CN110697849A - Wastewater treatment active carbon adsorption tower - Google Patents

Wastewater treatment active carbon adsorption tower Download PDF

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Publication number
CN110697849A
CN110697849A CN201911022114.5A CN201911022114A CN110697849A CN 110697849 A CN110697849 A CN 110697849A CN 201911022114 A CN201911022114 A CN 201911022114A CN 110697849 A CN110697849 A CN 110697849A
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CN
China
Prior art keywords
adsorption tower
active carbon
electrolytic
fixedly connected
activated carbon
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Withdrawn
Application number
CN201911022114.5A
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Chinese (zh)
Inventor
吕玲
张日龙
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Guangzhou Grandwell Technology Service Co Ltd
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Guangzhou Grandwell Technology Service Co Ltd
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Priority to CN201911022114.5A priority Critical patent/CN110697849A/en
Publication of CN110697849A publication Critical patent/CN110697849A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4691Capacitive deionisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
  • Water Treatment By Sorption (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an activated carbon adsorption tower for wastewater treatment, which comprises an electrolytic adsorption tower, wherein the left side and the right side of the electrolytic adsorption tower are fixedly connected with liquid medicine storage boxes, the top ends of two groups of liquid medicine storage boxes are respectively provided with a liquid medicine inlet slotted hole, a sealing cover is arranged on the slotted hole of the liquid medicine inlet slotted hole, the left side and the right side above the outer wall of the electrolytic adsorption tower are provided with a feeding hole, an activated carbon adsorption component is arranged below the outer wall of the electrolytic adsorption tower, and the outer walls of the left side and the right side of the activated carbon adsorption component are respectively fixedly connected with a supporting rod. In the invention, the waste liquid enters the electrolytic bath at the uppermost layer, then the spot welding piece is opened, the spot welding piece operates, and the cathode and anode are controlled simultaneously, the cathode and anode realize the electrolysis of the waste water, electrolyze organic matters in the waste water, and expose the waste water in the next time through the exposure groove arranged in the electrolytic bath, so that the organic matters in the waste water are secondarily treated.

