CN110714368B - Preparation method of tipping paper containing edible pigment ink for cigarettes - Google Patents

Preparation method of tipping paper containing edible pigment ink for cigarettes Download PDF

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Publication number
CN110714368B
CN110714368B CN201911075926.6A CN201911075926A CN110714368B CN 110714368 B CN110714368 B CN 110714368B CN 201911075926 A CN201911075926 A CN 201911075926A CN 110714368 B CN110714368 B CN 110714368B
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China
Prior art keywords
tipping paper
parts
pigment ink
cigarette
cigarettes
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CN201911075926.6A
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Chinese (zh)
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CN110714368A (en
Inventor
刘玲红
邱诗波
姚里程
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Hubei Danyaxiang Biological Technology Co ltd
China Tobacco Hubei Industrial LLC
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Hubei Danyaxiang Biological Technology Co ltd
China Tobacco Hubei Industrial LLC
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Priority to CN201911075926.6A priority Critical patent/CN110714368B/en
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/22Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/82Paper comprising more than one coating superposed
    • D21H19/824Paper comprising more than one coating superposed two superposed coatings, both being non-pigmented

Abstract

The invention discloses a preparation method of tipping paper for cigarettes containing edible pigment ink, which comprises the following steps: (1) printing water-based ink containing anthocyanin pigments to the tipping paper base paper layer through a flexible plate; (2) spraying starch paste on the tipping paper obtained in the step (1), and drying at low temperature of 50-70 ℃; (3) bonding ascorbic acid powder containing edible bonding agent to the tipping paper obtained in the step (2); (4) the filter tip is dried, shielded from light and stored at low temperature, can be harmlessly checked whether the filter tip for cigarette is sucked by other products, and can eliminate the damage of nicotine to human body to a certain extent.

