CN110714345A - Antistatic plush fabric - Google Patents

Antistatic plush fabric Download PDF

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Publication number
CN110714345A
CN110714345A CN201911033783.2A CN201911033783A CN110714345A CN 110714345 A CN110714345 A CN 110714345A CN 201911033783 A CN201911033783 A CN 201911033783A CN 110714345 A CN110714345 A CN 110714345A
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CN
China
Prior art keywords
antistatic
agent
dye
fiber
plush
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201911033783.2A
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Chinese (zh)
Inventor
王云根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu Yunyu Weaving Co Ltd
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Changshu Yunyu Weaving Co Ltd
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Publication date
Application filed by Changshu Yunyu Weaving Co Ltd filed Critical Changshu Yunyu Weaving Co Ltd
Priority to CN201911033783.2A priority Critical patent/CN110714345A/en
Publication of CN110714345A publication Critical patent/CN110714345A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/6426Heterocyclic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/622Sulfonic acids or their salts
    • D06P1/623Aliphatic, aralophatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/627Sulfates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses an antistatic plush fabric, which comprises raw materials of cotton fibers or viscose fibers, wherein an antistatic agent, a permeating wetting agent, a dispersing agent and a leveling agent are added into a dyeing solution, wherein the dye in the dyeing solution adopts a sun-proof dye, the antistatic agent adopts a light stabilizer compatible and compounded with the sun-proof dye, the dye and the antistatic agent are permanently and uniformly attached and coated on the surfaces of the cotton fibers or the viscose fibers by a dyeing process, so that antistatic dyed plush fibers are obtained, and the antistatic dyed plush fabric is prepared by the antistatic dyed plush fibers through a textile process; the antistatic treatment method is simple, and can simultaneously realize lasting antistatic and dyeing effects.

Description

Antistatic plush fabric
Technical Field
The invention belongs to the technical field of knitted fabrics, and particularly relates to an antistatic plush fabric.
Background
As is well known, pile fibers are widely made into a pile fabric used in the clothing and home textile industries due to their flexibility, thermal insulation, and other comfort properties. However, due to the fluff property of the plush fabric, the surface of the plush fabric has serious electrostatic problems.
Generally, the electrostatic phenomenon of the knitted fabric mainly refers to a phenomenon generated by complicated and staggered charge generation process and disappearance process. The actual static level is a dynamic balance process achieved by the two opposite processes, and the antistatic basic raw materials of the knitted fabric mainly comprise: the static electricity of the fabric is reduced, the leakage of the static electricity is accelerated, and the condition for rapidly shielding the static electricity is formed.
More antistatic solutions are provided for plush fabrics, and for example, the invention patent with the publication number of CN105346158A discloses an antistatic plush fabric which comprises a plush layer and an antistatic composite layer; the plush layer comprises a plush yarn tissue and a bottom yarn tissue; the mass percentage of the pile yarn tissue in the fabric is 65-85%, the mass percentage of the bottom yarn tissue in the fabric is 15-35%, the pile yarn tissue is composed of 10% of conductive yarn and 90% of polyester yarn, and the bottom yarn tissue is composed of 20% of conductive yarn and 80% of polyester yarn; the antistatic composite layer is weft-knitted fabric of carbon fiber. Also, for example, the patent of invention with publication number CN109423770A discloses an antistatic polyester fabric, which is composed of ground cloth filaments and plush, wherein the ground cloth filaments are woven by nylon carbon filaments and polyester filaments, the nylon carbon filaments are 20-30D, and the polyester filaments are 70-80D. The invention has the advantages that the conductive yarn formed by combining the nylon carbon yarn and the common polyester yarn is added into the polyester fabric through a weaving method, so that the antistatic performance of the polyester fabric is improved, and the polyester fabric can rapidly leak fabric electrostatic charges. The technologies are basically a solution idea of adopting conductive yarns in polyester fabrics, and because the conductive yarns have serious color limitation and are added into wool fibers for co-spinning, color difference can be caused.
