CN110629558A - High-efficiency protective composite board and preparation method, application and application method thereof - Google Patents
High-efficiency protective composite board and preparation method, application and application method thereof Download PDFInfo
- Publication number
- CN110629558A CN110629558A CN201810552419.6A CN201810552419A CN110629558A CN 110629558 A CN110629558 A CN 110629558A CN 201810552419 A CN201810552419 A CN 201810552419A CN 110629558 A CN110629558 A CN 110629558A
- Authority
- CN
- China
- Prior art keywords
- powder coating
- composite board
- super
- photovoltaic module
- thermosetting powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 124
- 238000000034 method Methods 0.000 title claims abstract description 89
- 230000001681 protective effect Effects 0.000 title claims description 65
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 145
- 239000011248 coating agent Substances 0.000 claims abstract description 133
- 239000000843 powder Substances 0.000 claims abstract description 130
- 239000000835 fiber Substances 0.000 claims abstract description 92
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 69
- 229920000728 polyester Polymers 0.000 claims abstract description 55
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000005022 packaging material Substances 0.000 claims abstract description 16
- 230000004224 protection Effects 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000004566 building material Substances 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims description 70
- 239000004744 fabric Substances 0.000 claims description 41
- 238000007731 hot pressing Methods 0.000 claims description 39
- 238000004806 packaging method and process Methods 0.000 claims description 37
- 238000003475 lamination Methods 0.000 claims description 30
- 229920001225 polyester resin Polymers 0.000 claims description 29
- 239000004645 polyester resin Substances 0.000 claims description 29
- 238000010438 heat treatment Methods 0.000 claims description 28
- 238000004132 cross linking Methods 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 238000010030 laminating Methods 0.000 claims description 12
- 238000013329 compounding Methods 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- 239000000155 melt Substances 0.000 claims description 6
- 239000004809 Teflon Substances 0.000 claims description 4
- 229920006362 Teflon® Polymers 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000012785 packaging film Substances 0.000 claims description 3
- 229920006280 packaging film Polymers 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 238000003860 storage Methods 0.000 abstract description 7
- 230000006750 UV protection Effects 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000009966 trimming Methods 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 13
- 239000005038 ethylene vinyl acetate Substances 0.000 description 13
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 13
- 239000002657 fibrous material Substances 0.000 description 10
- 230000009286 beneficial effect Effects 0.000 description 7
- 238000009434 installation Methods 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 229910021419 crystalline silicon Inorganic materials 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 238000005538 encapsulation Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- -1 hydroxyalkyl amide Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- BTZVDPWKGXMQFW-UHFFFAOYSA-N Pentadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCC(O)=O BTZVDPWKGXMQFW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920006124 polyolefin elastomer Polymers 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- LWBHHRRTOZQPDM-UHFFFAOYSA-N undecanedioic acid Chemical compound OC(=O)CCCCCCCCCC(O)=O LWBHHRRTOZQPDM-UHFFFAOYSA-N 0.000 description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- NEPKLUNSRVEBIX-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OCC2OC2)C=CC=1C(=O)OCC1CO1 NEPKLUNSRVEBIX-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- HHFDXDXLAINLOT-UHFFFAOYSA-N n,n'-dioctadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCCCNCCNCCCCCCCCCCCCCCCCCC HHFDXDXLAINLOT-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- YNOWBNNLZSSIHM-UHFFFAOYSA-N tris(oxiran-2-ylmethyl) benzene-1,2,4-tricarboxylate Chemical compound C=1C=C(C(=O)OCC2OC2)C(C(=O)OCC2OC2)=CC=1C(=O)OCC1CO1 YNOWBNNLZSSIHM-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0022—Glass fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
- D06N3/123—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds with polyesters
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/048—Encapsulation of modules
- H01L31/0481—Encapsulation of modules characterised by the composition of the encapsulation material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/536—Hardness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/12—Photovoltaic modules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/08—Cars
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/08—Inorganic fibres
- D06N2201/087—Carbon fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/06—Building materials
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/261—Body finishing, e.g. headliners
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The invention discloses an efficient protection composite board and a preparation method, application and application method thereof, wherein the composite board is prepared from the following raw materials in parts by weight: 80-20 parts of a binder; wherein the thermosetting powder coating is cross-linked and cured uniformly on the fibers; the thermosetting powder coating is an ultra-weather-resistant polyester powder coating; on the premise of having the inherent advantages of the thermosetting powder coating, the coating also has excellent ultraviolet resistance, ageing resistance, impact resistance, flexibility and other properties, fire resistance and other properties, has stable storage property, is convenient to store and transport, has low manufacturing cost, realizes light weight and flexibility, has beautiful light-transmitting decoration, and is very suitable to be used as a photovoltaic packaging material, a building material and an automobile exterior trimming part material.
Description
Technical Field
The invention belongs to the field of protective materials, and particularly relates to an efficient protective composite board and a preparation method thereof, and also relates to application and an application method of the efficient protective composite board.
Background
Thermosetting powder coating refers to a solvent-free 100% solids powder coating. Thermosetting powder coatings are generally composed of thermosetting resins, curing agents, pigments, fillers, auxiliaries and the like, and are widely applied to the fields of buildings, woodware, automobiles, household appliances and the like as substrate protective coatings due to the characteristics of no solvent, no pollution, recoverability, environmental protection, energy and resource saving, labor intensity reduction, high mechanical strength of coatings and the like.
Since thermosetting powder coating is powder in nature, it is always considered to be applied only to coating protective materials for various hard substrates such as metal, wood, glass, etc. The inventor's Chinese invention patents associated with prior application numbers CN201610685536.0 and CN201610685240.9 respectively disclose a packaging material for a photovoltaic module and a preparation method thereof, and propose that a composite material obtained by compounding fiber cloth with super-weather-resistant polyester powder paint or super-weather-resistant polyester powder paint is used as the packaging material of the photovoltaic module to replace a traditional toughened glass layer or a back plate layer to solve the problems of light weight and convenient installation of the photovoltaic packaging material, thereby obtaining a surprising technical effect, which is a technical breakthrough in the photovoltaic packaging industry.
