CN110519986A - The stabilization formulations of water sensitivity active matter - Google Patents

The stabilization formulations of water sensitivity active matter Download PDF

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Publication number
CN110519986A
CN110519986A CN201780057151.2A CN201780057151A CN110519986A CN 110519986 A CN110519986 A CN 110519986A CN 201780057151 A CN201780057151 A CN 201780057151A CN 110519986 A CN110519986 A CN 110519986A
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China
Prior art keywords
particulate composition
acid
composition
methyl
agriculture chemistry
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CN201780057151.2A
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Chinese (zh)
Inventor
阿伦·沙旺特
萨卡帕·瓦达卡库塔
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SA Kapawadakakuta
A Lunshawangte
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SA Kapawadakakuta
A Lunshawangte
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Publication of CN110519986A publication Critical patent/CN110519986A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of stable agriculture chemistry particulate compositions, the agriculture chemistry particulate composition includes: at least one first agricultural chemical activity object ingredient, wherein the first agricultural chemical activity object includes at least one of water-soluble active ingredient or water sensitivity active ingredient;At least one heat-staple plasticizer, wherein the plasticizer, which has, is greater than 20 DEG C and the fusing point less than 150 DEG C;Acceptable excipient at least one agriculture chemistry;Wherein the particulate composition has the wetability less than 20 minutes.The invention further relates to the techniques for preparing the stable agriculture chemistry particulate composition.The invention additionally relates to the methods of the application stable agriculture chemistry particulate composition.

Description

The stabilization formulations of water sensitivity active matter
1. invention field:
The present invention relates to a kind of stable particulate composition, which includes at least one agricultural chemical activity object Ingredient (agrochemical active ingredient), wherein the agricultural chemical activity object includes being used for agriculture chemistry purposes Water-soluble active ingredient or one of water sensitivity active ingredient or more.More particularly it relates to one Kind stable agriculture chemistry particulate composition, the agriculture chemistry particulate composition include at least one agricultural chemical activity object at Point, wherein the agricultural chemical activity object includes one of water-soluble active ingredient or water sensitivity active ingredient or more Kind;At least one heat-staple plasticizer, wherein the plasticizer, which has, is greater than 20 DEG C and the fusing point less than 150 DEG C;At least one Acceptable excipient on kind agriculture chemistry.Particulate composition has the wetability less than 20 minutes.
The invention further relates to the technique for preparing stable agriculture chemistry particulate composition, the stable agriculture chemistry particle Composition includes one of water-soluble active ingredient or water sensitivity active ingredient or more.In addition, the present invention relates to And it is handled and is planted with the stable agriculture chemistry particulate composition comprising water-soluble active ingredient or water sensitivity active ingredient The method of object or soil.
2. the description of related fields:
In description embodiment of the present invention, for the sake of clarity, specific term is selected.However, being not intended to the present invention It is limited to the specific term so selected, and it will be understood that each specific term includes being operated in a similar manner to realize similar mesh All technically equivalent ones.
In recent years, particle agrochemical composition has become very popular, because they are than conventional chemurgy length of schooling Such as wettable pulvis of agent and emulsifiable concentrate are safer and be more convenient for handling.Known various agricultural chemical activity objects are with moisture The Informal development for dissipating property granular preparation, this is because the advantage as provided by such preparation.Most of granulations used at present Method, generally referred to herein as wet granulation need to introduce water for pelletizing, and step are dried then to remove Water.
Unfortunately, certain activating agents have chemical stabilization highly sensitive and unstable in an aqueous medium and due to difference Property be easy degradation or modified disadvantage under the influence of water.Typically, hydrolysis is the degradation mechanism that the most common water mediates;So And such active matter may also undergo oxidation, dehalogenation, bond cleavage solution, Beckmann rearrangement and other forms when contacting with water Degradation.Active matter tends to lose its activity when contacting with water or is converted into another form.Such active matter is typically Often lose its activity at any time, and the unstability is unfavorable for desired field effect so that they to soil or plant or Desired target is unavailable.In addition, some agricultural chemical activity objects cannot be formulated into stable water due to its water-soluble nature Particle dispersion preparation.
In order to overcome these disadvantages, such activating agent has been formulated in anhydrous liquid medium.However, such system Agent does not allow to be incorporated to hydrophilic active agent.In addition, usually these known active matters are configured in order to avoid being exposed to water Emulsifiable concentrate, dust, wettable pulvis etc..However, these preparations include a large amount of organic solvents, such as toluene, dimethylbenzene Deng leading to the organic solvent emission of annual thousands of tons of in nature, caused seriously in terms of toxicity and pollution to environment and soil Risk and threat.In addition, these compositions also need to apply with very high application dose.
Especially, in rice field, such agrochemical formulations are premised on uneven dispersion.In recent years, it (is answered for dispersion With) agricultural chemicals and reduce agricultural chemicals and saving labour has become important, and need to be improved agricultural chemicals Dosage form.
In addition, commercially available preparation tends in a position sedimentation or is deposited on bottom, or floats, is dispersed in water surface On, without providing the fine dispersion or disintegration of active matter, this then fails to obtain desired dispersibility and component to crop It is uniformly distributed for intake.In addition, such granular preparation has excessively poor hardness, cause these compositions in these particles Or premature decomposition during production, storage, processing and the application of pulvis, lead to a large amount of losses released the control, phytotoxicity problem It is leached with excessive nutrients, then reduces them the Field information the effect of.Therefore, such composition is with significant higher Dosage is applied, to also increase the cost of the application of peasant.Include water sensitivity active ingredient or water-soluble active object The composition of the prior art of ingredient provides the composition of the property without good wetability and disintegration time.These are existing There is the composition of technology to also tend to float the duration of lasting length, and root zone or desired will not be reached Target area, and therefore tend to leach, lead to insufficient injurious insect control, the loss to peasant and the destruction to environment.
Therefore, preparation has the stable anhydrous agriculture chemistry of water-soluble active ingredient or water sensitivity active ingredient Granular preparation is significant challenge.Therefore, the composition with water-soluble active ingredient or water sensitivity active ingredient is deposited In demand, the composition can provide the good stability of preparation under cold and warm conditions, show activating agent to oxidation or The good tolerability of hydrolysis shows good hardness during storage or processing, while to reduce within the extended period Application rate provide improved crop protection from pest attack.
It has now been found that, surprisingly compared with conventional formulation, have one or more of water-soluble active objects at Divide or the stable agriculture chemistry particulate composition of water sensitivity active ingredient provides excellent effect, is easy to apply, protect All properties for holding active matter avoid the decomposition of active matter, and are friendly to peasant and environment.It is interesting that It is found to have the stable anhydrous particle group of water-soluble active object or water sensitivity active matter and at least one thermostabilization plasticizer Close object effectively work under the dosage of reduction, provide broader crop protection range and to various insects, weeds, mite class and The control of fungi improves the growth of crop/plant and quality, and is therefore that highly cost is effective in nature, this is not The wetability of enhancing is only showed, and improved hardness and good disintegration in water is also shown, thereby, it is ensured that extended Uniform application and availability in period.
Summary of the invention
The present invention relates to stable agriculture chemistry particulate composition, the stable agriculture chemistry particulate composition include to Few one or more agricultural chemical activity object ingredient, wherein agricultural chemical activity object includes one or more of water-soluble actives Object ingredient or water sensitivity active ingredient;At least one heat-staple plasticizer, the plasticizer have greater than 20 DEG C and small In 150 DEG C of fusing point;With excipient acceptable at least one agriculture chemistry;Wherein particulate composition is showed less than 20 points The wetability of clock.
The invention further relates to the technique for preparing stable particulate composition, the technique is related at least one agriculture chemistry Active ingredient and at least one heat stabilized polymer are mixed and blended to obtain mixture, and agricultural chemical activity object is at sorting From one of water-soluble active ingredient or water sensitivity active ingredient or more;Heating and cooling mixture are to obtain Stable agriculture chemistry particulate composition;Wherein particulate composition shows the wetability less than 20 minutes.
The invention further relates to by handling plant, crop, plant propagation material, seed, children with stable particulate composition At least one of seedling or surrounding soil carry out cover crop or improve the method for its health or yield;The stable particle combination Object has at least one agricultural chemical activity object ingredient, which is selected from water-soluble active ingredient or water One of Sensitive active object ingredient or more;At least one heat-staple plasticizer;On at least one agriculture chemistry Acceptable excipient;Wherein particulate composition shows the wetability less than 20 minutes.
It has been surprisingly observed that, composition not only shows the wetability less than 20 minutes, but also has small In the hardness of 5N, it was demonstrated that the decomposition of the reduction of active matter, disintegration, dispersion and the good physical properties to suspend are raw to entire crop Order the good releasing properties in period.In addition, composition showed under the application dose of significantly reduced composition it is astonishing Higher field effect.
Invention description
In description embodiment of the present invention, for the sake of clarity, specific term is taken.However, being not intended to the present invention It is limited to the specific term so selected, and it will be understood that each specific term includes being operated in a similar manner to realize similar mesh All technically equivalent ones.
The present invention relates to stable agriculture chemistry particulate composition, it includes: at least one agricultural chemical activity object ingredient. Agricultural chemical activity object ingredient includes one of water-soluble active ingredient or water sensitivity active ingredient or more.Group Closing object also includes at least one heat-staple plasticizer for having and being greater than 20 DEG C and the fusing point less than 150 DEG C;With at least one agriculture The chemically acceptable excipient of industry.Particulate composition shows the wetability less than 20 minutes.
According to the present invention, term " water sensitivity active ingredient " means chemically and/or physically unstable activity Agent.Term " chemical instability " especially means the degradation of active ingredient (active principle).Water sensitivity agricultural Chemically-reactive substance ingredient be when being exposed to water undergo water mediate degradation such as hydrolyze, aoxidize, dehalogenation, bond cleavage solution, Beckman Reset those of the degradation with other forms ingredient.
As used herein, term " degradation " indicates the loss of activity of water sensitivity active ingredient after contact with water. Degradation can be determined simply by measuring the amount of existing active ingredient before and after contacting with water.
Term " physical instability " especially means the change of its color in the crystallization or precipitating or composition of activating agent.
Term " water-soluble active ingredient " is the water dissolved in big degree to a small extent or even Agricultural chemical activity object ingredient.According to embodiment, agricultural chemical activity object ingredient has in water at 20 DEG C is greater than 0.1mg/ The solubility risen.According to embodiment, agricultural chemical activity object ingredient has the dissolution for being greater than 0.5mg/ and rising at 20 DEG C in water Degree.According to embodiment, agricultural chemical activity object ingredient has the solubility for being greater than 1mg/ and rising at 20 DEG C in water.According to implementation Scheme, agricultural chemical activity object ingredient have the solubility for being greater than 1g/ and rising at 20 DEG C in water.
According to embodiment, agricultural chemical activity object is at least one selected from the following: anti-fouling agent, attractant, insecticidal Agent, herbicide, nematicide, pheromone, defoliant (defoliant), acaricide, plant growth regulator, is killed at fungicide Algae agent, anti-feedant, avicide, bactericide, bird repellent, biological insecticides, biocide, chemosterilants, safener, insect Attractant, insect repellent, insect growth regulator, IGR, drive mammal agent, mating disrupting agent, desiccant, disinfectant, molluscacide, Antimicrobial, acaricide, ovicide, fumigant, plant activator, rat poison, synergist, virucide, repellant, microorganism Protective agent that insecticide, plant are incorporated to, other pesticide activity objects or its salt, derivative and mixture for mixing.
According to embodiment, the first agricultural chemical activity object or the second agricultural chemical activity object are selected from but not limited to following At least one of one or more: avermectin, amino methyl avermectin, abscisic acid, ACC, accephate, acequinocyl (acequinocyl), Acetamiprid, Acethion (acethion), Acetochlor, benzethazet acetofenate (acetofenate), Acetoxon (acetophos), acetyl worm nitrile, Acibenzolar (acibenzolar), acifluorfen, aclonifen, acetonitrile, acrep, the third chrysanthemum of fluorine Ester, methacrylaldehyde, acrylonitrile, acynonapyr, acypetacs, double third ring worm esters (afidopyropen), afoxolaner, first Careless amine, quinclorac, alanycarb, albendazole, Aldicarb, Aldicarb sulfone, aldimorph, aldoxycarb (aldoxycarb), chlorine Methanonaphthalene, allethrin, d- counter-propylene chrysanthemum ester, allicin, allidochlor, A Luo mycin, alloxydimsodium, allyl alcohol, allyxycarb, Alorac, α-Bromadiolone, α-cypermethrin, α -5a,6,9,9a-hexahydro-6,9-methano-2,4, alphamethrin (alphamethrin), hemel, aluminum phosphate (aluminium phosphide), aluminum phosphate (aluminum phosphide), azoles mepanipyrim, amine piperazine ketone (ametridione), ametryn (ametryn), ametryn (ametryne), special careless piperazine ketone (amibuzin), amicarbazone, mix Kind clever (amicarthiazol), amidithion (amidithion), first alachlor (amidochlor), sulfanilamide (SN) mite ester (amidoflumet), amidosulfuron, aminocarb, the third pyrimidine acid of chlorine, chlorine Fampridine acid, 4-aminopyridine, aminotriazole(ATA), methyl Amiprophos (amiprofos-methyl), amiprophos, amiprophos-methyl (amiprophos-methyl), amisulbrom, amine are inhaled Phosphorus, Amitraz, Amrol, Amcide Ammate, ambam (amobam), amorphous silica gel, amorphous silica, Aminopropyl phosphoric acid, anabasine, ancymidol, anilazine, anilofos, dredges grass grand (anisuron), anthraquinone, ANTU at AMS (antu), apholate (apholate), aramite, arprocarb (arprocarb), arsenic trioxide, asomate, aspirin, The spirit of sulphur grass, Chinese mugwort thiophene reach loose (athidathion), atraton, atrazine, aureofungin, AVERMECTIN B1, AVG, Aviglycine, penta ring azoles, nimbin, grass fragrant fixed (azafenidin), pyridine phosphorus, menazon (azidithion), tetrazolium are phonetic Sulphur is grand, triazotion, azinphos ethyl (azinphosethyl), methyl azinphos-methyl (azinphos-methyl), methyl azinphos-methyl (azinphosmethyl), nitrine net (aziprotryn), nitrine net (aziprotryne), azithiram, azobenzene, three Azoles tin, Alamos (azothoate), Fluoxastrobin, Bachmedesh (bachmedesh), oatax (barban), oatax (barbanate), hexafluorosilicic acid barium, solbar, barium fluosilicate, barthrin ester, basic copper carbonate, basic copper chloride, alkali formula Copper sulphate, BCPC, beflubutamid, M 9834, benalaxyl-M (benalaxyl-M), benazolin, benzene carbazones (bencarbazone), benzene diuril (benclothiaz), benzene pyridazine propyl ester (bendaqingbingzhi), Ficam, titanium dioxide Benzene (bendioxide), benfluralin (benefin), benfluralin (benfluralin), Benfuracard micro, benfuresate, benodanil, Benomyl, benoxacor, benzene dislike that phosphorus (benoxafos), benequinox, bensulfuron-methyl, bensulide, bensultap, it is grand for benzene (bentaluron), bentazon, bentazone, benzene metsulfovax, benthiozole, benthiocarb, bentranil, benzadox, benzalkonium chloride, benzyl Olefin(e) acid (benzamacril), isoxaben (benzamizole), benzamorf, lindane, benzfendizone, benzene first are sub- Amine (benzimine), benzyl grass amine, the bicyclic ketone of benzo, 5a,6,9,9a-hexahydro-6,9-methano-2,4 (benzoepin), benzofenap, benzofluor, benzyl hydroximic acid, Citrazon (Benzomate), benzo phosphate (benzophosphate), diazosulfide, benzo alkene