CN110668846A - Preparation process of matte wear-resistant dry particle brick - Google Patents
Preparation process of matte wear-resistant dry particle brick Download PDFInfo
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- CN110668846A CN110668846A CN201910963814.8A CN201910963814A CN110668846A CN 110668846 A CN110668846 A CN 110668846A CN 201910963814 A CN201910963814 A CN 201910963814A CN 110668846 A CN110668846 A CN 110668846A
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- glaze
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- brick
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention particularly relates to a preparation process of a matte wear-resistant dry particle brick, which comprises the following steps: preparing a colored blank; preparing wear-resistant dry particles: mixing and grinding the raw materials, calcining the raw materials at high temperature to form frits, screening the frits in a granulator, and selecting dry granules with the mesh number of 60-180 meshes; preparing glaze slip: grinding the glaze until the fineness of the glaze is 0.3-0.5% of the screen residue, and putting the glaze into a glaze bin for later use; and (3) glaze line production: uniformly spraying the overglaze on the surface of the blank body through a high-pressure glaze spraying cabinet, then spraying ink on the surface of the blank body through a 3D ink jet printer to form a pattern, pumping the wear-resistant dry particles to a bell jar through a high-pressure pump, uniformly distributing the wear-resistant dry particles on the surface, enabling the blank body to pass from the bottom, and uniformly distributing the dry particles on the surface of the blank body; drying, sintering, polishing and antifouling treatment. The matte wear-resistant dry particle brick prepared by the preparation process has the advantages of high wear resistance, high hardness, super skid resistance and the like.
Description
Technical Field
The invention belongs to the technical field of building ceramics, and particularly relates to a preparation process of a matte wear-resistant dry particle brick.
Background
In the existing preparation process of ceramic tiles, in order to make the surface of the ceramic tile have a certain three-dimensional decoration effect and a certain anti-slip effect, dry particles are usually laid on the surface of a glaze layer of the ceramic tile after glazing is performed on the surface of a green tile, and finally the green tile is fired at high temperature to form a tile surface effect with a certain convex effect. However, in the preparation process of the conventional dry-particle brick, in order to ensure the stability of the brick surface structure and avoid the reduction of the three-dimensional effect of the dry particles by the glaze layer, the dry particles are distributed on the surface of the glaze layer, but the embedding effect of the dry particles is limited, so that the brick surface after being fired has the defects of poor wear resistance, poor anti-slip effect, low hardness and the like.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a preparation process of a matte wear-resistant dry particle brick, and the matte wear-resistant dry particle brick prepared by the preparation process has the advantages of high wear resistance, high hardness, super skid resistance and the like.
The technical problem to be solved by the invention is realized by the following technical scheme:
a preparation process of a matte wear-resistant dry particle brick comprises the following steps:
(1) preparing a colored blank;
(2) preparing wear-resistant dry particles: mixing and grinding the raw materials, calcining the raw materials at high temperature to form frits, screening the frits in a granulator, and selecting dry granules with the mesh number of 60-180 meshes;
(3) preparing glaze: grinding the glaze until the fineness of the glaze is 0.3-0.5% of the screen residue, and putting the glaze into a glaze bin for later use;
(4) and (3) glaze line production: uniformly spraying the overglaze on the surface of the blank body through a high-pressure glaze spraying cabinet, then spraying ink on the surface of the blank body through a 3D ink jet printer to form a pattern, pumping the wear-resistant dry particles to a bell jar through a high-pressure pump, uniformly distributing the wear-resistant dry particles on the surface, enabling the blank body to pass from the bottom, and uniformly distributing the dry particles on the surface of the blank body;
(5) drying, sintering, polishing and antifouling treatment.
Further, the raw materials in the step (2) comprise, by mass: 15-20% of potassium feldspar, 45-50% of albite, 15-20% of quartz and 15-20% of alumina.
Further, the aluminum content of the alumina is 99% or more.
Further, the calcination temperature in the step (2) is 1280-1300 ℃, and the calcination time is 2-3 hours.
Further, the overglaze in the step (4) comprises a first overglaze and a second overglaze, and the specific gravity of the first overglaze is about 1.40g/cm3About 200g of glaze is applied per brick, and the specific gravity of the second overglaze is about 1.55g/cm3The glazing amount is about 250 g/brick.