Description

Wastewater treatment active carbon adsorption tower
Technical Field
The invention belongs to the technical field of wastewater, and particularly relates to an activated carbon adsorption tower for wastewater treatment.
Background
The activated carbon adsorption tower is equipment for treating gas and liquid, waste water or impurities in the waste water are treated by adsorption, the traditional activated carbon is usually placed in a box body and washed by the waste water to adsorb the impurities in the waste water, but the activated carbon is washed out of an activated carbon adsorption plate by continuous washing, so that the cost is also increased;
the above brief description of the problem that the activated carbon is easy to cause when in use is provided, and further, in the actual operation, how to ensure that the activated carbon plays the role to the maximum when in use, so that the activated carbon is prevented from being washed away, and whether the activated carbon can be recycled or not is the problem that manufacturers know and consider most, and further, the cost is reduced.
Disclosure of Invention
The invention aims to: in order to solve the problems, the active carbon adsorption tower for wastewater treatment is provided.
The technical scheme adopted by the invention is as follows:
a wastewater treatment activated carbon adsorption tower comprises an electrolytic adsorption tower, wherein the left side and the right side of the electrolytic adsorption tower are fixedly connected with liquid medicine storage boxes, the top ends of two groups of liquid medicine storage boxes are respectively provided with a liquid medicine inlet slotted hole, a sealing cover is arranged on the slotted hole of the liquid medicine inlet slotted hole, the left side and the right side above the outer wall of the electrolytic adsorption tower are respectively provided with a feed inlet, an activated carbon adsorption member is arranged below the outer wall of the electrolytic adsorption tower, and the outer walls of the left side and the right side of the activated carbon adsorption member are respectively fixedly connected with a support rod;
the bottom fixedly connected with deckle board of bracing piece, horizontal board fixedly connected with supporting leg about the deckle board, it is two sets of all fix through the supporting leg between the deckle board, the outer limit fixedly connected with rail in top of electrolysis adsorption tower, fixedly connected with cat ladder on the frame of rail.
The electrolytic adsorption tower is characterized in that a concave groove is formed in the wall of an inner cavity of the electrolytic adsorption tower, an electrolytic tank is installed at the notch of the concave groove, an open groove is formed in the front face of the electrolytic tank, and a through hole is formed in the notch of the open groove.
The liquid inlet pipe is fixedly connected between the concave groove and the electrolytic bath, a sealing element is arranged on the outer side of the concave groove, and an input port of the sealing element is connected with an output port of the liquid medicine storage box.
The electrolytic bath is arranged between the two groups of liquid inlet pipes, the left end and the right end of the outer wall of the electrolytic bath are respectively connected with a liquid level detector and a cathode electrode, a line body is electrically connected between the two groups of cathode electrodes, the input end of the line body is electrically connected with an electric energy accumulator, the number of the electric energy accumulators is three, wires are electrically connected between the three groups of the electric energy accumulators, and spot welding pieces are arranged on the front surface of the electric energy accumulator and used for connecting the line body.
Wherein, the board is placed to the horizontal face fixedly connected with active carbon of inner chamber of active carbon adsorption component, four groups fixedly connected with opening plate between the board is placed to the active carbon, the below of opening plate is provided with the lining layer board, the leakage fluid dram is installed to the bottom of active carbon adsorption component, the inner chamber left side of opening plate with the outer wall intercommunication that the board was placed to the active carbon, the active carbon is placed the outer wall top of board and has been seted up to the perforation, the active carbon is placed the bottom of board and has been seted up the pore, the active carbon is placed the inner chamber of board and leans on lower position to install the active carbon layer, fixedly connected with siphunculus on the outer wall on the active carbon layer, the output fixedly connected with low liquid box of siphunculus, low liquid box height is less than the height that the board.
And an exposure groove is arranged in an inner groove of the electrolytic bath, is positioned between the two groups of the cathode and the anode and is electrically connected with an electric energy accumulator.
In summary, due to the adoption of the technical scheme, the invention has the beneficial effects that:
1. in the invention, the waste liquid enters the uppermost electrolytic tank, then the electric energy accumulator is opened to operate and control the cathode and the anode simultaneously, the cathode and the anode realize the electrolysis of the waste water, electrolyze organic matters in the waste water, and expose the waste water through the exposure tank arranged in the electrolytic tank, so as to carry out secondary treatment on the organic matters in the waste water.
2. According to the invention, the waste liquid enters the low liquid box, and the low liquid box is connected with the liquid outlet, so that the two rows of discharge of the liquid in the low liquid box are realized, the discharge of the activated carbon in the waste water treatment process is also avoided, when the electrolyzed waste water is discharged for a certain amount, the liquid can be discharged from the fine holes due to the air pressure, namely the position lower than the counter-pressure holes, and the liquid cannot be discharged due to the small designed fine holes when the activated carbon enters the fine holes.
3. In the invention, the liquid medicine enters the sealing element and enters the notch of the electrolytic tank again through the liquid inlet pipe, and the discharge plate arranged between the four groups of electrolytic tanks is used for discharging the waste water into the next group of electrolytic tank for carrying out electrolysis again.
Drawings
FIG. 1 is a schematic diagram of the structure of the present invention;
FIG. 2 is a view showing the internal structure of an electrolytic adsorption tower in the present invention;
FIG. 3 is a view showing the internal structure of an electrolytic cell in the present invention;
FIG. 4 is a top view of an activated carbon adsorption element according to the present invention;
FIG. 5 is a view showing the construction of the activated carbon placing plate and the components of the present invention.