fluorine bacterium azoles (benzovindiflupyr), Citrazon (benzoximate), suffer, benzpyrimoxan, benzthiazuron, benzyl gland are fast It is purine, Ergol, jamaicin, β-cyfloxylate, β-cypermethrin, benzene thiazine (bethoxazin), BHC, γ-BHC, double Alanyl phosphine, fluorine benzofenap (bicyclopyrone), Bifenazate, bifenox, Biphenthrin, κ-Biphenthrin, double third Aminoacyl phosphine (bilanafos), binapacryl, sick cyanogen nitre (bingqingxiao), bioaeroprofen, S-bioallethrin, life Object ethane pyrethroids (bioethanomethrin), biopermethrin, bioresmethrin, biphenyl, bisazir, thiophene, thiophene are withered Azoles-copper, methylene two (x- naphthalene-y- sulfonic acid) biphenyl mercury (bisphenylmercury methylenedi (x-naphthalene- Y-sulphonate)), bispyribac-sodium, bistrifluron, dimehypo (bisultap), Bitertanol, Bithionol, biphenyl pyrrole bacterium It is amine, blasticidin-S, borax, Bordeaux mixture, boric acid, pyrrole bacterium amide, BPCMS, BPPS, brassin lactones, ethyl brassinolide, small Moth-eaten sex pheromone, Brodifacoum (brodifacoum), broproxyfen (brofenprox), brofenxalerate, bromine flutolanil (broflanilide), brofluthrinate, bromacil, Bromadiolone, α-Bromadiolone, 2-dichloroethylk dimethyl phosphate, bromethalin (bromethalin), bromine Resmethrin (bromethrin), bromobenzene alkene phosphorus (bromfenvinfos), acetbromamide, chaff Bromoxynil (bromobonil), bromine Chloranocryl, bromociclen (bromociclen), bromocyclne, bromo-DDT, Faneron, bromophos (bromofos), bromine first Alkane, bromophos (bromophos), Rilariol (bromophos-ethyl), fenisobromolate, bromothalonil (bromothalonil), Bromoxynil, bromine grass are quick, bromine bacterium azoles, bronopol, BRP, BTH, Bucarpolate (bucarpolate), close and kill It is prestige, Ding Huancao phosphorus (buminafos), bupirimate, Buprofezin, Burgundy mixture (burgundy mixture), white The peace that disappears (busulfan), busulfan (busulphan), butacarb, butachlor, butafenacil, tebutam (butam), suppression grass Phosphorus, butane-Fipronil, special Pyrimitate (butathiofos), butenachlor, butylene-Fipronil, butethrin (butethrin), fourth sulphur imidazolone (buthidazole), Ding Saite, tebuthiuron, fallen leaves phosphorus (butifos), butocarboxim, butyl ester Phosphorus, dihydropyrone (butopyronoxyl), butanone sulfone prestige, butralin, butrizol (butrizol), butroxydim, buturon, fourth Amine, butylate, butyl chloride phosphorus (butylchlorophos), butylene-Fipronil, Phytar, cadusafos, cafenstrole, calciferol (calciferol), calcium arsenate, calcium chlorate, nitrolim, cyanogas, calcium polysulfide, calvinphos (calvinphos), kecaoan Ester (cambendichlor), toxaphene, camphor, d- camphor, difoltan, captan, metham-sodium (carbam), carbamorph, chlorine go out Kill prestige, sevin (carbaril), sevin (carbaryl), prestige sulphur spirit (carbasulam), carbathion, carbendazim (carbendazim), carbendazim (carbendazol), carbetamide, carbophenothion, furadan, curing calcium, carbon tetrachloride, Carbonyl sulfide, carbophenothion, carbophos, carbosulfan, carboxazole, carbonyl compound, carboxin, azoles humulone, ring Propionyl bacterium amine, cartap, hydrochloric acid cartap, carvacrol, carvol, CAVP, CDAA, CDEA, CDEC, cellocidin (cellocidin), CEPC, ceralure, benequinox, cevadilla (cevadilla), cheshunt mixture (cheshunt Mixture), Kui sulphur phosphorus (chinalphos), methyl Kui sulphur phosphorus (chinalphos-m é thyl), Chinomethionate (chinomethionate), chiralaxyl, chitosan, pest of going out azoles (chlobenthiazone), chlomethoxyfen, chloral Sugar, Amiben, chloramine phos (chloraminephosphorus), chloramphenicol, Imugan, four chloro 1,4-benzoquinone, chloranocryl, chlorine Worm benzamide, chloroazifoppropynyl (chlorazifop), chlorazine, chlorbenside (chlorbenside), d ichlorbenzuron (chlorbenzuron), chlorbicyclen (chlorbicyclen), bromax (chlorbromuron), Chlorophenocarb (chlorbufam), Niran (chlordane), chlordecone (chlordecone), Spanon (chlordimeform), chlorine eneyne Pyrethroids (chlorempenthrin), chloretazate (chloretazate), ethephon (CEPHA),2-(chloroethyl) phosphonic acid (chlorethephon), chlorethoxyfos (chlorethoxyfos), ethoxy benzene grand (chloreturon), Fenac (chlorfenac), chlorfenapyr (chlorfenapyr), fenchlorazole (chlorfenazole), Qikron (chlorfenethol), telvar (chlorfenidim), Bidisin (chlorfenprop), chlorfenizon (chlorfenson), chlorfensulfide (chlorfensulphide), chlorfenviphos (chlorfenvinphos), dimethylvinphos (chlorfenvinphos- Methyl), UC 62644 (chlorfluazuron), chlorflurazole (chlorflurazole), chloroflurenol (chlorflurecol), Chlorine fluorenes carboxylic acid (chlorfluren, chloro Florencol (chlorflurenol), chloridazon (chloridazon), chlorimuronethyl (chlorimuron), monoxone (chlorinate), chlormephos (chlormephos), cycocel (chlormequat), sulphur grass Ketone (chlormesulone), chlomethoxyfen (chlormethoxynil), chlornidine (chlornidine), Mo 9 granular (chlornitrofen), monoxone, chlorobenzilate (chlorobenzilate), chloro dinitronaphthalene (chlorodinitronaphthalene), chlorof é nizon, chloroform, α-chlorethanol (α-chlorohydrin), Yi Tuoming (chloromebuform), C-9140 (chloromethiuron), chloroneb (chloroneb), chlorophacinone (chlorophacinone), metrifonate (chlorophos), chlorophthalim, chloropicrin (chloropicrin), trichlorine Propionic acid (chloropon), chloroprallethrin, Acaralate (chloropropylate), Bravo (chlorothalonil), chlorine wheat grand (chlorotoluron), Chloroxuron (chloroxifenidim), chloroxifenidium (chloroxuron), chloroxynil (chloroxynil), San fourth Lv Bian Phosphonium (chlorphonium), chlorphoxim (chlorphoxim), chlorine acid imide (chlorphthalim), chlorine pyrazoxon (chlorprazophos), grass lose extremely (chlorprocarb), chlorpropham (chlorpropham), chlopyrifos (chlorpyrifos), chlorpyrifos-methyl (chlorpyrifos-methyl), four chloro-quinoxalines (chlorquinox), chlorsulfuron (chlorsulfuron), chlorthal (chlorthal), chlorothiamid (chlorthiamid), Actellic (chlorthiophos), chlortoluron (chlortoluron), Chlozolinate (chlozolinate), Vitamin D3 (cholecalciferol), choline chloride, ring tebufenozide (chromafenozide), cicloheximide (cicloheximide), TrinexAN_SNacethyl (cimectacarb), TrinexAN_SNacethyl (cimetacarb), cinerin (cinerin I), cinerin I, cinerin, cinidon-ethyl (cinidon-ethyl), ring Grass ether in heptan (cinmethylin), cinosulfuron (cinosulfuron), sintofen (cintofen), benzonitrile amide (ciobutide), cisanilide (cisanilide), cis- resmethrin (cismethrin), chlorine acyl grass phosphine (clacyfos), ring Methoxyphenone (clefoxydim), Clenpirin (clenpirin), clenpyrin (clenpyrin), clethodim (clethodim), Climbazole (climbazole), iodine chlorine pyridine ester (cliodinate), alkynes oxalic acid (clodinafop), cloethocarb (cloethocarb), clofencet (benzene pyridazine acid clofencet), DDT (clofenotane), clofentezine (clofentezine), Chlorfenvinphos (clofenvinfos), Clofibric acid (clofibric acid), clofop, clomazone (clomazone), clomeprop (clomeprop), niclosamide (clonitralid), tune tartaric acid (cloprop), the third oxygen of chlorine are fixed (cloproxydim), lontrel (clopyralid), cloquintocet (cloquintocet), cloransulammethyl (cloransulam), closantel (closantel), clothianidin (clothianidin), clotrimazole (clotrimazole), cloxyfonac (cloxyfonac), carat cultivate (cloxylacon), carat cultivate (clozylacon), CMA, CMMP, CMP, CMU, lanolin alcohol (codlelure), Vitamin D3 (colecalciferol), colophonate (colophonate), copper acetate, copper acetoarsenite (copper acetoarsenite), copper arsenate, basic copper carbonate, hydrogen Copper oxide, copper naphthenate (copper naphthenate), copper oleate, copper oxychloride (copper oxychloride), 8- quinoline Quinoline copper (copper8-quinolinolate), cupric silicate (copper silicate), copper sulphate, basic copper sulfate, copper chromate Zinc (copper zinc chromate), coumaran (coumachlor), Warfarin (coumafene), Coumafos (coumafos), coumafuryl (coumafuryl), Resistox (coumaphos), coumatetralyl (coumatetralyl), first fragrant bacterium Ester (coumethoxystrobin), Dithion (coumithoate), coumoxystrobin (coumoxystrobin), 4-CPA, 4- CPB, CPMC, CPMF, 4-CPP, CPPC, Kusakira (credazine), cresols (cresol), cresylic acid, crimidine (crimidine), Crotamiton (crotamiton), crotoxyphos (crotoxyfos), Crotoxyphos (crotoxyphos), educate poultry Phosphorus (crufomate), ice crystal (cryolite), cue-lure (cue-lure), cufraneb (cufraneb), hexichol are grand (cumyleron), cumyluron (cumyluron), cuprobam (cuprobam), cuprous oxide (cuprous oxide), curcuma zedoary Alcohol (curcumenol), CVMP, cyanamide (cyanamide), cyanatryn (cyanatryn), cyanazine (cyanazine), cyanophenyl Phosphorus (cyanofenphos), cyanogen (cyanogen), cynock (cyanophos), cyanthoate (cyanthoate), cyanogen insect amide (cyan-traniliprole), cyanuric acid (cyanuric acid), cyazofamid (cyazofamid), spread are net (cybutryne), ring bacterium amine (cyclafuramid), cyclanilide (cyclanilide), general sieve of cyclammonium (cyclaniliprole), cyclethrin (cyclethrin), cycloate (cycloate), cycloheximide (cycloheximide), cycloprate (cycloprate), cycloprothrin (cycloprothrin), ring pyridate (cyclopyrimorate), cypromisulfuron (cyclosulfamuron), cycloxydim (cycloxydim), Alipur-O (cycluron), nitrile pyrrole mite ester (cyenopyrafen), cyflufenamid (cyflufenamid), cyflumetofen (cyflumetofen), cyfloxylate (cyfluthrin), β-cyfloxylate, chlorine fluorine cyanogen insect amide (cyhalodiamide), cyhalofop-butyl (cyhalofop), lambda-cyhalothrin (cyhalothrin), gamma-cyhalothrin, λ- Lambda-cyhalothrin, plictran (cyhexatin), Tifatol (cymiazole), cymoxanil (cymoxanil), cyometrinil (cyometrinil), cypendazole (cypendazole), cypermethrin (cypermethrin), α-cypermethrin, β-chlorine cyanogen chrysanthemum Ester, θ-cypermethrin, ζ-cypermethrin, benzene grass fast (cyperquat), cyanophenyl pyrethroids (cyphenothrin), Prefox (cyprazine), tricyclic fenacet (cyprazole), Cyproconazole (cyproconazole), cyclopropyl pyrimidine (cyprodinil), cyprofuram (cyprofuram), cypromid (cypromid), cyclopropyl-sulfonylamide (cyprosulfamide), cyromazine (cyromazine), Cythioate (cythioate), dodine (cytrex), 1,3-D, 2, 4-D, 3,4-DA, daimuron (daimuron), Dalapon (dalapon), daminozide (daminozide), dazomet (dazomet), 2,4-DB, 3,4-DB, DBCP, d- camphor (d-camphor), DCB, DCIP, DCPA (USA), DCPA (Japan), DCPTA, DCU, DDD, DDPP, DDT, ppTPAJa, DDVP, 2,4-DEB, debacarb (debacarb), decafentin (decafentin), bromine Cyano chrysanthemate (decamethrin), a first Furadan (decarbofuran), Metadelphene (deet), dehydroactic acid (dehydroacetic acid), diquat dibromide (deiquat), delachlor (delachlor), dioxathion (delnav), bromine cyanogen Pyrethroids (deltamethrin), demephion (demephion), demephion-O, demephion-S, demeton (demeton), in methyl Inhale phosphorus, different demeton (demeton-O), the different demeton of methyl (demeton-O-methyl), demeton-S, demeton-methyl-S (demeton-S-methyl), the different demeton sulfone (demeton-S-methylsulphon) of methyl, the different demeton sulfone of methyl (demeton-S-methyl sulphone), DEP, 2,4-DEP, bioaeroprofen (depall é thrine), rotenone (derris), 2,4-DES, desmedipham (desmedipham), desmetryn (desmetryn), desmetryn (desmetryne), d- Trans- chlorine prallethrin (d-fanshiluquebingjuzhi), diafenthiuron (diafenthiuron), torak (dialifor), torak (dialifos), Avadex (di-allate), Avadex (diallate), diamines phosphorus (diamidafos), dicamba (dianat), diatomite (diatomaceous earth), diatomite (diatomite), diazine Agriculture (diazinon), 2-dichloroethylk dimethyl phosphate (dibrom), glycol dibromide, Dibutyl phthalate, dibutyl succinate, dicamba (dicamba), isochlorothion (dicapthon), dichlobenil (dichlobenil), dichlobentiazox, dichlofenthion (dichlofenthion), Euparen (dichlofluanid), dichlone (dichlone), dichloral urea (dichloralurea), d ichlorbenzuron (dichlorbenzuron), diuron (dichlorfenidim), two Chlorflurecols (dichlorflurecol), dichloro Florencol (dichlorflurenol), dichlormate (dichlormate), dichlormide (dichlormid), o-dichlorohenzene (o-dichlorobenzene), o-dichlorohenzene (ortho-dichlorobenzene), to two Chlorobenzene (p-dichlorobenzene), paracide (para-dichlorobenzene), 1,2- dichloroethanes, methylene chloride, Dichlorophen, 3,6- lontrel, 1,2- dichloropropane, 1,3- dichloropropylene, 2,4- drop propionic acid (dichlorprop), essence 2,4- drop propionic acid (dichlorprop-P), DDVP (dichlorvos), sclex (dichlozoline), sclex (dichlozoline), diclobutrazol (diclobutrazol), double chlorine zarilamid (diclocymet), diclofop-methyl (diclofop), diclomezine (diclomezine), botran (dicloran), dicloromezotiaz, diclosulam (diclosulam), dicofol (dicofol), DDT (dicophane), bicoumarin (dicou-marol), Dicresyl, Carbicron (dicrotophos), dicryl (dicryl), bicoumarin (dicumarol), CGA 183893 (dicyclanil), dicyclonon, dieldrin (dieldrin), Hooker HRS 16 (dienochlor), diethyl weeding are fast (dietham-quat), acetyl alachlor (diethatyl), Ethodan (diethion), Ethodan (di é thion), diethofencarb (diethofencarb), Synergistic Phosphorus (dietholate), Ethodan (di é thon), pyrocarbonic acid diethyl ester (diethyl Pyrocarbonate), Metadelphene (di-ethyltoluamide), difenacoum (difenacoum), difenoconazole (difenoconazole), penta taste diclofop-methyl (difenopenten), difenoxuron (difenoxuron), difenzoquat (difenzoquat), difethialone (difethialone), flufenzine (diflovidazin), diflubenzuron (diflubenzuron), Diflufenican (diflufenican), diflufenican (diflufenicanil), diflufenzopyr (diflufenzopyr), fluorine mepanipyrim (diflumetorim), dikegulac (dikegulac), dilor, dimatif, tetrafluoro first Ethofenprox (dimefluthrin), BFPO (dimefox), dimefuron (dimefuron), dimehypo (dimehypo), piperazine grass Pellet (dimepiperate), dimethachlon (dimetachlone), dimetan (dimetan), dimethyl phenyl carbamate (dimethacarb), bacterium Core net (dimethachlone), dimethachlor (dimethachlor), Lysimachia sikokiana net (dimethametryn), P DimethenamidP (dimethenamid), smart P DimethenamidP (dimethenamid-P), dimethipin (dimethipin), dimethirimol (dimethirimol), Rogor (dimethoate), dimethomorph (dimethomorph), dimethrin (dimethrin), mosquito repellent Spirit (dimethyl carbate), dimethyl disulfide, repefral, dimethylvinphos (dimethylvinphos), dimetilan (dimetilan), dimexan (dimexano), rice reach hydrazone (dimidazon), diformazan SSF 126 (dimoxystrobin), basudin (dimpylate), daimuron (dimuron), Dinitrocyclohexylphenol (dinex), alkene azoles Alcohol (diniconazole), olefin conversion-M (diniconazole-M), R- olefin conversion (R-diniconazole), dinitramine (dinitramine), dinitrophenol dinitrophenolate, dinobuton (dinobuton), dinocap (dinocap), dinocap -4, dinocap -6, disappear Mite prestige (dinocton), Di Lete (dinofenate), the mite that disappears more (dinopenton), the third nitre phenol (dinoprop), dinosam (dinosam), dinoseb (dinoseb), nitre monooctyl ester (dinosulfon), dinotefuran (dinotefuran), dinoterb (dinoterb), dinoterbon (dinoterbon), difenolan (diofenolan), salithion (dioxabenzofos), Elacron (dioxacarb), dioxathion (dioxathion), dioxathion (dioxation), diphacine-Na (diphacin), diphacinone (diphacinone), diphenadione (diphenadione), diphenamide (diphenamid), diphenamide (diphenamide), diphenylamines (diphenylamine), diphenyl sulphone (DPS), diphenyl sulfide (diphenylsulphide), dikegulac (diprogulic acid), dipropalin (dipropalin), sancap (dipropetryn), metrifonate (dipterex), Dipymetitrone, Dipyrithione (dipyrithione), diquat dibromide (diquat), dimehypo (disosultap), female dance poison Zeller attractant (disparlure), dicamba methyl esters (disugran), disul, disulfiram (disulfiram), disulfoton (disulfoton), Plondrel (ditalimfos), dithianon (dithianon), thiapyran phosphorus (dithicrofos), two sulphur It is ether (dithioether), thiometon (dithiom é ton), dithiopyr (dithiopyr), diuron (diuron), double Xanthate (dixanthogen), (R)-4-isopropenyl-1-methyl-1-cyclohexene (d-limonene), DMDS, DMPA, DNOC, dodemorph (dodemorph), Dodicin (dodicin), dodine (dodine), benzene oxycetylene mite (dofenapyn), dodine (doguadine), Dominicalure, Duola can fourth (doramectin), 2,4-DP, 3,4-DP, DPC, hydrazine oxazolone (drazoxolon), DSMA, d-trans Allethrin 93 (d-trans-allethrin), d-trans resmethrin (d-trans- Resmethrin), toxic fluoride phosphate (dufulin), Sha flutter grand (dymron), EBEP, EBP, gram line pellet (ebufos), α-ecdyson (α-ecdysone), β-ecdyson, ecdysterone (ecdysterone), kobam (echlomezol), EDB, EDC, EDDP, Edifenphos (edifenphos), Radix Glycyrrhizae saliva (eglinazine), emamectin benzoate (emamectin), EMPC, Prallethrin (empenthrin), enadenine (enadenine), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), α -5a,6,9,9a-hexahydro-6,9-methano-2,4, endothall (endothal), grass Algae goes out (endothall), endothion (endothion), drinox (endrin), Enestroburin (enestroburin), En Kang Azoles (enilconazole), Enestroburin (enoxastrobin), ephirsulfonate, EPN, propionylbrassinolide (epocholeone), young ether (epofenonane), epoxiconazole (epoxiconazole), eprinomectin are protected (eprinomectin), triazole sulphur (epronaz), ε-metofluthrin (epsilon-metofluthrin), epsilon- Momfluorothrin, EPTC, erbon (erbon), ergocalciferol (ergocalciferol), bioallethrin (esd é pall é thrine), esfenvalerate (esfenvalerate), ESP, esprocarb (esprocarb), ethylene silicon (etacelasil), etaconazole (etaconazole), etaphos, Ethisul (etem), Guardian (ethaboxam), gram Careless amine (ethachlor), fourth fluchloralin (ethalfluralin), ethametsulfuron (ethametsulfuron), N-alpha-chloroacetyl-N-isopropyl-o ethylaniline (ethaprochlor), ethephon (CEPHA),2-(chloroethyl) phosphonic acid (ethephon), sulfone thiophene grand (ethidimuron), ethiofencarb (ethiofencarb), suppression Careless prestige (ethiolate), Ethodan (ethion), ethiozin (ethiozin), ethiprole (ethiprole), ethirimol (ethirimol), beneficial fruit (ethoate-methyl), ethobenzanid (ethobenzanid), ethofumesate (ethofumesate), Rutgers 612 (ethohexadiol), ethoprop (ethoprop), phonamiphos (ethoprophos), chlorine fluorine Careless ether (ethoxyfen), (3- ethoxycarbonyl propyl) mercuric bromide, ethoxyquin (ethoxyquin), ethoxysulfuron (ethoxysulfuron), 'Inshuzhi ' (ethychlozate), ethylan, ethyl-DDD, ethylene, Bromofume, dichloride second Alkene, ethylene oxide, Ethyl formate, S-Ethyl ethylthio sulfonate (ethylicin), acetic mercury (ethylmercury acetate), bromination Ethyl mercury (ethylmercury bromide), ethylmercuric chloride (ethylmercury chloride), 2,3- dihydroxypropyl Thiolation ethyl mercury (ethylmercury 2,3-dihydroxypropyl mercaptide), ethyl mercury phosphate (ethylmercury phosphate), N- (ethyl mercury)-tolysulfonyl aniline, N- (ethyl mercury)-are to toluene Sulphonanilide, coke Etherophosphoric acid, etinofen (etinofen), ETM, ethamine grass ether (etnipromid), suppression amide (etobenzanid), ethofenprox (etofenprox), etoxazole (etoxazole), Grandox fumigant (etridiazole), etrimfos (etrimfos), the phonetic sulphur of second Phosphorus (é trimphos), eugenol (eugenol), EXD, Famoxate (famoxadone), Dovip (famphur), Fenac (fenac), Fenamidone (fenamidone), fenaminosulf (fenaminosulf), alkene oxime amine (fenaminstrobin), benzene Line phosphorus (fenamiphos), fenapanil (fenapanil), Fenarimol (fenarimol), acyl benzene sulphur prestige (fenasulam), Fenazaflor (fenazaflor), quinoline mite azoles (fenazaquin), benzoxazole (fenbuconazole), fenbutatin oxide (fenbutatin Oxide), fenchlorazole (fenchlorazole), Nankor (fenchlorphos), ronnel (fenclofos), fenclorim (fenclorim), ethylbenzene prestige (fenethacarb), fenfluthrin (fenfluthrin), first furan anilide (fenfuram), Fenhexamid (fenhexamid), fenuron (fenidin), kind clothing ester (fenitropan), fenifrothion (fenitrothion), fenson (f é nizon), phenol bacterium ketone (fenjuntong), Bassa (fenobucarb), fentin hydroxide (fenolovo), 2,4,5- tears propionic acid (fenoprop), fenothiocarb (fenothiocarb), the phonetic amide of oxygen (fenoxacrim), Cyanogen bacterium ether amines (fenoxanil), fenoxaprop-P (fenoxaprop), fenoxapropPethyl (fenoxaprop-P), different evil benzene Sulfone (fenoxasulfone), fenoxycarb (fenoxycarb), fenpiclonil (fenpiclonil), fenpicoxamid, pyrrole chlorine cyanogen Pyrethroids (fenpirithrin), Fenpropathrin (fenpropathrin), fenpropidin (fenpropidin), butadiene morpholine (fenpropimorph), amine benzene pyrrole bacterium ketone (fenpyrazamine), fenpyroximate (fenpyroximate), Fenquinotrione, pyridazine ketone acid (fenridazon), fenson (fenson), fensulfothion (fensulfothion), Fen Te Ke Er (fenteracol), diclofop-methyl thiazole (fenthiaprop), Entex (fenthion), ethyl Entex (fenthion-ethyl), diclofop-methyl thiazole (fentiaprop), fentin (fentin), fentrazamide (fentrazamide), fentrifanil, fenuron (fenuron), fenuron-TCA, fenvalerate (fenvalerate), Fervam (ferbam), ferimzone (ferimzone), ferric phosphate, ferrous sulfate, Fipronil (fipronil), wheat straw volt (flamprop), efficient wheat straw lies prostrate (flamprop-M), flazasulfuron (flazasulfuron), flocoumafen (flocoumafen), flometoquin, flonicamid (flonicamid), florasulam (florasulam), chlorine fluorine Pyridine ester (florpyrauxifen), fluacrypyrim (fluacrypyrim), trifluoro miaow pyridine amide (fluazaindolizine), fluorine Careless spirit (fluazifop), careless spirit (fluazifop-P), fluazinam (fluazinam), fluazolate of smart fluorine (fluazolate), fluazuron (fluazuron), fipronil bisamide (flubendiamide), flumethiazide (flubenzimine), brofluthrinate (flubrocythrinate), flucarbazonesodium (flucarbazone), flucetosulfuron (flucetosulfuron), fluchloralin (fluchloralin), volt health urea flucofuron), flucycloxuron (flucycloxuron), flucythrinate (flucythrinate), fludioxonil (fludioxonil), Fluenyl (flu é n é Thyl), Fluenyl (fluenetil), fluorine thiophene worm sulfone (fluensulfone), flufenacet (flufenacet), phonetic worm amine (flufenerim), Diflufenican (flufenican), flufenoxuron (flufenoxuron), fluorine bacterium mite ester (flufenoxystrobin), trifluoro ethofenprox (flufenprox), flufenpyrethyl (flufenpyr), flufenzine (flufenzine), butene-fipronil (flufiprole), fluhexafon, fluorine indenes azoles bacterium amine (fluindapyr), flumethrin (flumethrin), fluorine acyl bacterium amine (flumetover), flumetralim (flumetralin), fluorine ethofumesate (flumetsulam), Fluphenazinum (flumezin), flumiclorac (flumiclorac), flumioxazin (flumioxazin), alkynes grass amine (flumipropyn), flumorph (flumorph), fluometuron (fluometuron), fluopicolide (fluopicolide), Fluopyram fluopyram), fluoraracide (fluorbenside), fluoridamid (fluoridamid), Fluorakil 100 (fluoroacetamide), fluoroacetic acid, fluorochloridone (fluorochloridone), fluorodifen (fluorodifen), Fluoroglycofen-ethyl (fluoroglycofen), fluoromide (fluoroimide), fluoromide (fluoromide), azoles Pyridine grass (fluoromidine), fluoronitrofen (fluoronitrofen), fluroxypyr (fluoroxypyr), fluorine sulphur are grand (fluothiuron), fluotrimazole (fluotrimazole), fluoxastrobin (fluoxastrobin), flupoxam (flupoxam), fluorine third phonetic careless (flupropacil), flupropadine (flupropadine), tetrafluoro propionic acid (flupropanate), Fluorine pyrrole furanone (flupyradifurone), flupyrsulfuron-methyl-sodium (flupyrsulfuron), Fluquinconazole (fluquinconazole), fluorine thunder Rana (fluralaner), flurazole (flurazole), Florencol (flurecol), suppression Careless fourth (flurenol), fluridone (fluridone), fluorine grass pyrrone (flurochloridone), fluorine determine miaow (fluromidine), fluroxypramide (fluroxypyr), flurprimidol (flurprimidol), fluorine sulfonamide (flursulamid), Flurtamone (flurtamone), Flusilazole (flusilazole), flusulfamide (flusulfamide), flufenzine (flutenzine), KIH 9201 (fluthiacet), flufenacet (fluthiamide), fluorine replace Buddhist nun (flutianil), fluorine acyl Amine (flutolanil), Flutriafol (flutriafol), taufluvalinate (fluvalinate), τ-taufluvalinate (tau- Fluvalinate), fluxametamide, fluxapyroxad (fluxapyroxad), fluxofenim (fluxofenim), Folpel, sterilize single (folpet), fomesafen (fomesafen), Dyfonate (fonofos), foramsulfuron (foramsulfuron), chloropyuril (forchlorfenuron), formaldehyde, medimeform (formetanate), An Guo (formothion), amine first prestige (formparanate), ioxynil (fosamine), triethylphosphine acid (fosetyl), fosmethilan (fosmethilan), fospirate (fospirate), fosthiazate (fosthiazate), fosthietan (fosthietan), Frontalin, Rabcide (fthalide), furidazol (fuberidazole), flur (fucaojing), fluofazone (fucaomi), fluorine bacterium mite ester (fujunmanzhi), fluorochloro ether (fulumi), coumafuryl (fumarin), fluoronaphthalene diclofop-methyl (funaihecaoling), Fuphenthiourae (fuphenthiourea), ethylene glycol contracting alditol (furalane), furalaxyl (furalaxyl), proventhrin (furamethrin), furametpyr (furametpyr), furan tebufenozide (furan Tebufenozide), furathiocarb (furathiocarb), furcarbanil (furcarbanil), furconazole (furconazole), cis- furconazole_cis (furconazole-cis), furethrin (furethrin), furfural (furfural), solution Careless oxazole (furilazole), seed dressing amine (furmecyclox), furan bacterium grand (furophanate), fluorine furan grass ether (furyloxyfen), γ-BHC, gamma-cyhalothrin, γ-HCH, Genit (genit), gibberellic acid (gibberellic Acid), gibberellin A 3, gibberellin (gibberellins), gliftor (gliftor), gliftor (glitor), chloralose (glucochloralose), glufosinate-ammonium (glufosinate), smart glufosinate-ammonium (glufosinate-P), glyoxide (glyodin), glyoxime (glyoxime), glyphosate (glyphosate), glyphosine (glyphosine), pink bollworm property Lure (gossyplure), Grandemone (grandlure), griseofulvin (griseofulvin), Guanoctine (guanoctine), the pungent salt of biguanides (guazatine), halacrinate (halacrinate), fluorine chloropyridine ester (halauxifen), halfenprox (halfenprox), chlorine tebufenozide (halofenozide), fluorine nitre sulfonamide (halosafen), Halosulfuronmethyl (halosulfuron), halozydine (haloxydine), fluazifop-butyl (haloxyfop), smart fluazifop-butyl (haloxyfop-P), fluazifop-butyl-R, HCA, HCB, HCH, γ-HCH, hexamethyl melamine (hemel), hempa (hempa), HEOD, heptachlor (heptachlor), heptafluthrin, heptenophos (heptenophos), heptopargil (heptopargil), Herbimycin (herbimycin), Antibiotic TAN 420F, speed kill sulphur phosphorus (heterophos), chlordene, six six six (hexachloran), Hexachloroacetone, hexachloro-benzene, hexachlorobutadiene, hexachlorophene, hexaconazole (hexaconazole), flubenzuron (hexaflumuron), Hexafluoramin, hexafluoride (hexaflurate), hexalure (hexalure), caproamide (hexamide), ring piperazine Ketone (hexazinone), own sulphur phosphorus (hexylthiofos), Hexythiazox (hexythiazox), HHDN, holosulf, high rape Plain lactone (homobrassinolide), ring grass oxime (huancaiwo), CGA 183893 (huanchongjing), sulphur grass spirit (huangcaoling), ciproconazole (huanjunzuo), hydramethylnon (hydramethylnon), hydrargaphen (hydrargaphen), white lime, cyanamide, hydrogen cyanide, hydroprene (hydroprene), S- hydroprene, hydroxyl isoxazole (hydroxyisoxazole), 4- hydroxylphenylethyl alcohol, 8- sulfovinic acid quinoline (8-hydroxyquinoline sulfate), evil Mould spirit (hymexazol), quinoline prestige (hyquincarb), IAA, IBA, IBP, Icaridin (icaridin), imazalil (imazalil), miaow grass ester (imazamethabenz), imazamox (imazamox), imazapic (imazapic), Imazapyr (imazapyr), Scepter (imazaquin), Imazethapyr (imazethapyr), imidazoles sulphur are grand (imazosulfuron), glyoxalin (imibenconazole), new cigarette phosphorus (imicyafos), imidacloprid (imidacloprid), imidaclothiz (imidaclothiz), iminoctadine (iminoctadine), Imiprothrin (imiprothrin), inabenfide (inabenfide), indanofan (indanofan), indenes piperazine benfluralin (indaziflam), indenes Worm prestige (indoxacarb), inezin (inezin), infusorial earth (infusorial earth), iodine oxalic acid dinitrile (iodobonil), iodine gram prestige (iodocarb), iodfenphos (iodofenphos), iodomethane, iodine metsulfuron-methyl (iodosulfuron), excellent fragrant sulphur grand (iofensulfuron), ioxynil (ioxynil), ipazine (ipazine), IPBC, IPC, kind bacterium azoles (ipconazole), three azole amides (ipfencarbazone), three Fluconazoles of Chinese mugwort point (ipfentrifluconazole), different rice blast net (iprobenfos), iprodione (iprodione), iprovalicarb (iprovalicarb), Bing Caoding (iprymidam), ipsdienol (ipsdienol), ipsenol (ipsenol), IPSP, IPX, isazofos (isamidofos), fluorine azoles phosphorus (isazofos), Telodrin (isobenzan), isocarbamide (isocarbamid), fourth amidine amide (isocarbamide), isocarbophos (isocarbophos), isoprocil (isocil), different Drinox (isodrin), propylamine phosphorus (isofenphos), methyl propylamine phosphorus, isopropyl metsulfovax (isofetamid), Isoflucypram, isolan (isolan), butylamine piperazine (isomethiozin), isonoruron (isonoruron), different phosphorus is sent (isopamphos), isopolinate, Mobucin (isoprocarb), isoprocil (isoprocil), isopropalin (isopropalin), fluazolate (isopropazol), Isoprothiolane (isoprothiolane), isoproturon (isoproturon), azoles naphthalene bacterium amine (isopyrazam), different phonetic alcohol (isopyrimol), Hosdon (isothioate), different thiophene It is bacterium amine (isotianil), isouron (isouron), different acyl bacterium ketone (isovaledione), isoxaben (isoxaben), different Dislike chlorine humulone (isoxachlortole), isoxadifen (isoxadifen), isoxaflutole (isoxaflutole), different evil Careless ether (isoxapyrifop), isoxathion (isoxathion), isuron, ivermectin (ivermectin), isoxaben (ixoxaben), izopamfos (izopamfos), izopamfos (izopamphos), japonilure, japothrins (japothrins), jasmolin I (jasmolin I), jasmolin II, jasmonic (jasmonic acid), methylsulphur worm hydrazone (jiahuangchongzong), methyl Synergistic Phosphorus (jiajizengxiaolin), first fragrant bacterium ester (jiaxiangjunzhi), solution Humulane (jiecaowan), desorpenic (jiecaoxi), jinggangmycin A (Jinganmycin A), iodfenphos (jodfenphos), Juvenile hormone I, juvenile hormone II, juvenile hormone III, Kadethrin (kadethrin), κ-Biphenthrin (kappa- Bifenthrin), κ-Tefluthrin (kappa-tefluthrin), karbutilate (karbutilate), Ka Tazan (karetazan), kasugarnycin (kasugamycin), gram bacterium spirit (kejunlin), penta ring of chlorine (kelevan), gram spiral shell are more (ketospiradox), diatomite (kieselguhr), kinetin (kinetin), kinoprene (kinoprene), S- alkene worm Alkynes ester (S-kinoprene), kiralaxyl, kresoxim-methyl (kresoxim-methyl), quinoline oxalene (kuicaoxi), diclofop-methyl (lactofen), Rule (latilure), arsenic are replaced in λ-lambda-cyhalothrin (lambda-cyhalothrin), lancotrione, drawing Lead plumbate, lenacil (lenacil), rayperidin (lepimectin), teptophos (leptophos), Bifenazate (lianbenjingzhi), lime sulfur (lime sulfur), (R)-4-isopropenyl-1-methyl-1-cyclohexene (d-limonene), lindane (lindane), three Three cyclononane of methyl dioxy (lineatin), linuron (linuron), pyridine worm phosphorus (lirimfos), litlure, cabbage looper Gyplure (looplure), lufenuron (lufenuron), chlorine fluorine cyanogen insect amide (l ü fuqingchongxianan), chlorine acyl grass phosphine (l ü xiancaolin), chlorine nalidixic bacterium ester (lvdingjunzhi), fluorine chlorine ether pyrethroids (lvfumijvzhi), chlorine acyl grass phosphine (lvxiancaolin), remove the evil phosphorus (lythidathion), M-74, M-81, MAA, magnesium phosphide, malathion (malathion), Marathon (maldison), maleic acid hydrazide (maleic hydrazide), the third mite cyanogen (malonoben), maltodextrin (maltodextrin), MAMA, mancopper (mancopper), Mancozeb (mancozeb), Man get Luo Bin (mandestrobin), mandipropamid (mandipropa-mid), maneb (maneb), matrine (matrine), nitrine Phosphorus (mazidox), MCC, MCP, 1-MCP, MCPA, 2,4-MCPA, MCPA- thioethyl ester, MCPB, 2,4-MCPB, MCPP, adjacent acyl Amine (mebenil), Afos (mecarbam), first prestige benzene miaow (mecarbinzid), mecarphon (mecarphon), 2- first -4- Chloropropionic acid (mecoprop), essence 2- first -4- chloropropionic acid (mecoprop-P), medimeform (medimeform), medinoterb acetate (medinoterb), Medlure (medlure), mefenacet (mefenacet), Metalaxyl-M (mefenoxam), pyrazoles solution Oxalic acid (mefenpyr), fluorine chlorine ether bacterium azoles (mefentrifluconazole), mefluidide (mefluidide), Mei Jiate Acid (megatomoic acid), melissyl alcohol (melissyl alcohol), dicoumarin (melitoxin), MEMC, aphid of going out Loose (menazon), MEP, mepanipyrim (mepanipyrim), fluorine chlorine ether pyrethroids (meperfluthrin), mephenate, amine Phosphorus (mephosfolan), strong cotton element (mepiquat), mebenil (mepronil), the mite that disappears more (meptyldinocap), deinsectization Prestige (mercaptodimethur), Entex (mercaptophos), Entex mercaptan (mercaptophos thiol), horse traction Sulphur phosphorus (mercaptothion), mercury oxide, calogreen, De-Green (merphos), merphos oxide, goes out at mercury chloride Green bristlegrass saliva (mesoprazine), mesosulfuron (mesosulfuron), mesotrione (mesotrione), mesulfen (mesulfen), first oxydemeton_methyl (mesulfenfos), mesulfen (mesulphen), metacresol, metaflumizone (metaflumizone), metalaxyl (metalaxyl), Metalaxyl-M (metalaxyl-M), R- metalaxyl, the methaldehyde (metaldehyde), metham-sodium (metam), metamifop (metamifop), metamitron (metamitron), methyl pair Sulphur phosphorus (metaphos), metaxon, metazachlor (metazachlor), bis ether halosulfuronmethyl (metazosulfuron), M-chloro drazoxolon (metazoxolon), metcamifen, metconazole (metconazole), metepa (metepa), diformazan Norflurazon (metflurazon), methabenz thiazuron (methabenzthiazuron), methacrifos (methacrifos), fluorine alkene nitre grass (methalpropalin), metham-sodium (metham), acephatemet (methamidophos), methasulfocarb (methasulfocarb), Methazole (methazole), methuroxam (methfuroxam), methabenzthiazuron (methibenzuron), methidathion (methidathion), first sulphur benzene prestige (methiobencarb), methiocarb (methiocarb), Sulfonylurea (methiopyrisulfuron), Metapside (methiotepa), first sulphur oxazoline (methiozolin), methiuron (methiuron), desinsection ethephon (methocrotophos), MTMC (m é tholcarb), weed eradication lead to (methometon), Methomyl (methomyl), methoprene (methoprene), S- methoprene, methoxy third net (methoprotryn), methoxy third are net (methoprotryne), butyl quinacrine (methoquin-butyl), methothrin (methothrin), methoxychlor (methoxychlor), 2 methoxyethyl mercury chloride, methoxyfenozide (methoxyfenozide), Kayaphenone (methoxyphenone), sterile spy (the methyl apholate), methyl bromide, methyl eugenol (methyl of methyl Eugenol), iodomethane, methyl propylamine phosphorus, methyl-isorhodanate, parathion-methyl (methyl parathion), Methylethyl Phosphorus (methylacetophos), methyl chloroform (methylchloroform), 1- methyl cyclopropene, methyl dithiocarbamates first Acid, methyldymron (methyldymron), methylene chloride, methyl Entex (methylmer-captophos), methyl times sulphur Phosphorous oxides (methylmercaptophos oxide), methyl Entex mercaptan, benzoic acid methyl mercury, morsodren (methylmercury dicyandiamide), methyl mercury pentachlorophenolate (methylmercury Pentachlorophenoxide), the new decyl amide of methyl (methylneodecanamide), fenifrothion (methylnitrophos), azinphos-methyl (methyltriazothion), first sulphur oxazoline (metiozolin), Carbatene (metiram), Carbatene zinc (metiram-zinc), metobenzuron (metobenzuron), metobromuron (metobromuron), first Oxygen benzyl Flumethrin (metofluthrin), ε-metofluthrin (epsilon-metofluthrin), propisochlor (metolachlor), S- propisochlor, MTMC (metolcarb), tribenuron-methyl (metometuron), SSF 126 (metominostrobin), metosulam (metosulam), metoxadiazone (metoxadiazone), metoxuron (metoxuron), metrafenone (metrafenone), Carbatene (metriam), metribuzin (metribuzin), Metrifonate (metrifonate), Metrifonate (metriphonate), metsulfovax (metsulfovax), metsulfuron-methyl (metsulfuron), Menite (mevinphos), Mexacarbate (mexacarbate), destroyed (miechuwei), RH-945 (mieshuan), mosquito eradication Pyrethroids (miewenjuzhi), the mite rhzomorph (milbemectin) that goes out, Mir are than mycin oxime compounds (milbemycin oxime), generation Gloomy ring (milneb), mite of going out mutter (mimanan), mipafox (mipafox), MIPC, mirex (mirex), MNAF, mushroom alcohol (moguchun), molinate (molinate), Cupric sulfate (molosultap), monalide (monalide), monalide, Momfluorothrin, epsilon-momfluorothrin, special dimefuron (monisuron), single carbonamidine (monoamitraz), chloroacetic acid, Azodrin (monocrotophos), afesin (monolinuron), Cupric sulfate (monomehypo), sulfiram (monosulfiram), monosulfmeturon (monosulfuron), Cupric sulfate (monosultap), Telvar (monuron), telvar-TCA, Ceroxone (morfamquat), moroxydine (moroxydine), morphothion (morphothion), morzid, moxidectin (moxidectin), MPMC, MSMA, MTMC, α-multistriatin, lure worm Alkene (muscalure), nitrile bacterium azoles (myclobutanil), myclozolin (myclozolin), melissyl alcohol (myricyl Alcohol), NAA, NAAm, Dithane A40 (nabam), naftalofos (naftalofos), 2-dichloroethylk dimethyl phosphate (naled), naphthalene (naphthalene), naphthaleneacetamide, α-naphthylacetic acid, naphthalic anhydride, naftalofos (naphthalophos), 1- naphthols (1- Naphthol), naphthoxy acetic acid (naphthoxyacetic acid), methyl α-naphthyl acetate, naphthalene indane -1,3- diketone (naphthylindane-1,3-diones), naphthoxy acetic acid, naproanilide (naproanilide), napropamide (napropamide), napropamide-M, quinclorac (naptalam), natamycin (natamycin), NBPOS, neburea (neburea), neburea (neburon), nendrin, anabasine (neonicotine), nichlorfos (nichlorfos), Niclofen, niclosamidum (niclosamide), Boscalid (nicobifen), nicosulfuron (nicosulfuron), cigarette Alkali (nicotine), nicotine sulphate, volt ant spirit (nifluridide), nikkomycin (nikkomycin), NIP, nipyralofen (nipyraclofen), pyrrole chlorine grass amine (nipyralofen), Nitenpyram (nitenpyram), nithiazide (nithiazine), nitralin (nitralin), trichloromethyl pyridine (nitrapyrin), nitrilacarb (nitrilacarb), remove Careless ether (nitrofen), fluoroform grass ether (nitrofluorfen), nitrostyrolene, nitrothalisopropyl (nitrothal- Isopropyl), Shoxin (nobormide), nonyl alcohol, Shoxin (norbormide), herban (norea), norflurazon (nor-flurazon), Ninicotine (nornicotine), herban (noruron), novaluron (novaluron), noviflumuron (noviflumuron), NPA, nuarimol (nuarimol), slave mutter ketone (nuranone), OCH, Octachlorodipropyl Ether, pungent thiophene Ketone (octhilinone), 2- (octylsulfo) ethyl alcohol, o-dichlorohenzene, fenfuram (ofurace), flolimat (omethoate), o-phenyl phenol, weeding red (orbencarb), orfralure, drought red (orthobencarb), adjacent dichloro Benzene, orthosulfamuron (orthosulfamuron), oryctalure, orysastrobin (orysastrobin), oryzalin (oryzalin), Osthole (osthol), Osthole (osthole), ostramone, ovatron, chlorfenizon (ovex), Oxabetrinil (oxabetrinil), oxadiargyl (oxadiargyl), oxadiazon (oxadiazon), Wakil (oxadixyl), oxamate (oxamate), oxamyl (oxamyl), grass rattle away loose (oxapyrazon), careless pyridazone (oxapyrazone), oxasulfuron (oxasulfuron), fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin), oxaziclomefone (oxaziclomefone), copper 8-hydroxyquinolinate (oxine-copper), quinoline-Cu, oxolinic acid (oxolinic acid), evil imidazoles (oxpoconazole), oxycarboxin (oxycarboxin), metilomerkaptofosoksid (oxydemeton-methyl), oxydeprofos (oxydeprofos), Disystom-s (oxydisulfoton), oxyenadenine (oxyenadenine), Oxyfluorfen (oxyfluorfen), oxymatrine (oxymatrine), terramycin (oxytetracycline), chinomethionat (oxythioquinox), PAC, paclobutrazol (paclobutrazol), paichongding (paichongding), allethrin (pall é Thrine), PAP, paracide, to fluon (parafluron), paraquat (paraquat), parathion (parathion), first Base parathion (parathion-methyl), Felodipine (parinol), copper acetoarsenite (Paris green), PCNB, PCP, PCP-Na, paracide, PDJ, pebulate (pebulate), Dinitrocyclohexylphenol (p é dinex), pefurazoate (pefurazoate), N-nonanoic acid (pelargonic acid), penconazole (penconazole), Pencycuron (pencycuron), pendimethalin (pendimethalin), benzethazet acetofenate (penfenate), fluorine azoles bacterium aniline (penflufen), penfluron (penfluron), Pendimethalin (penoxalin), penoxsuam (penoxsulam), pentachlorophenol, lauric acid pentachloro- Phenyl ester, pentanochlor (pentanochlor), pyrrole metsulfovax (penthiopyrad), pentmethrin (pentmethrin), ring Penta oxadiazon (pentoxazone), mirex (perchlordecone), yellow grass lie prostrate (perfluidone), Permethrin (permethrin), pethoxamid (pethoxamid), PHC, 2-cyano-3-amino-3-phenylancryic acetate (phenamacril), ethyl 2-cyano-3-amino-3-phenylancryic acetate, ph é Naminosulf, phenazine oxide (phenazine oxide), ph é n é tacarbe, phenisopham (phenisopham), phenkapton (phenkapton), phenmedipham (phenmedipham), ethyl phenmedipham, phenobenzuron (phenobenzuron), phenothiol (phenothiol), phenothrin (phenothrin), phenproxide (phenproxide), phenthoate dimephenthoate cidial (phenthoate), 8- benzene Base mercury phenoxyl quinoline (8-phenylmercurioxyquinoline), phenyl mercury urea (phenylmercuriurea), acetic acid benzene Mercury changes benzene mercury, the benzene Mercury derivatives of catechol, phenylmercuric nitrate, Mercusol, 2- phenylphenol, thimet (phorate), Gophacide (phosacetim), Phosalone (phosalone), phosphorus go out fourth (phosametine), Gophacide (phosazetim), Gophacide (phosazetin), three phosphor tins (phoscyclotin), phosdiphen (phosdiphen), mould epidemic disease Only (phosethyl), phosfolan (phosfolan), phosfolan_methyl, phosglycin (phos-glycin), phosmet (phosmet), nichlorfos (phosnichlor), phosphamide, phosphamidon, hydrogen phosphide (phosphine), phosphine oxamate (phosphinothricin), phosphorus worm prestige (phosphocarb), phosphorus, three phosphor tins (phostin), phoxim (phoxim), methyl Phoxim, Rabcide (phthalide), naftalofos (phthalophos), tetramethrin (phthalthrin), Picarbutrazox, Pai Karuiding (picaridin), picloram (picloram), pyrrole Clovoxamine (picolinafen), pyridine Oxygen bacterium ester (picoxystrobin), pimaricin (pimaricin), Duocide (pindone), pinoxaden (pinoxaden), pipron (piperalin), piperazine, Butacide (piperonyl butoxide), piperonyl cyclohexenone (piperonyl cyclonene), piperophos (piperophos), piperazine strong plain (piproctanly), the strong element of piperazine (piproctanyl), Piprotal (piprotal), methylamine crow phosphorus (pirimetaphos), Aphox (pirimicarb), Piriminil, pyrimidine oxygen (pirimioxyphos), ethyl-pyrimidine phosphorus (pirimiphos-ethyl), pirimiphos-methyl, spy Valeryl indandione rodenticide (pival), benzethazet acetofenate (plifenate), PMA, PMP, polybutene, is gathered Duocide (pivaldione) Carbamate, polyethoxy quinoline, polyoxin D (polyoxin D), resists toxaphene (polychlorcamphene) more Mycin, Polyoxin (polyoxorim), polythiane (polythialan), potassium arsenite, potassium azide, potassium cyanate, ethyl are yellow Ortho acid potassium, cyclic potassium naphthenate, potassium polysulfide, potassium rhodanide, pp '-DDT, Prallethrin (prallethrin), precocene I (precocene I), precocene II, precocene III, pretilachlor (pretilachlor), amide pyrimidine moiety (primidophos), primisulfuronmethyl (primisulfuron), probenazole (probenazole), Prochloraz (prochloraz), Proclonol (proclonol), cyclopropylniitrile saliva (procyazine), procymidone (procymidone), prodiamine (prodiamine), Profenofos (profenofos), profluazol (profluazol), profluralin (profluralin), third Flumethrin (profluthrin), clefoxidim (profoxydim), desinsection pacify (profurite-aminium), proglinazine (proglinazine), naphthenic acid (prohexadione), Prophyl dihydro jasmonate (prohydrojasmon), promacyl are adjusted (promacyl), Carbamult (promecarb), prometon (prometon), prometryn (prometryn), prometryn (prometryne), promurit (promurit), pronamide (pronamide), propachlor (propachlor), Kayaphos (propafos), propamidine (propamidine), Propamocarb (propamocarb), propanil (propanil), Kayaphos (propaphos), propaquizafop (propaquizafop), propargite (propargite), proparthrin (proparthrin), Put out net (propazine), propetamphos (propetamphos), Chem hoe (propham), propiconazole (propiconazole), Piperidines (propidine), propineb (propineb), propisochlor (propisochlor), arprocarb (propoxur), procarbazone (propoxycarbazone), propyl isome (propyl isome), the third Sulfometuron Methyl (propyrisulfuron), propyzamide (propyzamide), the third oxygen quinoline (proquinazid), Psoralen lactone (prosuler), methyl mercapto nitralin (prosulfalin), prosulfocarb (prosulfocarb), the third sulphur of fluorine are grand (prosulfuron), prothidathion (prothidathion), prothiocarb (prothiocarb), prothioconazoles (prothioconazole), Toyodan (prothiofos), Fac (prothoate), cyclopropyl chlorine ether (protrifenbute), Good-rite n.i.x. (proxan), prymidophos, prynachlor (prynachlor), psoralen (psoralen), psoralen (psoralene), pydanon, pydiflumetofen, pyflubumide, pymetrozine (pymetrozine), pyracarbolid (pyracarbolid), pyraclofos (pyraclofos), pyraclonil (pyraclonil), pyraclostrobin (pyraclostrobin), pyraflufen-ethyl (pyraflufen), Fipronil (pyrafluprole), Pyramat (pyramat), azoles amine Bacterium ester (pyrametostrobin), pyraoxystrobin (pyraoxystrobin), sulphonyl grass pyrazoles (pyrasulfotole), pyrazoles are phonetic Pyridine (pyraziflumid), pyrazoxyfen (pyrazolynate), pyrazon (pyrazon), determines bacterium at pyrazolate (pyrazolate) Phosphorus (pyrazophos), pyrrole sulphur grand (pyrazosulfuron), pyrazothion (pyrazothion), general fragrant grass (pyrazoxyfen), anti-Chryson (pyresmethrin), pyrethrins I, chrysanthemumdicarboxylic acid monomethyl ester pyrethrolone ester, pyrethrins (pyrethrins), iso-propyl-ester nitrofen (pyribambenz-isopropyl), propyl-ester nitorfen (pyribambenz-propyl), Pyrrole bacterium benzene prestige (pyribencarb), pyribenzoxim (pyribenzoxim), pyributicarb (pyributicarb), trichloropyridine Phenol (pyriclor), alcohol pyridazines (pyridafol), pyridalyl (pyridalyl), reaches piperazine sulphur phosphorus at pyridaben (pyridaben) (pyridaphenthion), pyridaphethione (pyridaphenthione), pyridate (pyridate), pyridinitril (pyridinitril), pyrifenox (pyrifenox), fluorine worm pyrrole quinoline (pyrifluquinazon), pyriftalid (pyriftalid), group go out his phosphorus (pyrim é taphos), pyrimethanil (pyrimethanil), send phonetic prestige ((pyrimicarbe), pyrimidifen (pyrimidifen), KIH 6127 (pyriminobac), pyriminostrobin (pyriminostrobin), pirimiphos ethyl (pyrimiphos- é thyl), methyl Actellic (pyrimiphos-m é thyl), Pyrimisulfan, Diothyl (pyrimitate), pyrinuron (pyrinuron), pyriofenone, pyrazoles worm pyridine (pyriprole), pyridine alcohol (pyripropanol), Nylar (pyriproxyfen), oxazole (pyrisoxazole), Pyrithiobacsodium (pyrithiobac), pyrolan (pyrolan), pyroquilon (pyroquilon), phonetic oxygen sulfone (pyroxasulfone), pyroxsulam (pyroxsulam), chlorine pyrrole spirit (pyroxychlor), KIH 9201 (qincaosuan), green withered spirit (qingkuling), quassia (quassia), quinocetone (quinacetol), quinalphos (quinalphos), methyl quinalphos, quinazamid (quinazamid), chloro-quinolinic acid (quinclorac), quinoline gram azoles (quinconazole), quinmerac (quinmerac), quinoclamine (quinoclamine), quinofumelin, Chinomethionate (quinomethionate), quinone duckweed amine (quinonamid), the peaceful phosphorus (quinothion) of poultry, quinoxyfen (quinoxyfen), Quinalphos (quintiofos), pentachloronitrobenzene (quintozene), quizalofop-ethyl (quizalofop), Quizalotop-ethyl (quizalofop-P), dimethyl phthalate (quwenzhi), drive fly determine (quyingding), pyrrole imidazoles (rabenzazole), Lei Funi Special (rafoxanide), R- olefin conversion (R-diniconazole), rebemide, diquat dibromide (reglone), Renofluthrin, renriduron, rescalure, resmethrin (resmethrin), d-trans resmethrin, sulphur cyanogen Aniline (rhodethanil), Chinese azalea extract-III (rhodojaponin-III), Ribavirin (ribavirin), rimsulfuron (rimsulfuron), butene-fipronil (rizazole), R- metalaxyl (R-metalaxyl), rodethanii (rod é Thanil), Nankor (ronnel), rotenone (rotenone), ryania (ryania), caustic barley (sabadilla), pyrimidine Sulphamide (saflufenacil), thiophene bacterium cyclopentadienyl (saijunmao), the gloomy ketone of thiophene (saisentong), salicylanilide (salicylanilide), silafluofene (salifluofen), sanguinarine (sanguinarine), santonin (santonin), Sarolaner, S-bioallethrin (S-bioallethrin), schradane (schradan), scilliroside (scilliroside), another fourth saliva (sebuthylazine), secbumeton (secbumeton), fluorine azoles ring bacterium amine (sedaxane), Selamectin (selamectin), single carbonamidine (semiamitraz), sesoxane (sesamex), sesamolin (sesamolin), match Loose (sesone), sethoxydim (sethoxydim), sevin (sevin), S- hydroprene (S-hydroprene), double methylamines grass Phosphorus (shuangjiaancaolin), the careless phosphorus (shuangjianancaolin) in double first south, Tupersan (siduron), tetrafluoro ether chrysanthemum Ester (sifumijvzhi), siglure (siglure), silafluofene (silafluofen), silatran (silatrane), silicon gas Gel (silica aerogel), silica gel, sulphur silicon bacterium amine (silthiofam), sulphur silicon bacterium amine (silthiopham), Silthiopham (silthiophan), tears propionic acid (silvex), Simanex (simazine), simeconazoles (simeconazole), Gesadrual (simeton), symetryne (simetryn), symetryne (simetryne), sintofen (sintofen), S- kinoprene (S- Kinoprene), white lime (slaked lime), SMA, S- methoprene (S-methoprene), S- propisochlor (S- Metolachlor), sodium arsenite, sodium azide, sodium chlorate, Cymag, sodium fluoride, Fratol, sodium hexafluorisilicate, cycloalkanes Sour sodium, sodium-o-phenyl phenolate, sodium pentachlorophenol, sodium pentachlorophenol, sodium-o-phenyl phenolate, sodium polysulfide, prodan, tetraboric acid Disodium, sodium tetrathiocarbonate, sodium sulfocyanate, pentanochlor (solan), sophamide (sophamide), ethyl pleocidin (spinetoram), pleocidin (spinosad), Envidor (spirodiclofen), Spiromesifen (spiromesifen), Spiral shell worm ethyl ester (spirotetramat), volution bacterium amine (spiroxamine), stirofos (stirofos), streptomysin (streptomycin), strychnia (strychnine), sulcatol (sulcatol), sulphur worm urea (sulcofuron), Sulphur humulone (sulcotrione), sulfallate (sulfallate), sulfentrazone (sulfentrazone), sulfiram (sulfiram), sulfluramid (sulfluramid), sulfodiazole, Sulfometuron Methyl (sulfometuron), sulphosate (sulfosate), Sulfosulfuron (sulfosulfuron), sulfotep (sulfotep), sulfotep (sulfotepp), sulfone worm pyridine (sulfoxaflor), sulfoxide (sulfoxide), sulfoxime (sulfime ether), sulphur, sulfuric acid, vikane, a word used for translation sulphur in heptan ester (sulglycapin), sulphosate (sulphosate), sulprofos (sulprofos), sultropen (sultropen), swep (swep), 2,4,5-T, τ-taufluvalinate (tau-fluvalinate), tavron (tavron), tazimcarb (tazimcarb), 2,4,5-TB, 2,3,6-TBA, TBTO, TBZ, TCA, TCBA, TCMTB, TCNB, TDE, Tebuconazole (tebuconazole), tebufenozide (tebufenozide), tebufenpyrad (tebufenpyrad), tebufloquin, butyl pyrimidine Phosphorus (tebupirimfos), tebutam (tebutam), tebuthiuron (tebuthiuron), tecloftalam (tecloftalam), tetrachloro Nitrobenzene (tecnazene), tecoram, tetradiphon (tedion), diflubenzuron (teflubenzuron), Tefluthrin (tefluthrin), κ-Tefluthrin (kappa-tefluthrin), special furans grand (tefuryltrione), tembotrions (tembotrione), Swebate (temefos), Swebate (temephos), for sending (tepa), TEPP, tepraloxydim (tepraloxydim), tepraloxydim (teproloxydim), terallethrin (terallethrin), terbacil (terbacil), terbucarb (terbucarb), terbuchlor (terbuchlor), terbufos (terbufos), Te Dingtong (terbumeton), Garagard (terbuthylazine), Azac (terbutol), terbutryn (terbutryn), terbutryn (terbutryne), terraclor, terramycin (terramicin), terramycin (terramycin), tetcyclacis (tetcyclacis), tetrachloroethanes, Ravap (tetrachlorvinphos), tetraconazole (tetraconazole), trichlorine Sulfenone (tetradifon), tetradisul, four fluon (tetrafluron), tetramethrin (tetramethrin), tetrafluoro ether Pyrethroids (tetramethylfluthrin), Tetramine (tetramine), polynactin (tetranactin), fluorine cyanogen worm Amide (tetraniliprole), tetrapion (tetrapion), Diphenylsulfide (tetrasul), thallium sulfate (thallium Sulfate), thallous sulfate (thallous sulfate), thiophene first chlorine (thenylchlor), θ-cypermethrin (theta- Cypermethrin), probenazole (thiabendazole), thiacloprid (thiacloprid), thiadiazine (thiadiazine), Thiophene difluoro (thiadifluor), Diacloden (thiamethoxam), thifensulfuron methyl (thiameturon), thiapronil (thiapronil), thiazfluron (thiazafluron), thiazfluron (thiazfluron), thiophene ketone (thiazone), thiophene grass are fixed (thiazopyr), benzene thiophene sulphur phosphorus (thicrofos), thicyofen (thicyofen), thiadiazoles grass amine (thidiazimin), thiophene Benzene grand (thidiazuron), thiophene ketone sulphur grand (thiencarbazone), thifensulfuron methyl (thifensulfuron), thifluzamide (thifluzamide), thimerosal (thimerosal), thimet (thimet), benthiocarb (thiobencarb), Talcord (thiocarboxime), hexachloro-benzene imines (thiochlorfenphim), sulphur chlorobenzene imines (thiochlorphenphime), Thiocyanogen dinitrobenzene, thiocyclam (thiocyclam), match pellet (thiodan), Thiodiazole-copper (thiodiazole-copper), sulphur Double prestige (thiodicarb), thiofanox (thiofanocarb), thiofanox (thiofanox), sufluoxime (thiofluoximate), thio hempa (thiohempa), thimerosal (thiomersal), thiometon (thiometon), thionazin (thionazin), thiophanate (thiophanate), ethyl thiophanate, thiophanate-methyl, to sulphur Phosphorus (thiophos), Eradex (thioquinox), thiosemicarbazides (thiosemicarbazide), dimehypo (thiosultap), thiotepa (thiotepa), oxamyl (thioxamyl), thiram (thiram), thiuram (thiuram), thuringiensin (thuringiensin), thiabendazolum (tiabendazole), tiadinil (tiadinil), Eliminate it is fragrant that (tiafenacil, adjust amine (tiaojiean), TIBA, Tifatol (tifatol), tiocarbazil (tiocarbazil), Phonetic grass amine (tioclorim) kills sweet smell (tioxazafen), sulphur benzonitrile first (tioxymid), TMTD, Tirpate for evil (tirpate), tolelofos-methyl (tolclofos-methyl), Tolfenpyrad (tolfenpyrad), tolprocarb, Tolpyralate, Tolylfluanid (tolyfluanid), Tolylfluanid (tolylfluanid), cresyl violet base mercury (tolylmercury acetate), coumafuryl (tomarin), topramezone (topramezone), toxaphene (toxaphene), 2,4,5-TP, 2,3,3-TPA, TPN, tralkoxydim (tralkoxydim), tralocythrin (tralocythrin), tralomethrin (tralomethrin), bromo pyrrole carbonitrile (tralopyril), d-trans propylene chrysanthemum Ester, d-trans resmethrin, transfluthrin (transfluthrin), trans permethrin (transpermethrin), song His amine (tretamine), tri-allate (tri-allate), triacontanol (triacontanol), triazolone (triadimefon), Triadimenol (triadimenol), fluorine ketone sulphur grass amine (triafamone), tri-allate (triallate), prestige Bacterium phosphorus (triamiphos), triapenthenol (triapenthenol), triarathene (triarathene), triarimol (triarimol), Triasulfuron (triasulfuron) frustrates aphid prestige (triazamate), triazbutil (triazbutil), triaziflam (triaziflam), Hostathion (triazophos), Hostathion (triazothion), azoles bacterium piperazine (triazoxide), ternary chlorine Change copper, ternary copper sulphate, tribenuron-methyl, De-Green (tribufos), tributyl tin oxide (tributyltin oxide), kill Grass fear (tricamba), trichlamide (trichlamide), trichlopyr (trichlopyr), metrifonate (trichlorfon), different Nankor -3 (trichlormetaphos-3), trichloronat (trichloronat), trichloronate (trichloronate), trichlorine trinitrobenzen, metrifonate (trichlorphon), Triclopyr (triclopyr), chlorine nalidixic bacterium ester (triclopyricarb), three cresols, tricyclazole (tricyclazole), tin tricyclohexylhydroxide, tridemorph (tridemorph), tridiphane (tridiphane), grass reach rule (trietazine), trifenmorph (trifenmorph), trichlorine Third oxygen phosphorus (trifenofos), trifloxystrobin (trifloxystrobin), trifloxysulfuron (trifloxysulfuron), trifluoro Kill piperazine (trifludimoxazin), trifluoro-benzene pyrimidine (triflumezopyrim), fluorine bacterium azoles (triflumizole), desinsection in ground Grand (triflumuron), trefanocide (trifluralin), triflusulfuronmethyl, trifop, trifluoro dogstail oxime (trifopsime), piperazine Ammonia spirit (triforine), trihydroxy triazine (trihydroxytriazine), tri--iodo-benzoic acid of 2,3,5-, tri--iodine of 2,3,5- Benzoic acid lures fly carboxylic ester (trimedlure), Landrin (trimethacarb), trimeturon (trimeturon), TrinexAN_SNacethyl (trinexapac), triphenyltin, triprene (triprene), indenes oxalyl (tripropindan), triptolide (triptolide), tritac (tritac), trithialan (trithialan), triticonazole (triticonazole), trifluoro methylsulphur Grand (tritosulfuron), trunc-call, disleave clever (tuoyelin), uniconazole P (uniconazole), smart uniconazole P (uniconazole-P), good fortune manicure arsenic (urbacide), uredepa (uredepa), valerate, valida (validamycin), Validacin (Takeda), downy mildew go out (valifenalate), Duocide (valone), Kilval (vamidothion), Vangard (vangard), vaniliprole, vernolate (vernolate), vinclozolin (vinclozolin), vitamine D3, Warfarin (warfarin), sulfur-phosphor (xiaochongliulin), octyl trichlamide (xinjunan), alkene oxime amine (xiwojunan), Enestroburin (xiwojunzhi), XMC, xylachlor (xylachlor), dimethlbenzene (xylenols), Meobal (xylylcarb), killing azoles (xymiazole), suppression food hydrazine (yishijing), zarilamid (zarilamid), zeatin (zeatin), Octacide 264 (zengxiaoan, Synergistic Phosphorus (zengxiaolin), ζ-cypermethrin (zeta-cypermethrin), zinc naphthenate, zinc phosphide, zinc thiazole (zinc Thiazole), zinc thiazole (zinc thiazole), zinc trichlorophenate (zinc trichlorophenate), zinc trichlorophenate (zinc Trichlorophenoxide), zineb (zineb), ziram (ziram), Zuo Lapu phosphorus (zolaprofos), Warfarin (zoocoumarin), zoxamide (zoxamide), azoles amine bacterium ester (zuoanjunzhi), cafenstrole (zuocaoan), azoles bacterium Ester (zuojunzhi), azoles Sulfometuron Methyl (zuomihuanglong), 1-MCP, 1- methyl cyclopropene, 1- naphthols, 1,2- dichloro third Alkane, 1,3-D, 1,3- dichloropropane, 2iP, 2 methoxyethyl mercury chloride, 2- (octylsulfo) ethyl alcohol, 2- phenylphenol, 2,3, 3-TPA, 2,3,5 triiodobenzoic acid, 2,3,6-TBA, 2,4-D, 2,4-DB, 2,4-DEB, 2,4-DEP, 2,4-DES, 2,4-DP, 2,4-MCPA, 2,4-MCPB, 2,4,5-T, 2,4,5-TB, 2,4,5-TP, (3- ethoxycarbonyl propyl) mercuric bromide, 3,4-DA, 3,4- DB, 3,4-DP, 3,6- lontrel, 4-aminopyridine, 4-CPA, 4-CPB, 4-CPP, 4- hydroxylphenylethyl alcohol, 8- hydroxyl quinoline Quinoline sulfate, 8- phenyl mercury phenoxyl quinoline or its salt, derivative and mixture.
