CN110524658A - A kind of compound hay mould inhibitor and its preparation method and application - Google Patents

A kind of compound hay mould inhibitor and its preparation method and application Download PDF

Info

Publication number
CN110524658A
CN110524658A CN201910851881.0A CN201910851881A CN110524658A CN 110524658 A CN110524658 A CN 110524658A CN 201910851881 A CN201910851881 A CN 201910851881A CN 110524658 A CN110524658 A CN 110524658A
Authority
CN
China
Prior art keywords
hay
mould inhibitor
compound
present
mould
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910851881.0A
Other languages
Chinese (zh)
Inventor
郭旭生
许冬梅
柯文灿
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanzhou University
Original Assignee
Lanzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanzhou University filed Critical Lanzhou University
Priority to CN201910851881.0A priority Critical patent/CN110524658A/en
Publication of CN110524658A publication Critical patent/CN110524658A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/007Straw

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of compound hay mould inhibitors and its preparation method and application, belong to hay Prevention of Mould Development field.Compound hay mould inhibitor provided by the invention includes the component of following mass fraction: 440~505 parts of propionic acid ammonium;20~50 parts of propylene glycol.The present invention utilizes the sterilization and anticorrosion fungicidal properties of propionic acid ammonium, can reduce the harmful microorganism quantity in hay, prevent hay moldy metamorphism after Baling at high moisture.Meanwhile the materials safety that the present invention uses is high, it is free from environmental pollution.Embodiment the result shows that, dramatically increased using compound hay mould inhibitor provided by the invention treated hay protein content compared to control group, micro organism quantity has significant decrease.

