CN110684377A - Pellet filling material for wooden new year picture and preparation method thereof - Google Patents

Pellet filling material for wooden new year picture and preparation method thereof Download PDF

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Publication number
CN110684377A
CN110684377A CN201910862518.9A CN201910862518A CN110684377A CN 110684377 A CN110684377 A CN 110684377A CN 201910862518 A CN201910862518 A CN 201910862518A CN 110684377 A CN110684377 A CN 110684377A
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CN
China
Prior art keywords
component
new year
pellet
yttrium nitrate
oxide
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Pending
Application number
CN201910862518.9A
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Chinese (zh)
Inventor
居华倩
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Foshan Polytechnic
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Foshan Polytechnic
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Priority to CN201910862518.9A priority Critical patent/CN110684377A/en
Publication of CN110684377A publication Critical patent/CN110684377A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/62—Metallic pigments or fillers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The invention provides a red lead filling material for woodcut new year pictures and a preparation method thereof. The pellet material comprises the raw materials of neodymium carbonate, aluminum oxide, yttrium nitrate, dichromium trioxide and aluminum hydroxide. The red lead filling pellet for the wood plate new year picture comprises neodymium carbonate, yttrium nitrate, chromium oxide and aluminum oxide, is prepared into a red rare earth pellet material, and can be used for the step of filling the wood plate new year picture. The preparation method comprises the following steps: 1) mixing neodymium carbonate, aluminum oxide and a proper amount of water, and grinding into a component A; 2) mixing yttrium nitrate, chromic oxide, aluminum hydroxide and a proper amount of water, and grinding into a component B; 3) and uniformly mixing the component A, the component B and the auxiliary agent, and drying to obtain the finished product of the lead filling material for the woodedition new year pictures. Because the raw materials use yttrium nitrate with strong acid groups, the component A and the component B can form NdAlO in the preparation process3And yttrium, chromium,The aluminum codoped molecular structure ensures that the lead material can be durable and does not fade under the environment of long-term sunshine all year round.