With the continuous popularization, application and implementation of the applicant and a large amount of experimental research, the inventor finds that the composite materials with more excellent performance and technical effect can be obtained by compounding different types of thermosetting powder coatings and fiber cloth under specific conditions, and the composite materials can be applied to wider fields, so that the light weight and flexibility of related products are realized, and the products are endowed with higher quality.
Disclosure of Invention
In view of the above, the invention aims to provide an efficient protective composite board, and a preparation method, an application and an application method thereof, on the premise of exerting the inherent advantages of the thermosetting powder coating, the efficient protective composite board has excellent ultraviolet resistance, ageing resistance, impact resistance, flexibility and other properties, fire resistance and other properties, is stable in storage performance, convenient to store and transport, low in manufacturing cost, light in weight, flexible, attractive in appearance, light-transmitting and decorative, and is very suitable for being used as a photovoltaic packaging material, a building material and an automobile exterior trim material.
It should be noted that: the invention relates to Chinese patent with prior application numbers of CN201610685536.0 and CN201610685240.9, and provides a composite material obtained by thermally bonding super-weather-resistant polyester powder coating or super-weather-resistant polyester powder coating on fiber cloth, wherein the composite material is simultaneously crosslinked and cured in the lamination process of a photovoltaic module, this is because one skilled in the art would recognize this as the best process path based on common general knowledge and routine experience, because the heating environment of lamination is also suitable for the cross-linking and curing conditions of the powder coating, and the two are simultaneously carried out, the bonding of the composite thermosetting layer structure with other layer structures can be facilitated, therefore, in the process path, even when technical problems such as differences in the properties of thermosetting materials and thermoplastic materials commonly used for encapsulating materials are encountered, a stepwise heating and pressure cooling step is used in an effort to solve the technical problems.
However, in practical applications, the applicant finds that the composite material has poor storage stability and is inconvenient for long-term transportation due to the thermal bonding composite process, so that long-distance transportation cannot be generally specified, packaging cannot be produced nearby, and the storage period cannot generally exceed 3 months, which undoubtedly increases the manufacturing cost; moreover, the super-weatherable polyester powder coating usually generates bubbles and/or gas during crosslinking and curing, and the bubbles and gas generated during the lamination process of the photovoltaic module directly influence the flatness and the lamination quality of the photovoltaic module, so that the applicant hopes to perform research and experiment again on the basis of the innovative composite materials, and finally surprises that the technical scheme of the invention is obtained.
The technical scheme adopted by the invention is as follows:
the high-efficiency protective composite board comprises the following raw materials of fiber and thermosetting powder coating, wherein the weight ratio of the fiber to the thermosetting powder coating is 20-80 parts: 80-20 parts of a binder; wherein the thermosetting powder coating is cross-linked and cured uniformly on the fibers; the thermosetting powder coating is an ultra-weather-resistant polyester powder coating.
The high-efficiency protective composite board comprises a thermoplastic film and a composite material layer which are compounded into a whole, wherein the composite material layer is prepared from fibers and thermosetting powder coating, and the weight ratio of the fibers to the thermosetting powder coating is 20-80 parts: 80-20 parts of a binder; wherein the thermosetting powder coating is cross-linked and cured uniformly on the fibers; the thermosetting powder coating is an ultra-weather-resistant polyester powder coating.
More preferably, the weight ratio of the fiber to the thermosetting powder coating is 30-70 parts: 70-30 parts; more preferably, the weight ratio of the fiber to the thermosetting powder coating is 30-50 parts: 70-50 parts.
Preferably, the fibers are fiber cloth woven from fiber materials or fiber cloth non-woven from fiber materials or chopped fibers or milled fibers. The invention exemplifies the fiber shapes of the preferred schemes, and the preferred fiber shapes are beneficial to the preparation of the high-efficiency protective composite board and enable the relative performance to be more excellent.
Preferably, the weight per unit area of the fiber cloth ranges from 30 to 400g/m2。
Preferably, the fiber material is any one or combination of glass fiber, carbon fiber and aramid fiber; preferably, the fiber material has a monofilament diameter in the range of 3-23 μm.
Preferably, the super-weatherable polyester powder coating comprises super-weatherable polyester resin and a curing agent, wherein the super-weatherable polyester resin is one or a mixture of hydroxyl super-weatherable polyester resin and carboxyl super-weatherable polyester resin; wherein, the hydroxyl value range of the hydroxyl super-weather-resistant polyester resin is 30-300mgKOH/g, the glass transition temperature range is 50-75 ℃, and the viscosity range is 15-200 Pa.s; the acid value range of the carboxyl super-weather-resistant polyester resin is 15-85mgKOH/g, the glass transition temperature range is 50-75 ℃, and the viscosity range is 15-200 Pa.s.
Preferably, the weight part of the curing agent accounts for 5-25% of the weight part of the super-weatherable polyester powder coating, and the curing agent is any one or a mixture of several of blocked isocyanate, phthalic anhydride, trimellitic anhydride, sebacic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecanedioic acid, hexadecanedioic acid, carboxyl polyester, hydrogenated epoxy and GMA super-weatherable polyester in any proportion.
Preferably, the thickness of the high-efficiency protective composite board ranges from 0.2 mm to 15 mm.
Preferably, the preparation method of the high-efficiency protective composite board is characterized in that the high-efficiency protective composite board is prepared by a fiber and thermosetting powder coating pre-compounding process and then a hot-pressing curing process, wherein the pre-compounding process is a coating process or a coating and thermal bonding process or a melt co-extrusion process.
The invention provides a pre-compounding process which can adopt a coating process or a coating thermal bonding process or a melt co-extrusion process, and further, the coating process is to uniformly coat the super-weather-resistant polyester powder coating on the fiber cloth; the coating and thermal bonding process is to uniformly coat the super-weather-resistant polyester powder coating on the fiber cloth and then heat the fiber cloth so that the super-weather-resistant polyester powder coating is well bonded on the fiber cloth, thereby being beneficial to the implementation of the subsequent hot-pressing curing process, and specifically, the process provided in CN201610685536.0 can be directly adopted; the melt co-extrusion process is to mix and extrude the super-weather-resistant polyester powder coating and the chopped fiber or the milled fiber to obtain the pre-compounded fiber and the thermosetting powder coating in the shape of a sheet, so that the implementation of the subsequent hot-pressing curing process is facilitated; of course, as a less preferred embodiment, those skilled in the art may also refer to other known manufacturing methods in the prior art, such as the manufacturing process of the glass fiber reinforced plastic in the prior art, to manufacture the high-efficiency protective composite board of the present invention, which also fall into the protection scope of the high-efficiency protective composite board of the present invention, and on the basis of the core technical solution of the present invention, the technical solution of the present invention implemented by using other existing manufacturing processes of the thermosetting reinforced fiber products such as the glass fiber reinforced plastic should not be regarded as novel and inventive relative to the present invention.