Description

A kind of compound hay mould inhibitor and its preparation method and application
Technical field
The present invention relates to hay Prevention of Mould Development field, in particular to a kind of compound hay mould inhibitor and preparation method thereof and answer With.
Background technique
During making hay, control moisture is an important link.The too low herbage blade that will lead to of moisture largely takes off It falls, causes nutriment loss and economic loss, and if moisture is excessively high, the nocuousness such as saccharomycete, mould during storage Bacterium meeting growth and breeding generates mycotoxin, it cannot be guaranteed that hay safety, while also bringing along nutriment loss and economic damage It loses.For solve the problems, such as hay manufacturing process control moisture this, it is necessary to develop a kind of suitable Baling at high moisture production hay Mould inhibitor used.
Summary of the invention
In view of this, it is an object of that present invention to provide a kind of compound hay mould inhibitors and its preparation method and application.This hair The compound hay mould inhibitor of bright offer can reduce harmful microorganism quantity, effectively save hay nutriment.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
The present invention provides a kind of compound hay mould inhibitor, the component including following mass fraction:
440~505 parts of propionic acid ammonium;
20~50 parts of propylene glycol.
Preferably, the compound hay mould inhibitor includes the component of following mass fraction:
450~500 parts of propionic acid ammonium;
30~40 parts of propylene glycol.
The present invention provides the preparation methods of above-mentioned compound hay mould inhibitor, comprising the following steps:
By propionic acid ammonium and mixed with propylene glycol, compound hay mould inhibitor is obtained.
The present invention provides application of the above-mentioned compound hay mould inhibitor in high-moisture hay baling.
Preferably, the biodiversity content of the high-moisture hay is 25~30%, and the compound hay mould inhibitor is in height Dosage when moisture hay baling is 4~6L/t.
The present invention provides a kind of compound hay mould inhibitor, the components including following mass fraction: propionic acid ammonium 440~505 Part;20~50 parts of propylene glycol.The present invention utilizes the sterilization and anticorrosion performance of propionic acid ammonium, can reduce the harmful microorganism number in hay Amount, prevents hay moldy metamorphism after Baling at high moisture.Meanwhile the materials safety that the present invention uses is high, it is free from environmental pollution.Implement Example the result shows that, had using compound hay mould inhibitor provided by the invention treated hay protein content compared to control group aobvious It writes and increases, micro organism quantity has significant decrease.
The present invention provides the preparation methods of above-mentioned compound hay mould inhibitor, this method is easy to operate, are suitable for industrial mass Amount production, while no waste mine occurs in process of production, it is free from environmental pollution.
Detailed description of the invention
Fig. 1 is each group temperature variation after 30% moisture bundling processing in embodiment 1;
Fig. 2 is each group temperature variation after 25% moisture bundling processing in embodiment 1.
Specific embodiment
The present invention provides a kind of compound hay mould inhibitor, the component including following mass fraction:
440~505 parts of propionic acid ammonium;
20~50 parts of propylene glycol.
Unless otherwise specified, the raw materials used present invention is commercially available.
In terms of mass fraction, compound hay mould inhibitor provided by the invention includes 440~505 parts of propionic acid ammonium, preferably 450~500 parts.The present invention utilizes the sterilization and anticorrosion performance of propionic acid ammonium, can reduce the harmful microorganism quantity in hay, prevent Hay moldy metamorphism after Baling at high moisture.
On the basis of the mass fraction of the propionic acid ammonium, compound hay mould inhibitor provided by the invention includes 4~10 parts Propylene glycol, preferably 5~8 parts.In the present invention, the propylene glycol has good resistance to frost while as solvent, It can make composite dry grass mould inhibitor normal use at low temperature.
The present invention provides the preparation methods of above-mentioned compound hay mould inhibitor, comprising the following steps:
By propionic acid ammonium and mixed with propylene glycol, compound hay mould inhibitor is obtained.
In the present invention, the mixed mode is preferably stirred;The present invention is to the rate of the stirring without spy Different requirement, can be uniform by the propionic acid ammonium and mixed with propylene glycol.
After obtaining the compound hay mould inhibitor, the present invention preferably packs the compound hay mould inhibitor.This hair The bright mode to the packaging does not have special requirement, uses manner of packing well known to those skilled in the art.
The preparation method of compound hay mould inhibitor of the invention is easy to operate, suitable for industrial mass production, while No waste mine occurs in production process, free from environmental pollution.
The present invention provides application of the above-mentioned compound hay mould inhibitor in high-moisture hay baling.In the present invention, institute The biodiversity content for stating high-moisture hay is preferably 25~30%, and more preferably 26~28%;The compound hay mould inhibitor Dosage in high-moisture hay baling is preferably 4~6L/t, more preferably 5~6L/t.The present invention is to the high-moisture hay Type there is no a special requirement, herbage well known in the art can use compound hay mould inhibitor provided by the invention.
In the present invention, the method for the application is preferred are as follows: before bundling, the compound hay mould inhibitor is sprayed at height Moisture hay surface.
The present invention does not have special requirement to the mode of the sprinkling, uses spray pattern well known to those skilled in the art The sprinkling of compound hay mould inhibitor is uniform.
Compound hay mould inhibitor provided by the invention and its preparation method and application is carried out below with reference to embodiment detailed Explanation, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
By 440 parts of propionic acid ammoniums and 20 parts of mixed with propylene glycol, compound hay mould inhibitor is obtained.
Hay is carried out to the clover that moisture content is 25wt.% and 30wt.% using this compound hay mould inhibitor respectively to beat Bundle processing, the dosage of hay baling compound hay mould inhibitor when handling are 4L/t, 6L/t.It is mould proof that compound hay is not added in setting simultaneously The clover of agent carries out identical hay baling processing, as a control group.
Alfalfa hay nutritional ingredient after handling 30 days above-mentioned hay baling detects, and examination criteria is " GBT 20806-2006 " and " GBT 6432 ", acquired results are listed in Table 1 below.
The compound hay mould inhibitor of table 1 treated alfalfa hay nutritional ingredient testing result
In table 1, DM indicates dry matter.
As shown in Table 1, either moisture content be 25wt.% or 30wt.% hay, using provided by the invention multiple After closing the processing of hay mould inhibitor, the content that fiber and pickling fiber are washed in hay declines compared with control group conspicuousness, and protein content is aobvious Work property increases.
The harmful bacteria in hay after handling 30 days above-mentioned hay baling detects, and detection method is plate technique Acquired results are listed in Table 2 below by method.
Harmful bacteria testing result in the compound hay mould inhibitor of table 2 treated alfalfa hay
As shown in Table 2, compared with the control group, either moisture content is the hay of 25wt.% or 30wt.%, is used The quantity of saccharomycete and mould has reduction after compound hay mould inhibitor bundling processing, and addition 6L/t mould inhibitor can make fungi count Measuring conspicuousness reduces.
Above-mentioned hay is terminated to the temperature of the hay bale of 30 days storage periods to carry out from bundling using temperature-indicating instrument Detection, wherein 30% moisture bundling processing after each group temperature variation as shown in Figure 1,25% moisture bundling processing after each group temperature Variation diagram is as shown in Figure 2.
By Fig. 1 and Fig. 2 it is found that temperature in all processing group bales all presents first to rise to decline afterwards finally tends towards stability Trend.When 30% moisture bundling, control group bale maximum temperature is 26.67 DEG C, and adds the post-processing of 4L/t and 6L/t mould inhibitor Group maximum temperature is respectively 24.08 DEG C and 23.10 DEG C, reduces 2.59 DEG C and 3.57 DEG C respectively.Compared with the control group, 30% water It is divided to two mould inhibitor processing group heating rates of 4L/t and 6L/t of bundling slower, maximum temperature is lower, and steady fixed time temperature Declined, and adds 6L/t mould inhibitor processing group and become apparent compared with 4L/t processing group effect.In the test of 25% moisture bundling Also have it is similar as a result, control group maximum temperature be 26.06 DEG C, and 4L/t and 6L/t processing group maximum temperature be 23.41 DEG C and 23.44 DEG C, 2.65 DEG C and 2.62 DEG C are had dropped respectively, are added not significant between two kinds of processing groups of 4L/t and 6L/t mould inhibitor Sex differernce.This result shows that, during modulating hay, addition mould inhibitor have significantly to the activity of microorganism in bale Property inhibiting effect, can effectively control the temperature in bale, the mould inhibitor effect of addition 6L/t is preferable when 30% moisture bundling, And 4L/t and 6L/t mould inhibitor is added when 25% moisture bundling good effect.
Embodiment 2
By 505 parts of propionic acid ammoniums and 50 parts of mixed with propylene glycol, compound hay mould inhibitor is obtained.
Hay is carried out to the clover that moisture content is 25wt.% and 30wt.% using this compound hay mould inhibitor respectively to beat Bundle processing, the dosage of hay baling compound hay mould inhibitor when handling are 4L/t, 6L/t.After handling 30 days above-mentioned hay baling Hay nutritional ingredient detected, acquired results are similar to Example 1.
Embodiment 3
By 450 parts of propionic acid ammoniums and 30 parts of mixed with propylene glycol, compound hay mould inhibitor is obtained.
Hay is carried out to the clover that moisture content is 25wt.% and 30wt.% using this compound hay mould inhibitor respectively to beat Bundle processing, the dosage of hay baling compound hay mould inhibitor when handling are 4L/t, 6L/t.After handling 30 days above-mentioned hay baling Hay nutritional ingredient detected, acquired results are similar to Example 1.
As seen from the above embodiment, harmful microorganism quantity can be effectively reduced in compound hay mould inhibitor provided by the invention, Effectively save forage nutrition substance.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (5)