According to embodiment, the first agricultural chemical activity object ingredient is water sensitivity active ingredient.According to embodiment, Water sensitivity active matter includes but is not limited to one of following or more: clodinafop-propargyl (clodinafop-propargyl), Acetamiprid (acetamiprid), pinoxaden (pinoxaden), azimsulfuron (azimsulfuron), tribenuron-methyl (bensulfuron), chlorimuronethyl (chlorimuron), chlorsulfuron, cinosulfuron, cypromisulfuron, ethametsulfuron, ethoxy sulphur Grand, flazasulfuron, fluorine pyridine sulphur grand (flupyrsulfuron), halosulfuronmethyl (halosulfuron), imidazoles sulphur is grand, iodine methylsulphur Grand, mesosulfuron, metsulfuron-methyl, nicosulfuron, primisulfuronmethyl, the third sulphur of fluorine are grand, pyrrole sulphur is grand, rimsulfuron, Sulfometuron Methyl, sulfo nyl Grand, thifensulfuron methyl, triasulfuron, tribenuron-methyl, triflusulfuronmethyl, trifloxysulfuron, tritosulfuron, cloquitocet_mexyl (cloquintocet- Mexyl), Diacloden, mesotrione, cartap (cartap), hydrochloric acid cartap, orthene (acephate), trifluoro Carboxylic grass ether (acifluorfen), acifluorfen sodium (acifluorfen-sodium), Aldicarb (aldicarb), aminocarb (aminocarb), chlorine Fampridine sour (aminopyralid), the clever sodium (asulam sodium) of sulphur grass, pyridine phosphorus (azamethiphos), Bromoxynil (bromoxynil), chloropicrin, dazomet, dicamba, diflufenzopyr, dimethachlor, thiophene grass Amine, bispyribac-sodium-sodium (bispyribac-sodium), efficient P DimethenamidP, Rogor, dinotefuran, DNOC, dodine, endothion, Ethephon (CEPHA),2-(chloroethyl) phosphonic acid, ethiprole, double different thiocyanic acid ethylene sulfide (ethylene bisisothiocyanate sulphide), cyanogen Bacterium ether amines, phosethyl-Al (fosetyl-aluminium), fosthiazate, glufosinate-ammonium (glufosinate-ammonium), biguanides Pungent salt, miaow grass ester-methyl (imazamethabenz-methyl), imazamox, imazapic, imazapyr, weed eradication Quinoline, Imazethapyr, ioxynil, fourth amidine amide, MCPA, MCPB, 2- first -4- chloropropionic acid, metalaxyl, metamitron, metham-sodium sodium (metam-sodium), acephatemet, metribuzin, Azodrin, oxamyl, oxasulfuron, oxycarboxin, picloram-diformazan Base ammonium (picloram-dimethylammonium), picloram-triethanolamine (picloram-trolamine), Aphox, third Tribenuron-methyl-sodium (propoxycarbazone-sodium), pyrithiobac-sodium-sodium (pyrithiobac-sodium), is coughed up general fragrant grass Quinoline ketone (pyroquilone), pyroxsulam, dichloro quinolinic acid-dimethyl ammonium (quinclorac- Dimethylammonium), quinmerac, quinoclamine, pyrimidine sulphamide, sethoxydim, methyl Sulfometuron Methyl, tembotrione, special fourth Saliva, methyl thifensulfuron methyl, thifluzamide, thiocyclam oxalates (thiocyclam hydrogen oxalate), thiocyclam, long effect Prestige, topramezone, methyl tribenuron-methyl (tribenuron-methyl), metrifonate, Triclopyr, uniconazole P, Fipronil and its salt or Derivative.
According to embodiment, the first agricultural chemical activity object ingredient is water-soluble active object.It is water-soluble according to embodiment Active matter includes but is not limited to one of following or more: orthene, Acetamiprid, Acethion (acethion), second Acid, Acetochlor (acetochlor), acetyl worm nitrile (acetoprole), S- methyl Acibenzolar (acibenzolar-S- Methyl), acifluorfen, acifluorfen sodium, aclonifen (aclonifen), methacrylaldehyde, acrylonitrile, double third ring worm esters (afidopyropen), alachlor (alachlor), alanycarb (alanycarb), Aldicarb, aldimorph, aldoxycarb (aldoxycarb), allidochlor (allidochlor), alloxydimsodium (alloxydim), allyl alcohol, allyxycarb (allyxycarb), Alorac, α-chlorethanol, α -5a,6,9,9a-hexahydro-6,9-methano-2,4, α-hexachlorocyclohexanes, alpha-naphthylthiourea, alum, aluminum phosphate, alumina silicate, azoles mepanipyrim (ametoctradin), special saliva ketone (ametridione), ametryn, special careless piperazine ketone (amibuzin), amicarbazone (amicarbazone), amidithion (amidithion), first alachlor, amidosulfuron (amidosulfuron), Mitemate (amidothioate), aminocarb, the third pyrimidine acid of chlorine (aminocyclopyrachlor), chlorine Fampridine acid, amiprophos-methyl, Amisulbrom (amisulbrom), Citram (amiton), dimethylaniline amidine (amitraz), Amrol (amitrole), second Sour ammonium, ammonium carbonate, ammonium hydroxide, Amcide Ammate, ammonium sulfate, ammonium thiocyanate, aminopropyl phosphoric acid (ampropylfos), ring Third ancymidol (ancymidol), anilofos (anilofos), dredges grass grand, ANTU, aramite at anilazine (anilazine) (aramite), the careless clever sodium of arsenic trioxide, asomate (asomate), sulphur, sulphur grass clever (asulam), Chinese mugwort thiophene reach pine, atraton (atraton), atrazine (atrazine), penta ring azoles (azaconazole), grass fragrant fixed, pyridine phosphorus, azimsulfuron, ethyl Azinphos-methyl (azinphos-ethyl), methyl azinphos-methyl, nitrine be net, azithiram (azithiram), azobenzene, Alamos, Azoxybenzene, Fluoxastrobin (azoxystrobin), oatax, barium carbonate, solbar, beflubutamid (beflubutamid), M 9834, benalaxyl-M, benazolinethyl (benazolin ethyl), benazolin, Bencarbazone, benclothiaz, Ficam (bendiocarb), Benfuracard micro (benfuracarb), benfuresate (benfuresate), benodanil (benodanil), benomyl (benomyl), benequinox (benquinox), tribenuron-methyl, methyl Tribenuron-methyl, bensulide (bensulide), bensultap (bensultap), benzene its grand (bentaluron), bentazone (bentazone), benzene metsulfovax-isopropyl (benthiavalicarb-isopropyl), benzene metsulfovax, benzadox ammonium (benzadox-ammonium), benzadox, benzalkonium chloride, benzyl olefin(e) acid isobutyl ester (benzamacril isobutyl), benzyl olefin(e) acid (benzamacril), antibacterial quinoline (benzamorf), benzfendizone (benzfendizone), benzyl grass amine (benzipram), Benzofenap (benzofenap), fluorine sulfanilamide (SN) grass (benzofluor), benzoic acid, benzo alkene fluorine bacterium azoles, Citrazon, suffer (benzoylprop), suffer-ethyl, benzthiazuron (benzthiazuron), Ergol, β-cypermethrin, benzene thiazine (bethoxazin), fluorine benzofenap, Bifenazate (bifenazate), bifenox (bifenox), binapacryl (binapacryl), bioaeroprofen, biopermethrin (biopermethrin), bioresmethrin (bioresmethrin), biphenyl (biphenyl), bis- (2- chloroethyl) ethers, bis- (methyl mercury) sulfate, bispyribac-sodium-sodium, Bisthiosemi, double trichloromethyl sulfones, Bitertanol (bitertanol), Bithionol (bithionol), biphenyl pyrrole bacterium amine (bixafen), animal oil, Bordeaux mixture, boric acid, pyrrole bacterium amide (boscalid), brassin lactones (brassinolide), bromine fluorine Pyrethroids (brofluthrinate), bromacil (bromacil), Bromadiolone (bromadiolone), bromobenzene alkene phosphorus, chaff oxalic acid dinitrile (bromobonil), bromobutide (bromobutide), bromocyclne (bromocyclen), Faneron (bromofenoxim), bromomethane, bromophos, Rilariol, fenisobromolate (bromopropylate), Bromoxynil, bromine grass are quick (brompyrazon), bromine bacterium azoles (bromuconazole), bromuron, bronopol (bronopol), metalkamate (bufencarb), Ding Huancao phosphorus, bupirimate (bupirimate), Buprofezin (buprofezin), butachlor (butachlor), butafenacil (butafenacil), butamifos (butamifos), butanethiol, special Pyrimitate (butathiofos), butenachlor (butenachlor), fourth sulphur imidazolone, Ding Saite (buthiobate), tebuthiuron (buthiuron), butocarboxim (butocarboxim), butonate (butonate), dihydropyrone, butanone sulfone prestige (butoxycarboxim), butralin (butralin), butroxydim (butroxydim), buturon (buturon), butylate (butylate), Phytar (cacodylic acid), cadusafos (cadusafos), cafenstrole (cafenstrole), bone Change alcohol, Loprazolam calcium (calcium acid methanearsonate), calcium arsenate, calcium carbide, calcium carbonate, calcium chloride, cyanogen Ammonification calcium (calcium cyanamide), calcium hydroxide, calcium phosphate, calcium phosphide, kecaoan ester (cambendichlor), poisoning Sweet smell (camphechlor), difoltan (captafol), captan (captan), carbamorph (carbamorph), sok (carbanolate), careless spirit (carbasulam), carbendazim, carbetamide (carbetamide), furadan of sevin, kappa (carbofuran), carbon dioxide, carbon disulfide, carbon tetrachloride, carbophenothion (carbophenothion), carbosulfan (carbosulfan), first grass prestige (carboxazole), carboxin sulfoxide, carboxin, carfentrazoneethyl (carfentrazone- Ethyl), ring propionyl bacterium amine (carpropamid), cartap, hydrochloric acid cartap, oxolinic acide (chinomethionat), pest of going out Azoles (chlobenthiazone), chlomethoxyfen (chlomethoxyfen), chloralose (chloralose), Amiben (chloramben), Imugan (chloraniformethan), four chloro 1,4-benzoquinone (chloranil), chloranocryl (chloranocryl), Rynaxypyr (chlorantraniliprole), chlorazifop propargyl, chloroazifoppropynyl (chlorazifop), chlorazine, chlorbenside, chlorbicyclen, bromax, Chlorophenocarb, Niran, chlordecone, Spanon, chloretazate, chlorine Oxygen phosphorus, ethoxy benzene grand (chloreturon), Fenac, chlorfenapyr, benzene imidazoles bacterium (chlorfenazole), Qikron, methyl Bidisin, chlorfenizon, chlorfensulfide, chlorfenviphos, fluorine crow kill (chlorfluazole), chloroflurenol (chlorfluren methyl), Chlorine fluorenes carboxylic acid (chlorfluren), methyl chloride are for Florencol, chloro Florencol, chloridazon, ethyl chlorimuronethyl, chlormephos, short Strong element chloride, Mo 9 granular, chlorobenzilate, Yi Tuoming, C-9140, chloroneb, chlorophacinone, chloropicrin, chloropon, propyl ester Qikron, chlortoluron, chloroxifenidium, chloroxylenol, chloroxynil, San fourth Lv Bian Phosphonium chloride, chlorphoxim, goes out at Bravo Worm pyridine, grass lose dead (chlorprocarb), chlorpropham, chlopyrifos, chlorpyrifos-methyl, four chloro-quinoxalines, chlorsulfuron, chlorine four Ring element, chlorthal dimethyl, chlorothiamid, chlorothion (chlorthion), Actellic, chlozolinate, choline chloride, ring tebufenozide (chromafenozide), cinmethylin, cinosulfuron, benzonitrile amide (ciobutide), cisanilide, cis- Permethrin, alkene grass Ketone, Climbazole, iodine chlorine pyridine ester (cliodinate, alkynes oxalic acid (clodinafop), clodinafop-propargyl, cloethocarb, clofencet, Clofop, chlorine ether oxygen isobutyl propionate (clofop-isobutyl), clomazone, adjust tartaric acid, the third oxygen of chlorine fixed (cloproxydim), lontrel monoethanolamine salt, lontrel, methyl cloransulammethyl, closantel, Clothianidin, cloxyfonac, cuprous oxide (1), copper acetoarsenite, bis- (3- phenylo salicylic acid) copper, copper acetate II, copper chloride II, Kocide SD II, copper oxychloride, copper sulphate, COS-OGA, coumaran, coumafuryl, coumatetralyl, first fragrant bacterium ester, Dithion, fourth Fragrant bacterium ester, Kusakira, crimidine, Crotamiton, Crotoxyphos, cufraneb, cumyluron, cuprobam, cyanamide, cyanatryn, cyanogen grass Saliva, cynock, cyanthoate, cyanogen insect amide (cyantraniliprole), cyazofamid, spread net (cybutryne), cyclopropionate acyl General sieve of amine, cyclammonium (cyclaniliprole), cyclethrin, cycloate, cycloheximide, ring pyridate (cyclopyrimorate), cypromisulfuron, cycloxydim, Alipur-O, nitrile pyrrole mite ester, cyflufenamid, cyhalofop-butyl, butyl cyanide Fluorine grass ester (cyhalofop-butyl), plictran, Tifatol, cymoxanil, cypendazole, the fast chloride of benzene grass, benzene grass is fast, ring is careless Saliva, Cyproconazole, cyclopropyl pyrimidine, cyprofuram, cypromid, cyclopropyl-sulfonylamide, cyromazine, dazomet, daminozide, Dalapon-sodium, Dalapon, DAEP, debacarb, decafentin, defenuron, dehydroactic acid, delachlor, demephion, demephion-O, demephion- S, the different demeton sulfone of demeton, methyl, the different demeton of methyl, the different demeton sulfone of methyl, demeton-methyl-S, Benzyl Benzoate ammonium acyl Amine, desmedipham, desmetryn, torak, Avadex, diamines phosphorus (diamidaphos), diammonium ethylenebis (two Thiocarbamate), diammonium hydrogen phosphate, basudin, dibromochloropropane, dicamba, dichlobenil, dichlofenthion, Euparen, dichloro Naphthoquinones, antiphen (dichlorophen), 2,4- drop propionic acid, essence 2,4- drop propionic acid, DDVP, diclobutrazol, double chlorine cyanogen bacterium It is amine, diclofop-methyl, methyl diclofop-methyl, diclomezine, botran, diclosulam, dicofol, Carbicron, two ring cinene, double Dodecyl dimethyl ammonium chloride, dieldrin, ethyl alachlor, diethofencarb, Metadelphene, difenacoum, phenylate first Ring azoles, difenopenten ethyl, penta taste diclofop-methyl (difenopenten), difenoxuron, difenzoquat metilsulfate, oat Withered, difethialone, flufenzine, diflufenzopyr, fluorine mepanipyrim, difunon, dikegulac, dikegulac-sodium, BFPO, dimefuron, piperazine Careless pellet, dimethachlor, Lysimachia sikokiana only, P DimethenamidP, efficient P DimethenamidP, dimethipin, dimethirimol, Rogor, dimethomorph, diformazan Base disulfide, dimethyl (4- piperidinyl carbonyl oxygroup -2,5- methylbenzyl) sulfonium toluene-4-sulfonic acid ester, dimethylvinphos, dimexan, Careless pyridazone (dimidazon), tosoxamide, Dinitrocyclohexylphenol, Dinitrocyclohexylphenol (dinex-diclexine), olefin conversion, olefin conversion- M, dinitramine, dinobuton, dinocap, the mite prestige that disappears, Di Lete, the mite that disappears be more, dinosam, dinoseb acetic acid esters, dinoseb, nitre are pungent Ester, dinotefuran, dinoterb, difenolan, salithion (dioxabenzophos), Elacron, dioxathion, diphacinone, diphenamide, Diphenylamines, dipropalin, sancap, Dipyrithione, diquat dibromide dibromide, diquat dibromide, methylsulphur acid disodium (disodium Methanearsonate), eight boric acid disodium tetrahydrates (disodium octaborate tetrahydrate), phosphonic acids two Sodium, disulfoton, disul sodium (disul-sodium), Plondrel, dithianon, dithiopyr, diuron, double xanthate, DNOC, ten Two cyclomorpholine acetic acid esters, dodemorph, dodine, suspend mode oily (dormant oil), hydrazine oxazolone, toxic fluoride phosphate, enemy's pest Phosphorus, ethyl glycinamide Kusatsu, Prallethrin, 5a,6,9,9a-hexahydro-6,9-methano-2,4, endothall, endothion, drinox, Enestroburin (enoxastrobin), table chlorine Alcohol, EPN, propionylbrassinolide, the young ether of guarantor, epoxiconazole, EPTC, erbon, esprocarb, ethylene silicon, etaconazole, Yi Tafu are killed (etaphos), Ethisul, Guardian, ethametsulfuron acid, methyl ethametsulfuron, ethamine, glyoxal, ethyl mercaptan, ethephon (CEPHA),2-(chloroethyl) phosphonic acid, Sulfone thiophene is grand, ethiofencarb, Ethodan, ethiozin, ethiprole, ethirimol, ethofumesate, beneficial fruit, phonamiphos, ethyl chloride fluorine grass Ether, ethoxyfenethyl, ethoxyquin, ethoxysulfuron, double different thiocyanic acid ethylene sulfide, dichloroethanes, bromination ethyl mercury, nitre grass Phenol, Grandox fumigant, etrimfos, Fenamidone, fenaminosulf, alkene oxime amine, fenamiphos, fenapanil, Fenarimol, acyl benzene sulphur prestige (fenasulam), fenazaflor, quinoline mite azoles, benzoxazole, ethyl fenchlorazole, Nankor, fenfluthrin, first furan anilide, ring acyl Bacterium amine, kind clothing ester, fenifrothion, Bassa, 2,4,5- tears propionic