CN110746817A - Fragrant ink stick and preparation method thereof - Google Patents
Fragrant ink stick and preparation method thereof Download PDFInfo
- Publication number
- CN110746817A CN110746817A CN201810801419.5A CN201810801419A CN110746817A CN 110746817 A CN110746817 A CN 110746817A CN 201810801419 A CN201810801419 A CN 201810801419A CN 110746817 A CN110746817 A CN 110746817A
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- parts
- stirring
- ink stick
- oil
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
Abstract
The invention belongs to the field of ink preparation, and particularly relates to an aromatic ink stick and a preparation method thereof, wherein the preparation method of the aromatic ink stick comprises the following steps: 1) refining smoke; 2) boiling the glue; 3) material blending: mixing 12-30 parts of the tobacco material obtained in the step 1) with 100-200 parts of water and 0-10 parts of alcohol, uniformly stirring by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 1-10 parts of musk pressure-sensitive microcapsules, stirring while heating, and evaporating excessive water until the mixture is in a gel paste shape to obtain a blank; 4) and (5) molding. According to the application, the microcapsule is added into the rubber material, so that the essence molecules are released from the perfume essential oil in the core material in the grinding extrusion process, the smell is fragrant, and when the microcapsule is not used, the perfume essential oil is protected to be non-volatile by the closure of the wall material, the utilization rate of the perfume essential oil is improved, and the cost of the perfume is saved.
Description
Technical Field
The invention belongs to the field of ink preparation, and particularly relates to an aromatic ink stick and a preparation method thereof.
Background
Ink sticks have been popular with literary persons, calligraphy and painting artists and are collected. Since Song, famous ink gradually became the furnishing and appreciating article on the cultural relics' writing case. The requirement of fine ink quality, and the pursuit of form and decorative beauty, which prompts the ink to form an industrial art door and become a treasure of the artworks.
However, since the ink stick uses the malodorous coal and the perishable gelatin as main raw materials, the addition of the perfume is needed, but the fragrance is dissipated after a long time, which affects the use effect.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provides an aromatic ink stick and a preparation method thereof.
In order to achieve the purpose, the invention adopts the following technical scheme:
a preparation method of an aromatic ink stick comprises the following steps:
1) smoke refining: placing the main oil in a cup, placing a cigarette bowl above a lamp holder, and then searching cigarettes at regular time to obtain cigarette materials for later use;
2) boiling glue: adding 3-6 parts of bone glue into 2-3 times of distilled water, heating and melting into liquid, then adding 1-3 parts of gum arabic and 0-0.5 part of borneol, and stirring and mixing to obtain a glue solution for later use;
3) material blending: mixing 12-30 parts of the tobacco material obtained in the step 1) with 100-200 parts of water and 0-10 parts of alcohol, uniformly stirring by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 1-10 parts of musk pressure-sensitive microcapsules, stirring while heating, and evaporating excessive water until the mixture is in a gel paste shape to obtain a blank;
4) placing the manufactured blank in a charging bucket, then manufacturing the blank into ink stick blanks with different shapes through different moulds, and standing and forming; and (5) obtaining the product.
The preparation method of the aromatic pressure-sensitive microcapsule comprises the following steps: 1) preparing a wall material: mixing melamine: formaldehyde: mixing distilled water, adjusting pH to 8-9 with triethanolamine solution, heating to 60-90 deg.C, stirring for 40-60mins to obtain transparent prepolymer reaction solution; 2) adding an emulsifier and distilled water into the perfume essential oil, and stirring at a high speed to obtain a core material emulsion; 3) adding the core material emulsion obtained in the step 2) into the prepolymer reaction liquid obtained in the step 1), uniformly stirring, and dropwise adding an ammonium chloride solution to adjust the pH value to 4-5; stirring for reaction for 2-3h, vacuum filtering, washing the obtained filter cake with ethanol for 2 times, and drying at 30-60 deg.C.
The melamine: formaldehyde: the molar ratio of distilled water is 1: 2-3: 4-5; the perfume essential oil: emulsifier: the mass ratio of the distilled water is 1: 0.1-0.5: 10-20.