Preferably, the hot press curing process step comprises:
A10) placing the pre-compounded fiber and the thermosetting powder coating in hot-pressing equipment;
A20) carrying out hot pressing on the pre-compounded fiber and the thermosetting powder coating under the preset hot pressing condition, wherein the super-weather-resistant polyester powder coating finishes crosslinking and curing on the fiber;
A30) obtaining the high-efficiency protection composite board;
preferably, the heating temperature range of the hot-pressing condition is 130-220 ℃, the heating time is 8-30 minutes, and the pressure range is 0.01-0.5 MPa; more preferably, the heating temperature range of the hot-pressing condition is 150-.
Likewise, the hot-press curing process is the preferred cross-linking curing process of the present invention, and the present invention is not limited to other cross-linking curing processes in other embodiments for preparing the high-efficiency protective composite board to be protected by the present invention.
Preferably, the application of the high-efficiency protective composite board is applied to photovoltaic packaging materials, building materials and automobile exterior trimming part materials; and to applications requiring these excellent property-exhibiting materials.
Preferably, the high-efficiency protective composite board is applied to a photovoltaic packaging material to obtain a photovoltaic module, wherein the high-efficiency protective composite board is used as a light receiving surface packaging layer of the photovoltaic module; of course, it is also possible to use it as a back-light surface encapsulation layer of a photovoltaic module as a less preferred solution.
Preferably, the photovoltaic module comprises a photovoltaic module layer structure, which comprises a light receiving surface packaging layer, a packaging film layer, a battery string and a backlight surface packaging layer of the photovoltaic module, wherein the high-efficiency protection composite board is used as the light receiving surface packaging layer of the photovoltaic module, and the backlight surface packaging layer is made of the backlight surface packaging layer made of pre-compounded fibers and thermosetting powder coating.
Preferably, the application method of the high-efficiency protective composite board as described above, wherein the photovoltaic module layer structure is prepared by a lamination process, includes the following steps:
B10) sequentially laying the light receiving surface packaging layer and the rest material layers;
B20) covering the upper part with high-temperature Teflon cloth, and laminating in a laminating machine to obtain a laminated part;
B30) and cutting the edge of the laminated part to obtain the photovoltaic module layer structure.
Preferably, the application method of the high-efficiency protective composite board is characterized in that the photovoltaic module layer structure is prepared by a lamination process, the lamination process comprises a first heating stage, a second heating stage and a third pressurizing and cooling stage, the heating temperature range of the first stage is 110-; the heating temperature range of the second stage is 130-; the cooling temperature of the third stage is 25-60 deg.C, and the pressure is 0.05-0.25 MPa.
The composite board obtained by uniformly crosslinking and curing the super-weather-resistant polyester powder coating on the fiber is detected to have excellent ultraviolet resistance, ageing resistance, impact resistance, flexibility, fire resistance and other performances on the premise of having the inherent advantages of the thermosetting powder coating, and the performances are obviously superior to the structural performance of a packaging layer obtained by directly crosslinking and curing the thermosetting powder coating when the thermosetting powder coating is laminated on a photovoltaic module, which is a technical effect not thought by CN201610685536.0 and CN201610685240.9, and the composite board has stable storage performance, is convenient to store and transport, has low manufacturing cost, realizes light weight and flexibility, has attractive light-transmitting decoration, and is very suitable for being used as a photovoltaic packaging material, a building material and an automobile exterior trim material; the material is particularly suitable for serving as a light receiving surface packaging layer of a photovoltaic module;
in order to further facilitate the lamination process when the composite board of the invention is applied to a photovoltaic layered material as a layer structure, the invention also provides a composite board which is formed by hot-pressing and compounding a thermoplastic film on one side, and the composite board still maintains the technical effect of the invention, wherein the thermoplastic film can be a certain layer structure of a photovoltaic module, such as a fluoroplastic film layer;
the invention further provides a preferable photovoltaic module, which has a photovoltaic module layer structure with high-efficiency anti-subfissure effect, and specifically comprises a light receiving surface packaging layer, a packaging film layer, a battery string and a backlight surface packaging layer of the photovoltaic module, wherein a high-efficiency protective composite board is used as the light receiving surface packaging layer of the photovoltaic module, and the backlight surface packaging layer is prepared by taking pre-compounded fibers and thermosetting powder coating as raw materials, so that the photovoltaic layer structure not only effectively ensures the adhesion of each layer structure in the laminating process, but also more importantly, the applicant surprisingly discovers through a large number of tests that the photovoltaic module adopting the sequential laminating structure has high-efficiency anti-subfissure capability, can obviously and effectively avoid the subfissure of the battery string, can not generate subfissure under the bending installation environment, namely, realizes the curved surface/radian attractive design, and also obviously lightens the packaging weight of the photovoltaic module, compared with the existing flexible crystalline silicon assembly, the curved surface/radian attractive design can be realized, but the hidden crack rate of the battery string is high, and the existing flexible thin film assembly is low in photoelectric conversion efficiency, complex in manufacturing process and high in manufacturing cost, so that the optimized photovoltaic assembly provided by the invention is directly beneficial to batch popularization and application of the flexible crystalline silicon assembly.
On the basis of the preferable photovoltaic module technical scheme, the invention further provides a preferable application process, as mentioned above, the invention firstly prepares the high-efficiency protective composite board through the hot-pressing curing process, so that the composite board prepared by the single hot-pressing curing process has low possibility of generating flaws, and if the composite board has flaws locally, the composite board can be cut independently for other applications; and then the photovoltaic module layer structure is prepared by a lamination process, so that the problem of high defective rate of the whole lamination structure caused by defects generated when raw materials of the light receiving surface packaging layer and/or the backlight surface packaging layer are cured in the lamination process is effectively avoided.