acid, 2,4,5- tears propionic acid butoxyethyl (fenoprop- Butotyl), fenothiocarb, cyanogen bacterium ether amines, ethyl fenoxaprop-P, smart ethyl fenoxaprop-P, different evil benzene sulfone (fenoxasulfone), fenoxycarb, fenpiclonil, fenpirithrin, Fenpropathrin, fenpropidin, butadiene morpholine, amine benzene pyrrole bacterium ketone, Fragrant Kui triketone (fenquinotrione), pyridazine ketone acid, fenson, fensulfothion, ethyl thiazole diclofop-methyl, diclofop-methyl thiazole, times Sulphur phosphorus, fentin acetic acid esters, Fentin chloride compound, fentin hydroxide, fentrazamide, fenuron, fervam, phosphoric acid Iron, Fipronil, wheat straw volt, efficient wheat straw volt-isopropyl, flazasulfuron, flocoumafen, flonicamid, florasulam, phonetic mite Ester, fluorine grass spirit-butyl, smart fluorine grass spirit-butyl, fluazinam, flumethiazide, flucarbazonesodium sodium, flucetosulfuron, fluchloralin, fluorine cyanogen penta Pyrethroids, fludioxonil, Fluenyl, fluorine thiophene worm sulfone (fluensulfone), flufenacet, fluorine Fen Neilin (flufenerim), fluorine bacterium Mite ester, ethyl flufenpyrethyl, butene-fipronil, fluorine ethofumesate, Flumiclorac pentyl-amyl (flumiclorac-pentyl), propine fluorine Careless amine, alkynes grass amine, flumorph, fluometuron, fluopicolide, fluopyram, fluoraracide, Fluorakil 100, fluorodifen, second Fluoroglycofen, ethofumesate, fluorine sulphur grand (fluothiuron), fluotrimazole, fluoxastrobin, flupoxam, the phonetic grass of fluorine third (flupropacil), hydrochloric acid flupropadine (flupropadine hydrochloride), flupropadine, tetrapion, fluorine pyrrole furan Mutter ketone (flupyradifurone), flupyrsulfuron-methyl-sodium (flupyrsulfuron), flupyrsulfuron-methyl-sodium sodium, Fluquinconazole, Florencol, Fluridone, fluorine grass pyrrone, fluroxypramide, methyl fluroxypramide (fluroxypyr-meptyl), flurprimidol, flurtamone, Flusilazole, Flusulfamide, KIH 9201 methyl, fluorine are for Buddhist nun (flutianil), flutolanil, Flutriafol, fluxapyroxad, fluxofenim, sterilizing list, fluorine Sulfanilamide (SN) grass ether, foramsulfuron, chloropyuril, formaldehyde, medimeform, An Guo, amine first prestige (formparanate), kills wood at Dyfonate Phosphine, triethylphosphine acid, phosethyl-Al, fosmethilan, fospirate, fosthiazate, fosthietan, furidazol, furan tebufenozide (fufenozide), Fuphenthiourae, furalaxyl, furalaxyl-M, furametpyr, furathiocarb, furconazole, cis- furconazole, furfural, Furilazole, seed dressing amine, fluorine furan grass ether, gliftor, gliotoxin, glufosinate-ammonium, glufosinate-ammonium, smart glufosinate-ammonium, glutaraldehyde, glyoxide, Glyphosate trimethyl sulfosalt, glyphosate, isopropyl amine salt, glyphosate, glyphosate potassium, glyphosine, griseofulvin, the pungent salt of biguanides, Halacrinate, halauxifen methyl, fluorine chloropyridine ester (halauxifen), chlorine tebufenozide, fluorine nitre sulfonamide, chlorine Pyrazosulfuron (halosulfuron-methyl), halozydine, fluazifop-butyl, ethyoxyl fluazifop-butyl (haloxyfop- Etotyl), his fluorine woods (heptafluthrin) of smart fluazifop-butyl, smart fluazifop-butyl methyl, standing grain, Heptamaloxyloglucan, heptenophos, heptopargil, speed kill sulphur phosphorus (heterophos), hexachlorophene, hexaconazole, lithium Object, hexazinone, own sulphur phosphorus (hexylthiofos, Hexythiazox, ciproconazole (huanjunzuo), hydrogen peroxide, hydroprene, evil Mould spirit, quinoline prestige, Icaridin, imazalil, miaow grass ester, miaow grass ester-methyl, imazamox, imazapic, imidazoles cigarette Acid, Scepter, Imazethapyr, imidazoles sulphur is grand, glyoxalin, new cigarette phosphorus (imicyafos), imidacloprid, iminoctadine triacetate, Iminoctadine tris (albesilate), iminoctadine, Imiprothrin, inabenfide, indanofan, indaziflam, indenes worm Prestige, inezin, iodine oxalic acid dinitrile (iodobonil), iodfenphos, iodomethane, iodine metsulfuron-methyl, iodine metsulfuron-methyl-sodium (iodosulfuron-methyl-sodium), the excellent fragrant grand sodium of sulphur (iofensulfuron sodium), excellent fragrant sulphur are grand (iofensulfuron), ioxynil lithium, ioxynil sodium, ioxynil sodium, ioxynil, kind bacterium azoles, three azole amides, different rice blast net, Iprodione, iprovalicarb, IPSP, ferric sulfate, isazofos (isamidofos), fluorine azoles phosphorus, fourth amidine amide, isocarbophos, different grass Fixed, propylamine phosphorus, propylamine phosphorus-methyl, Ai Suofeita (isofetamid), isolan, butylamine piperazine, isonoruron different send phosphorus (isopamphos), isopolinate, Mobucin, isopropalin, Isoprothiolane, isoproturon, azoles naphthalene bacterium amine, different phonetic alcohol (isopyrimol), Hosdon, isotianil, isouron, isoval, isoxaben, isoxachlorotole, isoxaflutole, different Dislike careless ether, izopamfos, kaolin (kaolin), karbutilate, Ke Laifan (kelevan), kinoprene, kresoxim-methyl, diclofop-methyl, ring Careless fixed, teptophos, lime sulfur, limestone, lindane, linuron, perfluorooctane sulfonate lithium, phosphorus of removing the evil, magnesium phosphide, horse traction sulphur Phosphorus, maleic acid hydrazide, the third mite cyanogen, mancopper, Mancozeb, Man get Luo Bin (mandestrobin), mandipropamid, Dai Sen Manganese, mazidox, MCPA, MCPA- thioethyl ester, MCPB, cumenyl methyl carbamate, mebenil, Afos, first prestige Benzene miaow (mecarbinzid), mecarphon, 2- first -4- chloropropionic acid, essence 2- first -4- chloropropionic acid, Medetomidine (medetomidine), medinoterb acetate acetic acid esters, medinoterb acetate, mefenacet, mefluidide, menadione, menazon, phonetic bacterium Amine, mephosfolan, chlormequat chloride (mepiquat chloride), strong cotton plain (mepiquat), mebenil, the mite that disappears be more, mercury oxide, chlorine Change mercurous, De-Green, mesosulfuron, mesosulfuron (mesosulfuron-methyl), mesotrione, first oxydemeton_methyl (mesulfenfos), metalaxyl, Metalaxyl-M, the methaldehyde, metamifop, metamitron, metham-sodium-potassium, metham-sodium Sodium, metazachlor, piperazine pyrazosulfuron (metazosulfuron), m-chloro drazoxolon (metazoxolon), metconazole, methyl tears Bar, methabenz thiazuron, methacrifos, acephatemet, methasulfocarb, methazole, methuroxam, methidathion, methiocarb, Sulfonylurea (methiopyrsulfuron), Metapside, first sulphur azoles (methiozolin), methiuron, desinsection ethephon (methocrotophos), methomyl, methoprene, methoxy third be net, methoxychlor, methoxyfenozide, Kayaphenone, different thiocyanic acid first Ester, methyl (((1- (5- (2- chloro- 4- (trifluoromethyl) phenoxy group) -2- nitrobenzophenone) -2- methoxyethlyen) amino) oxygen Base) acetic acid esters (fucaomi), methyl arsenones, methylarsonic acid, methyldymron, dithiocyanic acid methylene ester (methylene Bisthiocyanate), Carbatene, metobenzuron, metobromuron, metofluthrin, propisochlor, MTMC, SSF 126, sulphur Careless azoles amine, metoxuron, metrafenone, metribuzin, metsulfovax, metsulfuron-methyl, metsulfuron-methyl (metsulfuron-methyl), speed Go out phosphorus, Mexacarbate, mipafox, molinate, not fluorine kill woods (momfluorothrin), monalide, Azodrin, afesin, Monosodium methanearsonate (monosodium methylarsonate), monosulfmeturon, monosulfmeturon-methyl, telvar, Ceroxone Dichloride, Ceroxone, morphothion, mucochloric anhydride (mucochloric anhydride), nitrile bacterium azoles, myclozolin, (3- is chloro- by N- 2,6- 3,5-dimethylphenyl) -2- methoxyl group-N- (tetrahydro -2- oxygroup -3- furyl) acetamide, Dithane A40,2-dichloroethylk dimethyl phosphate, nano silver Insecticide (Nanosilver pesticide), naphthalene, naphthalic anhydride, naproanilide, napropamide, napropamide-M, quinclorac, grass are not Grand, bis- (dimethyl dithiocarbamic acid) nickel, niclosamidum, nicosulfuron, Nitenpyram, Nithiazine (nithiazine), nitralin, trichloromethyl pyridine, nitrilacarb (nitrilacarb), nitrofen, nitrothalisopropyl, the N- methyl new last of the ten Heavenly stems Amide, N-Nitrosodimethylamine, Shoxin, monometflurazone (norflurazon), Ninicotine, herban, noviflumuron, fluorobenzene pyrimidine Alcohol, O, O- dimethyl α-(2,4- Dichlorophenoxy base oxethyl) ethyl phosphonic acid ester, octhilinone, fenfuram, flolimat, weeding Pellet, orthosulfamuron, orysastrobin, oryzalin, oxabetrinil, oxadiargyl, oxadiazon, Wakil, oxamyl, grass rattle away pine, Oxapyrazon-dimolamine, grass are rattled away loose sodium, oxasulfuron, fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin), oxazines Humulone, dislikes oxpoconazole fumarate (oxpoconazole fumarate), oxycarboxin, metilomerkaptofosoksid, different sulfoxide at oxolinic acid Phosphorus, Disystom-s, Oxyfluorfen, paclobutrazol, paraffin oil (C11-C30) [4c], paraffin oil C15-C30) [4b], paraffin oil [3Not NEU], paraquat dichloride, paraquat, parathion, parathion-methyl, pebulate, penconazole, Pencycuron, diformazan Penta spirit, fluorine azoles bacterium aniline, penoxsuam, pentachlorophenol, pentanochlor, pyrrole metsulfovax, pentoxazone, yellow grass volt, Permethrin, Peracetic acid, pethoxamid, phenisopham, phenmedipham, phenthoate dimephenthoate cidial, phenylmercuric acetate (phenyl mercuric acetate), nitric acid benzene Mercury (phenylmercury nitrate), thimet, Gophacide, Phosalone, phosphorus go out fourth (phosametine), phosdiphen, Phosfolan, phosfolan, phosmet, nichlorfos (phosnichlor), phosphamidon, hydrogen phosphide, phoxim, Rabcide, Picarbutrazox, picloram, picloram-dimethyl ammonium, picloram-triethanolamine, ZEN 90160, Duocide, oxazoline grass The strong plain bromide of ester, pipron, piperophos, piperazine, piperazine strengthen element, Aphox, ethyl-pyrimidine phosphorus, pirimiphos-methyl, benzethazet acetofenate, Polybutene, saleratus, potassium iodide, potassium phosphate, potassium rhodanide, Prallethrin, pretilachlor, methyl primisulfuronmethyl, primisulfuronmethyl, Prochloraz, procymidone, Profenofos, profluazol, profluralin, the third Flumethrin, clefoxidim, ethyl proglinazine, proglinazine, tune Naphthenic acid, Prohexadione calcium, promacyl, Carbamult, prometon, prometryn, propachlor, hydrochloric acid Propamocarb, Propamocarb, propanil, the third worm Phosphorus, propargite, puts out net, Chem hoe, propiconazole, propineb, propionic acid, propisochlor, arprocarb, propyl benzene sulphur at propaquizafop Grand, procarbazone-sodium, the phonetic sulphur of piperazine imidazoles (propyrisulfuron), propyzamide, the third oxygen quinoline, prosulfocarb, the third sulphur of fluorine Grand, prothidathion, prothiocarb, prothioconazoles, Fac, cyclopropyl chlorine ether, proximpham (proximpham), prynachlor, pyrrole Aphid ketone, pyracarbolid, pyraclofos, pyraclonil, pyraclostrobin, pyraflufen-ethyl, Pyramat, azoles amine bacterium ester, pyraoxystrobin, Ppyrazophos, Ethyl pyrrole sulphur is grand, general fragrant grass, iso-propyl-ester nitrofen, propyl-ester nitorfen, pyribenzoxim, pyridaphethione (pyridafenthion), rattles away Piperazine alcohol (pyridafol), alcohol pyridazines-O- methyl (pyridafol-O-methyl), pyridate, pyrifenox, fluorine worm pyrrole quinoline (pyrifluquinazon), pyriftalid, pyrimethanil, KIH 6127 (pyriminobac-methyl), pyriminostrobin (pyriminostrobin), Nylar (pyrimisulfan), pyriofenone, Nylar, oxazole, pyrithiobac-sodium- Sodium, pyroquilon, sulfone pyrrole grass azoles (pyroxasulfone), pyroxsulam, QRD-460, quartz sand, quinalphos, chloro-quinolinic acid, Dichloro quinolinic acid-dimethyl ammonium, quinmerac, quinoclamine, quinone duckweed amine, the peaceful phosphorus (quinothion) of poultry, quinalphos, pentachloro- nitro It is benzene, quizalofop-ethyl ethyl, Quizalotop-ethyl ethyl, Quizalotop-ethyl-tefuryl (quizalofop-P-tefuryl), rimsulfuron, phonetic Pyridine sulphamide, schradane, another fourth saliva, secbumeton, fluorine azoles ring bacterium amine (sedaxane), sethoxydim, Tupersan, silica, sulphur Silicon bacterium amine, sodium thiosulfate, silver thiosulfate, Simanex, simeconazoles, symetryne, sintofen, S- methoprene, S- propisochlor, 5- nitroguaiacol sodium salt (sodium5-nitroguaiacolate), sodium silicoaluminate, sodium arsenite, sodium carbonate, sodium chlorate, chlorine Change sodium, bicarbonate, sodium hypochlorite, ortho-nitrophenol sodium, paranitrophenol sodium salt, sodium tetraborate pentahydrate, ethyl pleocidin, spiral shell First mite ester, spiral shell worm ethyl ester, volution bacterium amine, toxaphene (strobane), sulphur humulone, sulfallate, sulfentrazone, sulfluramid, methyl Sulfometuron Methyl, Sulfosulfuron, sulfotep, the pyridine of sulfone worm, sulfuryl fluoride, sulphur, sulfuric acid, sulprofos, TCA- sodium, Tebuconazole, tebufenozide, pyrrole mite Amine, isobutyl ethoxyquin (tebufloquin), butyl pyrimidine phosphorus, tebutam, tebuthiuron, tecloftalam, tecnazene, seven fluorine Pyrethroids, special furan triketone (tefuryltrione), tembotrions (tembotrione), tepraloxydim, terallethrin, special grass Fixed, terbuchlor, terbufos, Te Dingtong, Garagard, terbutryn, tetcyclacis, Ravap, tetraconazole, pyrophosphoric acid tetrem Ester, tetramethrin, etrafluorine ethofenprox, thiophene first chlorine, probenazole, thiacloprid, Diacloden, thiapronil, thiazfluron, thiophene grass be fixed, thiophene bacterium Nitrile, thiadiazoles grass amine, Thidiazuron, oxazolone sulphur pheno acid methyl esters (thiencarbazone-methyl), thifensulfuron methyl, methyl thifensulfuron methyl, Thifluzamide, benthiocarb, Talcord, thiocyclam oxalates, thiocyclam, thiodicarb, thiofanox, thiometon, thionazin, first Base thiophanate, thiosultap, dimehypo sodium (thiosultap-disodium), Cupric sulfate sodium (thiosultap- Monosodium), thiocarbamide, thiram, tiadinil, to eliminate fragrant that (tiafenacil), tiocarbazil, tioxazafen, methyl vertical Withered phosphorus, Tolfenpyrad, Tolylfluanid (tolylfluanid), topramezone, tralkoxydim, tralocythrin, trans- chlorine Pyrethroids, triazolone, Triadimenol, tri-allate, triamiphos, triapenthenol, triarathene, triasulfuron, frustrate aphid prestige, Hostathion, azoles bacterium piperazine, Tribenuron-methyl, methyl tribenuron-methyl (tribenuron-methyl), De-Green, tributyltin oxide, trichlamide, metrifonate, malicious earth Phosphorus, Triclopyr-butoxyethyl (triclopyr-butotyl), Triclopyr-triethyl ammonium, Triclopyr, chlorine nalidixic bacterium ester (triclopyricarb), tricyclazole, tridemorph, tridiphane, grass up to rule, trichlorine the third oxygen phosphorus (trifenofos), trifloxystrobin, Trifloxysulfuron, trifloxysulfuron sodium, triflumezopyrim, fluorine bacterium azoles, insecticidal lung, trifluoro-benzene pyrimidine (triflumezopyrim), fluorine bacterium azoles, trefanocide, triflusulfuronmethyl, methyl triflusulfuronmethyl (triflusulfuron-methyl), Trifluoro dogstail oxime, triforine, Landrin, ethyl TrinexAN_SNacethyl, metaformaldehyde, triprene, triticonazole, tritosulfuron, alkene effect Azoles, ureasulfuric acid, urea, figured silk fabrics bacterium amine (valifenalate), valinomycins, Kilval, verbutin (verbutin), weed eradication Enemy, vinclozolin, Warfarin, XMC, xylachlor, Meobal, zarilamid (zarilamid), zinc borate, zinc oxide, generation Gloomy zinc, ziram, zoxamide or its salt or mixture.
