CN110527757A - A kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof - Google Patents
A kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof Download PDFInfo
- Publication number
- CN110527757A CN110527757A CN201910902171.6A CN201910902171A CN110527757A CN 110527757 A CN110527757 A CN 110527757A CN 201910902171 A CN201910902171 A CN 201910902171A CN 110527757 A CN110527757 A CN 110527757A
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- parts
- perovskite oxide
- added
- castor oil
- color inhibition
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Links
- 230000005764 inhibitory process Effects 0.000 title claims abstract description 14
- 235000004443 Ricinus communis Nutrition 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000004359 castor oil Substances 0.000 claims abstract description 27
- 235000019438 castor oil Nutrition 0.000 claims abstract description 27
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 27
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 claims abstract description 21
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910010252 TiO3 Inorganic materials 0.000 claims abstract description 12
- 239000000908 ammonium hydroxide Substances 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 12
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229940001584 sodium metabisulfite Drugs 0.000 claims abstract description 12
- 235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000010792 warming Methods 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000006210 lotion Substances 0.000 abstract description 19
- 239000010985 leather Substances 0.000 abstract description 17
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 238000004383 yellowing Methods 0.000 abstract description 6
- 229960001777 castor oil Drugs 0.000 description 23
- 239000011575 calcium Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 150000002927 oxygen compounds Chemical class 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 102000008186 Collagen Human genes 0.000 description 3
- 108010035532 Collagen Proteins 0.000 description 3
- 229920001436 collagen Polymers 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 240000000528 Ricinus communis Species 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 229910002971 CaTiO3 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
Abstract
The present invention relates to a kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof, the environment-friendly type color inhibition lotion of preparation can effectively promote the anti-yellowing property of crust leather, and can enhance the binding ability and clean absorption rate of lotion after use.The present invention uses following raw material to be made: in terms of dry mass part, 43.3 parts -44.1 parts of castor oil；Nanometer zirconium-aluminium codope perovskite oxide Zr0.05Al0.1Ca0.85TiO31.7 parts -2.5 parts；14 parts -14.8 parts of maleic anhydride；The sodium metabisulfite solution that 14.9 parts -26.7 parts of pH is 8；Appropriate ammonium hydroxide；26.1 parts -26.9 parts of deionized water.
Description
Technical field
The present invention relates to a kind of modified castor oil based emulsions and preparation method thereof, and in particular to a kind of color inhibition type perovskite
Oxide modifying castor oil lotion and preparation method thereof.
Background technique
Lotion can assign the certain physical mechanical property of leather, plentiful soft feel, be widely used in leather processing and produced
Cheng Zhong.Currently, the common lotion oil base body of leather has mineral oil, vegetable and animals oils, mineral oil belongs to non-renewable resources, animal oil
It is difficult to be widely used because of its unhappy smell and it typically is solid-state due to, and vegetable oil has under from a wealth of sources, cheap, room temperature and is in
The advantages that liquid the first choice as lotion oil base body.
Castor-oil plant is one of the ten big oil crops that the current whole world is found, is a kind of higher plant of fat content.China
It is castor oil Fu Chan state, yield is located at third place in the world, and the main place of production concentrates on the ground such as Xinjiang, northeast.Castor oil belongs to non-food
With oil, it is uniquely to contain hydroxyl, renewable, biodegradable, cheap vegetable oil.Succinate sulfonated castor oil
The advantages that cheap environmentally friendly, from a wealth of sources with it, can be applied in leather processing technique, and can get good economic benefit.
And in practical applications, especially light leather is in use often due to the unsaturated bond in lotion is oxidized
Leather xanthochromia occurs, greatly limits the service life of light color leather.Therefore, in leather often with adding UV absorbing material in lotion
It is one of the key technology for improving leather color inhibition.
