CN110538659B - 用于裂解焦油精制的催化剂 - Google Patents
用于裂解焦油精制的催化剂 Download PDFInfo
- Publication number
- CN110538659B CN110538659B CN201810529547.9A CN201810529547A CN110538659B CN 110538659 B CN110538659 B CN 110538659B CN 201810529547 A CN201810529547 A CN 201810529547A CN 110538659 B CN110538659 B CN 110538659B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- tar
- coal tar
- parts
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 111
- 238000007670 refining Methods 0.000 title claims abstract description 8
- 239000011280 coal tar Substances 0.000 claims abstract description 48
- 239000011269 tar Substances 0.000 claims abstract description 27
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 26
- 239000000295 fuel oil Substances 0.000 claims abstract description 15
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005977 Ethylene Substances 0.000 claims abstract description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 4
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims description 18
- 229910052680 mordenite Inorganic materials 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 2
- 238000006477 desulfuration reaction Methods 0.000 abstract description 10
- 230000023556 desulfurization Effects 0.000 abstract description 10
- 239000000446 fuel Substances 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 28
- 229910052739 hydrogen Inorganic materials 0.000 description 28
- 239000001257 hydrogen Substances 0.000 description 28
- 239000003921 oil Substances 0.000 description 28
- 238000004073 vulcanization Methods 0.000 description 28
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
- 239000000843 powder Substances 0.000 description 24
- 238000002360 preparation method Methods 0.000 description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 19
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 238000011156 evaluation Methods 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 239000011593 sulfur Substances 0.000 description 16
- 229910052717 sulfur Inorganic materials 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 15
- 239000012018 catalyst precursor Substances 0.000 description 15
- 239000007864 aqueous solution Substances 0.000 description 14
- 239000010949 copper Substances 0.000 description 10
- 239000003502 gasoline Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 8
- 241000219782 Sesbania Species 0.000 description 8
- QPZLAIPVODCKBU-UHFFFAOYSA-O [N+](=O)([O-])[O-].[NH4+].[Co] Chemical compound [N+](=O)([O-])[O-].[NH4+].[Co] QPZLAIPVODCKBU-UHFFFAOYSA-O 0.000 description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 8
- 239000002283 diesel fuel Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- 239000003292 glue Substances 0.000 description 8
- 239000003350 kerosene Substances 0.000 description 8
- 239000002808 molecular sieve Substances 0.000 description 8
- 229910017604 nitric acid Inorganic materials 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910052787 antimony Inorganic materials 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- -1 copper nitrate-antimony trichloride Chemical compound 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- XPFWRDAWFVVLPR-UHFFFAOYSA-H [Bi+3].[Sb](Cl)(Cl)Cl.[Cl-].[Cl-].[Cl-] Chemical compound [Bi+3].[Sb](Cl)(Cl)Cl.[Cl-].[Cl-].[Cl-] XPFWRDAWFVVLPR-UHFFFAOYSA-H 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 1
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
- B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810529547.9A CN110538659B (zh) | 2018-05-29 | 2018-05-29 | 用于裂解焦油精制的催化剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810529547.9A CN110538659B (zh) | 2018-05-29 | 2018-05-29 | 用于裂解焦油精制的催化剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110538659A CN110538659A (zh) | 2019-12-06 |
CN110538659B true CN110538659B (zh) | 2021-12-28 |