According to another embodiment, agricultural chemical activity object is pesticide activity object, and the pesticide activity object includes but not It is limited to one of classification of active matter selected from the following or more: anabasine insecticide, oxygroup phenoxy group acid esters, hexamethylene Two ketoxime herbicides, sulfonylureas and cloquintocet herbicide-safener, HPPD inhibit herbicide, Phenylpyrazole, neires toxin Like object insecticide and organophosphorus ester insecticide.
According to embodiment, the first agricultural chemical activity object ingredient is preferably chosen from one of following or more: going out Mite quinone (Acequinocyl), methacrylaldehyde, alachlor, alloxydimsodium, α -5a,6,9,9a-hexahydro-6,9-methano-2,4, aminocarb, dimethylaniline amidine, anilazine, pyridine Phosphorus, triazotion, oatax, Benfuracard micro, benomyl, bensultap, Bifenazate, bromomethane, oenanthyl Bromoxynil (bromoxynil heptanoate), decoyl Bromoxynil (bromoxynil octanoate), butanone sulfone prestige, captan, west dimension Because of carbetamide, carbosulfan, carfentrazoneethyl, cartap, hydrochloric acid cartap, oxolinic acide, cinidon-ethyl, clodinafop-propargyl, four Mite piperazine, cyflumetofen, cymoxanil, dazomet, desmedipham, Euparen, DDVP, dicofol, dithianon, edifenphos, sulphur Pellet, ethephon (CEPHA),2-(chloroethyl) phosphonic acid, ethiofencarb, Famoxate, ethyl fenchlorazole, Bassa (enobucarb), fentin acetic acid esters, fervam, Flazasulfuron, fluazinam, Flumiclorac pentyl-amyl, flumioxazin, fluoroglycofen-ethyl, flupyrsulfuron-methyl-sodium sodium, sterilizing list, mite killing Amidine, An Guo, methyl halosulfuronmethyl, ethyoxyl fluazifop-butyl (haloxyfop-etotyl), heptachlor, heptenophos, hydramethylnon, iodine Bromoxynil octanoate (ioxynil octanoate), iprodione, isoxaflutole, malathion, Mancozeb, maneb, prestige hundred Mu sodium, acephatemet, Carbatene, Menite, Mexacarbate, 2-dichloroethylk dimethyl phosphate, quinclorac, trichloromethyl pyridine, fenfuram, oxidation pleasure Fruit, oxamyl, oxasulfuron, oxycarboxin, phenmedipham, thimet, phosdiphen, phosmet, phoxim, oxazoline grass Ester, pipron, propineb, ethyl pyraflufen-ethyl, pyridate, quizalofop-ethyl-ethyl, Quizalotop-ethyl-tefuryl (quizalofop-P-tefuryl), rimsulfuron, spiral shell worm ethyl ester, sulfotep, sulfuryl fluoride, Swebate, terbufos, pyrophosphoric acid Tetra-ethyl ester, thiocyclam oxalates, thiocyclam, thiram, Tolylfluanid (tolylfluanid), transfluthrin, frustrate aphid prestige, Methyl tribenuron-methyl (tribenuron-methyl), metrifonate, Triclopyr, trifloxysulfuron sodium, triforine, figured silk fabrics bacterium amine (valifenalate), vinclozolin, zineb, ziram and zoxamide.
According to another embodiment, the first agricultural chemical activity object ingredient is preferably chosen from one of following or more Kind: acequinocyl (Acequinocyl), methacrylaldehyde, alachlor, dimethylaniline amidine, oatax, Benfuracard micro, benomyl, desinsection Sulphur, Bifenazate, captan, carbosulfan, cartap, hydrochloric acid cartap, oxolinic acide, cinidon-ethyl, clodinafop-propargyl, four mites Piperazine, cyflumetofen, cymoxanil, dazomet, desmedipham, DDVP, dicofol, dithianon, ethephon (CEPHA),2-(chloroethyl) phosphonic acid, Famoxate, three Phenylacetate, fervam, fluazinam, Flumiclorac pentyl-amyl, flumioxazin, sterilizing list, medimeform, An Guo, ethyoxyl fluorine pyrrole Standing grain spirit, heptachlor, iprodione, isoxaflutole, Mancozeb, maneb, metham-sodium sodium, acephatemet, Carbatene, Mexacarbate, two Bromine phosphorus, quinclorac, fenfuram, phenmedipham, thimet, pinoxaden, phosmet, propineb, pyridate, quinoline standing grain Spirit-ethyl, sulfuryl fluoride, tetraethyl pyrophosphate, thiocyclam, thiram, Tolylfluanid (tolylfluanid), phenyl tetrafluoride chrysanthemum Ester frustrates aphid prestige, metrifonate, triforine, vinclozolin and ziram.
According to another embodiment, the first agricultural chemical activity object ingredient is preferably chosen from one of following or more Kind: alachlor, Amitraz, barban, benomyl, bensultap, Bifenazate, captan, carbosulfan, cartap, salt Sour cartap, cyflumetofen, dazomet, desmedipham, dithianon, fentin acetate, flumicloracpentryl, flumioxazin, sterilizing List, An Guo, heptachlor, isoxaflutole, maneb, Carbatene, 2-dichloroethylk dimethyl phosphate, fenfuram, phenmedipham, phosmet, oxazoline grass Ester, vikane, tetraethyl pyrophosphate and ziram.
According to another embodiment again, agricultural chemical activity object can be cartap, hydrochloric acid cartap, in pinoxaden It is any.
According to another embodiment, the second agricultural chemical activity object is Fipronil.
According to embodiment, the first agricultural chemical activity object or the second agricultural chemical activity object with total composition by weight The concentration range of meter at least 0.01% exists.According to embodiment, agricultural chemical activity object with total composition by weight extremely Few 1% concentration range exists.According to embodiment, agricultural chemical activity object is with by weight at least the 5% of total composition Concentration range exists.According to embodiment, agricultural chemical activity object is with by weight at least 10% concentration model of total composition Enclose presence.According to embodiment, agricultural chemical activity object exists with by weight at least 20% concentration range of total composition. According to embodiment, agricultural chemical activity object exists with by weight at least 30% concentration range of total composition.According to reality Scheme is applied, agricultural chemical activity object exists with by weight at least 40% concentration range of total composition.According to embodiment, Agricultural chemical activity object exists with by weight at least 50% concentration range of total composition.According to embodiment, chemurgy Active matter is learned to exist with by weight at least 60% concentration range of total composition.According to embodiment, agricultural chemical activity Object exists with by weight at least 70% concentration range of total composition.According to embodiment, agricultural chemical activity object is with total By weight at least 80% concentration range of composition exists.According to embodiment, agricultural chemical activity object is with total composition By weight at least 90% concentration range exist.
According to another embodiment, agriculture chemistry particle is selected from water-dispersible granule, fine grained, microparticle, solubility Particle, emulsifiable particle, dispersible particle, bulky grain (broadcast granule), disintegratable particle squeeze out particle.Root According to another embodiment again, agriculture chemistry particle is preferably bulky grain, disintegratable particle or squeezes out particle.
According to embodiment, particulate composition is included as of polygon, spherical shape, ellipse or any Polyhedral Particles Grain, without the excellent property for influencing to observe.According to embodiment, agriculture particle is substantially spherical.
According to embodiment, particulate composition is in the size range of 0.1mm to 6mm.According to another embodiment, Grain composition is in the size range of 0.1mm to 3mm.According to another embodiment again, particulate composition is in 0.1mm to 2mm Size range in.According to still other embodiments, particulate composition is in the size range of 0.1mm to 1mm.
According to embodiment, the particle of formation has particle size in the range of 0.1 micron to 100 microns.According to Embodiment, the particle of formation have particle size in the range of 0.1 micron to 60 microns.According to embodiment, formed Particle there is particle size in the range of 0.1 micron to 30 microns.According to embodiment, the particle of formation has Particle size in the range of 0.1 micron to 20 microns.
According to another embodiment, compared with known composition, particulate composition of the invention shows reduction Bulk density, this is conducive to particle and is disintegrated faster, and is also prevented from composition and settles in water.With known bead or particle It compares, particulate composition also shows improved hardness and wearability.
Particulate composition surprisingly has good hardness.According to embodiment, showed by particulate composition Hardness is at least 1 newton.
According to embodiment, particulate composition has the hardness of at least 3 newton.According to embodiment, particulate composition tool There is the hardness of at least 5 newton.According to another embodiment, particulate composition has the hardness of at least 10 newton.According to another A embodiment, particulate composition have the hardness of at least 20 newton.According to another embodiment, particulate composition has extremely The hardness of few 30 newton.
According to another embodiment, particulate composition has the hardness of at least 40 newton.According to another embodiment, Particulate composition has the hardness of at least 60 newton.The hardness showed by particle is assessed by hardometer, the hardometer Such as by Shimadzu, Brinell Hardness (AKB-3000 model), Mecmesin, Agilent, Vinsyst, Ametek The hardometer provided with Rockwell.
According to embodiment, particulate composition has the disintegration time less than 30 minutes.According to embodiment, particle combination Object has the disintegration time less than 20 minutes.According to an embodiment, when particulate composition has the disintegration less than 10 minutes Between.According to embodiment, particulate composition has the disintegration time less than 5 minutes.According to embodiment, particulate composition has Disintegration time less than 3 minutes.According to embodiment, particulate composition has the disintegration time less than 2 minutes.According to embodiment party Case, particulate composition have the disintegration time less than 1 minute.According to embodiment, particulate composition has collapsing less than 30 seconds Solve the time.Disintegration time is assessed by disintegration test equipment, and the disintegration test equipment is such as by Electrolab The disintegration test equipment that Edutec, Arentek and Shimadzu are provided.
It is disintegrated in less than 30 minutes according to another embodiment, at least 99% particulate composition again.According to again another One embodiment, at least 50% particulate composition are disintegrated in less than 20 minutes.According to another embodiment again, at least 30% particulate composition is disintegrated in less than 10 minutes.According to another embodiment again, at least 20% particulate composition It is disintegrated in less than 5 minutes.It is disintegrated in less than 3 minutes according to another embodiment, at least 10% particulate composition again. It is disintegrated in less than 1 minute according to another embodiment, at least 5% particulate composition again.According to still other embodiment party Case, at least 2% particulate composition are disintegrated in less than 30 seconds.
According to embodiment, the bulk density of particulate composition is less than 1.5gms/ml.According to embodiment, particle combination The bulk density of object is preferably less than 1.2gms/ml.According to another embodiment, the bulk density of particulate composition is preferably Less than 1.0g/ml.According to another embodiment, the bulk density of particulate composition is preferably less than 0.9g/ml.
According to another embodiment, compared with known particle, what particulate composition of the invention showed improvement can Floatability, this advantageously combined object reduce the leaching of active matter to the excellent availability of crop or plant.Composition shows The sedimentation of composition reduction in water.Compared with known particle, particulate composition also shows improved disintegration, disperses and hang It is floating.
Floatability can be defined as particulate composition and keep on the surface of the liquid without the ability of sinking.According to reality Scheme is applied, the floatability of particulate composition is less than 99%.According to another embodiment, the floatability of particulate composition is small In 90%.According to embodiment, the floatability of particulate composition is less than 80%.According to embodiment, particulate composition can Floatability is less than 70%.According to embodiment, the floatability of particulate composition is less than 60%.According to embodiment, particle group The floatability of object is closed less than 50%.According to embodiment, the floatability of particulate composition is less than 40%.According to embodiment party Case, the floatability of particulate composition is less than 30%.According to embodiment, agriculture chemistry particulate composition has less than 25% Floatability.According to embodiment, agriculture chemistry particulate composition has the floatability less than 15%.According to embodiment, Agriculture chemistry particulate composition has the floatability less than 10%.According to embodiment, agriculture chemistry particulate composition has Floatability less than 5%.According to embodiment, agriculture chemistry particulate composition has the floatability less than 3%.According to reality Scheme is applied, agriculture chemistry particulate composition has the floatability less than 1%.According to embodiment, the combination of agriculture chemistry particle Object has the floatability less than 0.5%.
Wearability determines granular materials to the tolerance of abrasion.Determine that the process of wearability is related to by rolling in bucket Particle is stirred to simulate fluidized bed.After a period of time that passed, material is sieved and is weighed to determine and has already decreased to Lower than the amount of the material of certain size (referred to as " fine powder ").According to embodiment, the wearability of particle is at least 30%.According to The wearability of embodiment, particle or bead is at least 40%.It is at least by the wearability that particle shows according to embodiment 50%.According to embodiment, the wearability of particle is at least 60%.According to embodiment, the wearability of particle is at least 70%. According to another embodiment, particle shows at least 80% wearability.According to embodiment, particle shows at least 90% Wearability.The details of test is defined by being such as applicable to the various standards of discussed purpose, such as those skilled in the art By those of ASTM definition standard known to member.
Dispersibility is defined as the ability that particle disperses when being added in liquid such as water or solvent.In order to according to standard CIPAC tests the dispersibility that MT 174 determines particulate composition, it is known that the particulate composition of amount is added into the water for limiting volume In, and suspension is mixed to form by stirring.After standing lasting short time period, top 9/10ths is taken out, and It is dry by remaining 1/10th, and method determines by weight.This method is actually the shortening test of suspension, and is suitable for Determine particulate composition evenly dispersed difficulty or ease in water.According to embodiment, particulate composition has at least 40% dispersion Property.According to embodiment, particulate composition has at least 50% dispersibility.According to embodiment, particulate composition has extremely Few 60% dispersibility.According to embodiment, particulate composition has at least 70% dispersibility.According to embodiment, particle Composition has at least 80% dispersibility.According to embodiment, particulate composition has at least 90% dispersibility.
Suspension is defined as being suspended in the amount of the active ingredient in the liquid column of specified altitude after a given time, It is indicated with the percentage of the amount of active ingredient in original suspension.In order to determine the suspension of particulate composition (according to CIPAC MT-184), the suspension of the particulate composition of the known concentration in CIPAC standard water is produced, and in steady temperature quilt In graduated cylinder as defined in being placed on, and allow to keep continuing the specific time without interruption.The 9/10 of top is taken out, and then Remaining 1/10 is measured by chemical method, gravimetric method or by solvent extraction, and calculates suspension.
According to embodiment, particulate composition has at least 10% suspension.According to embodiment, particulate composition tool There is at least 20% suspension.According to embodiment, particulate composition has at least 30% suspension.According to embodiment, Particulate composition has at least 40% suspension.According to embodiment, particulate composition has at least 50% suspension.
According to embodiment, particulate composition has at least 60% suspension.
According to embodiment, particulate composition has at least 70% suspension.
Wetability is wettable condition or state, and can be defined as the degree that solid is soaked by liquid, is passed through Adhesion strength between solid phase and liquid phase measures.The wetability of particulate composition is measured using standard Cipac test MT-53, Standard Cipac test MT-53 describes the program for determining the time of the wettable preparation of complete wetting.By the amount of weighing Particulate composition is waterborne in beaker from defined height drop, and determines the time for being used for complete wetting.According to embodiment party Case, particulate composition have the wetability less than 30 minutes.According to another embodiment, particulate composition has less than 20 points The wetability of clock.According to another embodiment, particulate composition has the wetability less than 15 minutes.According to another implementation Scheme, particulate composition have the wetability less than 10 minutes.According to another embodiment, particulate composition has less than 5 The wetability of minute.According to another embodiment, particulate composition has the wetability less than 2 minutes.According to another reality Scheme is applied, particulate composition has the wetability less than 1 minute.According to another embodiment, particulate composition, which has, to be less than 30 seconds wetabilitys.
According to another embodiment, agricultural chemical activity object is solid active object.According to other embodiments, agricultural Chemically-reactive substance has the fusing point greater than 35 DEG C.According to other embodiments, agricultural chemical activity object has greater than 40 DEG C Fusing point.According to other embodiments, agricultural chemical activity object has the fusing point greater than 45 DEG C.According to other embodiments, Agricultural chemical activity object has the fusing point greater than 50 DEG C.
According to embodiment, composition also includes fertilizer, the second pesticide activity object, macronutrient (macronutrient) and one of micronutrient or its salt or more.
According to another embodiment, fertilizer includes but is not limited to one of following or more: single nutrients fertilizer Material, multiple nutrient fertilizer, micronutrient, binary fertilizer, compound fertilizer, organic fertilizer, its derivative or mixture.It is preferred that Ground, fertilizer include but is not limited at least one of nitrogenous fertilizer, sulfur fertilizer, phosphate fertilizer, potash fertilizer or its salt, derivative and mixture.According to Still other embodiments, nitrogenous fertilizer may include urea, ammonium sulfate, ammonium nitrate, anhydrous ammonia, nitric acid-sulfuric acid ammonium (ammonium Nitrate sulphate), Diammonium phosphate (DAP), nitrogen solution, monoammonium phosphate, ammonium polyphosphate, three perphosphates, they derivative, Its oxide, salt and mixture.
According to still other embodiments, the fertilizer based on sulphur may include elementary sulfur, ATS (Ammonium thiosulphate), calcium sulfate, stone Cream or derivatives thereof, oxide, salt and mixture.
According to another embodiment, macronutrient include but is not limited to carbohydrate, fat and protein or its One of salt, derivative and mixture or more.
According to another embodiment, micronutrient includes but is not limited to one of following or more: vitamin Such as vitamin A, vitamin B, vitamin C, vitamin D, vitamin E, vitamin K, carotenoid;Minerals such as boron, Calcium, chloride, chromium, cobalt, copper, fluoride, iodine, iron, magnesium, manganese, molybdenum, phosphorus, potassium, selenium, sodium, zinc;With organic acid such as acetic acid, lemon Acid, lactic acid, malic acid, choline and taurine or its salt, derivative and mixture.
According to embodiment, fertilizer, the second pesticide activity object, macronutrient and one of micronutrient or its salt Or more in by weight the 0.01% to 95% of total composition concentration range.
According to embodiment, heat-staple plasticizer includes surfactant, polyethers, thermoplastic material, resin, lubrication Agent, protecting colloid, water soluble salt, nitrogenous fertilizer, water-soluble polymer, water solubility copolymer, complexing agent, carbohydrate or its derivative One of object and combination or more.