Drawings
FIG. 1 is a block diagram of the hot press curing process of example 1 of the present invention;
FIG. 2 is a block diagram of the lamination process steps of example 1 of the present invention;
FIG. 3 is a schematic view of the layer structure in the course of the lamination process of example 1 of the present invention;
fig. 4 is a schematic view of a photovoltaic module laminate structure 100a according to example 1 of the present invention;
fig. 5 is a schematic view of a photovoltaic module laminate structure 100b according to example 2 of the present invention;
fig. 6 is a schematic view of a photovoltaic module laminate structure 100c according to example 3 of the present invention;
fig. 7 is a schematic view of a photovoltaic module laminate structure 100d according to example 4 of the present invention.
Detailed Description
The embodiment discloses a high-efficiency protective composite board, which is prepared from the following raw materials in parts by weight: 80-20 parts of a binder; wherein the thermosetting powder coating is uniformly cross-linked and cured on the fiber; the thermosetting powder coating is super weather-resistant polyester powder coating.
The embodiment also discloses a high-efficient protection composite board, composite board is including compound thermoplastic film and the combined material layer as an organic whole, and the raw materials of combined material layer are fibre and thermosetting powder coating, and the weight share of fibre and thermosetting powder coating is 20-80 parts: 80-20 parts of a binder; wherein the thermosetting powder coating is uniformly cross-linked and cured on the fiber; the thermosetting powder coating is super weather-resistant polyester powder coating.
The embodiment of the invention provides a composite board obtained by uniformly crosslinking and curing an ultra-weather-resistant polyester powder coating on fibers, and detection shows that the composite board obtained by the invention has excellent ultraviolet resistance, ageing resistance, impact resistance, flexibility, fire resistance and other properties on the premise of having the inherent advantages of the thermosetting powder coating, and the properties are obviously superior to the structural properties of a packaging layer obtained by crosslinking and curing the composite board when the composite board is directly laminated on a photovoltaic module, which is a technical effect not thought by CN201610685536.0 and CN201610685240.9, and the composite board has stable storage performance, is convenient to store and transport, low in manufacturing cost, realizes light weight and flexibility, has attractive, light-transmitting and decorative properties, and is very suitable for being used as a photovoltaic packaging material, a building material and an automobile exterior trim material; the light receiving surface packaging layer is particularly suitable for being used as a light receiving surface packaging layer of a photovoltaic module.
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments described in the present invention, and for those skilled in the art, other drawings can be obtained according to the drawings without creative efforts.
Example 1:
the high-efficiency protective composite board 110a is characterized in that the raw materials of the composite board 110a are fiber cloth woven by fiber materials and thermosetting powder coating, and the weight ratio of the fiber cloth to the thermosetting powder coating is 20-80 parts: 80-20 parts of a binder; wherein, the thermosetting powder coating is evenly crosslinked and cured on the fiber cloth to obtain the composite board; the thermosetting powder coating is super weather-resistant polyester powder coating.
More preferably, the weight ratio of the fiber to the super weather-resistant polyester powder coating is 30-70 parts: 70-30 parts; still more preferably, in the present embodiment, the weight ratio of the fiber to the super weather-resistant polyester powder coating is 30-50 parts: 70-50 parts of the composite board is more beneficial to comprehensive excellent performances of the high-efficiency protective composite board on ultraviolet resistance, ageing resistance, impact resistance, flexibility, fire resistance and the like;
in the specific implementation of the invention, the weight ratio of the suggested fiber cloth to the thermosetting powder coating is 20-80 parts: 80-20 parts, the composite board with various excellent performance performances can be obtained in the range, certainly, the technical effect close to the invention can be obtained by floating a certain weight part range outside the upper limit and the lower limit, and the technical scheme adopting the technical scheme suitable for floating to obtain the close technical effect can be considered to be in the protection range of the invention.
Preferably, the fiber cloth has a weight per unit area ranging from 30 to 400g/m2(ii) a The fiber material is any one or combination of several of glass fiber, carbon fiber and aramid fiber; the monofilament diameter range of the fiber material is 3-23 μm; specifically, in the present embodiment, the fiber material is glass fiber.
In the present embodiment, the super weather-resistant polyester powder coating includes a super weather-resistant polyester resin and a curing agent; preferably, in the embodiment of the present invention, the super-weatherable polyester resin is one or a mixture of two of hydroxyl super-weatherable polyester resin and carboxyl super-weatherable polyester resin, so as to ensure that the super-weatherable polyester resin has good insulation and weather resistance and meets the relevant standard requirements, and particularly, in the present embodiment, the super-weatherable polyester resin is hydroxyl super-weatherable polyester resin;
preferably, in the embodiment of the present invention, the hydroxyl super-weatherable polyester resin is a mixture polymerized by one or more monomers of neopentyl glycol, adipic acid, and ethylene glycol, and of course, a person skilled in the art can select other types of monomers to polymerize to obtain the hydroxyl super-weatherable polyester resin according to actual needs, which is not illustrated in the embodiment of the present invention, and specifically, in the embodiment, the hydroxyl super-weatherable polyester resin is polymerized by an adipic acid monomer;
preferably, in the embodiment of the present invention, the hydroxyl value of the hydroxyl super-weatherable polyester resin is in the range of 30 to 300mgKOH/g, the glass transition temperature is in the range of 50 to 75 ℃, and the viscosity is in the range of 15 to 200 Pa.s, specifically, in the embodiment, the hydroxyl value of the hydroxyl super-weatherable polyester resin is 100mgKOH/g, the glass transition temperature is in the range of 60 ℃, and the viscosity is in the range of 80 Pa.s;
in other embodiments of the present invention, the super-weatherable polyester resin may also be a carboxyl super-weatherable polyester resin, which is a mixture polymerized from one or two monomers of terephthalic acid and isophthalic acid, wherein the carboxyl super-weatherable polyester resin has an acid value ranging from 15 to 85mgKOH/g, a glass transition temperature ranging from 50 to 75 ℃, and a viscosity ranging from 15 to 200Pa · s;