1. a kind of compound hay mould inhibitor, which is characterized in that the component including following mass fraction:
440~505 parts of propionic acid ammonium;
20~50 parts of propylene glycol.
2. compound hay mould inhibitor according to claim 1, which is characterized in that the component including following mass fraction:
450~500 parts of propionic acid ammonium;
30~40 parts of propylene glycol.
3. the preparation method of compound hay mould inhibitor of any of claims 1 or 2, which comprises the following steps:
By propionic acid ammonium and mixed with propylene glycol, compound hay mould inhibitor is obtained.
4. the compound hay of the preparation of preparation method described in compound hay mould inhibitor as claimed in claim 1 or 2 or claim 3 is mould proof Application of the agent in high-moisture hay baling.
5. application according to claim 4, which is characterized in that the biodiversity content of the high-moisture hay be 25~ 30%, dosage of the compound hay mould inhibitor in high-moisture hay baling is 4~6L/t.
CN201910851881.0A 2019-09-10 2019-09-10 A kind of compound hay mould inhibitor and its preparation method and application Pending CN110524658A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910851881.0A CN110524658A (en) 2019-09-10 2019-09-10 A kind of compound hay mould inhibitor and its preparation method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910851881.0A CN110524658A (en) 2019-09-10 2019-09-10 A kind of compound hay mould inhibitor and its preparation method and application