Description

Pellet filling material for wooden new year picture and preparation method thereof
Technical Field
The invention relates to the technical field of pigment compositions, in particular to a pellet filling material for woodcut new year pictures and a method for preparing the pellet filling material.
Background
The Buddha mountain wood-version new year picture is a famous folk new year picture in south China and is a wonderful flower of traditional folk culture in south China. The Chinese character 'Tianjin Yanliuqing', Suzhou peach blossom depressed place 'and Shandong Huai Fang' are the same name of the new year pictures, and are the national non-material cultural heritage at present. The "fill-in pellet" is the last process of Buddha mountain print, and the red pellet unique to Buddha mountain is used to dye the periphery of the new year print red. (Note that the Paodan is drawn around the New year painting as a background color, and the pigment of the middle character is not). The red filling is not only red but not rough, and can not fade for a long time in the environment with long sunshine time in the south, so the red filling is named as 'permanent red'. The red filling has bright and striking color and even color blocks, and even if the paper is impregnated by the pigment, the surface of the paper is not concave-convex and the paper is not printed by a water-jet printing pen. The lead used for the "red lead filling" is also called the "Vermilion", i.e. Vermilion. Mercury sulfide is commonly known as mercury sulfide. Is the earliest bright red pigment and is used for oil paintings, inkpads, vermilion painting and lacquer carving devices and the like. The quality of Vermilion produced by the former Foshan is the best, the price is the most expensive, commodities are sold in domestic and foreign ports, and the' large-area red-lead used annual drawing production field mainly comprises Guangdong Foshan and Fujian Zhangzhou, both fields are in subtropical warm and humid climate, and the characteristics of red-lead sun protection and moisture resistance are the common preference of both fields, and the red-lead used annual drawing production field also becomes the characteristic of the two-field annual drawing. "
However, the process technology for manufacturing the Vercirrus by the ancient method is a secret technology with higher technical content, which is handed over by fathers and sons in the past and is not publicized for the secret. The basic manufacturing process recorded from historical data only needs rough description and manual allocation depending on experience, is difficult to recover, and is not beneficial to industrial mass production. The traditional Vermilion is prepared by putting mercury (mercury) and sulfur as main raw materials in a big iron pan in proportion, burning with big fire, and sublimating. Mercury is highly toxic and volatile, and has a great health hazard to manufacturers.
Disclosure of Invention
Aiming at the problems that the traditional lead preparation process is difficult to recover in the prior art and the problems that the traditional lead preparation process is complex and the raw materials are high in toxicity are shown by the existing mastered data, the disclosure aims to provide the lead filling material for the wood-plate new year pictures, the lead filling material is pure in color development and good in weather resistance, the raw materials of the lead filling material do not contain toxic components, the lead filling material is green and environment-friendly, the raw materials are easy to obtain, the preparation process is simple, and the industrialization is easy.
A pellet for filling wooden new year picture is prepared from neodymium carbonate, aluminum oxide, yttrium nitrate, chromic oxide, and aluminum hydroxide.
The neodymium carbonate and the aluminum oxide are used as a component A, the yttrium nitrate, the chromium oxide and the aluminum hydroxide are used as a component B, and the mass ratio of the component A to the component B is (0.177-14.524).
Further, the mass ratio of neodymium carbonate to aluminum oxide in the component A is (4.5-4.6): 1. The weight ratio of yttrium nitrate, chromic oxide and aluminum hydroxide in the component B is 1 (0.185-0.202) to 0.002-0.016.
Further, the raw material also comprises an auxiliary agent, wherein the auxiliary agent comprises but is not limited to an anticorrosive agent, a surfactant, a binder and a dispersing agent; preferably, the preservative is selected from a benzomicazole ester preservative or a chlorosulfonated polyethylene preservative; preferably, the surfactant is an anionic cellulose ether surfactant; preferably, the adhesive is an epoxy adhesive; the dispersant is a non-ionic wetting dispersant.
Another aspect of the invention aims to provide a method for preparing a red lead filling material for woodcut new year pictures, which comprises the following steps:
1) mixing neodymium carbonate, aluminum oxide and a proper amount of water, and grinding into a component A;
2) mixing yttrium nitrate, chromic oxide, aluminum hydroxide and a proper amount of water, and grinding into a component B;
3) and uniformly mixing the component A, the component B and the auxiliary agent, and drying to obtain the finished product of the lead filling material for the woodedition new year pictures.
Preferably, the step 3 is carried out by stirring and mixing at a rotating speed of 3000 r/min. The drying mode is selected from vacuum drying or freeze drying.
The red lead filling pellet for the wood plate new year picture comprises neodymium carbonate, yttrium nitrate, chromium oxide and aluminum oxide, is prepared into a red rare earth pellet material, and can be used for the step of filling the wood plate new year picture. Because the raw materials use yttrium nitrate with strong acid groups, the component A and the component B can form NdAlO in the preparation process3And the molecular structure co-doped with yttrium, chromium and aluminum ensures that the lead material can be durable and not fade under the environment of long-term sunshine.
Detailed Description
The present invention will be described in further detail with reference to the following embodiments. It will be understood by those skilled in the art that the following examples are illustrative of the present invention only and should not be taken as limiting the scope of the invention. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products commercially available.
Example 1
The pellet filling material for the wooden new year pictures comprises the following preparation processes:
1) 940g of Nd2(CO3)3(Neodymium carbonate) with 205g of Al2O3(alumina) and 1.5L water were mixed and ground to component A;
2) 13.79kg of Y (NO)3)3·6H2O (yttrium nitrate) and 0.072g of Cr2O3(chromium oxide), 2.78kg of Al (OH)3(aluminum hydroxide) and 30L of water were mixed and ground into component B;
3) and (2) mixing the component A prepared in the step (1), the component B prepared in the step (2), 1.77kg of chlorosulfonated polyethylene, 900g of carboxymethyl cellulose and 1.8kg of polyethylene glycol, mixing at the rotating speed of 3000r/min for at least 25 minutes, and then carrying out vacuum drying to obtain the finished product of the wood plate new year picture lead filling material.
Example 2
The pellet filling material for the wooden new year pictures comprises the following preparation processes:
1) 9.37kg of Nd2(CO3)3(Neodymium carbonate) with 2.04kg of Al2O3(alumina) and 15L of water were mixed and ground to component A;
2) 1.7kg of Y (NO)3)3·6H2O (yttrium nitrate) 0.071g Cr2O3(chromium oxide), 319g of Al (OH)3(aluminum hydroxide) and 4L of water were mixed and ground to component B;
3) mixing the component A prepared in the step 1, the component B prepared in the step 2, 1.34kg of methyl-1H-2-benzimidazole carbamate, 700g of carboxymethyl cellulose and 1.4kg of WinSperse 4080A (purchased from Weipersian New Material (Weifang) Co., Ltd.), mixing at the rotating speed of 3000r/min for at least 20 minutes, and then carrying out vacuum drying to obtain the finished product of the wooden new year picture red filling material.
The prepared pellet is respectively coated on special paper for woodblock new year pictures, and continuously irradiated by a 200W incandescent lamp at a distance of 1m under the environment of ventilation and relative humidity of more than 85%. In the examples 1 and 2, no discoloration, yellowing or peeling phenomenon is generated after 3 ten thousand hours of continuous irradiation.
The above description is intended to describe in detail the preferred embodiments of the present invention, but the embodiments are not intended to limit the scope of the claims of the present invention, and all equivalent changes and modifications made within the technical spirit of the present invention should fall within the scope of the claims of the present invention.