Description

Preparation method of tipping paper containing edible pigment ink for cigarettes
Technical Field
The invention relates to the field of tipping paper preparation, in particular to a preparation method of tipping paper for cigarettes containing edible pigment ink.
Background
The tipping paper for the cigarette is special paper for tipping a filter tip and a cigarette, a consumer must use a type of printed matter contacted with a mouth when smoking the cigarette, the tipping paper is non-toxic and harmless according to the sanitary standard of food packaging paper in China, the tipping paper for the cigarette is usually printed with a certain color or pattern to distinguish the positions of the filter tip and the cigarette, however, the water-based ink pigment used on the market is generally azo organic pigment or inorganic pigment such as titanium white, iron oxide, carbon black and the like, the organic pigment or the inorganic pigment has certain toxicity, and when the ink is applied to food packaging printing, certain risk and hidden trouble exist.
Meanwhile, when a consumer smokes at a party with relatives and friends, the consumer only holds cigarettes in the mouth due to the fact that the consumer has a lot of hands or is in a etiquette, and the cigarettes are put into a cigarette case or are transmitted to other people under an unknown condition after the consumer does not smoke the cigarettes, so that one problem affects the body health, and the other problem affects the oral hygiene.
Disclosure of Invention
In order to solve the problems, the invention provides a preparation method of cigarette tipping paper containing edible pigment printing ink, which can be used for harmlessly detecting whether a cigarette filter head is sucked by other products and eliminating the damage of nicotine to human bodies to a certain extent.
The technical scheme of the invention is to provide a preparation method of cigarette tipping paper containing edible pigment ink, which is characterized by comprising the following steps:
(1) printing water-based ink containing anthocyanin pigments to the tipping paper base paper layer through a flexible plate;
(2) spraying starch paste on the tipping paper obtained in the step (1), and drying at low temperature of 50-70 ℃;
(3) bonding ascorbic acid powder containing edible bonding agent to the tipping paper obtained in the step (2);
(4) shading and airing.
Preferably, the edible binder in step (3) is maltodextrin.
Preferably, the aqueous ink containing anthocyanin pigment comprises the following components in parts by mass: 35-50 parts of acrylic resin emulsion, 20-35 parts of anthocyanin pigment, 2-4 parts of wetting dispersant, 0.5-2 parts of transfer agent, 0.2-2 parts of defoaming agent, 10-25 parts of deionized water, 5-10 parts of cosolvent and 0.1-1 part of pH regulator.
Preferably, the defoaming agent is one or more of silicon emulsion, oleic acid monoglyceride and sorbitol oleate.
Preferably, the wetting dispersant is one or more of nonylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, alkylamide taurate, dialkyl succinic acid sulfonate and alkylphenol polyoxyethylene ether.
Preferably, the drying time required in step (2) is 20-40 h.
Preferably, the bonding operation mode in the step (3) is low-temperature spraying.
Preferably, the using amount of the ascorbic acid powder is 2-4 times of the mass of the anthocyanin pigment, and the purity of the ascorbic acid powder is 70% -99%.
The anthocyanin pigment is a water-soluble pigment widely existing in plants, forms colorful colors of fruits, flowers and vegetables, is mostly in the form of glycoside with sugar, has strong antioxidant activity due to high activity, temperature, pH, oxygen, metal particles, ascorbic acid and the like which can influence the stability of the anthocyanin, can be faded by adding or condensing with the ascorbic acid due to the structure of the anthocyanin, can not adopt the processes of blanching and the like when the water-based ink of the anthocyanin pigment is used, needs to adopt a flexible plate printing with small influence on the stability of the anthocyanin for color protection of the anthocyanin, and in the scheme, the finished tipping paper can be regarded as being composed of three layers, namely a water-based ink layer containing the anthocyanin pigment and a starch paste layer, namely a glutinous rice paper layer from inside to outside in sequence, namely the glutinous rice paper layer, The ascorbic acid layer is used for protecting the filter head after the tipping paper is finished or the filter head is tipped in during actual use, so that substances such as light, oxygen and the like can be prevented from damaging the ascorbic acid and losing the effect of the ascorbic acid.
It is worth noting that the function principle of the scheme is to assemble the prepared tipping paper containing three layers of substances on the cigarette, when a consumer starts to smoke the cigarette, the lips are contained on the filter head wrapped by the tipping paper of the scheme, when the product is sucked, the water vapor or saliva in the oral cavity can be used for coating the ascorbic acid on the lips, and the temperature of the saliva and the lips melts the glutinous rice paper which is originally used for separating the ascorbic acid from the aqueous ink containing the anthocyanin pigment to be in direct contact with the aqueous ink, so that the ascorbic acid is in direct contact with the aqueous ink, the ascorbic acid is in direct contact with the anthocyanin, and with the increase of saliva and the continuous clamping of lips, the ascorbic acid is accelerated to react with the anthocyanin until the anthocyanin fades, the fading of the anthocyanin indicates that the cigarette is smoked or contained by a consumer, and the next cigarette smoker can judge whether the cigarette end is sanitary.
Meanwhile, the smoker mostly eats vitamin C, namely ascorbic acid, which is beneficial to improving the resistance of cells, keeping the elasticity of blood vessels, eliminating nicotine in the body and relieving the damage of cigarettes to the body of the smoker.
The cigarette with the anthocyanin has the beneficial effects that by the principle that the anthocyanin can fade through the ascorbic acid, when the cigarette is smoked, the glutinous rice paper which is originally used as a partition is melted by saliva or lip temperature, so that the anthocyanin and the ascorbic acid are directly contacted and fade, and a consumer is reminded of whether the cigarette is smoked by other people, and the cigarette is safe and nontoxic.
Detailed Description
In order to make the present invention more comprehensible, the technical solutions of the present invention are further described below with reference to specific embodiments, but the present invention is not limited thereto.
Example 1
Preparing water-based ink: weighing 50g of acrylic resin emulsion, 25g of deionized water and 5g of cosolvent, putting the weighed acrylic resin emulsion, the deionized water and the cosolvent into a reaction kettle, uniformly mixing, adding 20g of anthocyanin pigment, 2g of nonylphenol polyoxyethylene ether, 0.5g of transfer agent, 0.2g of oleic acid monoglyceride and 0.1g of pH carbonate buffer salt into the reaction kettle after uniformly stirring, adjusting the pH to 7, dispersing the transfer agent at a high speed at a stirring speed of 800 r/min, grinding the transfer agent to the fineness of less than or equal to 20 mu m by a sand mill, obtaining the water-based flexographic printing ink containing the edible pigment, and filtering to obtain the water-based printing ink containing the edible pigment.
Preparing tipping paper for cigarettes: (1) loading water-based ink containing edible pigments into an ink fountain roller, transferring the water-based ink into an anilox roller under the action of the ink fountain roller, uniformly coating an ink layer with a certain thickness on an image-text part of a printing plate through the anilox roller, and transferring the ink layer of the image-text part to the surface of a printing stock under the action of the pressure of an impression cylinder to form clear images and texts, wherein in the embodiment, the number of anilox lines of the anilox roller is 150 lpi, the printing speed is 100 m/min, and each group of printing plates is provided with 100 mu m of compression; (2) uniformly spraying 100g of starch paste on tipping paper printed by water-based ink containing edible pigment by using a spraying machine, and drying at the low temperature of 50 ℃ for 40h until the starch paste is transparent glutinous rice paper, wherein the spraying thickness of the starch paste is 0.1 mm; (3) uniformly mixing 40g of ascorbic acid powder and 50g of 50% maltodextrin, and spraying the mixture to the sticky rice paper layer at 25 ℃, wherein the maltodextrin is used as a bonding agent to improve the adhesive force of the ascorbic acid on the sticky rice paper, and meanwhile, the sticky rice paper cannot be melted due to low water content; (3) and (5) air-drying by a fan, and storing in a low-temperature shading mode.
Example 2
Preparing water-based ink: weighing 35g of acrylic resin emulsion, 20g of deionized water and 10g of cosolvent, putting the weighed acrylic resin emulsion, 20g of deionized water and 10g of cosolvent into a reaction kettle, uniformly mixing, adding 35g of anthocyanin pigment, 0.2g of fatty alcohol-polyoxyethylene ether, 2g of transfer agent, 2g of silicon emulsion, 1g of pH carbonate buffer salt into the reaction kettle after uniformly stirring, adjusting the pH to 7, adding the transfer agent into the reaction kettle, dispersing at a high speed at a stirring speed of 1000 r/min, grinding by a sand mill until the fineness is less than or equal to 20 mu m to obtain water-based flexographic ink color paste, and filtering to obtain the water-based ink containing the edible pigment.
Preparing tipping paper for cigarettes: (1) loading water-based ink containing edible pigments into an ink fountain roller, transferring the water-based ink into an anilox roller under the action of the ink fountain roller, uniformly coating an ink layer with a certain thickness on an image-text part of a printing plate through the anilox roller, and transferring the ink layer of the image-text part to the surface of a printing stock under the action of the pressure of an impression cylinder to form clear images and texts, wherein in the embodiment, the number of anilox lines of the anilox roller is 150 lpi, the printing speed is 100 m/min, and each group of printing plates is provided with 100 mu m of compression; (2) uniformly spraying 100g of starch paste on tipping paper printed by water-based ink containing edible pigment by using a spraying machine, and drying at the low temperature of 50 ℃ for 40h until the starch paste is transparent glutinous rice paper, wherein the spraying thickness of the starch paste is 0.1 mm; (3) uniformly mixing 40g of ascorbic acid powder and 50g of 50% maltodextrin, and spraying the mixture to the sticky rice paper layer at 25 ℃, wherein the maltodextrin is used as a bonding agent to improve the adhesive force of the ascorbic acid on the sticky rice paper, and meanwhile, the sticky rice paper cannot be melted due to low water content; (3) and (5) air-drying by a fan, and storing in a low-temperature shading mode.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications made in accordance with the claims of the present invention should be covered by the present invention.