Further, before the wear-resistant dry granules in the step (4) are pumped to a bell jar by a high-pressure pump, the required dry granules are prepared from the wear-resistant dry granules by a stirring cylinder for a glaze line, the preparation is ready for use, and the stirring cylinder keeps stirring and circulating states.
Further, the preparation method of the additive color blank in the step (1) comprises the following steps: grinding according to the formula of the blank, adding water, grinding into slurry, ball-milling, grinding with ball stone inside for 14-16 h in a 60T large-scale ball mill, sieving with 250 mesh to obtain 0.2-0.3% of residue on sieve, and aging in a slurry tank for 2-3 days; spray-drying the slurry, drying and pulverizing the slurry by a spray-drying tower according to the particle size and the water content requirement of the powder, and putting the powder into a storage bin for later use; the powder is processed by a coloring roller and is prepared into required coloring powder with pigment in a color mixer according to the proportion, the required coloring powder is sent to a press for standby after patterns are formed by skip cloth, and the required patterns are pressed into exquisite patterns by the special pattern effect of a fine carving concave-convex mould.
Further, the matte wear-resistant dry-particle brick prepared by the preparation process comprises a blank body, a glaze spraying layer and a particle decorative layer which are sequentially arranged from bottom to top, wherein the particle decorative layer is formed by combining fine particles of 60-180 meshes.
Compared with the prior art, the invention has the beneficial effects that:
1. the preparation process of the matte wear-resistant dry-particle brick comprises the steps of firstly preparing a colored blank, wear-resistant dry particles and glaze, then spraying the glaze on the surface of the blank at high pressure to form a good protective layer on the brick surface, increasing the whiteness, being equivalent to the ground color, playing a role of covering the surface of the blank, then spraying ink on the surface of the blank to form a beautiful and vivid-texture pattern, then uniformly spraying the wear-resistant dry particles on the surface of the blank after glaze spraying, and then carrying out drying, sintering, polishing and antifouling treatment to obtain the matte wear-resistant dry-particle brick.
2. The matt wear-resistant dry particle brick has good color development and wide firing temperature range, can be rough and fine in hand feeling by matching different fire degrees at high, medium and low temperatures, and has wide application range and strong decorative effect; the texture and the stereoscopic impression of the particles on the surface of the matte wear-resistant dry particle brick are strong, and the particles are transparent after being fired at high temperature, so that the ink-jet color development is not influenced; meanwhile, the effects of skid resistance, wear resistance and pollution resistance are enhanced, and spherical particles are still kept after high-temperature sintering, so that the concave-convex feeling is strong.
Drawings
FIG. 1 is a schematic diagram of a manufacturing process of the matte wear-resistant dry-particle brick of the embodiment.
Detailed Description
The present invention will be described in further detail with reference to specific examples, but the embodiments of the present invention are not limited thereto.
In order to solve the problems of poor wear resistance, poor anti-skid effect and low hardness of the existing dry particle brick, the embodiment provides a preparation process of the matte wear-resistant dry particle brick.
The preparation process of the matte wear-resistant dry particle brick comprises the following steps:
(1) preparing a colored blank: and (3) loading and grinding the raw materials for preparing the blank, adding water, grinding into slurry, and carrying out ball milling to obtain the blank with the ball stones inside. Grinding for 14-16 hours by a 60T large-scale ball mill, putting the slurry into a slurry tank for ageing after the fineness of the slurry passes through 250 meshes and reaches 0.2-0.3% of screen residue, and ageing to ensure that the slurry is mixed more fully, the fineness and the components are more stable, and the slurry is generally aged for 2-3 days; the slurry is subjected to spray drying, is dried and powdered by a spray drying tower according to the particle size and the water content requirement of the material powder, and is put into a storage bin for later use; the powder is processed by a coloring roller and is prepared into required coloring powder with pigment in a color mixer according to the proportion, the required coloring powder is sent to a press for standby after patterns are formed by skip cloth, and the required patterns are pressed into exquisite patterns by the special pattern effect of a fine carving concave-convex mould.