The labels in the figure are: 1. an electrolytic adsorption tower; 2. entering the slot hole; 3. climbing a ladder; 4. a feed inlet; 5. a fence; 6. a liquid medicine storage box; 7. a sealing cover; 8. a support bar; 9. supporting legs; 10. an open slot; 11. perforating; 12. a recessed groove; 13. an electrolytic cell; 14. an activated carbon adsorption member; 15. a wire; 16. an electrical energy reservoir; 17. a liquid inlet pipe; 18. a seal member; 19. a liquid level detector; 20. a cathode and an anode; 21. a wire body; 22. an exposure groove; 23. spot welding parts; 24. an opening plate; 25. an activated carbon placing plate; 26. a lining support plate; 27. a liquid discharge port; 28. a frame plate; 29. a low liquid box; 30. pipe passing; 31. an activated carbon layer; 32. fine pores; 33 pairs of through-holes.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in further detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc., indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience of description and simplicity of description, but do not indicate or imply that the device or element being referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus, should not be construed as limiting the present invention; the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance; furthermore, unless expressly stated or limited otherwise, the terms "mounted," "connected," and "connected" are to be construed broadly, as they may be fixedly connected, detachably connected, or integrally connected, for example; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Referring to fig. 1-5, an activated carbon adsorption tower for wastewater treatment comprises an electrolytic adsorption tower 1, wherein the left side and the right side of the electrolytic adsorption tower 1 are fixedly connected with liquid medicine storage boxes 6, the top ends of two groups of liquid medicine storage boxes 6 are respectively provided with a liquid medicine inlet slotted hole 2, a sealing cover 7 is arranged on the slotted hole of the liquid medicine inlet slotted hole 2, feed inlets 4 are arranged on the left side and the right side above the outer wall of the electrolytic adsorption tower 1, the inner cavity wall of the electrolytic adsorption tower 1 is provided with a concave groove 12, a liquid inlet pipe 17 is fixedly connected between the concave groove 12 and an electrolytic tank 13, the electrolytic tank 13 is arranged between the two groups of liquid inlet pipes 17, the left end and the right end of the outer wall of the electrolytic tank 13 are respectively connected with a liquid level detector 19 and a positive electrode and a negative electrode 20, a wire 21 is arranged between the two groups of positive electrode and negative electrode 20, the input end of, the front of the electric energy accumulator 16 is provided with a spot welding part 23 for connecting a line body 21, the outer side of the concave groove 12 is provided with a sealing part 18, the input port of the sealing part 18 is connected with the output port of the liquid medicine storage box 6, the notch of the concave groove 12 is provided with an electrolytic tank 13, the front of the electrolytic tank 13 is provided with an open groove 10, an inner groove of the electrolytic tank 13 is provided with an exposure groove 22, the exposure groove 22 is positioned between two groups of negative and positive electrodes 20, 19 is electrically connected with the electric energy accumulator 23, the notch of the open groove 10 is provided with a pair of through holes 11, an activated carbon adsorption component 14 is arranged below the outer wall of the electrolytic adsorption tower 1, the outer walls at the left side and the right side of the activated carbon adsorption component 14 are both fixedly connected with supporting rods 8, the transverse surface of the inner cavity of the activated carbon adsorption component 14 is fixedly connected with an activated carbon placing plate 25, opening plates, drain opening 27 is installed to the bottom of active carbon adsorption component 14, the outer wall intercommunication of board 25 is placed with the active carbon to the inner chamber left side of opening plate 24, the active carbon is placed the outer wall top of board 25 and has been seted up to the perforation 33, the active carbon is placed the bottom of board 25 and has been seted up pore 32, the active carbon is placed the inner chamber of board 25 and is leaned on lower position and install active carbon layer 31, fixedly connected with siphunculus 30 on the outer wall of active carbon layer 31, the output fixedly connected with low liquid box 29 of siphunculus 30, low liquid box 29 highly is less than the height that board 25 was placed to the active carbon, the bottom fixedly connected with deckle board 28 of bracing piece 8, transverse plate fixedly connected with supporting leg 9 about deckle board 28, all fix through supporting leg 9 between two sets of deckle board 28, the outer marginal fixedly connected with rail 5 in top of.
The working principle is as follows: liquid enters the electrolytic adsorption tower 1 from the feed inlet 4, enters the inner cavity of the electrolytic adsorption tower 1, enters the open slot 10 formed in the front of the uppermost layer of electrolytic tank 13, removes impurities from the wastewater, separates the impurities on the plate surface of the electrolytic tank 13, then enters the uppermost layer of electrolytic tank 13, then opens the electric energy accumulator 23, the electric energy accumulator 23 operates, and simultaneously controls the cathode and anode electrodes 20, the cathode and anode electrodes 20 electrolyze the wastewater, electrolyze organic matters therein, and expose the organic matters in the wastewater through the exposure slot 22 arranged in the electrolytic tank 13, and perform secondary treatment on the organic matters in the wastewater;
the medicine is added from the position where the medicine liquid at the top end of the medicine liquid storage box 6 enters the slot hole 2 to treat the putrefactive odor in the wastewater, the medicine liquid enters the sealing element 18 and enters the slot of the electrolytic tank 13 again through the liquid inlet pipe 17, and the discharge plate arranged between the four groups of electrolytic tanks 13 is used for discharging the wastewater into the next group of electrolytic tank 13 to carry out electrolysis again;
the liquid enters the inner cavity of the activated carbon adsorption component 14 and is finally stored on the upper surface of the opening plate 24, because the opening plate 24 is communicated with the activated carbon placing plate 25, the wastewater entering the opening plate 24 and being electrolyzed is finally stored in the activated carbon placing plate 25, when the loaded wastewater of the activated carbon adsorption component 14 is leveled with the inner cavity of the activated carbon adsorption component 14, the wastewater in the activated carbon layer 31 enters the inside of the activated carbon placing plate 25, will enter the through pipe 30 to be displaced and enter the low liquid box 29, because the low liquid box 29 is connected with the liquid discharge port 27, the liquid in the low liquid box 29 can be largely discharged in two rows, the activated carbon in the wastewater treatment process is also prevented from being discharged, when the electrolyzed wastewater is discharged in a certain amount, the liquid can be discharged from the fine holes 32 due to the air pressure, namely, which is lower than the position of the counter-pressure holes 33, and the activated carbon at the moment enters the fine holes 32, the pores 32 are designed to be small, and thus cannot be discharged.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions and improvements made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (6)