Claims (7)

1. A preparation method of cigarette tipping paper containing edible pigment ink is characterized by comprising the following steps:
(1) printing water-based ink containing anthocyanin pigments to the tipping paper base paper layer through a flexible plate;
(2) spraying starch paste on the tipping paper obtained in the step (1), and drying at low temperature of 50-70 ℃;
(3) bonding ascorbic acid powder containing edible bonding agent to the tipping paper obtained in the step (2);
(4) drying, shading and storing at low temperature;
the tipping paper for the cigarette obtained by the preparation method sequentially comprises a water-based ink layer, a starch paste layer and an ascorbic acid layer from inside to outside; the starch paste layer is intended to be melted by the temperature of the saliva and the lips themselves.
2. The method for preparing the tipping paper for the cigarette containing the edible pigment ink according to the claim 1, wherein the edible binder in the step (3) is maltodextrin.
3. The method for preparing the tipping paper for the cigarettes containing the edible pigment ink according to claim 1, wherein the aqueous ink containing the anthocyanin pigment comprises the following components in parts by mass: 35-50 parts of acrylic resin emulsion, 20-35 parts of anthocyanin pigment, 2-4 parts of wetting dispersant, 0.5-2 parts of transfer agent, 0.2-2 parts of defoaming agent, 10-25 parts of deionized water, 5-10 parts of cosolvent and 0.1-1 part of pH regulator.
4. The method for preparing the tipping paper containing the edible pigment ink for the cigarettes as claimed in claim 3, wherein the defoaming agent is one or more of silicone emulsion, oleic acid monoglyceride and sorbitol oleate.
5. The method for preparing the cigarette tipping paper containing the edible pigment ink according to claim 3, wherein the wetting dispersant is one or more of fatty alcohol-polyoxyethylene ether, alkylamide taurate, dialkyl succinic acid sulfonate and alkylphenol polyoxyethylene ether.
6. The method for preparing the tipping paper containing the edible pigment ink for the cigarettes according to claim 1, wherein the drying time required in the step (2) is 20-40 h.
7. The method for preparing the tipping paper containing the edible pigment ink for the cigarettes according to claim 1, wherein the bonding operation mode in the step (3) is spraying.
CN201911075926.6A 2019-11-06 2019-11-06 Preparation method of tipping paper containing edible pigment ink for cigarettes Active CN110714368B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN110714368B true CN110714368B (en) 2021-12-31

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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103146258B (en) * 2013-03-20 2014-11-26 哈尔滨绿科科技有限公司 Special water-based ink for printing tipping paper for cigarette and preparation method thereof
CN104789035B (en) * 2015-05-06 2017-08-01 湖北中烟工业有限责任公司 A kind of cigarette tipping paper and preparation method thereof
CN109418673A (en) * 2017-08-31 2019-03-05 康师傅饮品控股有限公司 A kind of method and its application adjusting anthocyanidin stability
CN207452589U (en) * 2017-11-01 2018-06-05 浙江荣丰纸业有限公司 A kind of dulcet environment-friendly type cigarette ink tipping paper of tool
CN207452588U (en) * 2017-11-01 2018-06-05 浙江荣丰纸业有限公司 A kind of environment-friendly type cigarette ink tipping paper
CN109294332A (en) * 2018-09-13 2019-02-01 广东中烟工业有限责任公司 A kind of cigarette with anti-fake color shifting ink with and preparation method thereof and cigarette tipping paper

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