Perovskite type metal oxide chemical expression can be used to ABO3Expression, crystal structure are the compound gold of cubic system
Belong to oxide and can be used as excellent UV absorbing material with preferable structural stability and uv absorption property.This is received
Rice corpuscles is introduced into lotion, can be obviously improved the anti-yellowing property of crust leather after stuffing.Meanwhile the zirconium with flexibility, aluminium being doped into
Enter Ca-Ti ore type CaTiO3When middle, it often will appear cation vacancy, this will make active group on nanoparticle and collagen
And anionic emulsion is had an effect, make grease in conjunction with leather more closely, to increase the clean absorption rate cost of implementation of lotion
It reduces.
It is rarely reported at present about using the research of nanosized perovskite-type oxide modified castor fat liquor.
Summary of the invention
It is an object of the invention to overcome the shortcoming in above-mentioned background technique, a kind of nanometer calcium of color inhibition is provided
The preparation method of titanium ore oxide modifying castor oil lotion, the environment-friendly type color inhibition lotion of preparation, can effectively be promoted after use
The anti-yellowing property of crust leather, and the binding ability and clean absorption rate of lotion can be enhanced.
The technical scheme adopted by the invention is as follows:
A kind of color inhibition type perovskite oxide modified castor fat liquor, it is characterised in that be made of following raw material:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil；Nanometer zirconium-aluminium codope perovskite oxide
Zr0.05Al0.1Ca0.85TiO31.7 parts -2.5 parts；14 parts -14.8 parts of maleic anhydride；14.9 parts -26.7 parts of pH is 8
Sodium metabisulfite solution；Appropriate ammonium hydroxide；26.1 parts -26.9 parts of deionized water.
A kind of preparation method of color inhibition type perovskite oxide modified castor fat liquor, it is characterised in that by following steps
It realizes:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil and 1.7 parts -2.5 parts of nanometer zirconium-aluminium codope perovskite are taken
Oxide Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 65-80 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope
Perovskite oxide is scattered in castor oil；14 parts -14.8 parts of maleic anhydride is added, is warming up to 90-100 DEG C, reacts 3-
4.5 hour；65 DEG C are cooled to, the sodium metabisulfite solution that the pH for being added 14.9 parts -26.7 parts is 8 reacts 1 hour；Use ammonium hydroxide
Adjusting pH is 8, is reacted 2.5 hours；26.1 parts -26.9 parts of deionized water is added to adjust product solid content.
Compared with prior art, the present invention has the advantage that as follows with effect:
1, raw material sources are extensive, environmentally protective, cheap and easy to get, simple process；
2, crust leather anti-yellowing property is obviously improved after the lotion stuffing；
3, since nanoparticle can greatly enhance the binding ability and clean absorption rate of lotion, in reality in conjunction with grease and collagen
Lotion dosage, save the cost are reduced in production.
Specific embodiment
The present invention will be described in detail With reference to embodiment.
The present invention relates to a kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof, the present invention is first
Zirconium-aluminium codope perofskite type oxide is prepared using sol-gal process, and is introduced into the sulfonated castor-oil plant of succinate
In oil base body, a kind of nano-perovskite oxide modifying castor oil lotion of color inhibition is finally prepared.Zirconium-aluminium codope perovskite
Type oxide has excellent ultraviolet absorption ability, can assign leather higher anti-yellowing property.Additionally due to the oxide has
There is a flexibility, and aobvious cation vacancy, it can be with collagen and anionic emulsion in combination with considerably increasing the exhaustion of the lotion
Rate.The lotion is used for leather greasing process, and leather sample feel is smooth, soft, and fullness is good, and anti-yellowing property is promoted obvious.
The present invention is made of following raw material:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil；Nanometer zirconium-aluminium codope perovskite oxide
Zr0.05Al0.1Ca0.85TiO31.7 parts -2.5 parts；14 parts -14.8 parts of maleic anhydride；14.9 parts -26.7 parts of pH is 8
Sodium metabisulfite solution；Appropriate ammonium hydroxide；26.1 parts -26.9 parts of deionized water.