The emulsifier is a mixture of Span-80 and Tween-80; span-80: the mass ratio of the Tween to the Tween 80 is 1: 0.1-0.2.
The main oil is one or more of tung oil, soap green oil, rapeseed oil, soybean oil and hemp seed oil.
The application also comprises the fragrant ink stick obtained by the preparation method.
Compared with the prior art, the invention has the beneficial effects that:
according to the application, the microcapsule is added into the rubber material, so that the essence molecules are released from the perfume essential oil in the core material in the grinding extrusion process, the smell is fragrant, and when the microcapsule is not used, the perfume essential oil is protected to be non-volatile by the closure of the wall material, the utilization rate of the perfume essential oil is improved, and the cost of the perfume is saved.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following provides a detailed description of the present invention with reference to the embodiments.
The preparation method of the fragrant pressure-sensitive microcapsule comprises the following steps:
example 1: 1) preparing a wall material: mixing a mixture of 1: 2.5: 4.5 Melamine: formaldehyde: mixing distilled water, adjusting pH to 8-9 with triethanolamine solution, heating to 60-90 deg.C, stirring for 40-60mins to obtain transparent prepolymer reaction solution; 2) adding 0.3 part by mass of emulsifier and 15 parts by mass of distilled water into 1 part by mass of perfume essential oil, and stirring at a high speed to obtain a core material emulsion; the emulsifier is a mixture of Span-80 and Tween-80; span-80: the mass ratio of Tween to 80 is 1: 0.15. 3) Adding the core material emulsion obtained in the step 2) into the prepolymer reaction liquid obtained in the step 1), uniformly stirring, and dropwise adding an ammonium chloride solution to adjust the pH value to 4-5; stirring for reaction for 2-3h, vacuum filtering, washing the obtained filter cake with ethanol for 2 times, and drying at 30-60 deg.C.
Example 2: 1) preparing a wall material: mixing a mixture of 1: 2: 4 melamine: formaldehyde: mixing distilled water, adjusting pH to 8-9 with triethanolamine solution, heating to 60-90 deg.C, stirring for 40-60mins to obtain transparent prepolymer reaction solution; 2) adding 0.1 part by mass of emulsifier and 10 parts by mass of distilled water into 1 part by mass of perfume essential oil, and stirring at a high speed to obtain a core material emulsion; the emulsifier is a mixture of Span-80 and Tween-80; span-80: the mass ratio of Tween to 80 is 1: 0.1. 3) Adding the core material emulsion obtained in the step 2) into the prepolymer reaction liquid obtained in the step 1), uniformly stirring, and dropwise adding an ammonium chloride solution to adjust the pH value to 4-5; stirring for reaction for 2-3h, vacuum filtering, washing the obtained filter cake with ethanol for 2 times, and drying at 30-60 deg.C.
Example 3: 1) preparing a wall material: mixing a mixture of 1: 3: 5 melamine: formaldehyde: mixing distilled water, adjusting pH to 8-9 with triethanolamine solution, heating to 60-90 deg.C, stirring for 40-60mins to obtain transparent prepolymer reaction solution; 2) adding 0.5 part by mass of emulsifier and 20 parts by mass of distilled water into 1 part by mass of perfume essential oil, and stirring at a high speed to obtain a core material emulsion; the emulsifier is a mixture of Span-80 and Tween-80; span-80: the mass ratio of Tween to 80 is 1: 0.5. 3) Adding the core material emulsion obtained in the step 2) into the prepolymer reaction liquid obtained in the step 1), uniformly stirring, and dropwise adding an ammonium chloride solution to adjust the pH value to 4-5; stirring for reaction for 2-3h, vacuum filtering, washing the obtained filter cake with ethanol for 2 times, and drying at 30-60 deg.C.