Family
ID=68700973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810529547.9A Active CN110538659B (zh) | 2018-05-29 | 2018-05-29 | 用于裂解焦油精制的催化剂 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN110538659B (zh) |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1481958A (en) * | 1974-11-08 | 1977-08-03 | Coal Ind | Supercritical extraction and concurrent catalytic hydrogenation of coal digests |
JPH04122789A (ja) * | 1990-09-14 | 1992-04-23 | Osaka Gas Co Ltd | 重質油の接触水素化分解方法 |
CN1388220A (zh) * | 2001-05-30 | 2003-01-01 | 中国石油化工股份有限公司 | 具有脱硫作用的分子筛组合物及其制备 |
CN1903995A (zh) * | 2005-07-28 | 2007-01-31 | 中国石油化工股份有限公司 | 一种以轻烃为原料的催化重整方法 |
CN101037614A (zh) * | 2006-03-17 | 2007-09-19 | 中国石油天然气股份有限公司 | 一种加氢精制催化剂、制备方法及应用 |
CN101302439A (zh) * | 2008-06-24 | 2008-11-12 | 同济大学 | 煤焦油沥青轻质化制油的加氢催化剂及其制备方法 |
CN102068992A (zh) * | 2010-12-10 | 2011-05-25 | 中国科学院过程工程研究所 | 一种煤焦油制燃料油加氢精制催化剂及其制备和应用方法 |
CN103289740A (zh) * | 2013-01-23 | 2013-09-11 | 大连理工大学 | 一种煤焦油制清洁燃料油的方法 |
CN106635162A (zh) * | 2015-10-28 | 2017-05-10 | 中国石油化工股份有限公司 | 一种低碳烷烃异构化方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7799315B2 (en) * | 2003-06-11 | 2010-09-21 | Steven Amendola | Thermochemical hydrogen produced from a vanadium decomposition cycle |
-
2018
- 2018-05-29 CN CN201810529547.9A patent/CN110538659B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1481958A (en) * | 1974-11-08 | 1977-08-03 | Coal Ind | Supercritical extraction and concurrent catalytic hydrogenation of coal digests |
JPH04122789A (ja) * | 1990-09-14 | 1992-04-23 | Osaka Gas Co Ltd | 重質油の接触水素化分解方法 |
CN1388220A (zh) * | 2001-05-30 | 2003-01-01 | 中国石油化工股份有限公司 | 具有脱硫作用的分子筛组合物及其制备 |
CN1903995A (zh) * | 2005-07-28 | 2007-01-31 | 中国石油化工股份有限公司 | 一种以轻烃为原料的催化重整方法 |
CN101037614A (zh) * | 2006-03-17 | 2007-09-19 | 中国石油天然气股份有限公司 | 一种加氢精制催化剂、制备方法及应用 |
CN101302439A (zh) * | 2008-06-24 | 2008-11-12 | 同济大学 | 煤焦油沥青轻质化制油的加氢催化剂及其制备方法 |
CN102068992A (zh) * | 2010-12-10 | 2011-05-25 | 中国科学院过程工程研究所 | 一种煤焦油制燃料油加氢精制催化剂及其制备和应用方法 |
CN103289740A (zh) * | 2013-01-23 | 2013-09-11 | 大连理工大学 | 一种煤焦油制清洁燃料油的方法 |
CN106635162A (zh) * | 2015-10-28 | 2017-05-10 | 中国石油化工股份有限公司 | 一种低碳烷烃异构化方法 |
Also Published As
Publication number | Publication date |
---|---|
CN110538659A (zh) | 2019-12-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101927167B (zh) | 一种复合型煤焦油加氢催化剂及其制备方法 | |
CN102068992B (zh) | 一种煤焦油制燃料油加氢精制催化剂及其制备和应用方法 | |
CN102886274B (zh) | 一种煤焦油及乙烯焦油加氢处理催化剂及其制备方法 | |
CN103289740A (zh) | 一种煤焦油制清洁燃料油的方法 | |
CN109158100B (zh) | 一种催化裂解废塑料生产燃料油的催化剂及其制备方法 | |
CN110538676B (zh) | 裂解焦油加氢精制的催化剂 | |
CN110540864B (zh) | 用于裂解焦油精制的方法 | |
CN109569700B (zh) | 用于焦油制燃料油加氢催化剂 | |
CN109569635B (zh) | 用于焦油生产燃料油加氢催化剂 | |
CN110538659B (zh) | 用于裂解焦油精制的催化剂 | |
CN101302439A (zh) | 煤焦油沥青轻质化制油的加氢催化剂及其制备方法 | |
CN110538660B (zh) | 用于裂解焦油加氢精制的催化剂 | |
CN110540865B (zh) | 裂解焦油加氢精制的方法 | |
CN110538658B (zh) | 用于裂解焦油加氢精制的方法 | |
CN103122256B (zh) | 一种W-Mo-Ni催化剂在粗苯和洗油混合物加氢中的应用 | |
CN109575989B (zh) | 用于焦油制燃料油的方法 | |
CN109569578B (zh) | 用于焦油制取燃料油加氢催化剂 | |
CN106925281B (zh) | Ni基双金属催化剂及其制备方法和应用 | |
CN109575986B (zh) | 用于焦油生产燃料油的方法 | |
CN109575985B (zh) | 用于焦油制取燃料油的方法 | |
CN109575988B (zh) | 焦油制燃料油的方法 | |
CN109575987B (zh) | 焦油加氢制燃料油的方法 | |
CN109569707B (zh) | 焦油加氢制燃料油的催化剂 | |
CN109569708B (zh) | 焦油制燃料油加氢催化剂 | |
CN103146429A (zh) | 一种液化气加氢处理的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240621 Address after: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee after: CHINA PETROLEUM & CHEMICAL Corp. Country or region after: China Patentee after: Sinopec (Shanghai) Petrochemical Research Institute Co.,Ltd. Address before: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen Patentee before: CHINA PETROLEUM & CHEMICAL Corp. Country or region before: China Patentee before: SHANGHAI Research Institute OF PETROCHEMICAL TECHNOLOGY SINOPEC |
|
TR01 | Transfer of patent right |