CN110540789A - epoxy zinc-rich anticorrosive primer and preparation method thereof - Google Patents
epoxy zinc-rich anticorrosive primer and preparation method thereof Download PDFInfo
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- CN110540789A CN110540789A CN201910828482.2A CN201910828482A CN110540789A CN 110540789 A CN110540789 A CN 110540789A CN 201910828482 A CN201910828482 A CN 201910828482A CN 110540789 A CN110540789 A CN 110540789A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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Abstract
the invention relates to the technical field of anticorrosive primer, in particular to an epoxy zinc-rich anticorrosive primer and a preparation method thereof, wherein the epoxy zinc-rich anticorrosive primer comprises a component A and a component B, wherein the component A comprises epoxy resin, zinc powder, organic silicon rubber, organic bentonite, fumed silica and an organic solvent A; the component B comprises the following raw materials in parts by weight: curing agent and organic solvent B. According to the invention, the organic silicon rubber is added into the coating, and under a certain curing condition, the epoxy group of the epoxy resin and the silicon oxygen group of the organic silicon rubber can be crosslinked, so that the epoxy group is consumed, the crosslinking density of a cured product is reduced, and the flexibility of the coating can be effectively improved under the action of physical curing of the organic silicon rubber; and the alkoxy of the organic silicon rubber is also reactive with the hydroxyl of the zinc powder, so that the surface property of the zinc powder can be improved, the dispersibility of the zinc powder in the coating is improved, and the overall mechanical property of the coating is also improved.
Description
Technical Field
The invention relates to the technical field of anticorrosive primer, in particular to an epoxy zinc-rich anticorrosive primer and a preparation method thereof.
Background
the epoxy zinc-rich primer takes epoxy resin as a base material, polyamide as a curing agent, superfine zinc powder as a main antirust pigment, and a certain amount of aluminum paste and iron oxide red are added, so that the heat resistance can be improved, and the generation of zinc salt can be prevented. The paint has the advantages of excellent cathodic protection effect, excellent corrosion resistance, quick drying, strong adhesive force, good impact resistance and wear resistance, and good gas cutting performance and weldability. Has excellent adhesive force with steel after sand blasting treatment. The antirust primer is mainly used for temporary protection and corrosion prevention of steel surfaces, and can also be used for antirust primers of ships, bridges, offshore platforms and steel structures.
Because the zinc powder in the zinc-rich coating has high consumption and hydrophilic and oleophobic properties, the compatibility with epoxy resin is poor, the uniform dispersion of the zinc powder is difficult to realize, and the comprehensive performance of the coating is reduced.
Disclosure of Invention
in order to overcome the defects and shortcomings in the prior art, the invention aims to provide an epoxy zinc-rich anti-corrosion primer with excellent comprehensive performance and a preparation method thereof.
The purpose of the invention is realized by the following technical scheme:
an epoxy zinc-rich anti-corrosion primer is composed of a component A and a component B according to the weight ratio of 6-10: 1:
the component A comprises the following raw materials in parts by weight:
the component B comprises the following raw materials in parts by weight:
40-60 parts of curing agent
40-60 parts of organic solvent B.
When the epoxy resin is cured, internal stress is easily generated due to volume shrinkage, and the coating is also easily subjected to stress concentration due to the problem that the zinc powder is high in content and difficult to disperse, so that the overall mechanical property of the coating is poor. According to the invention, the organic silicon rubber is added into the coating, and under a certain curing condition, the epoxy group of the epoxy resin and the silicon oxygen group of the organic silicon rubber can be crosslinked, so that the epoxy group is consumed, the crosslinking density of a cured product is reduced, and the flexibility of the coating can be effectively improved under the action of physical curing of the organic silicon rubber; and the alkoxy of the organic silicon rubber is also reactive with the hydroxyl of the zinc powder, so that the surface property of the zinc powder can be improved, the dispersibility of the zinc powder in the coating is improved, and the overall mechanical property of the coating is also improved.
