CN110759662A - Building material additive and preparation method thereof - Google Patents
Building material additive and preparation method thereof Download PDFInfo
- Publication number
- CN110759662A CN110759662A CN201910924127.5A CN201910924127A CN110759662A CN 110759662 A CN110759662 A CN 110759662A CN 201910924127 A CN201910924127 A CN 201910924127A CN 110759662 A CN110759662 A CN 110759662A
- Authority
- CN
- China
- Prior art keywords
- building material
- polyvinyl alcohol
- material additive
- parts
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004566 building material Substances 0.000 title claims abstract description 47
- 239000000654 additive Substances 0.000 title claims abstract description 36
- 230000000996 additive effect Effects 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 35
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 35
- 239000000843 powder Substances 0.000 claims abstract description 35
- 239000002893 slag Substances 0.000 claims abstract description 29
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 24
- 239000010959 steel Substances 0.000 claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 18
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 18
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 239000004816 latex Substances 0.000 claims abstract description 11
- 229920000126 latex Polymers 0.000 claims abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 239000012190 activator Substances 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 15
- 239000011259 mixed solution Substances 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 6
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 230000005294 ferromagnetic effect Effects 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 239000008236 heating water Substances 0.000 claims description 5
- 229910001385 heavy metal Inorganic materials 0.000 claims description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical group OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000003292 glue Substances 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 3
- 239000002341 toxic gas Substances 0.000 abstract description 3
- 239000004570 mortar (masonry) Substances 0.000 description 25
- 206010016807 Fluid retention Diseases 0.000 description 10
- 239000004568 cement Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a building material additive and a preparation method thereof, wherein the building material additive comprises styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible latex powder, an alkali activator and an auxiliary agent. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.
Description
Technical Field
The invention relates to the field of building materials, in particular to a building material additive and a preparation method thereof.
Background
In the field of existing building materials, steel slag and volcanic ash are used for replacing cement clinker to prepare cement cementing materials to produce mortar with stable product performance and good workability, because the chemical composition and the phase composition of the steel slag and the volcanic ash are close to the quantity of common silicon cement, the steel slag can be recycled, and the utilization rate of the steel slag is improved.
However, in the prior art, when the cement clinker is replaced by the steel powder slag, the slag and the volcanic ash, a large amount of slag powder and a small amount of steel slag powder are needed to make the mortar meet the specification, so that the utilization rate of the steel slag is low, and the actual production cost is increased.
And when the slag powder and the steel slag powder are used, the water retention of concrete is poor, however, various building materials need certain water retention and mortar with poor water retention, and the building materials are easy to bleed and segregate in the transportation and storage processes, namely, water floats on the surface, sand and cement sink on the bottom, and the building materials need to be stirred again before use.
Various base layers needing mortar for construction have certain water absorption, if the water retention of the mortar is poor, in the smearing process of the mortar, as long as the premixed mortar is in contact with the block or the base layer, the premixed mortar can absorb water, and the outer surface of the mortar evaporates water to the atmosphere, so that the mortar is insufficient in water due to dehydration, further hydration of cement is influenced, normal development of the strength of the mortar is influenced, the strength, particularly the interface strength between a mortar hardened body and the base layer is reduced, and the mortar is cracked and falls off. The mortar with good water retention property has sufficient cement hydration, can normally develop the strength and can be well bonded with the base layer.
The ready-mixed mortar is usually built among water-absorbing blocks or coated on a base layer, and forms an integral body together with a matrix. The influence of poor water retention of the mortar on the engineering quality is as follows:
1. the normal setting and hardening of the mortar are influenced due to excessive water loss of the mortar, the binding force between the mortar and an object surface is reduced, the construction operation is not convenient, the strength of the masonry is reduced, and the engineering quality is greatly reduced.
2. If the mortar has poor water retention, water is easily absorbed by the bricks, so that the mortar is too dry and thick and is not flatly coated, the progress is influenced, and the wall surface is easy to crack due to shrinkage during construction.
