CN110724714A - Method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon - Google Patents
Method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/26—Composting, fermenting or anaerobic digestion fuel components or materials from which fuels are prepared
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The invention belongs to the field of a mixed brewing process of grass hydrocarbon and heavy hydrocarbon, and particularly relates to a method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon, which comprises the following steps: (1) processing, crushing and grinding biomass into 120-188 meshes; (2) adding biological peptide heavy hydrocarbon resolvase and graphite peptide; (3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); (4) adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon; (5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C8‑C24. The invention has the advantages of low energy consumption, low cost, low danger and obvious environmental protection efficiency.
Description
Technical Field
The invention belongs to the field of a mixed brewing process of grass hydrocarbon and heavy hydrocarbon, and particularly relates to a method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon.
Background
China faces multiple dilemmas in energy development. First, energy consumption is growing rapidly and energy supply is growing correspondingly, but energy supply increases continue to rely primarily on coal and imported petroleum. Secondly, although China sets out policies and targets for energy conservation and emission reduction, the effects of energy conservation and emission reduction are challenged by the acceleration of GDP. Thirdly, the energy structure adjustment progresses slowly, and the high coal ratio is still a real problem. Due to the factors, the price of energy in China is continuously increased, the pressure of energy environment is continuously increased, and the energy safety faces multiple challenges.
The "congenital deficiency" of energy structure in our country is also the natural endowment we often say. Since this century, the total energy consumption of our country has rapidly increased, mainly depending on coal, petroleum and natural gas. At present, China becomes one of the largest energy consuming countries in the world, but the energy production capacity in China does not rise as fast as the consumption capacity in China, wherein the petroleum consumption growth speed is obviously higher than the domestic yield increase. Second only to the united states, china is the second largest petroleum consumer world country. Production of natural gas and non-fossil energy (hydroelectric, nuclear and wind) has increased rapidly in recent years, but the total is still limited. The energy and related infrastructure investments are enormous. At present, the oil refining process is a production process with high energy consumption, high cost and high danger. Part of oil field and industrial waste remains a considerable part of deposited heavy hydrocarbon resources. How to utilize the renewable materials is significant for solving the problems of energy shortage and environmental pollution. The foreign developed biofuel oil uses soybean and rapeseed as raw materials, needs to be planted in large quantities, occupies land, and has limited resource amount, thus resulting in high cost, high oil price and great popularization difficulty.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the preparation method of the fermented biomass hydrocarbonized diesel oil, which has low energy consumption, low cost, low danger and remarkable environmental protection efficiency.
To solve the above-described problems, the present invention is thus achieved.
The method for producing the light diesel by fermenting the biomass hydrocarbon to brew the heavy hydrocarbon is characterized by comprising the following steps of:
(1) processing, crushing and grinding biomass into 120-188 meshes;
(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the biomass to the biologic peptide heavy hydrocarbon resolvase is 75-97: 7-18; the graphite peptide comprises the following components in percentage by weight: 1-5%;
(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the biomass is 0.02-0.06: 97-110; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 1-5: 3; tetrahydrofuran strontium bite is used as metal activator, and potassium calcium element is suitable. In Japan, where tetrahydrofuran strontium is produced, the marine organism "pancreas of electric eel" is contained as a bioenergy factor, also called as the n-side of RNA, and has strong activation to the enzyme, which is in direct proportion to the activity of the enzyme.
(4) Adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon;
(5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C8-C24(ii) a Weight ratio of grass hydrocarbon to heavy hydrocarbon: 18-94: 17-86.
As a preferred scheme, the graphite peptide is similar to petroleum peptide PCR-petroleum enzyme. See CN 00110698-petroleum peptide PCR-petroleum enzyme, coenzyme and its special activator.
Furthermore, the biomass is crop straws, plant branches and leaves or hay; the heavy hydrocarbon substances are heavy residual oil deposit, coal tar, waste asphalt, heavy oil, clean oil of chemical plants, waste rubber, old tires, waste engineering plastics or coal.