The organic silicon rubber is prepared from the following raw materials in parts by weight:
the preferred organic silicon rubber of the invention is fluorosilicone rubber, has better weather resistance and corrosion resistance compared with common silicon rubber, and is more favorable for exerting the corrosion resistance of the coating of the invention.
Wherein the vulcanizing agent is at least one of 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide, dicumyl peroxide and benzoyl peroxide.
the vulcanizing agent adopted by the invention is a peroxide vulcanizing agent, the vulcanizing time is short, and the corrosion of the zinc powder caused by the intervention of sulfur element is avoided. Preferably, the vulcanizing agent consists of 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide and dicumyl peroxide in a weight ratio of 2-3: 1. Compared with the three single vulcanizing agents, the preferable compound vulcanizing agent can better improve the toughness of the organic silicon rubber, thereby improving the flexibility of the coating.
wherein the release agent is calcium stearate and/or zinc stearate.
Wherein the structural control agent is hydroxyl silicone oil.
The addition of the hydroxyl silicone oil can improve the active group content of the organic silicone rubber, strengthen the combination effect of the organic silicone rubber and the zinc powder, and improve the dispersibility of the coating, so that the zinc-rich coating has higher hardness and better impact resistance.
the preparation method of the organic silicon rubber comprises the following steps:
(1) carrying out primary banburying on the fluorosilicone crude rubber and the vinyl polydimethylsiloxane at the temperature of 100-120 ℃ for 20-40 min;
(2) adding a structure control agent and a release agent for secondary banburying at the temperature of 120-140 ℃ for 20-30min, and then discharging to obtain a rubber compound;
(3) Adding a vulcanizing agent into the rubber compound for mixing, and then vulcanizing in a vulcanizing machine to obtain vulcanized rubber;
(4) and (3) crushing the vulcanized rubber by using a liquid nitrogen freezing crusher to obtain the organic silicon rubber.
Nitrile rubber is one of the common raw materials in the field of coating technology, because nitrile is prepared from butadiene and acrylonitrile by emulsion polymerization and can be made into powder by spray drying. Vulcanized rubber is vulcanized in a mold, and therefore has a certain volume. According to the invention, vulcanized rubber is crushed, so that the vulcanized rubber can be applied to the epoxy zinc-rich coating, the modification effect of the organic silicon rubber is fully utilized, and the overall performance of the coating is obviously improved.
wherein the vulcanization temperature is 150-170 ℃, and the vulcanization time is 2-4 h.
Wherein the fineness of the organic silicon rubber is 100-200 meshes. The fineness of the organic silicon rubber is preferably 100-200 meshes, so that the cost can be effectively controlled and the performance of the coating can be improved.
Wherein the curing agent is a polyamide curing agent.
The preparation method of the epoxy zinc-rich anti-corrosion primer comprises the following steps:
A. Preparation of component A: dissolving epoxy resin in an organic solvent A, adding zinc powder, organic bentonite, fumed silica and organic silicon rubber, mixing and dispersing to obtain a component A;
B. preparation of component B: and adding the curing agent into the organic solvent B for mixing and dispersing to obtain the component B.
The invention has the beneficial effects that: according to the invention, the organic silicon rubber is added into the coating, and under a certain curing condition, the epoxy group of the epoxy resin and the silicon oxygen group of the organic silicon rubber can be crosslinked, so that the epoxy group is consumed, the crosslinking density of a cured product is reduced, and the flexibility of the coating can be effectively improved under the action of physical curing of the organic silicon rubber; and the alkoxy of the organic silicon rubber is also reactive with the hydroxyl of the zinc powder, so that the surface property of the zinc powder can be improved, the dispersibility of the zinc powder in the coating is improved, and the overall mechanical property of the coating is also improved.
Detailed Description
the present invention will be further described with reference to the following examples for facilitating understanding of those skilled in the art, and the description of the embodiments is not intended to limit the present invention.
Example 1
An epoxy zinc-rich anti-corrosion primer is composed of a component A and a component B according to the weight ratio of 6-10: 1:
The component A comprises the following raw materials in parts by weight:
the component B comprises the following raw materials in parts by weight:
40 portions of curing agent
40 parts of organic solvent B.
the organic silicon rubber is prepared from the following raw materials in parts by weight:
Wherein the vulcanizing agent is 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide.
wherein the release agent is calcium stearate.
wherein the structural control agent is hydroxyl silicone oil.