Therefore, the increase of the water retention of the mortar is not only beneficial to construction, but also can increase the strength.
Disclosure of Invention
The invention aims to solve the problems that the existing building material additive can not ensure the water absorption of mortar, and the utilization rate of steel slag is very low, so that the actual production cost is increased.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the building material additive comprises styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible emulsion powder, alkali activator and auxiliary agent.
Further, the building material additive comprises, by weight, 23-27 parts of styrene-acrylic emulsion, 16-21 parts of polyvinyl alcohol, 20-28 parts of cellulose ether, 60-80 parts of composite steel powder slag, 35-53 parts of volcanic ash, 3-7 parts of dispersible latex powder and 1.3-3 parts of an auxiliary agent.
Further, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Further, the polyvinyl alcohol with molecular weight of 70000-100000 is selected as the polyvinyl alcohol.
Furthermore, the polyvinyl alcohol is selected from powdery polyvinyl alcohol with the mesh number of 80-120.
Further, the cellulose ether is hydroxypropyl methyl cellulose or hydroxyethyl methyl cellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Further, the fineness standard of the building material additive is 460-520 m/kg.
Compared with the prior art, the invention has the advantages and positive effects that:
the building material additive provided by the invention can improve the water retention property and flexibility of a building material, improve the caking property of the building material, reduce the friction of the building material such as mortar, enhance the working efficiency and quality, prevent a plastering layer from cracking and falling, increase the adhesive strength and smoothness, increase the consumption of steel slag in a gelling agent prepared by the formula and reduce the consumption of the slag. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
Example 1
The building material additive provided by the embodiment comprises the following components, by weight, 24 parts of styrene-acrylic emulsion, 18 parts of polyvinyl alcohol, 22 parts of cellulose ether, 63 parts of composite steel powder slag, 40 parts of volcanic ash, 4 parts of dispersible latex powder and 2 parts of an auxiliary agent.
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
Example 2
The building material additive provided by the embodiment comprises, by weight, 25 parts of styrene-acrylic emulsion, 20 parts of polyvinyl alcohol, 27 parts of cellulose ether, 73 parts of composite steel powder slag, 51 parts of volcanic ash, 5 parts of dispersible latex powder and 2.5 parts of an auxiliary agent. .
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
Example 3
The building material additive provided by the embodiment comprises 26 parts of styrene-acrylic emulsion, 17 parts of polyvinyl alcohol, 23 parts of cellulose ether, 64 parts of composite steel powder slag, 40 parts of volcanic ash, 3 parts of dispersible latex powder and 1.8 parts of an auxiliary agent. .
Preferably, the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
Preferably, the polyvinyl alcohol has a molecular weight of 70000-100000.
Preferably, the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
Preferably, the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
A preparation method of a building material additive comprises the following steps:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
Preferably, the fineness standard of the building material additive is 460-520 m/kg.
The building material additive provided by the invention can improve the water retention property and flexibility of a building material, improve the caking property of the building material, reduce the friction of the building material such as mortar, enhance the working efficiency and quality, prevent a plastering layer from cracking and falling, increase the adhesive strength and smoothness, increase the consumption of steel slag in a gelling agent prepared by the formula and reduce the consumption of the slag. The environment-friendly building glue with good moisture retention can not emit toxic gas, cannot endanger the safety of the crisis, and is popular with consumers.
All other embodiments, which can be derived from the embodiments of the present invention by a person skilled in the art without any creative effort, should be included in the protection scope of the present invention.
Claims (8)
1. A building material additive characterized by: comprises the components of styrene-acrylic emulsion, polyvinyl alcohol, cellulose ether, composite steel powder slag, volcanic ash, dispersible emulsion powder, alkali activator and auxiliary agent.