The organic supplementary material biological peptide heavy hydrocarbon resolvase is one kind of petroleum peptide (enzyme) extracted from extreme microbe industrial bacteria extracted from petroleum and constituted by active 'DNA' amino acid factor. The matter has one end of lipophilic molecular structure, under the condition of sublimation heat, the other end of hydrophilic group must be ensured to dissolve biological petroleum enzyme and obtain positive input, and make it be transferred into heavy hydrocarbon heterocyclic structure, and continuously act on C-C bond position in hydrocarbon chain according to original sublimation process temperature to make it be cracked, and self still is fixed in the complex petroleum enzyme marshalling on the peptide chain, and its quality standard is stability of synthesis in production. The heavy hydrocarbon dissociation enzyme of biological peptide used in the invention is prepared by mixing the armillaria lanuginosa petroleum enzyme produced by Liaoning Shangjingtangtaiwang petroleum auxiliary factory with the super-heavy crude oil and the heavy oil in any proportion at normal temperature and normal pressure, and after heating to 140 ℃, the chain breaking recombination of the macromolecular structures of the super-heavy crude oil and the heavy oil is carried out to form a small molecular structure, thus being capable of achieving the refining standard of oil products. The kinetic energy generated by the activity of the enzyme is higher than the potential energy of a macromolecular carbon skeleton of alkane, so that the carbon skeleton is cracked and the carbon-hydrogen bonds are broken, and the high-efficiency and rapid viscosity reduction and condensation reduction effects of super-heavy oil, high-pour-point oil and heavy (slag) oil products are achieved.
The invention uses biological peptide heavy hydrocarbon dissociation enzyme complex tetrahydrofuran strontium-bite and sodium hexahydroquinoline as compound free transfer factor assistant, which is affinity carboxyl in grass-leaved hydrocarbon essence, contains a large amount of organic calcium, organic silicon and active calcium in straws, determines the activity of hydrocarbon enzyme in grass-leaved hydrocarbon brewing according to the ratio of multiplier of a counting plate, adds graphite peptide, the enzymatic reaction acts on the C-C energy unbalance in the heavy hydrocarbon component in direct proportion, grass-leaved hydrocarbon basic groups and free radical ions are operated to receive absorption to maintain the residual ends of the dissociated small-molecule light-component hydrocarbon molecules, the surface tension of the molecules is balanced, in the process of exchanging the two-way cross flow state factors, a great number of cellulose, hemicellulose, xylan and inositol sugar obtain peptide-based free negative ion peptide hydrogen elements before sublimation, overheating and carbonization, and modification is carried out to participate in liquid phase recombination of modification and mixing. The graphite peptide and the petroleum peptide belong to the same kind of mineral deposit protein structure and are also called carbon-series DNA.
The invention utilizes the waste residue after the reaction of the grass hydrocarbon and the oils containing colloid and high asphaltene, such as heavy oil, heavy oil and the like, as the raw material of the graphite electrode, the waste residue after the reaction with the heavy residual oil and the waste asphalt is activated carbon and carbon powder, and the waste residue after the reaction with coal, coal tar and high molecular engineering plastics is the raw material of acetylene, thereby being beneficial to the recycling of waste resources, solving the problem of energy shortage and purifying the environment. The oil yield of the ton raw material reaches 50-60%; the cost is lower than 2000 yuan/ton. The normal pressure and the temperature of the low-energy consumption production operation are 240 ℃. Initial boiling point: 135 ℃ lower than the distillation range of the non-gramineous hydrocarbon by 138 ℃, and the measured amount of heavy super heavy oil: 100ml, 306 ℃ and 60.45 percent of yield.
Detailed Description
Example 1
The method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon comprises the following steps:
(1) processing, crushing and grinding crop straws into 120 meshes;
(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the crop straws to the biological peptide heavy hydrocarbon dissociation enzyme is 75: 7; the graphite peptide comprises the following components in percentage by weight: 1 percent;
(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the crop straws is 0.02: 97; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 1: 3;
(4) adding the prepared raw materials into crop straws which are 135 meshes and are auxiliary materials with the weight percentage of 1 percent; fermenting at 26 deg.C for 35h to obtain grass hydrocarbon;
(5) mixing grass-grain hydrocarbon with coal tar, heating until the heat in the tank reaches 1.8 ten thousand calories and the outlet temperature reaches 89 deg.C, and producing light fuel hydrocarbon C8-C24(ii) a Weight ratio of grass hydrocarbon to coal tar: 18:17.
Example 2
The method for producing light diesel oil by fermenting plant branch and leaf hydrocarbon to brew heavy hydrocarbon comprises the following steps:
(1) processing, crushing and grinding plant branches and leaves into 188 meshes;
(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the plant branches and leaves to the biologic peptide heavy hydrocarbon resolvase is 97: 18; the weight percentage content of the graphite peptide is 5 percent;
(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor auxiliary agent tetrahydrofuran strontium bite and sodium hexahydroquinoline to the plant branches and leaves is 0.06: 110; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 5: 3;
(4) adding the prepared raw materials into 178-mesh auxiliary material plant branches and leaves with the weight percentage of 7%; fermenting at 75 ℃ for 65 hours to obtain grass hydrocarbon;
(5) mixing grass-grain hydrocarbon and heavy hydrocarbon, heating until the heat in the tank reaches 1.8 ten thousand calories and the outlet temperature reaches 298 deg.C, producing light fuel hydrocarbon C8-C24(ii) a Weight ratio of grass hydrocarbon to heavy hydrocarbon: 94:86.
