CN110623372A - Environment-friendly button and preparation method thereof - Google Patents
Environment-friendly button and preparation method thereof Download PDFInfo
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- CN110623372A CN110623372A CN201910964736.3A CN201910964736A CN110623372A CN 110623372 A CN110623372 A CN 110623372A CN 201910964736 A CN201910964736 A CN 201910964736A CN 110623372 A CN110623372 A CN 110623372A
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- button
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Classifications
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B1/00—Buttons
- A44B1/02—Buttons characterised by their material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L99/00—Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/06—Other polishing compositions
- C09G1/08—Other polishing compositions based on wax
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an environment-friendly button and a preparation method thereof, wherein the environment-friendly button comprises, by weight, 2 ~ 20 parts of potato flour, 5 ~ 40 parts of corn flour, 15 ~ 50 parts of corn flour, 0.5 ~ 3 parts of toner and 10 ~ 40 parts of adhesive, and the environment-friendly button is prepared from natural renewable plant raw materials such as the potato flour, the corn flour and the corn flour, has better performance than a common button, is low in cost, decomposable, safe and reliable, belongs to an environment-friendly type, has more beautiful and glossy appearance and clear patterns after polishing treatment, is strong in stability, has good wear resistance and steam ironing resistance, is high in hardness and low in cost, and reaches the standards of all indexes of the environment-friendly button after detection.
Description
Technical Field
The invention relates to the technical field of buttons, in particular to an environment-friendly button and a preparation method thereof.
Background
Buttons are daily clothing articles which are commonly kept by people. Its use has been in the past for over six thousand years. The Islands ancestor Persian had been used to make buttons with stone as early as four thousand decades ago.
The original buttons are mainly stone buttons, wood buttons and shell buttons, and buttons with buttons and knotted buttons made of cloth are developed later. The disc knot button plays a great role in the development history of the clothes, and the original clothes functional fastener is transited to clothes decoration. The Chinese style button is the button form of the traditional clothes in China, and is a fancy button which is sewn into a strip by various cloth materials and knotted into various shapes. The Chinese style pan button has beautiful modeling and exquisite workmanship, looks like a thousand postures of artware, and is a unique wonderful flower in the Chinese clothes flower garden. The Chinese style plate deduction has the same use value as other buttons, is more used for decorating and beautifying clothes, is particularly applied to national clothes, more embodies the aesthetic feeling of the clothes, and is the plate button on the Tang suit which gives people the deepest impression.
Most of the existing buttons are chemical buttons, wherein the chemical buttons are divided into organic buttons, resin buttons, combined buttons, urea buttons, paint buttons, electroplating buttons, changli buttons and the like. The buttons are used as agricultural wastes and are not easy to be digested by the earth, most buttons are treated by burning and making into feed, a large amount of carbon dioxide is generated while resources are wasted, and the natural environment is polluted, so that the environment-friendly buttons are provided.
Aiming at the phenomenon, Chinese patent No. 201710721258.4 provides an environment-friendly button which comprises, by weight, 10 ~ 30 parts of potato flour, 70 ~ 90 parts of corn flour, 1 ~ 2.5.5 parts of toner and 20 ~ 40 parts of adhesive, and the environment-friendly button does not pollute the environment, but has high cost and needs to be improved in hardness.
Therefore, the invention aims to provide the environment-friendly button which is high in hardness and low in cost.
Disclosure of Invention
In order to overcome the technical problems, the invention provides an environment-friendly button and a preparation method thereof, and the environment-friendly button is hard and low in cost.
The technical problem to be solved by the invention is realized by the following technical scheme:
an environment-friendly button comprises, by weight, 2 ~ 20 parts of potato flour, 5 ~ 40 parts of corn flour, 15 ~ 50 parts of corn flour, 0.5 ~ 3 parts of toner and 10 ~ 40 parts of a bonding agent.
As a preferable scheme, the environment-friendly button comprises, by weight, 8 ~ 12 parts of potato powder, 15 ~ 25 parts of corn powder, 38 ~ 45 parts of corn powder, 1.4 ~ 2.2.2 parts of toner and 25 ~ 35 parts of adhesive.