At present, the prior art also adopts an antistatic method for directly carrying out graft polymerization modification on wool fibers, but the modification process is complex and the modification effect is not stable enough. The antistatic agent is added into the fabric, but the antistatic ability of the fabric is lost after the fabric is washed with water.
The applicant therefore sought a solution to the above mentioned technical problem.
Disclosure of Invention
In view of the above, the present invention aims to provide an antistatic plush fabric, which has a simple antistatic treatment method and can simultaneously achieve a lasting antistatic and dyeing effect.
The technical scheme adopted by the invention is as follows:
an antistatic plush fabric is prepared by adding an antistatic agent, a penetration wetting agent, a dispersing agent and a leveling agent into a dyeing solution, wherein the dye in the dyeing solution adopts a sun-proof dye, the antistatic agent adopts a light stabilizer compatible and compounded with the sun-proof dye, the dye and the antistatic agent are permanently and uniformly attached and coated on the surface of the cotton fiber or the viscose fiber through a dyeing process to obtain the antistatic dyed plush fiber, and the antistatic dyed plush fiber is prepared through a textile process.
Preferably, the light stabilizer is a hindered amine light stabilizer, the penetrating wetting agent is one or a mixture of more of turkey red oil, nekal powder and wax powder, the dispersing agent is an anionic surfactant, and the leveling agent is a mixture of a hydrophilic fiber leveling agent and a dye leveling agent.
Preferably, the weight ratio of the light stabilizer to the light-fast dye is 1:1-1: 3.
Preferably, the dispersing agent is a naphthalene formaldehyde sulfonic acid dispersing agent, the nucleophilic fiber leveling agent is sodium alkyl sulfonate or higher fatty alcohol sodium sulfate salt, and the dye leveling agent is a quaternary ammonium salt surfactant.
Preferably, the dyeing process comprises the operating steps of:
s1), adding water serving as a solvent into a dye vat, and keeping the temperature of the water in the dye vat at 40-60 ℃;
s2), adding the sun-proof dye into a dye vat, and stirring at a constant speed;
s3), sequentially adding an antistatic agent, a penetrating wetting agent, a dispersing agent and a leveling agent under a uniform-speed stirring state;
s4), after the stirring time at least reaches 1 hour, adding the cotton fiber or viscose fiber to be dyed into a dye vat, and uniformly stirring the cotton fiber or viscose fiber to obtain the antistatic dyed wool fiber;
s5), drying the antistatic dyed pile fiber.
The English name of the hindered amine light stabilizer related to the invention is Lightstabilizer, and the chemical formula is as follows: (C35H66N8) N, wherein N is 4-5 with CAS number 70624-18-9.
The method comprises the steps that an antistatic process is directly combined in a fabric raw material dyeing process to break through thinking tendency for the first time, a sun-proof dye is adopted as a coloring agent through special screening, a light stabilizer with compatibility and compoundability with the sun-proof dye is adopted as an antistatic agent, under the synergistic effect of auxiliaries such as a penetration wetting agent, a heat dissipation agent and a leveling agent, the antistatic agent and the coloring agent can be simultaneously and permanently and stably attached to the surface of cotton fiber or viscose fiber to obtain antistatic dyed wool pile fiber, and after the antistatic dyed wool fiber is subjected to a subsequent knitting process, the lasting dyeing and antistatic effect can be simultaneously realized; the antistatic process of the invention does not need to additionally add any other process, is directly used as an additive in the dyeing process, utilizes the lasting effect characteristic of the dyeing agent on the fiber, and adopts the light stabilizer which is completely compatible and compounded with the dyeing agent, thereby finally realizing the lasting antistatic effect of the antistatic agent on the plush fabric.
Drawings
FIG. 1 is a block diagram of the steps of a dyeing process in accordance with an embodiment of the present invention.