Claims (8)

1. The lead filling pellet material for the woodcut new year picture is characterized by comprising neodymium carbonate, aluminum oxide, yttrium nitrate, chromium oxide and aluminum hydroxide.
2. The pellet filling material for the woodcut new year pictures according to claim 1, wherein neodymium carbonate and aluminum oxide are used as a component A, yttrium nitrate, chromic oxide and aluminum hydroxide are used as a component B, and the mass ratio of the component A to the component B is 1 (0.177-14.524).
3. The pellet filling material for woodcut new year pictures as claimed in claim 2, wherein the mass ratio of neodymium carbonate to aluminum oxide in the component A is (4.5-4.6): 1.
4. The pellet as claimed in claim 2, wherein the weight ratio of yttrium nitrate, chromic oxide and aluminum hydroxide in component B is 1 (0.185-0.202) to 0.002-0.016.
5. The pellet for filling wooden new year pictures as claimed in any one of claims 1 to 4, wherein the raw material further comprises an auxiliary agent, and the auxiliary agent comprises but is not limited to an anticorrosive agent, a surfactant, a binder and a dispersing agent; preferably, the preservative is selected from a benzomicazole ester preservative or a chlorosulfonated polyethylene preservative; preferably, the surfactant is an anionic cellulose ether surfactant; preferably, the adhesive is an epoxy adhesive; the dispersant is a non-ionic wetting dispersant.
6. The preparation method of the red lead filling material for the wooden new year pictures is characterized by comprising the following steps of:
1) mixing neodymium carbonate, aluminum oxide and a proper amount of water, and grinding into a component A;
2) mixing yttrium nitrate, chromic oxide, aluminum hydroxide and a proper amount of water, and grinding into a component B;
3) and uniformly mixing the component A, the component B and the auxiliary agent, and drying to obtain the finished product of the lead filling material for the woodedition new year pictures.
7. The method according to claim 6, wherein the step 3 is carried out by stirring and mixing at a rotation speed of 3000 r/min.
8. The method according to claim 6, wherein the drying in step 3 is selected from vacuum drying and freeze drying.
CN201910862518.9A 2019-09-12 2019-09-12 Pellet filling material for wooden new year picture and preparation method thereof Pending CN110684377A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910862518.9A CN110684377A (en) 2019-09-12 2019-09-12 Pellet filling material for wooden new year picture and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910862518.9A CN110684377A (en) 2019-09-12 2019-09-12 Pellet filling material for wooden new year picture and preparation method thereof

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CN110684377A true CN110684377A (en) 2020-01-14

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0815055A1 (en) * 1995-03-13 1998-01-07 Colorobbia Italia S.p.a. Yttrium and/or rare earths aluminates having perovskite structure, preparation thereof and use as pigments
CN106187317A (en) * 2016-07-05 2016-12-07 佛山欧神诺陶瓷股份有限公司 A kind of high-temperature red rare-earth ceramic colorant and preparation method thereof
CN108359271A (en) * 2018-02-23 2018-08-03 中国科学院包头稀土研发中心 A kind of high temperature resistant purple rare-earth ceramic colorant and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0815055A1 (en) * 1995-03-13 1998-01-07 Colorobbia Italia S.p.a. Yttrium and/or rare earths aluminates having perovskite structure, preparation thereof and use as pigments
CN106187317A (en) * 2016-07-05 2016-12-07 佛山欧神诺陶瓷股份有限公司 A kind of high-temperature red rare-earth ceramic colorant and preparation method thereof
CN108359271A (en) * 2018-02-23 2018-08-03 中国科学院包头稀土研发中心 A kind of high temperature resistant purple rare-earth ceramic colorant and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
况金华: "《陶瓷生产工艺技术》", 31 May 2013, 武汉理工大学出版社 *
朱洪法: "《无机化工产品手册》", 31 December 2008, 金盾出版社 *
马世昌: "《化学物质辞典》", 30 April 1999, 山西科学技术出版社 *

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Application publication date: 20200114