Example 3
The method for producing the light diesel by fermenting the biomass hydrocarbon to brew the heavy hydrocarbon is characterized by comprising the following steps of:
(1) processing, crushing and grinding the hay into 150 meshes;
(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the hay to the biologic peptide heavy hydrocarbon resolvase is 80: 11; the graphite peptide comprises the following components in percentage by weight: 3 percent;
(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the hay is 0.05: 98; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 4: 3;
(4) adding auxiliary material hay with the weight percentage of 5 percent and 150 meshes into the prepared raw materials; fermenting at 55 deg.C for 40h to obtain grass hydrocarbon;
(5) mixing grass-grain hydrocarbon with thick oil, heating until the heat in the tank reaches 1.8 ten thousand calories and the outlet temperature reaches 111 deg.C to produce light fuel hydrocarbon C8-C24(ii) a Weight ratio of grass hydrocarbon to thick oil: 20:55.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (3)
1. The method for producing the light diesel by fermenting the biomass hydrocarbon to brew the heavy hydrocarbon is characterized by comprising the following steps of:
(1) processing, crushing and grinding biomass into 120-188 meshes;
(2) adding a biological peptide heavy hydrocarbon resolvase and graphite peptide into the product obtained in the step (1); the weight ratio of the biomass to the biologic peptide heavy hydrocarbon resolvase is 75-97: 7-18; the graphite peptide comprises the following components in percentage by weight: 1-5%;
(3) adding a compound free transfer factor auxiliary agent of strontium tetrahydrofuran and sodium hexahydroquinoline into the step (2); the weight ratio of the free transfer factor assistant tetrahydrofuran strontium bite and sodium hexahydroquinoline to the biomass is 0.02-0.06: 97-110; the weight ratio of the tetrahydrofuran strontium bite to the hexahydroquinoline sodium is 1-5: 3;
(4) adding the prepared raw materials into an auxiliary material biomass of 135-178 meshes and 1-7 wt%; fermenting at the temperature of 26-75 ℃ for 35-65 h to obtain the grass hydrocarbon;
(5) mixing the grass-grain hydrocarbon and the heavy hydrocarbon substances, heating until the heat in the tank reaches 1.8 ten thousand calories, and when the outlet temperature reaches 89-298 ℃, producing the light fuel hydrocarbon C8-C24(ii) a Weight ratio of grass hydrocarbon to heavy hydrocarbon: 18-94: 17-86.
2. The method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon according to claim 1, characterized in that: the graphite peptide is similar to petroleum peptide PCR-petroleum enzyme.
3. The method for producing light diesel oil by fermenting biomass hydrocarbon to brew heavy hydrocarbon according to claim 2, characterized in that: the biomass is crop straws, plant branches and leaves or hay; the heavy hydrocarbon substances are heavy residual oil deposit, coal tar, waste asphalt, heavy oil, clean oil of chemical plants, waste rubber, old tires, waste engineering plastics or coal.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748586A (en) * | 2020-06-30 | 2020-10-09 | 段杨阳 | Preparation method of biological graphite peptide RNA |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335450A (en) * | 2000-07-24 | 2002-02-13 | 姜国文 | Petroleum peptide PCR-petroleum enzyme, coenzyme and its special activator |
| CN104910949A (en) * | 2015-07-02 | 2015-09-16 | 王丽华 | Preparation method of fermented biomass alkylated diesel oil |
| US20170240925A1 (en) * | 2016-02-22 | 2017-08-24 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C. | Method of Transforming Biomass into Hydrocarbon |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335450A (en) * | 2000-07-24 | 2002-02-13 | 姜国文 | Petroleum peptide PCR-petroleum enzyme, coenzyme and its special activator |
| CN104910949A (en) * | 2015-07-02 | 2015-09-16 | 王丽华 | Preparation method of fermented biomass alkylated diesel oil |
| US20170240925A1 (en) * | 2016-02-22 | 2017-08-24 | Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.O.C. | Method of Transforming Biomass into Hydrocarbon |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111748586A (en) * | 2020-06-30 | 2020-10-09 | 段杨阳 | Preparation method of biological graphite peptide RNA |
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