Detailed Description
The embodiment of the invention discloses an antistatic plush fabric, which comprises raw materials of cotton fibers or viscose fibers, wherein an antistatic agent, a penetrating wetting agent, a dispersing agent and a leveling agent are added into a dyeing solution, wherein the dye in the dyeing solution adopts a sun-proof dye, the antistatic agent adopts a light stabilizer compatible and compounded with the sun-proof dye, the dye and the antistatic agent are attached and coated on the surfaces of the cotton fibers or the viscose fibers permanently and uniformly by a dyeing process, so that antistatic dyed plush fibers are obtained, and the antistatic dyed plush fibers are prepared by a textile process.
In order to make those skilled in the art better understand the technical solution of the present invention, the technical solution in the embodiment of the present invention will be clearly and completely described below with reference to the drawings in the embodiment of the present invention, and it is obvious that the described embodiment is only a part of the embodiment of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1: an antistatic plush fabric is prepared by adding an antistatic agent, a penetration wetting agent, a dispersing agent and a leveling agent into a dyeing solution, wherein the dye in the dyeing solution adopts a light-fast dye, the antistatic agent adopts a light stabilizer compatible and compounded with the light-fast dye, preferably, the light stabilizer adopts a hindered amine light stabilizer (commercially available), the hindered amine light stabilizer is 2 times of the weight ratio of the light-fast dye, the penetration wetting agent is selected from the mixture of Turkey red oil and wax powder, the dispersing agent adopts a naphthalene formaldehyde sulfonic acid dispersing agent, and the leveling agent adopts the mixture of alkyl sodium sulfonate and quaternary amine salt surfactant.
Preferably, referring to fig. 1, the dyeing process of embodiment 1 includes the following steps:
s1), adding water serving as a solvent into a dye vat, and keeping the temperature of the water in the dye vat at 40-60 ℃;
s2), adding the sun-proof dye into a dye vat, and stirring at a constant speed;
s3), sequentially adding an antistatic agent, a penetrating wetting agent, a dispersing agent and a leveling agent under a uniform-speed stirring state;
s4), after the stirring time reaches 1 hour, adding the cotton fiber or viscose fiber to be dyed into a dye vat, and uniformly stirring the cotton fiber or viscose fiber to obtain antistatic dyed wool fiber;
s5), drying the antistatic dyed pile fibers.
In this example 1, a dye and an antistatic agent are attached and coated on the surface of a cotton fiber permanently and uniformly by a dyeing process, so as to obtain an antistatic dyed pile fiber, and the antistatic dyed pile fiber is made into an antistatic pile fabric by a known textile process.
Example 2: the remaining technical solutions of this embodiment 2 are different from those of embodiment 1 in that: this embodiment 2 provides an antistatic plush fabric, which includes viscose, hindered amine light stabilizer 3 times the weight ratio of the light-fast dye, penetrating wetting agent selected from the mixture of turkey red oil and nekal, leveling agent using the mixture of higher fatty alcohol sodium sulfate and quaternary ammonium salt surfactant.
The application respectively tests the antistatic and dyeing lasting effects of the antistatic and dyeing wool fabric in the embodiment 1 and the embodiment 2, wherein the antistatic test method of the antistatic wool fabric is respectively based on the determination of electrostatic voltage half-life period of the electrostatic performance of the FZ/T01042-1996 textile material, and the electrostatic test method of the GB/T12703-1991 textile, a fabric friction type electrostatic tester is adopted as a test instrument, wherein the dyeing effect of the antistatic wool fabric is that the dyeing effect is achieved by 2000 wiping times, and no color difference is observed by naked eyes;
in the application, the tests of the example 1 and the example 2 after 10 times of water washing are respectively carried out, and no obvious antistatic performance and color surface color difference are found.