preferably, in the embodiment of the present invention, the weight part of the curing agent is 2-20% of the weight part of the super weather-resistant polyester powder coating, the curing agent is one or a mixture of several of triglycidyl isocyanurate, triglycidyl trimellitate, diglycidyl terephthalate, glycidyl methacrylate, hydroxyalkyl amide and isocyanate, specifically, in this embodiment, the curing agent is triglycidyl isocyanurate, and the triglycidyl isocyanurate is 5% of the weight part of the hydroxyl super weather-resistant polyester powder coating, and of course, those skilled in the art can select other types of curing agents and curing agents within the range of 2-20% by weight (including 2% and 20%) according to the type and actual situation of the super weather-resistant polyester resin, and can also obtain the same technical effect, the embodiments of the invention are not explained one by one;
wherein, the super-weather-resistant polyester powder coating is uniformly coated on the fiber cloth, and the super-weather-resistant polyester powder coating is coated on the fiber clothThe weight per unit area is in the range of 100-400g/m2Specifically, in the present embodiment, the weight per unit area of the super weather-resistant polyester powder coating applied on the fiber cloth is 100g/m2；
Of course, in other specific embodiments, the super-weatherable polyester powder coating provided in the embodiments of the present invention may further include an auxiliary agent in a certain weight portion, preferably, the auxiliary agent accounts for 0 to 40% of the weight portion of the super-weatherable polyester powder coating, so as to further improve the insulation and weather resistance of the super-weatherable polyester powder coating, and at the same time, the color of the super-weatherable polyester powder coating may be adjusted by adding the auxiliary agent according to actual needs, which is further beneficial to practical installation and application Distearylethylenediamine, a mixture of ethylene oxide and propylene oxide, hindered phenol, thiodipropionate diester, benzophenone, salicylate derivatives, hindered amine, alumina, fumed silica, tetrabromobisphenol A, decabromodiphenylethane, tricresyl phosphate, aluminum hydroxide, magnesium hydroxide, barium sulfate, titanium dioxide and carbon black in any proportion, and of course, other types of additives can be selected by persons skilled in the art according to actual needs, and the embodiment of the invention is not specifically described.
The super-weather-resistant polyester powder coating according to the embodiment of the present invention can be prepared by any of the known preparation techniques of powder coatings, and a typical method can be prepared by premixing, melt extrusion, grinding and the like, specifically, in the present embodiment, the super-weather-resistant polyester resin and the curing agent are premixed for a time preferably selected from 2 to 10 minutes (if the super-weather-resistant polyester powder coating contains the auxiliary agent, the premixing is also performed together), and then the premixed mixture is extruded and pressed into a sheet by a screw extruder, preferably, the length-to-diameter ratio of the extruder is selected from 15: 1-50: 1, the heating temperature of the extruder is selected to be between 80 and 120 ℃, and the rotating speed of a screw is selected to be 200-800 rpm; finally, the thin slices are crushed into small pieces and put into a mill to be ground into powder coating with certain particle size, preferably, the rotating speed of the mill is selected to be 50-150rpm, and preferably, the particle size range of the finished product of the super-weather-resistant polyester powder coating is controlled to be 35-300 mu m. Of course, other process parameters or powder coating preparation processes may also be employed to prepare the super weatherable polyester powder coating, which are believed to be routine technical choices for those skilled in the art, and therefore, the preparation of the super weatherable polyester powder coating will not be described in detail herein.
Specifically, in this embodiment, the high-efficiency protective composite board 110a is prepared by a pre-composite process of fiber cloth and thermosetting powder coating and then a hot-pressing curing process, wherein in this embodiment, the pre-composite process is a coating process, specifically, the super-weather-resistant polyester powder coating is uniformly coated on the fiber cloth by a coating machine, the coating device may also adopt a powder spreading head, and at this time, the coating device realizes a coating process in a powder spreading manner, so that the super-weather-resistant polyester powder coating is uniformly coated on the fiber cloth; other coating means known in the art may also be used; in other embodiments of the present invention, thermal bonding may also be performed after coating is completed, which is further beneficial for subsequent hot-press curing, but obviously, the process is relatively cumbersome;
preferably, the thickness of the high-efficiency protective composite board 110a ranges from 0.2 mm to 15 mm; more preferably, in the present embodiment, the thickness of the high-efficiency protective composite board 110a ranges from 0.8 mm to 5 mm; the specific thickness can be selected according to application requirements;
referring to fig. 1, in the present embodiment, the hot press curing process includes:
A10) placing the pre-compounded fiber cloth and thermosetting powder coating (namely the fiber cloth uniformly coated with the super-weather-resistant polyester powder coating obtained in the embodiment) in hot-pressing equipment;
A20) under the preset hot-pressing condition, hot-pressing the pre-compounded fiber cloth and the thermosetting powder coating, and finishing crosslinking and curing of the super-weather-resistant polyester powder coating on the fiber cloth;
the following hot pressing conditions of the present invention are preferred technical solutions proposed by the applicant in terms of energy consumption, crosslinking curing effect, efficiency, etc., and those skilled in the art can select the heating temperature, heating time and pressure of the hot pressing conditions according to actual needs during actual implementation as long as the ultra-weather-resistant polyester powder coating is ensured to complete crosslinking curing on the fiber cloth, and the changes of the hot pressing conditions during implementation should not be considered as limitations on the protection scope of the present invention.
Preferably, the heating temperature range of the hot-pressing condition is 130-220 ℃, and the heating time is 8-30 minutes; the pressure range of the hot pressing condition is 0.01-0.5 Mpa; particularly preferably, in the present embodiment, the heating temperature range of the hot-pressing condition is 150-; the pressure range of the hot pressing condition is 0.05-0.3 Mpa;
A30) and obtaining the high-efficiency protective composite board 110 a.
Further preferably, in the embodiment, before the step a30), a21) of pressure cooling is further included, and the preferable cooling temperature range suggested in the embodiment of the present invention is 25 to 60 ℃, and the applied pressure range is 0.05 to 0.25 Mpa; this further facilitates the flatness of the composite board 110a and maintains good flexibility.