Example 4: a preparation method of an aromatic ink stick comprises the following steps:
1) smoke refining: placing the main oil in a cup, placing a cigarette bowl above a lamp holder, and then searching cigarettes at regular time to obtain cigarette materials for later use;
2) boiling glue: adding 4 parts of bone glue into 2.5 times of distilled water, heating and melting into liquid, then adding 2 parts of Arabic gum and 0.25 part of borneol, and stirring and mixing to obtain a glue solution for later use;
3) material blending: mixing 20 parts of the tobacco material obtained in the step 1) with 150 parts of water and 5 parts of alcohol, uniformly stirring by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 5 parts of the musk pressure-sensitive microcapsule obtained in the example 1, stirring while heating, and evaporating excessive water until the mixture is in a gel paste shape to obtain a blank;
4) placing the manufactured blank in a charging bucket, then manufacturing the blank into ink stick blanks with different shapes through different moulds, and standing and forming; and (5) obtaining the product.
Example 5: a preparation method of an aromatic ink stick comprises the following steps:
1) smoke refining: placing the main oil in a cup, placing a cigarette bowl above a lamp holder, and then searching cigarettes at regular time to obtain cigarette materials for later use;
2) boiling glue: adding 3 parts of bone glue into 2 times of distilled water, heating and melting into liquid, then adding 1 part of Arabic gum, and stirring and mixing to obtain a glue solution for later use;
3) material blending: mixing 12 parts of the tobacco material obtained in the step 1) with 100 parts of water, stirring uniformly by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 1 part of musk pressure-sensitive microcapsule, heating while stirring, evaporating excessive water until the mixture is in a gel paste shape, and thus obtaining a blank;
4) placing the manufactured blank in a charging bucket, then manufacturing the blank into ink stick blanks with different shapes through different moulds, and standing and forming; and (5) obtaining the product.
Example 6: a preparation method of an aromatic ink stick comprises the following steps:
1) smoke refining: placing the main oil in a cup, placing a cigarette bowl above a lamp holder, and then searching cigarettes at regular time to obtain cigarette materials for later use;
2) boiling glue: adding 6 parts of bone glue into 3 times of distilled water, heating and melting into liquid, then adding 3 parts of gum arabic and 0.5 part of borneol, and stirring and mixing to obtain a glue solution for later use;
3) material blending: mixing 30 parts of the tobacco material obtained in the step 1) with 200 parts of water and 10 parts of alcohol, stirring uniformly by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 10 parts of musk pressure-sensitive microcapsules, stirring while heating, evaporating excessive water until the mixture is in a gel paste shape, and thus obtaining a blank;
4) placing the manufactured blank in a charging bucket, then manufacturing the blank into ink stick blanks with different shapes through different moulds, and standing and forming; and (5) obtaining the product. .
The above description is only a preferred embodiment of the present invention, and for those skilled in the art, the present invention should not be limited by the description of the present invention, which should be interpreted as a limitation.
Claims (6)
1. The preparation method of the fragrant ink stick is characterized by comprising the following steps:
1) smoke refining: placing the main oil in a cup, placing a cigarette bowl above a lamp holder, and then searching cigarettes at regular time to obtain cigarette materials for later use;
2) boiling glue: adding 3-6 parts of bone glue into 2-3 times of distilled water, heating and melting into liquid, then adding 1-3 parts of gum arabic and 0-0.5 part of borneol, and stirring and mixing to obtain a glue solution for later use;
3) material blending: mixing 12-30 parts of the tobacco material obtained in the step 1) with 100-200 parts of water and 0-10 parts of alcohol, uniformly stirring by using a mechanical stirrer at room temperature, slowly heating to 60-80 ℃, adding the glue solution and 1-10 parts of musk pressure-sensitive microcapsules, stirring while heating, and evaporating excessive water until the mixture is in a gel paste shape to obtain a blank;
4) placing the manufactured blank in a charging bucket, then manufacturing the blank into ink stick blanks with different shapes through different moulds, and standing and forming; and (5) obtaining the product.