1. The utility model provides a waste water treatment active carbon adsorption tower, includes electrolytic adsorption tower (1), its characterized in that: the electrolytic adsorption tower is characterized in that liquid medicine storage boxes (6) are fixedly connected to the left side and the right side of the electrolytic adsorption tower (1), liquid medicine entering slotted holes (2) are installed at the top ends of the two groups of liquid medicine storage boxes (6), sealing covers (7) are installed on the slotted holes where the liquid medicine enters the slotted holes (2), feed inlets (4) are installed on the left side and the right side above the outer wall of the electrolytic adsorption tower (1), an activated carbon adsorption component (14) is installed below the outer wall of the electrolytic adsorption tower (1), and support rods (8) are fixedly connected to the outer walls of the left side and the right side of the activated carbon adsorption component (14;
the bottom fixedly connected with deckle board (28) of bracing piece (8), horizontal board fixedly connected with supporting leg (9) about deckle board (28), it is two sets of all fix through supporting leg (9) between deckle board (28), the top outward flange fixedly connected with rail (5) of electrolysis adsorption tower (1), fixedly connected with cat ladder (3) on the frame of rail (5).
2. The wastewater treatment activated carbon adsorption tower of claim 1, wherein: seted up on the inner chamber wall of electrolysis adsorption tower (1) recessed groove (12), electrolysis trough (13) are installed to the notch department of recessed groove (12), open slot (10) have been seted up on the front of electrolysis trough (13), the notch of open slot (10) has been seted up to perforation (11).
3. The wastewater treatment activated carbon adsorption tower of claim 2, wherein: the recessed groove (12) with fixedly connected with feed liquor pipe (17) between electrolysis trough (13), the outside of recessed groove (12) is provided with sealing member (18), the input port of sealing member (18) with the delivery outlet of liquid medicine deposit box (6) is connected.
4. The wastewater treatment activated carbon adsorption tower of claim 2, wherein: the electrolytic tank (13) is arranged between the two groups of liquid inlet pipes (17), the left end and the right end of the outer wall of the electrolytic tank (13) are respectively connected with a liquid level detector (19) and a cathode electrode (20), a wire body (21) is electrically connected between the two groups of cathode electrodes (20), the input end of the wire body (21) is electrically connected with an electric energy accumulator (16), the number of the electric energy accumulators (16) is three, the three groups of the electric energy accumulators (16) are electrically connected with a lead (15), and spot welding pieces (23) are arranged on the front surface of the electric energy accumulator (16) and used for connecting the wire body (21).
5. The wastewater treatment activated carbon adsorption tower of claim 1, wherein: the active carbon placing plate comprises an inner cavity transverse face fixedly connected with an active carbon placing plate (25) of an active carbon adsorbing component (14), four groups of active carbon placing plates (25) and an opening plate (24) fixedly connected with the active carbon placing plate, a lining supporting plate (26) is arranged below the opening plate (24), a liquid outlet (27) is installed at the bottom end of the active carbon adsorbing component (14), the left side of the inner cavity of the opening plate (24) is communicated with the outer wall of the active carbon placing plate (25), a penetrating and pressing hole (33) is formed above the outer wall of the active carbon placing plate (25), a pore (32) is formed in the bottom of the active carbon placing plate (25), an active carbon layer (31) is installed at the lower part of the inner cavity of the active carbon placing plate (25), a through pipe (30) is fixedly connected with a through pipe (30) on the outer wall of the active carbon layer (31), and a low liquid box (29) is fixedly, the height of the low liquid box (29) is lower than that of the active carbon placing plate (25).
6. The wastewater treatment activated carbon adsorption tower of claim 1, wherein: an exposure groove (22) is arranged in an inner groove of the electrolytic tank (13), the exposure groove (22) is positioned between the two groups of the cathode and the anode (20), and the cathode (19) is electrically connected with an electric energy accumulator (23).
CN201911022114.5A 2019-10-24 2019-10-24 Wastewater treatment active carbon adsorption tower Withdrawn CN110697849A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911022114.5A CN110697849A (en) 2019-10-24 2019-10-24 Wastewater treatment active carbon adsorption tower