The preparation method of the organic silicon rubber comprises the following steps:
(1) carrying out primary banburying on the fluorosilicone raw rubber and the vinyl polydimethylsiloxane at the temperature of 100 ℃ for 20 min;
(2) Adding a structure control agent and a release agent for secondary banburying at the temperature of 120 ℃ for 20min, and then discharging to obtain a rubber compound;
(3) Adding a vulcanizing agent into the rubber compound for mixing, and then vulcanizing in a vulcanizing machine to obtain vulcanized rubber;
(4) And (3) crushing the vulcanized rubber by using a liquid nitrogen freezing crusher to obtain the organic silicon rubber.
wherein the vulcanization temperature is 150 ℃, and the vulcanization time is 2 h.
Wherein the fineness of the organic silicon rubber is 100 meshes.
wherein the curing agent is a polyamide curing agent.
Wherein the organic solvent A and the organic solvent B are both xylene.
The preparation method of the epoxy zinc-rich anti-corrosion primer comprises the following steps:
A. Preparation of component A: dissolving epoxy resin in an organic solvent A, adding zinc powder, organic bentonite, fumed silica and organic silicon rubber, mixing and dispersing to obtain a component A;
B. preparation of component B: and adding the curing agent into the organic solvent B for mixing and dispersing to obtain the component B.
example 2
An epoxy zinc-rich anti-corrosion primer is composed of a component A and a component B according to the weight ratio of 6-10: 1:
the component A comprises the following raw materials in parts by weight:
The component B comprises the following raw materials in parts by weight:
60 portions of curing agent
And 60 parts of an organic solvent B.
The organic silicon rubber is prepared from the following raw materials in parts by weight:
wherein the vulcanizing agent is benzoyl peroxide.
wherein the release agent is zinc stearate.
Wherein the structural control agent is hydroxyl silicone oil.
the preparation method of the organic silicon rubber comprises the following steps:
(1) Carrying out primary banburying on the fluorosilicone raw rubber and the vinyl polydimethylsiloxane at the temperature of 120 ℃ for 40 min;
(2) Adding a structure control agent and a release agent for secondary banburying at the temperature of 140 ℃ for 30min, and then discharging to obtain a rubber compound;
(3) Adding a vulcanizing agent into the rubber compound for mixing, and then vulcanizing in a vulcanizing machine to obtain vulcanized rubber;
(4) And (3) crushing the vulcanized rubber by using a liquid nitrogen freezing crusher to obtain the organic silicon rubber.
Wherein the vulcanization temperature is 170 ℃, and the vulcanization time is 4 h.
wherein the fineness of the organic silicon rubber is 200 meshes.
Wherein the curing agent is a polyamide curing agent.
Wherein the organic solvent A is xylene, and the organic solvent B is composed of xylene and n-butanol according to a weight ratio of 7: 3.
The preparation method of the epoxy zinc-rich anti-corrosion primer comprises the following steps:
A. preparation of component A: dissolving epoxy resin in an organic solvent A, adding zinc powder, organic bentonite, fumed silica and organic silicon rubber, mixing and dispersing to obtain a component A;
B. preparation of component B: and adding the curing agent into the organic solvent B for mixing and dispersing to obtain the component B.
example 3
An epoxy zinc-rich anti-corrosion primer is composed of a component A and a component B according to the weight ratio of 6-10: 1:
The component A comprises the following raw materials in parts by weight:
The component B comprises the following raw materials in parts by weight:
50 portions of curing agent
And 50 parts of an organic solvent B.
The organic silicon rubber is prepared from the following raw materials in parts by weight:
wherein the vulcanizing agent consists of 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide and dicumyl peroxide according to the weight ratio of 2.5: 1.
The release agent is composed of calcium stearate and zinc stearate according to the weight ratio of 1: 1.