(2) Preparing wear-resistant particles: selecting high-quality potassium feldspar, albite, quartz and alumina (whiteness is 50-60 degrees, and aluminum content is more than 99%), mixing and grinding according to a proportion. Calcining at 1280-1300 ℃ for 2-3 hours to obtain frit, and strictly screening the frit in a granulator to select dry granules with 60-180 meshes. Wherein, the potash feldspar accounts for 15 to 20 percent, the albite accounts for 45 to 50 percent, the quartz accounts for 15 to 20 percent, and the alumina accounts for 15 to 20 percent. Through a plurality of tests, the components and the mass percentage of the raw materials are shown in the table 1. The raw materials are put into a high-temperature calcining kiln, the maximum kiln temperature is about 1300 ℃, and the raw materials are taken out of the kiln for about 2 hours to form fusion cakes. The frits enter a granulator and are strictly screened by screens of 60 meshes, 100 meshes, 120 meshes, 160 meshes and 180 meshes to finally form the required dry granules.
TABLE 1
(3) Preparing glaze: grinding the overglaze by 5T ball milling to the fineness of 0.3-0.5% of the screen residue, and putting the overglaze into a glaze bin for later use; preparing dried particles, namely preparing the required dried particles by a stirring cylinder in a glaze line according to the proportion of the suspending agent, the wear-resistant dried particles and the additive, wherein the dried particles are easy to precipitate and need to be prepared and used at any time, and the stirring cylinder is in a stirring and circulating state at any time to prevent precipitation.
(4) And (3) glaze line production: the first overglaze (the specific gravity of overglaze is about 1.40 g/cm)3The glazing amount is about 200 g/brick), and the second glaze (the specific gravity is about 1.55 g/cm)3The glazing amount is about 250 g/brick), the two overglazes are uniformly sprayed on the surface of the blank body through a high-pressure glaze spraying cabinet to form a good protective layer, the whiteness is increased, the overglaze is equivalent to the ground color, and the function of covering the blank body is achieved; then, ink is sprayed to the surface of the blank by a 3D ink jet machine to form a pattern which is exquisite and vivid in texture; the well-stirred wear-resistant dry particles are pumped to a bell jar by a high-pressure pump (used for uniformly spraying the dry particles on the brick surface to ensure that the brick surface is more smooth) and are uniformly distributed on the bell jar, and the brick blank passes through the brick from the lower part, and the dry particles are uniformly distributed on the surface of the blank.
(5) Drying, sintering, polishing and antifouling treatment. The green body after being sprayed with the dry particles needs to be dried by a small drying kiln before entering a large kiln due to high moisture, and then is sintered according to a sintering curve strictly, so that the product is sensitive to the sintering curve and the sintering curve needs to be controlled strictly. The fiber module, the grinding brush and the elastic module aiming at the product are used for special polishing treatment, so that the surface is micro-polished, the natural arrangement of dry particles is not damaged, the glossiness is about 5-6 degrees, and the nano liquid is used for anti-fouling treatment, so that dirt is difficult to permeate. And finally sorting and checking.
The scheme of the preparation process of the matte wear-resistant dry particle brick in the embodiment refers to fig. 1.
Example 2:
the embodiment provides a matte wear-resistant dry particle brick which is prepared by the preparation process of the embodiment 1. The matte wear-resistant dry-particle brick comprises a blank body, a glaze spraying layer and a particle decorative layer which are sequentially arranged from bottom to top, wherein the particle decorative layer is formed by combining fine particles of 60-180 meshes. The matt wear-resistant dry particle brick has good color development and wide firing temperature range, can be rough and fine in hand feeling by matching different fire degrees at high, medium and low temperatures, and has wide application range and strong decorative effect; the texture and the stereoscopic impression of the particles on the surface of the matte wear-resistant dry particle brick are strong, and the particles are transparent after being fired at high temperature, so that the ink-jet color development is not influenced; meanwhile, the effects of skid resistance, wear resistance and pollution resistance are enhanced, and spherical particles are still kept after high-temperature sintering, so that the concave-convex feeling is strong.
The foregoing is a more detailed description of the invention in connection with specific preferred embodiments and it is not intended that the invention be limited to these specific details. For those skilled in the art to which the invention pertains, several simple deductions or substitutions can be made without departing from the spirit of the invention, and all shall be considered as belonging to the protection scope of the invention.