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Application Number Priority Date Filing Date Title
CN201911022114.5A CN110697849A (en) 2019-10-24 2019-10-24 Wastewater treatment active carbon adsorption tower

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101711941A (en) * 2008-09-30 2010-05-26 三星电子株式会社 Deionization apparatus and electrode module using thereof, and manufacturing method the same
KR20130128508A (en) * 2012-05-17 2013-11-27 (주)케이알피 Gold recovering apparatus using electrolysis and resin adsorption for continuous flow
CN104724798A (en) * 2013-12-19 2015-06-24 财团法人工业技术研究院 Composite material, electrode, device with electrode and electrochemical phosphorus removal method
CN205925344U (en) * 2016-08-26 2017-02-08 南通润弘环保设备工程有限公司 Long service life's active carbon absorption tower
CN206680328U (en) * 2017-03-28 2017-11-28 江西师范大学 A kind of efficient chemical water treatment facilities
CN206828296U (en) * 2017-06-14 2018-01-02 天津市嘉腾环保设备股份有限公司 A kind of degrading industrial waste water groove
CN107721036A (en) * 2017-11-20 2018-02-23 梁长棠 A kind of chemical industry wastewater electrolytic processing unit
CN207659263U (en) * 2017-10-12 2018-07-27 宋佳临 A kind of industrial sewage processing unit
CN208182760U (en) * 2018-01-16 2018-12-04 虹华环保科技(天津)有限公司 A kind of heavy metal wastewater treatment apparatus
CN208700646U (en) * 2018-06-07 2019-04-05 江苏理工学院 A kind of photocatalysis three-dimensional electrolysis fluidized-bed reactor

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101711941A (en) * 2008-09-30 2010-05-26 三星电子株式会社 Deionization apparatus and electrode module using thereof, and manufacturing method the same
KR20130128508A (en) * 2012-05-17 2013-11-27 (주)케이알피 Gold recovering apparatus using electrolysis and resin adsorption for continuous flow
CN104724798A (en) * 2013-12-19 2015-06-24 财团法人工业技术研究院 Composite material, electrode, device with electrode and electrochemical phosphorus removal method
CN205925344U (en) * 2016-08-26 2017-02-08 南通润弘环保设备工程有限公司 Long service life's active carbon absorption tower
CN206680328U (en) * 2017-03-28 2017-11-28 江西师范大学 A kind of efficient chemical water treatment facilities
CN206828296U (en) * 2017-06-14 2018-01-02 天津市嘉腾环保设备股份有限公司 A kind of degrading industrial waste water groove
CN207659263U (en) * 2017-10-12 2018-07-27 宋佳临 A kind of industrial sewage processing unit
CN107721036A (en) * 2017-11-20 2018-02-23 梁长棠 A kind of chemical industry wastewater electrolytic processing unit
CN208182760U (en) * 2018-01-16 2018-12-04 虹华环保科技(天津)有限公司 A kind of heavy metal wastewater treatment apparatus
CN208700646U (en) * 2018-06-07 2019-04-05 江苏理工学院 A kind of photocatalysis three-dimensional electrolysis fluidized-bed reactor

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