient, the strength of the masonry is reduced, and the engineering quality is greatly reduced.
2. If the mortar has poor water retention, water is easily absorbed by the bricks, so that the mortar is too dry and thick and is not flatly coated, the progress is influenced, and the wall surface is easy to crack due to shrinkage during construction.
Therefore, the increase of the water retention of the mortar is not only beneficial to construction, but also can increase the strength.
Disclosure of Invention
The invention aims to solve the problems that the existing building material additive can not ensure the water absorption of mortar, and the utilization rate of steel slag is very low, so that the actual production cost is increased.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the building material additive comprises styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible emulsion powder, alkali activator and auxiliary agent.
Further, the building material additive comprises, by weight, 23-27 parts of styrene-acrylic emulsion, 16-21 parts of polyvinyl alcohol, 20-28 parts of cellulose ether, 60-80 parts of composite steel powder slag, 35-53 parts of volcanic ash, 3-7 parts of dispersible latex powder and 1.3-3 parts of an auxiliary agent.
Further, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Further, the polyvinyl alcohol with molecular weight of 70000-100000 is selected as the polyvinyl alcohol.
Furthermore, the polyvinyl alcohol is selected from powdery polyvinyl alcohol with the mesh number of 80-120.
Further, the cellulose ether is hydroxypropyl methyl cellulose or hydroxyethyl methyl cellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Further, the fineness standard of the building material additive is 460-520 m/kg.
Compared with the prior art, the invention has the advantages and positive effects that:
the building material additive provided by the invention can improve the water retention property and flexibility of a building material, improve the caking property of the building material, reduce the friction of the building material such as mortar, enhance the working efficiency and quality, prevent a plastering layer from cracking and falling, increase the adhesive strength and smoothness, increase the consumption of steel slag in a gelling agent prepared by the formula and reduce the consumption of the slag. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Example 1
The building material additive provided by the embodiment comprises the following components, by weight, 24 parts of styrene-acrylic emulsion, 18 parts of polyvinyl alcohol, 22 parts of cellulose ether, 63 parts of composite steel powder slag, 40 parts of volcanic ash, 4 parts of dispersible latex powder and 2 parts of an auxiliary agent.
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
Example 2
The building material additive provided by the embodiment comprises, by weight, 25 parts of styrene-acrylic emulsion, 20 parts of polyvinyl alcohol, 27 parts of cellulose ether, 73 parts of composite steel powder slag, 51 parts of volcanic ash, 5 parts of dispersible latex powder and 2.5 parts of an auxiliary agent. .
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
Example 3
The building material additive provided by the embodiment comprises 26 parts of styrene-acrylic emulsion, 17 parts of polyvinyl alcohol, 23 parts of cellulose ether, 64 parts of composite steel powder slag, 40 parts of volcanic ash, 3 parts of dispersible latex powder and 1.8 parts of an auxiliary agent. .
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
The building material additive provided by the invention can improve the water retention property and flexibility of a building material, improve the caking property of the building material, reduce the friction of the building material such as mortar, enhance the working efficiency and quality, prevent a plastering layer from cracking and falling, increase the adhesive strength and smoothness, increase the consumption of steel slag in a gelling agent prepared by the formula and reduce the consumption of the slag. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.
All other embodiments, which can be derived from the embodiments of the present invention by a person skilled in the art without any creative effort, should be included in the protection scope of the present invention.

Claims (8)

1. A building material additive characterized by: comprises the components of styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible emulsion powder, alkali activator and auxiliary agent.
2. The building material additive according to claim 1, wherein: the building material additive comprises, by weight, 23-27 parts of styrene-acrylic emulsion, 16-21 parts of polyvinyl alcohol, 20-28 parts of cellulose ether, 60-80 parts of composite steel powder slag, 35-53 parts of volcanic ash, 3-7 parts of dispersible latex powder and 1.3-3 parts of an auxiliary agent.
3. The building material additive according to claim 1, wherein: the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
4. The building material additive according to claim 1, wherein: the polyvinyl alcohol is selected from polyvinyl alcohol with molecular weight of 70000-100000.
5. The building material additive according to claim 1, wherein: the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
6. The building material additive according to claim 1, wherein: the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
7. A method for preparing the building material additive according to claim 1, comprising the steps of:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
8. The method for preparing the building material additive according to claim 7, wherein: the fineness standard of the building material additive is 460-520 m/kg.
CN201910924127.5A 2019-09-27 2019-09-27 Building material additive and preparation method thereof Pending CN110759662A (en)

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Application Number Priority Date Filing Date Title
CN201910924127.5A CN110759662A (en) 2019-09-27 2019-09-27 Building material additive and preparation method thereof

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Publication Number Publication Date
CN110759662A true CN110759662A (en) 2020-02-07

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113831056A (en) * 2021-10-19 2021-12-24 湖北碞石科技有限公司 Inorganic rubber powder composite powder and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN102249625A (en) * 2010-12-17 2011-11-23 范会生 Composite cementitious material and preparation method thereof
WO2015076675A1 (en) * 2013-11-22 2015-05-28 Pqa B.V. Geopolymer materials comprising alkaline activator and an additive selected from sugar and/or organic acids
CN108264260A (en) * 2018-03-19 2018-07-10 四川省宇坤金属制品有限公司 additives for building materials and preparation method thereof
US20180208509A1 (en) * 2015-06-18 2018-07-26 EMPA Eidgenössische Materialprüfungs- und ForschungsanstaltüÜ Self-prestressed reinforced concrete elements
CN108863264A (en) * 2018-07-13 2018-11-23 桐城市景瑞建筑装饰工程有限公司 A kind of building latex material and preparation method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249625A (en) * 2010-12-17 2011-11-23 范会生 Composite cementitious material and preparation method thereof
WO2015076675A1 (en) * 2013-11-22 2015-05-28 Pqa B.V. Geopolymer materials comprising alkaline activator and an additive selected from sugar and/or organic acids
US20180208509A1 (en) * 2015-06-18 2018-07-26 EMPA Eidgenössische Materialprüfungs- und ForschungsanstaltüÜ Self-prestressed reinforced concrete elements
CN108264260A (en) * 2018-03-19 2018-07-10 四川省宇坤金属制品有限公司 additives for building materials and preparation method thereof
CN108863264A (en) * 2018-07-13 2018-11-23 桐城市景瑞建筑装饰工程有限公司 A kind of building latex material and preparation method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113831056A (en) * 2021-10-19 2021-12-24 湖北碞石科技有限公司 Inorganic rubber powder composite powder and preparation method thereof

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Application publication date: 20200207

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