2. The method of claim 1, wherein the fragrant pressure sensitive microcapsule is prepared by: 1) preparing a wall material: mixing melamine: formaldehyde: mixing distilled water, adjusting pH to 8-9 with triethanolamine solution, heating to 60-90 deg.C, stirring for 40-60mins to obtain transparent prepolymer reaction solution; 2) adding an emulsifier and distilled water into the perfume essential oil, and stirring at a high speed to obtain a core material emulsion; 3) adding the core material emulsion obtained in the step 2) into the prepolymer reaction liquid obtained in the step 1), uniformly stirring, and dropwise adding an ammonium chloride solution to adjust the pH value to 4-5; stirring for reaction for 2-3h, vacuum filtering, washing the obtained filter cake with ethanol for 2 times, and drying at 30-60 deg.C.
3. The method of making an aromatic ink stick according to claim 2, wherein the ratio of melamine: formaldehyde: the molar ratio of distilled water is 1: 2-3: 4-5; the perfume essential oil: emulsifier: the mass ratio of the distilled water is 1: 0.1-0.5: 10-20.
4. The method of claim 2, wherein the emulsifier is a mixture of Span-80 and Tween-80; span-80: the mass ratio of the Tween to the Tween 80 is 1: 0.1-0.2.
5. The method for preparing the fragrant ink stick according to claim 1, wherein the main oil is one or more of tung oil, soap green oil, rapeseed oil, soybean oil and hemp seed oil.
6. A fragrant ink stick obtained by the production method according to any one of claims 1 to 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810801419.5A CN110746817A (en) | 2018-07-20 | 2018-07-20 | Fragrant ink stick and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810801419.5A CN110746817A (en) | 2018-07-20 | 2018-07-20 | Fragrant ink stick and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110746817A true CN110746817A (en) | 2020-02-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810801419.5A Pending CN110746817A (en) | 2018-07-20 | 2018-07-20 | Fragrant ink stick and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116622264A (en) * | 2023-07-12 | 2023-08-22 | 歙县徽文墨厂 | Aromatic type fragrant ink and preparation method thereof |
Citations (5)
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|---|---|---|---|---|
| KR100743992B1 (en) * | 2006-03-13 | 2007-07-30 | 유병조 | Preparation method of song-yeon ink stick |
| CN103464068A (en) * | 2013-09-06 | 2013-12-25 | 上海应用技术学院 | Pressure-sensitive melamine resin essence microcapsule and preparation method thereof |
| CN106752366A (en) * | 2016-12-09 | 2017-05-31 | 钦州市钦南区科学技术情报研究所 | A kind of shelf-stable ink and preparation method thereof |
| CN107611416A (en) * | 2017-08-15 | 2018-01-19 | 武汉科技大学 | A kind of Si-C composite material, its preparation method and application |
| CN107686682A (en) * | 2017-09-20 | 2018-02-13 | 安徽良才墨业有限公司 | A kind of natural aromatic type china ink stick and preparation method thereof |
-
2018
- 2018-07-20 CN CN201810801419.5A patent/CN110746817A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100743992B1 (en) * | 2006-03-13 | 2007-07-30 | 유병조 | Preparation method of song-yeon ink stick |
| CN103464068A (en) * | 2013-09-06 | 2013-12-25 | 上海应用技术学院 | Pressure-sensitive melamine resin essence microcapsule and preparation method thereof |
| CN106752366A (en) * | 2016-12-09 | 2017-05-31 | 钦州市钦南区科学技术情报研究所 | A kind of shelf-stable ink and preparation method thereof |
| CN107611416A (en) * | 2017-08-15 | 2018-01-19 | 武汉科技大学 | A kind of Si-C composite material, its preparation method and application |
| CN107686682A (en) * | 2017-09-20 | 2018-02-13 | 安徽良才墨业有限公司 | A kind of natural aromatic type china ink stick and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116622264A (en) * | 2023-07-12 | 2023-08-22 | 歙县徽文墨厂 | Aromatic type fragrant ink and preparation method thereof |
| CN116622264B (en) * | 2023-07-12 | 2024-01-30 | 歙县徽文墨厂 | Aromatic type fragrant ink and preparation method thereof |
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Application publication date: 20200204 |