As a preferable scheme, the environment-friendly button comprises the following components in parts by weight: 10 parts of potato powder, 20 parts of corn powder, 40 parts of corn powder, 1.5 parts of toner and 28.5 parts of adhesive.
Preferably, the adhesive comprises, by weight, 35 ~ 50% of formaldehyde, 8 ~ 15% of ethylene glycol, 6 ~ 15% of ammonia water, 20 ~ 30% of urea and 4 ~ 10% of potato flour.
The invention also provides a preparation method of the environment-friendly button, which comprises the following steps:
(1) the material preparation step comprises mixing potato powder, corn powder, toner and adhesive in proportion, and stirring for 50 ~ 70 minutes to obtain blank making raw materials;
(2) blank making and drying: cutting the blank making raw materials into particles, and drying the particles to obtain a buckled blank;
(3) a buckle making and forming step: pressing the button blank into a button by using a hydraulic press;
(4) vehicle money punching: carrying out vehicle money processing on the button by using a scraper device and a punching device;
(5) a primary polishing step, polishing the buttons for 2 ~ 5 hours;
(6) and a fine polishing step, namely polishing the button for 6 ~ 10 hours to obtain the environment-friendly button.
In a preferable embodiment, the step of compounding is performed by stirring with a stirrer for 50 ~ 70 minutes.
Preferably, the drying step is a first drying step of drying in an oven at 50 ~ 70 ℃ for 30 ~ 60 minutes, and a second drying step of drying in an oven at 50 ~ 100 ℃ for 10 ~ 20 hours.
As a most preferred solution, the drying step is: primary drying at 60 ℃ for 45 minutes; the second drying step was carried out at a temperature of 70 ℃ for 15 hours.
As a preferable scheme, the initial polishing ingredient comprises 18 ~ 22 parts of aqueous gloss oil, 6 ~ 8 parts of grinding wax, 3 ~ 5 parts of water milling powder, 2 ~ 4 parts of cosmetic oil and 1 ~ 3 parts of lubricating oil for a sewing machine in parts by weight.
As a most preferred solution, the initial polishing formulation comprises, in parts by weight: 20 parts of water-based gloss oil, 7 parts of grinding wax, 4 parts of water grinding powder, 3 parts of cosmetic oil and 2 parts of sewing machine lubricating oil.
As a preferable scheme, the fine polishing ingredient comprises 28 ~ 32 parts of water-based gloss oil, 8 ~ 12 parts of grinding wax, 2 ~ 4 parts of water-milled powder, 1 ~ 3 parts of cosmetic oil and 0.5 ~ 1 parts of lubricating oil for a sewing machine by weight.
As a most preferred solution, the fine polishing formulation is: the fine polishing ingredient comprises the following components in parts by weight: 30 parts of water-based gloss oil, 10 parts of grinding wax, 3 parts of water grinding powder, 2 parts of cosmetic oil and 0.8 part of sewing machine lubricating oil.
As a preferable scheme, the water-based gloss oil comprises 6 ~ 8 parts of oil-soluble phenolic resin, 2 ~ 4 parts of emulsified silicone oil and 0.5 ~ 1 part of carboxymethyl cellulose in parts by weight.
As a most preferred embodiment, the aqueous gloss oil comprises, in parts by weight: 7 parts of oil-soluble phenolic resin, 3 parts of emulsified silicone oil and 0.8 part of carboxymethyl cellulose.
The invention has the beneficial effects that: (1) the environment-friendly button is prepared from natural renewable plant raw materials such as potato powder, corn powder and corn starch, and is simple in source, low in cost and decomposable;
(2) the environment-friendly button has more beautiful and glossy appearance and clear patterns; (3) does not cause environmental pollution and is environment-friendly; (4) the environment-friendly button is strong in stability, good in wear resistance and steam ironing resistance, the hardness of the button is improved by adjusting the proportion of the potato powder and the corn powder and adding the corn powder, and the cost of raw materials is reduced.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
An environment-friendly button, the environment-friendly button comprises the following components in parts by weight:
10 parts of potato powder, 20 parts of corn powder, 40 parts of corn powder, 1.5 parts of toner and 28.5 parts of adhesive.
The adhesive consists of the following substances in percentage by weight: 40% of formaldehyde, 12% of ethylene glycol, 10% of ammonia water, 28% of urea and 9% of potato powder.