Wherein the structural control agent is hydroxyl silicone oil.
The preparation method of the organic silicon rubber comprises the following steps:
(1) Carrying out primary banburying on the fluorosilicone raw rubber and the vinyl polydimethylsiloxane at the temperature of 110 ℃ for 30 min;
(2) Adding a structure control agent and a release agent for secondary banburying at the temperature of 130 ℃ for 25min, and then discharging to obtain a rubber compound;
(3) adding a vulcanizing agent into the rubber compound for mixing, and then vulcanizing in a vulcanizing machine to obtain vulcanized rubber;
(4) And (3) crushing the vulcanized rubber by using a liquid nitrogen freezing crusher to obtain the organic silicon rubber.
Wherein the vulcanization temperature is 160 ℃, and the vulcanization time is 3 h.
Wherein the fineness of the organic silicon rubber is 150 meshes.
Wherein the curing agent is a polyamide curing agent.
Wherein the organic solvent A consists of dimethylbenzene and n-butanol according to the weight ratio of 2:1, and the organic solvent B consists of dimethylbenzene and n-butanol according to the weight ratio of 7: 3.
the preparation method of the epoxy zinc-rich anti-corrosion primer comprises the following steps:
A. preparation of component A: dissolving epoxy resin in an organic solvent A, adding zinc powder, organic bentonite, fumed silica and organic silicon rubber, mixing and dispersing to obtain a component A;
B. Preparation of component B: and adding the curing agent into the organic solvent B for mixing and dispersing to obtain the component B.
The coating method of the present example was: and (3) uniformly mixing the component A and the component B, spraying the mixture on a base material, and curing for 20min at 70 ℃.
Comparative example 1
this comparative example differs from example 3 in that:
The organic silicon rubber is replaced by 150-mesh nitrile rubber powder with equal mass.
comparative example 2
this comparative example differs from example 3 in that:
the component A does not contain organic silicon rubber, and the zinc powder is treated by a silane coupling agent kh 550.
comparative example 3
This comparative example differs from example 3 in that:
the coating method of the comparative example was to mix the component a and the component B uniformly, spray the mixture on a substrate, and perform natural curing at room temperature.
The paint films of example 3 and comparative examples 1 to 3 were tested according to GB/T6739-2006, GB/T1720-1979, GB/T1731-1993, GB/T1732-1993 and GB/T1771-2007 for paint film hardness, paint film adhesion, paint film flexibility, paint film impact resistance and neutral salt spray resistance, respectively, with the test results as follows:
As can be seen from comparative example 1, the nitrile rubber has no obvious crosslinking effect on the coating, and the nitrile rubber plays a main role in physical film formation, so that the crosslinking degree of a paint film is higher, the integral hardness is higher, but the flexibility and the adhesiveness of the paint film are poorer, and the corrosion resistance of the paint film is more common due to uneven dispersion of zinc powder; as can be seen from comparative example 2, the silane coupling agent modified zinc powder can also effectively improve the dispersibility of the zinc powder, and after no silicone rubber participates in the zinc powder, the relative content of the zinc powder is improved, so that the corrosion resistance and hardness of the coating are relatively high, and the flexibility is improved compared with comparative example 1, while the nitrile rubber is an elastomer with better flexibility, which indicates that the physical blending of a rubber body and the epoxy resin have phase separation and are not beneficial to the improvement of the toughness of a paint film; as can be seen from comparative example 3, when the curing temperature is lower, the crosslinking action of the silicone rubber and the epoxy resin is weaker, so that the degree of crosslinking of the epoxy resin and the curing agent in the paint film is increased, the overall hardness of the paint film is increased, the flexibility is reduced, and the dispersibility of the zinc powder is not significantly improved, so that the paint film has substantially no advantage of corrosion resistance as compared with comparative example 1.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.
Claims (10)
1. An epoxy zinc-rich anti-corrosive primer is characterized in that: the composition comprises a component A and a component B according to the weight ratio of 6-10: 1:
the component A comprises the following raw materials in parts by weight:
The component B comprises the following raw materials in parts by weight:
40-60 parts of curing agent
40-60 parts of organic solvent B.