Therefore, the tests prove that the antistatic plush fabric provided by the embodiment has lasting antistatic and dyeing effects.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (5)

1. The antistatic plush fabric is characterized in that an antistatic agent, a penetration wetting agent, a dispersing agent and a leveling agent are added into a dyeing solution, wherein the dye in the dyeing solution adopts a sun-proof dye, the antistatic agent adopts a light stabilizer compatible and compounded with the sun-proof dye, the dye and the antistatic agent are attached and coated on the surface of the cotton fiber or the viscose fiber continuously and uniformly by a dyeing process to obtain antistatic dyed plush fiber, and the antistatic dyed plush fiber is prepared by a textile process.
2. The antistatic plush fabric as claimed in claim 1, wherein the light stabilizer is a hindered amine light stabilizer, the penetrating wetting agent is one or a mixture of several selected from Turkey red oil, nekal and wax powder, the dispersing agent is an anionic surfactant, and the leveling agent is a mixture of a hydrophilic fiber leveling agent and a dye leveling agent.
3. The antistatic plush fabric as claimed in claim 1, wherein the weight ratio of the light stabilizer to the light-fast dye is 1:1-1: 3.
4. The antistatic plush fabric as claimed in claim 2, wherein the dispersant is naphthalene formaldehyde sulfonic acid dispersant, the hydrophilic dye leveling agent is alkyl sodium sulfonate or higher fatty alcohol sodium sulfate, and the hydrophilic dye leveling agent is quaternary ammonium salt surfactant.
5. The antistatic plush fabric as claimed in claim 1, wherein the dyeing process comprises the following steps:
s1), adding water serving as a solvent into a dye vat, and keeping the temperature of the water in the dye vat at 40-60 ℃;
s2), adding the sun-proof dye into a dye vat, and stirring at a constant speed;
s3), sequentially adding an antistatic agent, a penetrating wetting agent, a dispersing agent and a leveling agent under a uniform-speed stirring state;
s4), after the stirring time at least reaches 1 hour, adding the cotton fiber or viscose fiber to be dyed into a dye vat, and uniformly stirring the cotton fiber or viscose fiber to obtain the antistatic dyed wool fiber;
s5), drying the antistatic dyed pile fiber.
CN201911033783.2A 2019-10-29 2019-10-29 Antistatic plush fabric Pending CN110714345A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115198431A (en) * 2022-07-14 2022-10-18 苏州聚科纺织科技有限公司 Double-sided integrated fluff fabric and manufacturing process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1265129A (en) * 1997-07-25 2000-08-30 巴斯福股份公司 Reactive dyes containing piperazine
CN101864188A (en) * 2009-04-17 2010-10-20 上海汇友精密化学品有限公司 Sunproof water-soluble dye, method for preparing same and application thereof
CN108912735A (en) * 2018-07-19 2018-11-30 浙江理工大学上虞工业技术研究院有限公司 Red sun-proof K-type reactive dye and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1265129A (en) * 1997-07-25 2000-08-30 巴斯福股份公司 Reactive dyes containing piperazine
CN101864188A (en) * 2009-04-17 2010-10-20 上海汇友精密化学品有限公司 Sunproof water-soluble dye, method for preparing same and application thereof
CN108912735A (en) * 2018-07-19 2018-11-30 浙江理工大学上虞工业技术研究院有限公司 Red sun-proof K-type reactive dye and preparation method thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
章俊玲: "涤纶高效光稳定剂的制备及其耐晒性能的研究", 《印染》 *
苏丹: "光稳定剂结构与棉上分散红TR-16耐光牢度的关系", 《纺织学报》 *
范佩琳: "光稳定剂对涤纶超细纤维织物耐光色牢度的影响", 《浙江理工大学学报(自然科学版)》 *
贾成通: "紫外线吸收剂/分散染料同浴上染涤纶的性能", 《浙江理工大学学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115198431A (en) * 2022-07-14 2022-10-18 苏州聚科纺织科技有限公司 Double-sided integrated fluff fabric and manufacturing process thereof

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