The preparation method of the environment-friendly button comprises the following steps:
(1) the material preparation step: mixing potato powder, corn powder, toner and adhesive in proportion, and stirring for 60 minutes by using a stirrer to obtain a blank making raw material;
(2) blank making and drying: cutting the blank making raw materials into particles, and putting the particles into an oven for drying;
(3) a buckle making and forming step: pressing the button blank into a button by using a hydraulic press;
(4) vehicle money punching: carrying out vehicle money processing on the button by using a scraper device and a punching device;
(5) a primary polishing step: polishing the buttons for 3 hours;
(6) and (3) fine polishing: polishing the button for 8 hours to obtain the environment-friendly button.
The drying step is as follows: primary drying at 60 ℃ for 45 minutes; the second drying step was carried out at a temperature of 70 ℃ for 15 hours.
The initial polishing ingredient comprises the following components in parts by weight: 20 parts of water-based gloss oil, 7 parts of grinding wax, 4 parts of water grinding powder, 3 parts of cosmetic oil and 2 parts of sewing machine lubricating oil.
The fine polishing material comprises the following components: the fine polishing ingredient comprises the following components in parts by weight: 30 parts of water-based gloss oil, 10 parts of grinding wax, 3 parts of water grinding powder, 2 parts of cosmetic oil and 0.8 part of sewing machine lubricating oil.
The abrasive wax was a korean wax.
The water-based gloss oil comprises the following components in parts by weight: 7 parts of oil-soluble phenolic resin, 3 parts of emulsified silicone oil and 0.8 part of carboxymethyl cellulose.
Example 2
Example 2 is different from example 1 in the compounding ratio of the button, and the other parts are the same.
An environment-friendly button, the environment-friendly button comprises the following components in parts by weight: 2 parts of potato powder, 40 parts of corn powder, 15 parts of corn powder, 3 parts of toner and 10 parts of adhesive.
Example 3
Example 3 is different from example 1 in the compounding ratio of the button, and the other parts are the same.
An environment-friendly button, the button comprises the following components in parts by weight: 20 parts of potato powder, 5 parts of corn powder, 50 parts of corn powder, 0.5 part of toner and 40 parts of adhesive.
To further demonstrate the effect of the present invention, the following experiments were performed to verify the properties of the button of the present invention.
Comparative example 1
Comparative example 1 is different from example 1 in that the button was prepared by a different method, and the others were the same.
The button of this comparative example was prepared as described in patent No. 201710721258.4.
1. Abrasion resistance test
Uniformly mixing the buttons and the pumice powder, placing the mixture in a PVC cylinder, covering a cylinder cover, rotating the cylinder at the rotating speed of 120 revolutions per minute for 20 minutes, taking out the buttons, brushing the buttons by using a soft brush, comparing whether the surface of the tested buttons is different from that of a sample, and if not, passing the test.
2. Strength test
And (3) mounting the button on a tensiometer, gradually increasing the pressure load on the button until the surface of the button is cracked, and recording the reading of the tensiometer as the strength of the button when the crack is generated.
3. Resistance to corrosion by washing liquids
Sewing buttons on the multi-fiber lining fabric, wherein the interval between every two buttons is 10 cm, placing sufficient laundry detergent in a beaker, heating to 50, 60, 70 and 80 ℃ respectively, then placing the buttons, the multi-fiber lining fabric and the laundry detergent in a washing machine, rotating at the rotating speed of 120 r/min for 20 minutes, then taking out the buttons, cleaning, detecting the color change of the buttons and the fading condition of the fabric by using a gray card, and if the color fastness is greater than 4, the color spot is greater than 5, and no deformation or other defects exist, passing the test.
4. Steam ironing resistance
Sewing buttons on the multi-fiber lining fabric, wherein each button is 10 cm apart, opening an iron, the steam pressure is 0.45 ~ 0.55.55 MPa, ironing the sample for 6 seconds by using the iron, detecting the color change of the buttons and the fading condition of the fabric by using a gray card, and passing the test if the color fastness is more than 4, the color spot is more than 5, and no deformation or other defects exist.
5. Heavy metal detection
The heavy metal detection button heavy metal tester is used for detecting according to GB/T 21295-2007.