2. the epoxy zinc-rich corrosion resistant primer according to claim 1, wherein: the organic silicon rubber is prepared from the following raw materials in parts by weight:
3. The epoxy zinc-rich corrosion resistant primer according to claim 2, wherein: the vulcanizing agent is at least one of 2, 5-dimethyl-2, 5-di-tert-butyl hexane peroxide, dicumyl peroxide and benzoyl peroxide.
4. The epoxy zinc-rich corrosion resistant primer according to claim 2, wherein: the release agent is calcium stearate and/or zinc stearate.
5. The epoxy zinc-rich corrosion resistant primer according to claim 2, wherein: the structural control agent is hydroxyl silicone oil.
6. the epoxy zinc-rich corrosion resistant primer according to claim 2, wherein: the preparation method of the organic silicon rubber comprises the following steps:
(1) Carrying out primary banburying on the fluorosilicone crude rubber and the vinyl polydimethylsiloxane at the temperature of 100-120 ℃ for 20-40 min;
(2) adding a structure control agent and a release agent for secondary banburying at the temperature of 120-140 ℃ for 20-30min, and then discharging to obtain a rubber compound;
(3) Adding a vulcanizing agent into the rubber compound for mixing, and then vulcanizing in a vulcanizing machine to obtain vulcanized rubber;
(4) And (3) crushing the vulcanized rubber by using a liquid nitrogen freezing crusher to obtain the organic silicon rubber.
7. the epoxy zinc-rich corrosion resistant primer according to claim 6, wherein: the vulcanization temperature is 150-170 ℃, and the vulcanization time is 2-4 h.
8. The epoxy zinc-rich corrosion resistant primer according to claim 6, wherein: the fineness of the organic silicon rubber is 100-200 meshes.
9. The epoxy zinc-rich corrosion resistant primer according to claim 1, wherein: the curing agent is a polyamide curing agent.
10. The method for preparing the epoxy zinc-rich corrosion resistant primer according to any one of claims 1 to 9, wherein the method comprises the following steps: the method comprises the following steps:
A. preparation of component A: dissolving epoxy resin in an organic solvent A, adding zinc powder, organic bentonite, fumed silica and organic silicon rubber, mixing and dispersing to obtain a component A;
B. preparation of component B: and adding the curing agent into the organic solvent B for mixing and dispersing to obtain the component B.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114181594A (en) * | 2022-02-15 | 2022-03-15 | 深圳市嘉达节能环保科技有限公司 | Zinc-coated resin compound and preparation method and application thereof |
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|---|---|---|---|---|
| JPS4879234A (en) * | 1972-01-26 | 1973-10-24 | ||
| CN101177486A (en) * | 2007-11-02 | 2008-05-14 | 广东信力特种橡胶制品有限公司 | Method for preparing fluorine silicon rubber base glue |
| CN102808334A (en) * | 2012-08-17 | 2012-12-05 | 杭州玖合新材料有限公司 | Thermosetting resin composite facing material and preparation method thereof |
| CN103881531A (en) * | 2014-03-10 | 2014-06-25 | 国家电网公司 | Epoxy zinc-enriched coating and preparation method thereof |
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2019
- 2019-09-03 CN CN201910828482.2A patent/CN110540789A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4879234A (en) * | 1972-01-26 | 1973-10-24 | ||
| CN101177486A (en) * | 2007-11-02 | 2008-05-14 | 广东信力特种橡胶制品有限公司 | Method for preparing fluorine silicon rubber base glue |
| CN102808334A (en) * | 2012-08-17 | 2012-12-05 | 杭州玖合新材料有限公司 | Thermosetting resin composite facing material and preparation method thereof |
| CN103881531A (en) * | 2014-03-10 | 2014-06-25 | 国家电网公司 | Epoxy zinc-enriched coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114181594A (en) * | 2022-02-15 | 2022-03-15 | 深圳市嘉达节能环保科技有限公司 | Zinc-coated resin compound and preparation method and application thereof |
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Application publication date: 20191206 |