Publications (1)

Publication Number Publication Date
CN110524658A true CN110524658A (en) 2019-12-03

Family

ID=68668025

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910851881.0A Pending CN110524658A (en) 2019-09-10 2019-09-10 A kind of compound hay mould inhibitor and its preparation method and application

Country Status (1)

Country Link
CN (1) CN110524658A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806353A (en) * 1983-09-27 1989-02-21 Thomas Richard D Mold inhibiting product
CN1864558A (en) * 2006-06-26 2006-11-22 中国农业大学 A grain conditioning method before steam flaking
CN101731451A (en) * 2010-01-21 2010-06-16 鲁昊 Compound mouldproof agent with acidizing effect and preparation method thereof
CN102919551A (en) * 2012-11-22 2013-02-13 生物源生物技术(深圳)有限公司 Method for producing propionic acid type mildewproof agent by utilizing microbial fermentation method, and application thereof
CN107683961A (en) * 2017-08-18 2018-02-13 吉林农业大学 One kind utilizes yeast waste liquor production feedstuff mildew water-preserving promoting agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806353A (en) * 1983-09-27 1989-02-21 Thomas Richard D Mold inhibiting product
CN1864558A (en) * 2006-06-26 2006-11-22 中国农业大学 A grain conditioning method before steam flaking
CN101731451A (en) * 2010-01-21 2010-06-16 鲁昊 Compound mouldproof agent with acidizing effect and preparation method thereof
CN102919551A (en) * 2012-11-22 2013-02-13 生物源生物技术(深圳)有限公司 Method for producing propionic acid type mildewproof agent by utilizing microbial fermentation method, and application thereof
CN107683961A (en) * 2017-08-18 2018-02-13 吉林农业大学 One kind utilizes yeast waste liquor production feedstuff mildew water-preserving promoting agent

Similar Documents

Publication Publication Date Title
US6221381B1 (en) Enhancing milk production by adding to feed a nonionic surfactant coated on a carrier
CN1031542C (en) Bacterial treatment to preserve hay quality by addition of microorganisms of the genus bacillus
Makkar et al. Effect of storage and urea addition on detannification and in sacco dry matter digestibility of mature oak (Quercus incana) leaves
CN106721006A (en) A kind of meat quality that improves fattens swine feed and preparation method thereof
CN111213786B (en) Water quality acidulant for preventing and controlling African swine fever as well as preparation method and application thereof
CN105941871A (en) Compound mouldproof additive for alfalfa hay
CN106666329A (en) Preservative for improving quality and fresh keeping effect of food and application of preservative
EP0411827B1 (en) Ensiling composition
GB2206028A (en) Antimicrobial preparations
EP0290295B1 (en) Antimicrobial preparations
CN110524658A (en) A kind of compound hay mould inhibitor and its preparation method and application
CN102640781B (en) Fresh meat composite biological preservative and preparation method of fresh meat composite biological preservative
CN106578836A (en) Application of polypeptides in food preservation
US20140342039A1 (en) Polysiloxane (silicone) treatment composition for suppression of mold and spoilage on animal feed and forage, and method of using same
CN109452479A (en) A kind of method that high-moisture corn fermentation generates people's pannage
RU2638188C2 (en) Method for herbs ensilaging by biological preservative "ferbak-sil b-1"
CA1160096A (en) Use of phospholipids as mould inhibiting agents in siloed forage
CN106417576A (en) Fresh keeping agent containing chitosan oligosaccharide and cinnamic acid, for bananas
US3001862A (en) Method for reducing the moisture content of crops
EP2563161B1 (en) Polysiloxane (silicone) treatment composition for suppression of mold and spoilage on animal feed and forage, and methods of using same
WO1990003122A1 (en) Antimicrobial preparations
US20100239718A1 (en) Use of polydimethylsiloxane and/or siloxane (silicone) derived chemical compounds in the suppression of mold and spoilage on harvested forages
CN109006973A (en) A kind of Perserving materials for hen egg
CN106804607A (en) A kind of bactericidal composition containing benziothiazolinone and thifluzamide and purposes
CN105410163A (en) Fruit and vegetable preservative and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191203