TABLE 1 button detection index table
As can be seen from table 1, example 1 is the best embodiment, examples 1, 2 and 3 all pass relevant tests, the performance is better than that of a common button, the environment-friendly button disclosed by the invention has higher hardness and lower cost than the button disclosed by patent No. 201710721258.4, the hardness of the button is improved and the cost is reduced by adding corn flour and reducing the content of corn flour and potato flour compared with the button disclosed by patent No. 201710721258.4, but the button formula disclosed by the invention cannot be matched with the button preparation method disclosed by patent No. 201710721258.4, namely the button formula disclosed by the invention has excellent effect when matched with the button preparation method disclosed by the invention.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. An environment-friendly button is characterized by comprising, by weight, 2 ~ 20 parts of potato flour, 5 ~ 40 parts of corn flour, 15 ~ 50 parts of corn flour, 0.5 ~ 3 parts of toner and 10 ~ 40 parts of adhesive.
2. The button of claim 1, wherein the button comprises 8 ~ 12 parts of potato flour, 15 ~ 25 parts of corn flour, 38 ~ 45 parts of corn flour, 1.4 ~ 2.2.2 parts of toner and 25 ~ 35 parts of adhesive.
3. The environmental button according to claim 1, wherein the button comprises, in parts by weight: 10 parts of potato powder, 20 parts of corn powder, 40 parts of corn powder, 1.5 parts of toner and 28.5 parts of adhesive.
4. The button of claim 1, wherein the binder is selected from the group consisting of formaldehyde 35 ~ 50%, ethylene glycol 8 ~ 15%, ammonia 6 ~ 15%, urea 20 ~ 30%, potato flour 4 ~ 10%.
5. The preparation method of the environment-friendly button is characterized by comprising the following steps:
(1) the material preparation step comprises mixing potato powder, corn powder, toner and adhesive in proportion, and stirring for 50 ~ 70 minutes to obtain blank making raw materials;
(2) blank making and drying: cutting the blank making raw materials into particles, and drying the particles to obtain a buckled blank;
(3) a buckle making and forming step: pressing the button blank into a button by using a hydraulic press;
(4) vehicle money punching: carrying out vehicle money processing on the button by using a scraper device and a punching device;
(5) a primary polishing step, polishing the buttons for 2 ~ 5 hours;
(6) and a fine polishing step, namely polishing the button for 6 ~ 10 hours to obtain the environment-friendly button.
6. The method for preparing environment-friendly button according to claim 5, wherein the step of compounding is stirring for 55 ~ 65 minutes.
7. The preparation method of the environmental button as claimed in claim 5, wherein the drying step comprises a first drying step in an oven at 50 ~ 70 ℃ for 30 ~ 60 minutes and a second drying step in an oven at 50 ~ 100 ℃ for 10 ~ 20 hours.
8. The method for preparing environment-friendly button according to claim 5, wherein the initial polishing formulation comprises, by weight, 18 ~ 22 parts of water-based varnish, 6 ~ 8 parts of grinding wax, 3 ~ 5 parts of water-milled powder, 2 ~ 4 parts of cosmetic oil and 1 ~ 3 parts of lubricating oil for clothes-horse.
9. The method for preparing environment-friendly button according to claim 5, wherein the fine polishing ingredient comprises 28 ~ 32 parts of water-based varnish, 8 ~ 12 parts of grinding wax, 2 ~ 4 parts of water-milled powder, 1 ~ 3 parts of cosmetic oil and 0.5 ~ 1 parts of lubricating oil for sewing machine.
10. The aqueous varnish according to any one of claims 8 or 9, wherein the aqueous varnish comprises 6 ~ 8 parts by weight of oil-soluble phenolic resin, 2 ~ 4 parts by weight of silicone emulsion, and 0.5 ~ 1 parts by weight of carboxymethyl cellulose.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113561538A (en) * | 2021-08-17 | 2021-10-29 | 高华文 | Manufacturing method of degradable button |
CN113621224A (en) * | 2021-09-03 | 2021-11-09 | 嘉兴赵氏钮扣股份有限公司 | Adhesive and button waste recycling process with same |
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CN113621224A (en) * | 2021-09-03 | 2021-11-09 | 嘉兴赵氏钮扣股份有限公司 | Adhesive and button waste recycling process with same |
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