The hot pressing equipment in the embodiment of the invention can directly select laminating equipment, can also adopt other suitable hot pressing equipment and can also adopt other hot pressing conditions, and only the super-weather-resistant polyester powder coating is ensured to be uniformly crosslinked and cured on the fiber cloth;
preferably, in this embodiment, the application of the high-efficiency protective composite board 110a described above is applied to a photovoltaic encapsulating material to obtain a photovoltaic module, where the high-efficiency protective composite board 110a is used as a light receiving surface encapsulating layer of the photovoltaic module, please refer to a photovoltaic module layer structure 100a shown in fig. 4, including the composite board layer 110a, the first EVA film layer 120a, the battery string 130a, the second EVA film layer 140a, and the back sheet layer 150a used as the light receiving surface encapsulating layer in this embodiment 1, specifically, as shown in fig. 2, in this embodiment, the photovoltaic module layer structure 100a is prepared by a lamination process, and the lamination process includes the following operation steps:
B10) as shown in fig. 3, the composite board layer 110a, the first EVA film layer 120a, the battery string 130a, the second EVA film layer 140a, and the back sheet layer 150a are sequentially laid;
B20) covering the upper part with high-temperature Teflon cloth, and laminating in a laminating machine to obtain a laminated part;
B30) and cutting the edge of the laminate to obtain the photovoltaic module layer structure 100 a.
The specific lamination process conditions can be a lamination process commonly used for the existing photovoltaic module, specifically, in the present embodiment, the lamination process conditions are lamination for 15 minutes at a temperature of 140-.
Example 2:
the difference between the other technical solutions of this embodiment 2 and embodiment 1 is that, in this embodiment 2, a high-efficiency protective composite board 110b, the composite board 110b includes a thermoplastic film and a composite material layer which are compounded into a whole under a hot-pressing condition, the raw materials of the composite material layer are fiber cloth woven by fiber materials and thermosetting powder coating, and the weight ratio of the fiber cloth to the thermosetting powder coating is 30-50 parts: 70-50 parts; wherein, the thermosetting powder coating is uniformly crosslinked and cured on the fiber cloth under the hot-pressing condition to obtain a composite material layer; the thermosetting powder coating is super weather-resistant polyester powder coating; preferably, in the present embodiment, the thermoplastic film is a fluoroplastic film;
in this embodiment, the application of the high-efficiency protective composite board 110b described above is applied to a photovoltaic encapsulating material to obtain a photovoltaic module, wherein the high-efficiency protective composite board 110b is used as a light-receiving-surface encapsulating layer of the photovoltaic module, please refer to a photovoltaic module layer structure 100b shown in fig. 5, which includes the composite board layer 110b used as the light-receiving-surface encapsulating layer in this embodiment 2, a first EVA film layer 120b, a battery string 130b, a second EVA film layer 140b, and a back sheet layer 150 b.
Example 3:
the difference between the other technical solutions of this embodiment 3 and embodiment 2 is that, in this embodiment, the high-efficiency protective composite board 110c is prepared by using a hot-press curing process, as shown in fig. 1, the hot-press curing process includes the following steps:
A10) placing the pre-compounded fiber cloth and thermosetting powder coating (namely the fiber cloth uniformly coated with the super-weather-resistant polyester powder coating obtained in the embodiment) in hot-pressing equipment;
A20) under the preset hot-pressing condition, hot-pressing the pre-compounded fiber cloth and the thermosetting powder coating, and finishing crosslinking and curing of the super-weather-resistant polyester powder coating on the fiber cloth; (ii) a In the present embodiment, the heating temperature range of the hot-pressing condition is 170-190 ℃, and the heating time is 18-22 minutes; the pressure range of the hot pressing condition is 0.1-0.2 Mpa;
A21) a pressure cooling step, wherein the cooling temperature is 25-60 ℃, and the applied pressure is in the range of
0.05-0.25Mpa；
A30) Obtaining a composite board 110 c;
in the application of the high-efficiency protective composite board 110c of this embodiment 3, the high-efficiency protective composite board 110c is applied to a photovoltaic encapsulating material to obtain a photovoltaic module, wherein the high-efficiency protective composite board 110c is used as a light receiving surface encapsulating layer of the photovoltaic module, please refer to a photovoltaic module layer structure 100c shown in fig. 6, which includes the composite board layer 110c used as the light receiving surface encapsulating layer of this embodiment 3, an EVA film layer 120c, a battery string 130c, a backlight surface encapsulating layer 140c (the backlight surface encapsulating layer 140c is cross-linked and cured in a laminating process) made of pre-compounded fibers and thermosetting powder coating (i.e., obtained by a coating and thermal bonding process) disclosed in embodiment 1 of CN201610685240.9, and a back sheet 150 c;
since the backlight face packaging layer 140c needs to complete cross-linking curing in the lamination process, the lamination process proposed by CN201610927383.6 can be preferably adopted in the present embodiment; the method comprises the following specific steps:
the photovoltaic module layer structure 100c of this embodiment 3 is prepared by a lamination process, please refer to fig. 2, and includes the following steps:
B10) sequentially laying the composite board layer 110c, the EVA film layer 120c, the battery string 130c, the backlight surface packaging layer 140c and the back plate 150 c;
B20) covering the upper part with high-temperature Teflon cloth, and laminating in a laminating machine to obtain a laminated part;
B30) and cutting the edge of the laminate to obtain the photovoltaic module layer structure 100 c.
Preferably, in the present embodiment, the lamination process comprises a first heating stage, a second heating stage and a third pressurized cooling stage, wherein the heating temperature of the first stage is in the range of 110-; the heating temperature range of the second stage is 130-; the cooling temperature of the third stage is 25-60 deg.C, and the pressure is applied in the range of
0.05-0.25 Mpa; the working principle of the present invention can be directly referred to the related description of CN201610927383.6, and the embodiments of the present invention are not specifically described.
Example 4:
in the present embodiment 4, the first high-efficiency protective composite board 110d similar to that of embodiment 2 and the second high-efficiency protective composite board 150d similar to that of embodiment 1 are included;
in the application of the high-efficiency protective composite board of this embodiment 4, the application is applied to a photovoltaic packaging material to obtain a photovoltaic module, where the first high-efficiency protective composite board 110d and the second high-efficiency protective composite board 150d are respectively used as a light receiving surface packaging layer and a backlight surface packaging layer of the photovoltaic module, please refer to the photovoltaic module layer structure 100d shown in fig. 7, which includes the first high-efficiency protective composite board 110d as the light receiving surface packaging layer, the first EVA film layer 120d, the battery string 130d, the second EVA film layer 140d, and the second high-efficiency protective composite board 150d as the backlight surface packaging layer of this embodiment 4.