2. The building material additive according to claim 1, wherein: the building material additive comprises, by weight, 23-27 parts of styrene-acrylic emulsion, 16-21 parts of polyvinyl alcohol, 20-28 parts of cellulose ether, 60-80 parts of composite steel powder slag, 35-53 parts of volcanic ash, 3-7 parts of dispersible latex powder and 1.3-3 parts of an auxiliary agent.
3. The building material additive according to claim 1, wherein: the auxiliary agent comprises a ferromagnetic element, a heavy metal trapping material and an active catalytic material.
4. The building material additive according to claim 1, wherein: the polyvinyl alcohol is selected from polyvinyl alcohol with molecular weight of 70000-100000.
5. The building material additive according to claim 1, wherein: the polyvinyl alcohol is powder polyvinyl alcohol with the mesh number of 80-120.
6. The building material additive according to claim 1, wherein: the cellulose ether is hydroxypropyl methylcellulose or hydroxyethyl methylcellulose.
7. A method for preparing the building material additive according to claim 1, comprising the steps of:
(1) heating water to above 95 deg.C, and dissolving polyvinyl alcohol in water.
(2) And (2) carrying out mixed grinding treatment on the composite steel powder slag and the volcanic ash for 50-70min according to the weight ratio to obtain a dry material, adding a proper amount of water, wherein the amount of the water is 20-30% of the amount of the dry material, and stirring and uniformly mixing to obtain a mixed solution.
(3) And (3) mixing the cellulose ether, the dispersible latex powder, the alkali activator and the auxiliary agent into the mixed solution obtained in the step (2) to obtain a prepared solution.
(4) And (3) mixing the polyvinyl alcohol obtained in the step (1) and the prepared liquid obtained in the step (3) to obtain the building material additive.
8. The method for preparing the building material additive according to claim 7, wherein: the fineness standard of the building material additive is 460-520 m/kg.
Priority Applications (1)
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CN201910924127.5A CN110759662A (en) | 2019-09-27 | 2019-09-27 | Building material additive and preparation method thereof |
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CN201910924127.5A CN110759662A (en) | 2019-09-27 | 2019-09-27 | Building material additive and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113831056A (en) * | 2021-10-19 | 2021-12-24 | 湖北碞石科技有限公司 | Inorganic rubber powder composite powder and preparation method thereof |
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CN102249625A (en) * | 2010-12-17 | 2011-11-23 | 范会生 | Composite cementitious material and preparation method thereof |
WO2015076675A1 (en) * | 2013-11-22 | 2015-05-28 | Pqa B.V. | Geopolymer materials comprising alkaline activator and an additive selected from sugar and/or organic acids |
CN108264260A (en) * | 2018-03-19 | 2018-07-10 | 四川省宇坤金属制品有限公司 | additives for building materials and preparation method thereof |
US20180208509A1 (en) * | 2015-06-18 | 2018-07-26 | EMPA Eidgenössische Materialprüfungs- und ForschungsanstaltüÜ | Self-prestressed reinforced concrete elements |
CN108863264A (en) * | 2018-07-13 | 2018-11-23 | 桐城市景瑞建筑装饰工程有限公司 | A kind of building latex material and preparation method |
-
2019
- 2019-09-27 CN CN201910924127.5A patent/CN110759662A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102249625A (en) * | 2010-12-17 | 2011-11-23 | 范会生 | Composite cementitious material and preparation method thereof |
WO2015076675A1 (en) * | 2013-11-22 | 2015-05-28 | Pqa B.V. | Geopolymer materials comprising alkaline activator and an additive selected from sugar and/or organic acids |
US20180208509A1 (en) * | 2015-06-18 | 2018-07-26 | EMPA Eidgenössische Materialprüfungs- und ForschungsanstaltüÜ | Self-prestressed reinforced concrete elements |
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CN108863264A (en) * | 2018-07-13 | 2018-11-23 | 桐城市景瑞建筑装饰工程有限公司 | A kind of building latex material and preparation method |
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Application publication date: 20200207 |
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