Claims (9)
1. A preparation process of a matte wear-resistant dry particle brick is characterized by comprising the following steps:
(1) preparing a colored blank;
(2) preparing wear-resistant dry particles: mixing and grinding the raw materials, calcining the raw materials at high temperature to form frits, screening the frits in a granulator, and selecting dry granules with the mesh number of 60-180 meshes;
(3) preparing glaze slip: grinding the glaze until the fineness of the glaze is 0.3-0.5% of the screen residue, and putting the glaze into a glaze bin for later use;
(4) and (3) glaze line production: uniformly spraying the overglaze on the surface of the blank body through a high-pressure glaze spraying cabinet, then spraying ink on the surface of the blank body through a 3D ink jet printer to form a pattern, pumping the wear-resistant dry particles to a bell jar through a high-pressure pump, uniformly distributing the wear-resistant dry particles on the surface, enabling the blank body to pass from the bottom, and uniformly distributing the dry particles on the surface of the blank body;
(5) drying, sintering, polishing and antifouling treatment.
2. The preparation process according to claim 1, wherein the raw materials in the step (2) comprise, by mass: 15-20% of potassium feldspar, 45-50% of albite, 15-20% of quartz and 15-20% of alumina.
3. The process according to claim 2, wherein the aluminum content of the alumina is 99% or more.
4. The process according to claim 1, wherein the calcination temperature in step (2) is 1280-1300 ℃, and the calcination time is 2-3 hours.
5. The process according to claim 1, wherein the overglaze in step (4) comprises a first overglaze and a second overglaze, the specific gravity of the first overglaze is about 1.40g/cm3, the glazing amount is about 200 g/brick, the specific gravity of the second overglaze is about 1.55g/cm3, and the glazing amount is about 250 g/brick.
6. The preparation process according to claim 1, wherein in the step (4), before the wear-resistant dry granules are pumped to the bell jar by the high-pressure pump, the wear-resistant dry granules are prepared into the required dried granules by a stirring cylinder on the glaze line, and the required dried granules are prepared and used at any time, and the stirring cylinder keeps a stirring and circulating state.
7. The manufacturing process according to claim 1, wherein the method for manufacturing the additive color body in the step (1) comprises the following steps: grinding according to the formula of the blank, adding water, grinding into slurry, ball-milling, grinding with ball stone inside for 14-16 h in a 60T large-scale ball mill, sieving with 250 mesh to obtain 0.2-0.3% of residue on sieve, and aging in a slurry tank for 2-3 days; spray-drying the slurry, drying and pulverizing the slurry by a spray-drying tower according to the particle size and the water content requirement of the powder, and putting the powder into a storage bin for later use; the powder is processed by a coloring roller and is prepared into required coloring powder with pigment in a color mixer according to the proportion, the required coloring powder is sent to a press for standby after patterns are formed by skip cloth, and the required patterns are pressed into exquisite patterns by the special pattern effect of a fine carving concave-convex mould.
8. A matte wear-resistant dry particle brick, which is prepared by the preparation process of any one of claims 1 to 7.
9. The matte wear-resistant dry particle brick according to claim 8, which comprises a blank body, a glaze spraying layer and a particle decorative layer which are sequentially arranged from bottom to top, wherein the particle decorative layer is formed by combining fine particles of 60-180 meshes.
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Cited By (5)
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| CN113149601A (en) * | 2021-04-13 | 2021-07-23 | 山东狮王陶瓷有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN113248144A (en) * | 2021-05-06 | 2021-08-13 | 佛山市三水宏源陶瓷企业有限公司 | Preparation method of matte and fine surface of dry grain glazed rock plate |
| CN113461443A (en) * | 2021-08-12 | 2021-10-01 | 东莞市唯美陶瓷工业园有限公司 | Ceramic plate with matte dry particle texture and preparation method thereof |
| CN113860887A (en) * | 2021-10-22 | 2021-12-31 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
| CN114735935A (en) * | 2022-03-31 | 2022-07-12 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light-level diffuse reflection ceramic rock plate and preparation method thereof |
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| CN114735935A (en) * | 2022-03-31 | 2022-07-12 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light-level diffuse reflection ceramic rock plate and preparation method thereof |
| CN114735935B (en) * | 2022-03-31 | 2023-09-22 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light diffuse reflection ceramic rock plate and preparation method thereof |
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Application publication date: 20200110 |