The present invention is realized by following steps:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil and 1.7 parts -2.5 parts of nanometer zirconium-aluminium codope perovskite are taken
Oxide Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 65-80 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope
Perovskite oxide is scattered in castor oil；14 parts -14.8 parts of maleic anhydride is added, is warming up to 90-100 DEG C, reacts 3-
4.5 hour；65 DEG C are cooled to, the sodium metabisulfite solution that the pH for being added 14.9 parts -26.7 parts is 8 reacts 1 hour；Use ammonium hydroxide
Adjusting pH is 8, is reacted 2.5 hours；26.1 parts -26.9 parts of deionized water is added to adjust product solid content.
Embodiment 1:
In terms of dry mass part, 43.3 parts of castor oil and 1.7 parts of nanometer zirconium-aluminium codope perovskite oxide are taken
Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 65 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope perovskite oxygen
Compound is scattered in castor oil；14 parts of maleic anhydride is added, is warming up to 90 DEG C, reacts 3 hours；65 DEG C are cooled to, is added
The sodium metabisulfite solution that 14.9 parts of pH is 8 reacts 1 hour；Adjusting pH with ammonium hydroxide is 8, is reacted 2.5 hours；It is added 26.1
The deionized water of part is to adjust product solid content.
Embodiment 2:
In terms of dry mass part, 43.5 parts of castor oil and 1.9 parts of nanometer zirconium-aluminium codope perovskite oxide are taken
Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 70 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope perovskite oxygen
Compound is scattered in castor oil；14.2 parts of maleic anhydride is added, is warming up to 90 DEG C, reacts 3 hours；65 DEG C are cooled to, is added
The sodium metabisulfite solution that the pH for entering 15.1 parts is 8, reacts 1 hour；Adjusting pH with ammonium hydroxide is 8, is reacted 2.5 hours；It is added
26.3 parts of deionized water is to adjust product solid content.
Embodiment 3:
In terms of dry mass part, 43.7 parts of castor oil and 2.1 parts of nanometer zirconium-aluminium codope perovskite oxide are taken
Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 70 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope perovskite oxygen
Compound is scattered in castor oil；14.4 parts of maleic anhydride is added, is warming up to 95 DEG C, reacts 3.5 hours；65 DEG C are cooled to,
The sodium metabisulfite solution that the pH for being added 15.3 parts is 8, reacts 1 hour；Adjusting pH with ammonium hydroxide is 8, is reacted 2.5 hours；It is added
26.5 parts of deionized water is to adjust product solid content.
Embodiment 4:
In terms of dry mass part, 43.9 parts of castor oil and 2.3 parts of nanometer zirconium-aluminium codope perovskite oxide are taken
Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 75 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope perovskite oxygen
Compound is scattered in castor oil；14.6 parts of maleic anhydride is added, is warming up to 95 DEG C, reacts 4 hours；65 DEG C are cooled to, is added
The sodium metabisulfite solution that the pH for entering 15.5 parts is 8, reacts 1 hour；Adjusting pH with ammonium hydroxide is 8, is reacted 2.5 hours；It is added
26.7 parts of deionized water is to adjust product solid content.
Embodiment 5:
In terms of dry mass part, 44.1 parts of castor oil and 2.5 parts of nanometer zirconium-aluminium codope perovskite oxide are taken
Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 80 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope perovskite oxygen
Compound is scattered in castor oil；14.8 parts of maleic anhydride is added, is warming up to 100 DEG C, reacts 4.5 hours；65 DEG C are cooled to,
The sodium metabisulfite solution that the pH for being added 15.7 parts is 8, reacts 1 hour；Adjusting pH with ammonium hydroxide is 8, is reacted 2.5 hours；It is added
26.9 parts of deionized water is to adjust product solid content.
The contents of the present invention are not limited to cited by embodiment, and those of ordinary skill in the art are by reading description of the invention
And to any equivalent transformation that technical solution of the present invention is taken, all are covered by the claims of the invention.
Claims (2)
1. a kind of color inhibition type perovskite oxide modified castor fat liquor, it is characterised in that be made of following raw material:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil；Nanometer zirconium-aluminium codope perovskite oxide
Zr0.05Al0.1Ca0.85TiO31.7 parts -2.5 parts；14 parts -14.8 parts of maleic anhydride；14.9 parts -26.7 parts of pH is 8
Sodium metabisulfite solution；Appropriate ammonium hydroxide；26.1 parts -26.9 parts of deionized water.