It should be noted that, regarding the selection of specific relevant parameters and types of the super-weatherable polyester powder coating and the fiber cloth in the embodiment of the present invention, those skilled in the art can directly use the technical information disclosed in CN201610685240.9, and the examples of the present invention are not necessarily illustrated.
In another embodiment of the present invention, the material of the encapsulating film layer may be the ethylene-vinyl acetate copolymer (EVA) described in examples 1 to 4 and examples 7 to 8, or may be a polyolefin elastomer (POE) or a polyvinyl butyral (PVB) or a polyethylene terephthalate film (PET), or may be an encapsulating film material of other known encapsulating materials for photovoltaic modules, and the present invention is not limited in particular.
Example 5:
the rest of the technical scheme of the embodiment 5 is the same as that of the embodiment 1 or the embodiment 2, and the difference is that: in this embodiment 5, the application of the high-efficiency protective composite board 110a or 110b is applied to building materials to obtain a building light-transmitting curtain wall and/or other building material structures.
Example 6:
the rest of the technical solutions in this embodiment 6 are the same as those in embodiment 1 or embodiment 2, except that: in this embodiment 6, the application of the high-efficiency protective composite board 110a or 110b is applied to an automobile exterior trim material to obtain an automobile exterior trim.
Example 7:
the rest of the technical solutions of this embodiment 7 are the same as those of embodiment 1 or embodiment 2, except that: the fibers of the present example are fiber cloths made of nonwoven fibrous materials.
Example 8:
the rest of the technical solutions of this embodiment 8 are the same as those of embodiment 1 or embodiment 2, except that: the fibers of this example 8 are chopped fibers or milled fibers in the form of particles with a length ranging from 3 to 50mm, and the pre-compounding process of this example employs a melt co-extrusion process; particularly preferably, in the present embodiment, chopped fibers in a size of 3mm are used as the fibers; the melt co-extrusion process comprises the following specific steps: the super-weather-resistant polyester powder coating and 3mm chopped fibers are blended and then extruded by a double-screw extruder to obtain pre-compounded fibers and thermosetting powder coatings in sheet shapes, the heating temperature range during melt co-extrusion can be selected to be 110-120 ℃, the selection is specifically made according to the actual extrusion requirement as long as the super-weather-resistant polyester powder coating is ensured to be in a molten state but not reach the curing temperature, and the selection is believed to be routine technical selection of persons skilled in the art, and the specific description is not repeated.
By examination, the excellent properties associated with the composite sheets prepared in examples 1-4 and examples 7-8 are simultaneously exhibited by:
1. the raw material performance is as follows: the method has the advantages of no solvent, no pollution, recoverability, environmental protection, energy and resource saving and labor intensity reduction;
2. the storage performance is as follows: can be preserved for a long time;
3. the weather resistance is shown as follows: the test of QUVB resistance for 1500 hours is passed, and the test of xenon resistance for 3000 hours is passed;
4. the mechanical performance is as follows: the pencil hardness is more than 2H; the tensile strength reaches about 46MPa, and is basically the same as that of glass; the elongation at break ranges from 150 to 250 percent;
5. the flexibility performance is as follows: the bending at any angle does not deform or break, and can be applied to the installation of complex curved surfaces;
6. light-transmitting decorative performance: the light transmittance reaches more than 90 percent, and the light-transmitting decorative effect of the glass is basically achieved;
7. and (3) light weight performance: the weight per unit area is equal to or less than or equal to 1kg/m2Much less than the weight per unit area of the glass;
8. the cost performance is as follows: the material cost is far lower than that of fluororesin materials and organosilicon materials;
example 7 is inferior to examples 1-4 in mechanical performance, and example 8 is inferior to examples 1-4 in preparation process and in flexibility and mechanical performance; thus, examples 1-4 are more preferred embodiments of the present invention;
the composite board prepared by the invention has excellent characteristics and low manufacturing cost, is a technical effect which is not thought by CN201610685536.0 and CN201610685240.9, and the composite board of the embodiment of the invention has the excellent performance, so the composite board is not only very suitable for being used as a photovoltaic packaging material, but also can be directly used as a building material and an automobile exterior trim material respectively as shown in embodiments 5 and 6, and the application fields needing the materials with the excellent performance, and the application of other fields of the composite board also belongs to the protection scope of the invention.
It should be further specifically noted that the applicant of the present invention has also found, particularly surprisingly, that in embodiment 3 of the present invention, a laminated structure of the composite board layer 110c, the EVA film layer 120c, the battery string 130c, and the backlight surface encapsulation layer 140c is adopted, so that subfissure of the battery string 130c can be obviously and effectively avoided, and subfissure does not occur in a bending installation environment, that is, a curved surface/radian aesthetic design is achieved, and the encapsulation weight of the photovoltaic module is also significantly reduced, while the existing flexible crystalline silicon module can achieve a curved surface/radian aesthetic design, but the subfissure rate of the battery string is very high, and the existing flexible thin film module has not only low photoelectric conversion efficiency, a complex manufacturing process, but also a very high manufacturing cost; therefore, the preferable photovoltaic module provided by the embodiment 3 is directly beneficial to the batch popularization and application of the flexible crystalline silicon module.
A large number of implementation and application cases of the applicant show that the yield of the subfissure of the cell string in embodiment 3 of the present invention reaches more than 99% (that is, the subfissure does not occur), the yield of the subfissure is obviously better than the yield of the subfissure in embodiments 1, 2 and 4, and the photovoltaic module provided in embodiment 3 meets the standard requirement of the photovoltaic industry on the subfissure, and belongs to the embodiment of the present invention which is most preferably applied to a photovoltaic packaging material to obtain a photovoltaic module.
It should be emphasized that, in other embodiments of the present invention, the thermosetting powder coating in the back light surface packaging layer 140c of this embodiment 3 may also be a fiber cloth compounded thermosetting powder coating, such as acrylic powder coating, epoxy powder coating, polyurethane powder coating, epoxy mixed powder coating, fluorocarbon powder coating, and other thermosetting powder coatings, and the applicant has verified through experiments that the packaging material obtained by compounding the thermosetting powder coating of this type with the fiber cloth (the compounding method may all adopt the preparation method of the packaging material disclosed in CN 201610685240.9) is applied to this back light surface packaging layer 140c of this embodiment 3, and the back light surface packaging layer 140c completes cross-linking and curing in the lamination process, and can obtain the same or a little different technical effect of anti-hidden cracking as that of this embodiment 3; therefore, the present invention is not particularly limited with respect to the specific type of thermosetting powder coating in the backlight surface encapsulating layer.
The invention further provides an application process of the preferable photovoltaic packaging material, as mentioned above, the high-efficiency protective composite board is prepared by the hot-pressing curing process in the embodiments 1 to 4 and 7 to 8, so that the composite board prepared by the single hot-pressing curing process has low possibility of generating flaws, and if the composite board has flaws locally, the composite board can be cut separately and used as other applications, thereby reducing the defective rate and saving the cost; and then the photovoltaic module layer structure is prepared by a lamination process, so that the problem of high defective rate of the whole lamination structure caused by defects generated when raw materials of the light receiving surface packaging layer and/or the backlight surface packaging layer are cured in the lamination process is effectively avoided.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (12)
1. The efficient protection composite board is characterized in that the composite board is prepared from the following raw materials in parts by weight: 80-20 parts of a binder;
wherein the thermosetting powder coating is cross-linked and cured uniformly on the fibers; the thermosetting powder coating is an ultra-weather-resistant polyester powder coating.
2. The high-efficiency protective composite board is characterized by comprising a thermoplastic film and a composite material layer which are compounded into a whole, wherein the raw materials of the composite material layer are fiber and thermosetting powder coating, and the weight ratio of the fiber to the thermosetting powder coating is 20-80 parts: 80-20 parts of a binder;
wherein the thermosetting powder coating is cross-linked and cured uniformly on the fibers; the thermosetting powder coating is an ultra-weather-resistant polyester powder coating.
3. The high efficiency protective composite sheet material of claim 1 or 2 wherein the fibers are woven or non-woven fiber cloth or chopped or milled fibers.
4. The high efficiency protective composite sheet material of claim 1 or 2, wherein the fibers have a weight per unit area in the range of 30-400g/m2。
5. The high-efficiency protective composite board according to claim 1 or 2, wherein the super-weatherable polyester powder coating comprises a super-weatherable polyester resin and a curing agent, and the super-weatherable polyester resin is one or a mixture of two of a hydroxyl super-weatherable polyester resin and a carboxyl super-weatherable polyester resin; wherein, the hydroxyl value range of the hydroxyl super-weather-resistant polyester resin is 30-300mgKOH/g, the glass transition temperature range is 50-75 ℃, and the viscosity range is 15-200 Pa.s; the acid value range of the carboxyl super-weather-resistant polyester resin is 15-85mgKOH/g, the glass transition temperature range is 50-75 ℃, and the viscosity range is 15-200 Pa.s.
6. The method for preparing the high-efficiency protective composite board as claimed in any one of claims 1 to 5, wherein the high-efficiency protective composite board is prepared by a hot-pressing curing process after a fiber and thermosetting powder coating pre-compounding process, wherein the pre-compounding process adopts a coating process or a coating thermal bonding process or a melt co-extrusion process.
7. The method for preparing the high-efficiency protective composite board as claimed in claim 6, wherein the hot-press curing process comprises the following steps:
A10) placing the pre-compounded fiber and the thermosetting powder coating in hot-pressing equipment;
A20) carrying out hot pressing on the pre-compounded fiber and the thermosetting powder coating under the preset hot pressing condition, wherein the super-weather-resistant polyester powder coating finishes crosslinking and curing on the fiber;
A30) obtaining the high-efficiency protection composite board;
wherein the heating temperature range of the hot pressing condition is 130-220 ℃, the heating time is 8-30 minutes, and the pressure range is 0.01-0.5 Mpa.
8. Use of the high-efficiency protective composite board as claimed in any one of claims 1 to 5, wherein the high-efficiency protective composite board is applied to photovoltaic packaging materials, building materials and automobile exterior trim materials.
9. The use of the high-efficiency protective composite board according to claim 8, wherein the photovoltaic encapsulating material is used for obtaining a photovoltaic module, and the high-efficiency protective composite board is used as a light receiving surface encapsulating layer of the photovoltaic module.
10. The use of the high-efficiency protective composite board according to claim 9, wherein the photovoltaic module comprises a photovoltaic module layer structure comprising a light receiving surface packaging layer, a packaging film layer, a battery string and a backlight surface packaging layer of the photovoltaic module, wherein the high-efficiency protective composite board is used as the light receiving surface packaging layer of the photovoltaic module, and the backlight surface packaging layer is made of pre-compounded fibers and thermosetting powder coating.
11. The application method of the high-efficiency protective composite board as claimed in claim 9 or 10, wherein the photovoltaic module layer structure is prepared by a lamination process, and the application method comprises the following operation steps:
B10) sequentially laying the light receiving surface packaging layer and the rest material layers;
B20) covering the upper part with high-temperature Teflon cloth, and laminating in a laminating machine to obtain a laminated part;
B30) and cutting the edge of the laminated part to obtain the photovoltaic module layer structure.
12. The application method of the high-efficiency protective composite board as claimed in claim 10, wherein the photovoltaic module layer structure is prepared by a lamination process, the lamination process comprises a first heating stage, a second heating stage and a third pressurizing and cooling stage, the heating temperature range of the first stage is 110-; the heating temperature range of the second stage is 130-; the cooling temperature of the third stage is 25-60 deg.C, and the pressure is 0.05-0.25 MPa.
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| CN201810552419.6A CN110629558A (en) | 2018-05-31 | 2018-05-31 | High-efficiency protective composite board and preparation method, application and application method thereof |
| PCT/CN2019/080318 WO2019228049A1 (en) | 2018-05-31 | 2019-03-29 | High-efficiency protective composite board and preparation method therefor, and application and application method therefor |
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