2. a kind of preparation method of color inhibition type perovskite oxide modified castor fat liquor, it is characterised in that by following steps reality
It is existing:
In terms of dry mass part, 43.3 parts -44.1 parts of castor oil and 1.7 parts -2.5 parts of nanometer zirconium-aluminium codope perovskite are taken
Oxide Zr0.05Al0.1Ca0.85TiO3, three-necked flask is added, being warming up to 65-80 DEG C of 25 min of stirring makes a nanometer zirconium-aluminium codope
Perovskite oxide is scattered in castor oil；14 parts -14.8 parts of maleic anhydride is added, is warming up to 90-100 DEG C, reacts 3-
4.5 hour；65 DEG C are cooled to, the sodium metabisulfite solution that the pH for being added 14.9 parts -26.7 parts is 8 reacts 1 hour；Use ammonium hydroxide
Adjusting pH is 8, is reacted 2.5 hours；26.1 parts -26.9 parts of deionized water is added to adjust product solid content.
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|---|---|---|---|
| CN201910902171.6A CN110527757A (en) | 2019-09-24 | 2019-09-24 | A kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910902171.6A CN110527757A (en) | 2019-09-24 | 2019-09-24 | A kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof |
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| Publication Number | Publication Date |
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| CN110527757A true CN110527757A (en) | 2019-12-03 |
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| CN201910902171.6A Pending CN110527757A (en) | 2019-09-24 | 2019-09-24 | A kind of color inhibition type perovskite oxide modified castor fat liquor and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182217A (en) * | 1987-01-20 | 1988-07-27 | Mitsubishi Petrochem Co Ltd | Production of abo3 type perovskite oxide |
| CN102994659A (en) * | 2012-12-28 | 2013-03-27 | 陕西科技大学 | Preparation method of leather fatliquor containing surface decoration nanosilicon dioxide |
| JP2013087151A (en) * | 2011-10-14 | 2013-05-13 | Asahi Glass Co Ltd | Infrared absorption particle and manufacturing method therefor |
| KR20130055940A (en) * | 2011-11-21 | 2013-05-29 | 삼성전기주식회사 | Perovskite powder, fabricating method thereof and multi-layer ceramic electronic parts fabricated by using the same |
| CN104480235A (en) * | 2014-11-05 | 2015-04-01 | 陕西科技大学 | Modified titanium dioxide/sulfonated hydrogenated castor oil succinate composite material and preparation method thereof |
| CN109371179A (en) * | 2018-11-13 | 2019-02-22 | 陕西科技大学 | Zr-Al codope Ca-Ti ore type poly-metals tanning agent and preparation method thereof |
-
2019
- 2019-09-24 CN CN201910902171.6A patent/CN110527757A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182217A (en) * | 1987-01-20 | 1988-07-27 | Mitsubishi Petrochem Co Ltd | Production of abo3 type perovskite oxide |
| JP2013087151A (en) * | 2011-10-14 | 2013-05-13 | Asahi Glass Co Ltd | Infrared absorption particle and manufacturing method therefor |
| KR20130055940A (en) * | 2011-11-21 | 2013-05-29 | 삼성전기주식회사 | Perovskite powder, fabricating method thereof and multi-layer ceramic electronic parts fabricated by using the same |
| CN102994659A (en) * | 2012-12-28 | 2013-03-27 | 陕西科技大学 | Preparation method of leather fatliquor containing surface decoration nanosilicon dioxide |
| CN104480235A (en) * | 2014-11-05 | 2015-04-01 | 陕西科技大学 | Modified titanium dioxide/sulfonated hydrogenated castor oil succinate composite material and preparation method thereof |
| CN109371179A (en) * | 2018-11-13 | 2019-02-22 | 陕西科技大学 | Zr-Al codope Ca-Ti ore type poly-metals tanning agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 中国科学院地球化学研究所: "中国科学院地球化学研究所年报", 贵州人民出版社, pages: 310 * |
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