According to embodiment, heat-staple plasticizer is selected from one of following or more: polyoxyethylene oxide, dimension (polyoxyethylene-is poly- for raw element E polyethanediol succinate, polyethylene glycol glycerol hydroxy stearic acid ester, polyethylene glycol, poloxamer The block copolymer of oxypropylene), polyox-yethylene-polyoxypropylene block copolymer, 1- phenyl -1,2- ethylene glycol, poly- (ethylene) oneself Two acid esters, ethylene oxide/propylene oxide block copolymer, vinyl-vinyl acetate copolymer, vinyl pyrrolidone and acetic acid The copolyvidone (Copovidone) of vinyl acetate, Vinylcaprolactam homopolymer-polyvinyl acetate-polyethylene glycol graft copolymerization Object, polyvinyl alcohol (PVA)-polyethylene glycol (PEG) graft copolymer and hydroxypropyl cellulose.
According to another embodiment, heat-staple plasticizer has the fusing point less than 250 DEG C.According to other embodiment party Case, heat-staple plasticizer have the fusing point less than 200 DEG C.According to other embodiments, heat-staple plasticizer has small In 150 DEG C of fusing point.According to other embodiments, heat-staple plasticizer has the fusing point less than 100 DEG C.
According to other embodiments, heat-staple plasticizer has the fusing point less than 80 DEG C.According to another embodiment party Case, heat-staple plasticizer have the fusing point of the fusing point lower than agricultural chemical activity object ingredient.
According to embodiment, heat-staple plasticizer has the molecular weight less than 100gms/mol.According to embodiment, heat Stable plasticizer has the molecular weight less than 500gms/mol.According to embodiment, heat-staple plasticizer, which has, to be less than The molecular weight of 1000gms/mol.According to embodiment, heat-staple plasticizer has the molecular weight less than 2000gms/mol.Root According to another embodiment, heat-staple plasticizer has the molecular weight less than 5000gms/mol.According to another embodiment party Case, heat-staple plasticizer have the molecular weight less than 10,000gms/mol.According to another embodiment, heat-staple increasing Moulding agent has the molecular weight for being less than 15,000gms/mol.According to another embodiment, heat-staple plasticizer, which has, to be less than The molecular weight of 20,000gms/mol.According to another embodiment, heat-staple plasticizer has less than 30,000gms/mol Molecular weight.According to another embodiment, heat-staple plasticizer has the molecular weight less than 50,000gms/mol.According to Another embodiment, heat-staple plasticizer have the molecular weight less than 60,000gms/mol.According to another embodiment party Case, heat-staple plasticizer have the molecular weight less than 70,000gms/mol.According to another embodiment, heat-staple increasing Moulding agent has the molecular weight for being less than 80,000gms/mol.According to another embodiment, heat-staple plasticizer, which has, to be less than The molecular weight of 90,000gms/mol.According to another embodiment, heat-staple plasticizer has less than 1,00,000gms/ The molecular weight of mol.According to another embodiment, heat-staple plasticizer has the molecular weight less than 1,00,000gms/mol. According to another embodiment, heat-staple plasticizer has the molecular weight less than 1,20,000gms/mol.According to another reality Scheme is applied, heat-staple plasticizer has the molecular weight less than 1,50,000gms/mol.According to another embodiment, heat is steady Fixed plasticizer has the molecular weight less than 2,00,000gms/mol.
According to embodiment, heat-staple plasticizer is water-soluble.Term " water-soluble active plasticizer " includes solvable In any plasticizer of water.According to embodiment, heat-staple plasticizer has in water at 20 DEG C is greater than the molten of 0.1mg/ liter Xie Du.According to embodiment, thermostabilization plasticizer has the solubility for being greater than 0.5mg/ and rising at 20 DEG C in water.According to embodiment party Case, heat-staple plasticizer have the solubility for being greater than 1mg/ and rising at 20 DEG C in water.According to embodiment, heat-staple plasticising Agent has the solubility for being greater than 1g/ and rising at 20 DEG C in water.According to embodiment, heat-staple plasticizer has in water at 20 DEG C Have and is greater than the solubility that 10g/ rises.According to embodiment, heat-staple plasticizer has in water at 20 DEG C is greater than what 25g/ rose Solubility.
According to another embodiment, heat-staple plasticizer is with by weight at least 0.01% concentration of total composition Range exists.According to another embodiment, heat-staple plasticizer is with by weight at least 0.1% concentration of total composition Range exists.According to another embodiment, heat-staple plasticizer is with by weight at least 1% concentration model of total composition Enclose presence.According to another embodiment, heat-staple plasticizer is with by weight at least 5% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 10% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 20% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 30% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 40% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 50% concentration range of total composition In the presence of.According to another embodiment, heat-staple plasticizer is with by weight at least 60% concentration range of total composition In the presence of.
According to embodiment, on agriculture chemistry acceptable excipient, auxiliary agent or additive include wetting agent, dispersing agent, It is emulsifier, adhesive, biocide, stick, disintegrating agent, filler, diluent, plasticizer, spreading agent, surfactant, molten Agent, coating agent, pigment, dyestuff, anti-caking agent, thixotropic agent, antidrift agent, colorant, buffer, pH adjusting agent, adhesive (adhesives), fragrance, evaporation suppressor, fertilizer, micronutrient, macronutrient, protecting colloid, defoaming agent, resist micro- life Agent, neutralizer, flavoring agent, viscosity modifier, thickener, penetrant, processing additives, chelating agent, moistens complexing agent Agent, preservative, polyethers, lubricant, protecting colloid, solvent, coating agent, antioxidant and stabilizer or derivative, mould inhibitor, hair Infusion, agglutination inhibitor, wax, fat and oil, such as Brazil wax, stearic acid, stearyl alcohol or castor oil, anti-caking agent And its mixture.Surfactant may include nonionic surface active agent, anionic surfactant or derivatives thereof With one of mixture or more.Acceptable excipient is that business manufactures, and passes through various public affairs on agriculture chemistry Department can get.According to embodiment, on agriculture chemistry acceptable excipient with by weight the 0.01% of total composition to 99% concentration range exists.According to embodiment, on agriculture chemistry acceptable excipient with total composition by weight 0.01% to 80% concentration range exists.According to embodiment, acceptable excipient is on agriculture chemistry with total composition By weight 0.01% to 60% concentration range exists.
According to embodiment, disintegrating agent used in particulate composition includes but is not limited to one of following or more Kind: sodium bicarbonate/sodium carbonate, saleratus/potassium carbonate or they and sour such as citric acid and fumaric acid mixture or salt,XL-10 crosslinking polyvinylpyrrolidone, microcrystalline cellulose, crosslinking sodium carboxymethylcellulose and methyl The salt of the polyacrylate of acrylate.According to embodiment, dispersing agent is with by weight the 0.01% to 80% of total composition Concentration range exist.
According to embodiment, dispersing agent used in particulate composition includes but is not limited to one of following or more Kind: polyvinylpyrrolidone, polyvinyl alcohol, lignosulfonates, phenol naphthalene sulfonate, ethoxylated alkylphenol, ethoxylation Fatty acid, alkoxylated linear alcohols, polyaromatic sulfonates, sodium alklyarylsulfonate, glyceride, copolymer-maleic anhydride, phosphorus The condensation product of the formaldehyde condensation products of acid esters, the condensation product of aryl sulfonic acid and formaldehyde, aryl sulfonic acid and ureaformaldehyde and naphthalene sulfonic acids, The sulfonic acid of the salt of the addition product of the addition product of ethylene oxide and aliphatic ester, ethylene oxide and aliphatic ester, the naphthalene of condensation Salt, lignin derivative, lignosulfonates, naphthaldehyde condensation compound, the sodium salt of isodecyl sulfosuccinic acid semiester, polycarboxylic acids Salt, sodium alkyl benzene sulfonate, the sodium salt of sulfonated naphthalene, the ammonium salt of sulfonated naphthalene, the salt of polyacrylic acid, the salt of phenolsulfonic acid and naphthalene sulfonic acids The sodium salt and naphthalene sulfonate-formaldehyde condensation product of salt, the sodium salt of copolymer-maleic anhydride and ammonium salt and the phenolsulfonic acid of condensation or Its salt, derivative.Dispersing agent is that business manufactures, and can get by various companies.
Dispersing agent with but be not limited toThe trade mark of lid lignin calcium sulfate, with brandD425Naphthaldehyde condensation compound sodium obtained by PW (emery 5353),The modified brown paper of AF sodium is wooden Element, Negel and alkyl carboxylateEFW mixture is commercially available.According to embodiment, dispersing agent with By weight 0.01% to 80% concentration range of total composition exists.
According to embodiment, wetting agent used in particulate composition includes but is not limited to one of following or more Kind: phenol naphthalene sulfonate, alkylnaphthalene sulfonate, Negel, the sodium salt of sulfonated alkyl carboxylic acid, polyoxyalkylated ethylo benzene Phenol, polyoxyethoxylated fatty alcohol, alkyl sulfo succinate, polyoxyethoxylated fatty amines, lignin derivative, lignin Sulfonate, alkane sulfonate, taurate, alkylbenzene sulfonate, polycarboxylic salt, the salt of sulfosuccinate, alkylnaphthalene sulphur Hydrochlorate, the phosphoric acid ester condensation products of formaldehyde, phenolsulfonic acid condensation product, acetylenic glycols and alkylphenol ethoxylate, methyl oil base ox Sulfonate, alkylbenzene sulfonate, alkyl polyglycol ether sulfonate, ethoxylated silicone, alkyl ether phosphate, alkyl ether sulfate Salt and alkyl sulfosuccinic monoesters or its salt or derivative.Wetting agent is that business manufactures, and can be obtained by various companies .Some of which with but brand name not limited to the following can get:Ag-Special Negel,280LP silicone surfactant,XC Negel,DS-10 detergent alkylate Sodium sulfonate,301-10F alkyl-alpha-alkene sulfonic acid sodium,SN naphthalenesulfonic acid-formaldehyde condensate, C14-C19 Alkene sulfonic acid sodium salt (such as (R) Hostapur OS) andSodium salt (such as (R) Genapol LRO).According to embodiment, wetting agent exists with by weight 0.01% to 80% concentration range of total composition.
According to embodiment, the illustrative example of adhesive used in particulate composition can be selected from but not limited to following At least one of: carbohydrate such as monosaccharide, disaccharides, oligosaccharides and polysaccharide;Protein;Lipid;Glycolipid;Glycoprotein;Rouge egg It is white;And these combination and derivative.Carbohydrate binder may include glucose, mannose, fructose, galactolipin, One of sucrose, lactose, maltose, xylose, arabinose, trehalose and its mixture or more.Adhesive can be with Including corn syrup;Cellulose such as carboxymethyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxymethyl ethylcellulose, Hydroxyethylpropyl cellulose, methyl hydroxyethylcellulose, methylcellulose;Starch such as amylose, extra large gel (seagel), Starch acetate, h and E starch, ionic starch, chain alkyl starch, dextrin, maltodextrin, cornstarch, amine form sediment Powder, phosphate starch and dialdehyde starch;Plant amylum such as cornstarch and potato starch;If other carbohydrate are all Glue, amylopectin, xylan, xanthan gum, glycogen, agar, alginic acid, phycocolloid, chitin, gum arabic, guar gum, thorn Chinese parasol tree Paulownia glue, bassora gum and locust bean gum.Adhesive can also include complicated organic substance such as phenyl naphthalene sulphonate, lignin and Nitration of lignin;The derivative of lignin such as lignosulfonates, illustratively include calcium lignosulfonate and sulfomethylated lignin Sour sodium, and the complicated composition based on carbohydrate comprising organic principle and inorganic constituents, such as molasses.Suitably Casco illustratively may include extract of soybean, zeins (zein), nucleoprotamine, collagen and Casein.Functional adhesive can also include organic polymer such as ethylene oxide polymer or copolymer, the epoxy of synthesis Propane copolymer, polyethylene glycol, polyethylene oxide, polyacrylamide, polyacrylate, polyvinylpyrrolidone, poly- alkylated pyrazole Pyrrolidone, polyvinyl alcohol, polyvinyl methyl ethermaleic anhydride, polyethylene acrylate, hydrated inorganic object such as sodium metasilicate, sorbierite or urine Element, polylactic acid, Polyethoxylated fatty acids, polyethoxylated fatty alcohols and latex.It will be understood by those skilled in the art, however, that Different adhesives can be used to be made without departing from the scope of the present invention.Adhesive is that business manufactures, and passes through various companies It can get.
According to embodiment, adhesive exists with by weight 0.01% to 80% concentration range of total composition.
According to embodiment, filler or carrier include but is not limited to one of following or more: attapulgite, height Ridge soil, clay, montmorillonite, montmorillonite (montromolite), bauxite, hydrated alumina, perlite, calcined alumina, silicon Diatomaceous earth, chalk, bleaching earth, dolomite, diatomite (kiesulguhr), loess, pyrophillite (prophyllites), talcum, awns Nitre, starch, lactose, white carbon black, sericite, white lime, sodium carbonate, sodium bicarbonate, volcano grey matter (volclay), vermiculite, lime Stone, natural and synthetic silicate, calcium silicates and magnesium silicate, titanium dioxide, calcium, magnesium, aluminium and titanium hydroxide, silicate, carbon Hydrochlorate and sulfate, aluminium, titanium, magnesium, calcium and zinc oxide, calcium carbonate and magnesium carbonate and charcoal, silica, mica, pottery Soil, expansive clay and non-expanded clay, synthesis and diatom silica, ammonium sulfate, sodium sulphate, potassium sulfate, sulfuric acid Calcium and barium sulfate, sand, gypsum and inorganic water-soluble salt.Filler is that business manufactures, and can get by various companies.
Commercially available silicate be Aerosil brand, Sipemat brand such as50S and CALFLO E and Aeroge Fa.Cabot, kaolin 1777, aluminosilicate,50S。
Preferred carrier includes but is not limited to one of following or more: attapulgite, kaolin, clay, illiteracy are de- Stone, montmorillonite, bauxite, hydrated alumina, perlite and its derivative, the aluminium oxide of calcining, diatomite, chalk, bleaching earth, Dolomite, diatomite, loess, pyrophillite, talcum, vermiculite, lime stone, natural and synthetic silicate, silica, mica.
Filler with but be not limited to ... the trade mark of .. is commercially available.According to embodiment, filler or carrier are with total composition By weight 0.01% to 90% concentration range exist.
According to embodiment, filler has at least 30% oil absorption capacity.According to other embodiments, filler tool There is the oil absorption capacity greater than 35%.According to other embodiments, filler has the oil absorption capacity greater than 50%.According in addition Embodiment, filler have greater than 75% oil absorption capacity.According to other embodiments, filler, which has, to be greater than 100% oil absorption capacity.According to another embodiment, filler has up to 175% oil absorption capacity.According to other reality Scheme is applied, filler has up to 160% oil absorption capacity.According to other embodiments, filler is with up to 115% Oil absorption capacity.According to embodiment, filler has oil absorption capacity in the range of 30% to 175%.
According to embodiment, composition optionally include anti-caking agent such asSoap L odium stearate,700 polyoxyethylene (100) stearyl ether,OT-B dioctyl sodium sulphosuccinate,L-77 silicon Ketone-copolyether, sodium phosphate and ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and calcium sulfate, magnesium hydroxide, Anhydrous calcium chloride, molecular sieve, sodium alkylsulfosuccinates, calcium oxide and barium monoxide, sodium carbonate or sodium bicarbonate.
According to embodiment, emulsifier or surfactant include ionic surface active agent, nonionic surface active agent With one of amphoteric surfactant or more.Ionic surface active agent includes but is not limited to one of following or more Kind: carboxylate, alkyl carboxylate, fatty acid salt, carboxylic acid fluoride salt, alkyl sulfate, alkyl ether sulfate, sulfonate, alkylbenzene Sulfonate, alpha-alkene sulfonate, aromatic sulfonic acid salt, naphthalene sulfonate, aliphatic alcohol sulfate, monoalkyl sulfosuccinate, alkane Base sulfosuccinate, naphthalene sulfonate, more library sulfonated esters, phosphate, alkylaryl ether phosphate, alkyl ether phosphate, season Ammonium salt, quaternized amine ethoxylate.Nonionic surface active agent includes but is not limited to one of following or more: Polyol ester, polyol fatty acid ester, polyethoxylated ester, polyethoxylated alcohols, the block of polyethylene glycol and polypropylene glycol are total Polymers, poloxamer, polysorbate, alkyl polysaccharide such as alkyl polyglycoside and its blend, amine ethoxylate, dehydration mountain Pears alcohol fat acid esters, ethylene glycol and glyceride, glucoside alkyl ether, alkyl sorbitol dehydration ester, tallow fatty acid sodium, polyoxyethylene second two Alcohol sorbitan Arrcostab, sorbitan derivatives, anhydro sorbitol aliphatic ester (sapn (Span)) and its ethoxy The sucrose ester of base derivative (tween) and fatty acid.More specifically, nonionic emulsifier includes but is not limited to one in following Kind or more: the poly- second two of polyethylene glycol, glyceryl laurate ester, lauryl glucoside, nonyl phenol polyethoxy ethanol, nonyl phenol Alcohol ether, castor oil ethoxylate, polyglycol ether, ethylene oxide and propylene oxide poly- addition product (polyadduct), poly- The block copolymer of alkylene glycol ether and hydroxy stearic acid, ethylene oxide propylene oxide block copolymer, tributyl phenoxy group Polyethoxy ethanol, octylphenoxy polyethoxy ethanol, ethoxylated propoxylated triphenyl vinyl phenol (ethopropoxylatedtristyrlphenols), ethoxylated alcohol, polyethenoxy sorbitan, anhydro sorbitol fat Acid esters, fatty acid glyceride, fatty acid polyglycerol ester, fatty acid alcohol polyglycol ether, acetylenediol, acetylene alcohol, oxyalkylene are embedding Section polymer, polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene styrene base aryl ether, polyoxyethylene second Glycol alkyl ether, polyethylene glycol, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerol Aliphatic ester, Crodaret or polyoxypropylene aliphatic ester;And its mixture.
Anionic surfactant includes but is not limited to one of following or more: fatty acid salt, benzoate, Polycarboxylate, the salt of alkyl sulfate, alkyl sulfate, alkyl aryl sulfate, alkyl biphenyl sulphate, alcohol sulfuric ester Salt, alkylsulfonate, alkylaryl sulfonates, arylsulphonate, lignosulfonates, alkyl diphenyl ether disulfonate, poly- Styrene sulfonate, the salt of alkyl phosphate, alkylaryl phosphate, styryl aryl orthophosphate, polyoxyethylene alkyl ether The salt of sulfuric ester, polyoxyethylene alkylaryl ether sulfate, polyoxyethylene alkylaryl ether sulfuric ester salt, polyxyethylated Ether phosphate, the salt of polyxyethylated aryl phosphate ester, the salt of polyoxyethylene aryl ether phosphate, the naphthalene sulphur with formaldehyde condensation Acid or salt and its mixture with the alkyl naphthalene sulfonic acid of formaldehyde condensation.
Also it can be used with the commercially available nonionic emulsifier of trade mark not limited to the following or surfactant: Atlas G5000 and TERMUL 5429, TERMUL 2510, 118、 X、OX-080、C 100、EL 200、Arlacel P135、Hypermer 8261、Hypermer B239、Hypermer B261、Hypermer B246sf、Solutol HS15、PromulgenTMD、 Soprophor 7961P、Soprophor TSP/461、Soprophor TSP/724、Croduret 40、Etocas 200、 Etocas 29、Rokacet R26、CHEMONIC OE-20、TritonTMN-101, polysorbas20, polysorbate40, polysorbate60, tween 65, Tween 80, Span20, Span40, Span60, Span80, Span83, Span85, Span120,TritonTM.Two Property surfactant may include glycine betaine, imidazoline, both sexes alkyl acetate and alkyl propionates, both sexes (two) acetic acid alkyl One of ester and dipropyl acid alkyl ester, lecithin or more.According to embodiment, surfactant or emulsifier are with total By weight 0.01% to 90% concentration range of composition exists.
According to embodiment, antioxidant can be selected from but not limited to one of following or more: amino acid (such as Glycine, histidine, tyrosine, tryptophan) and its derivative, imidazoles and imdazole derivatives (such as urocanic acid), peptide such as D, N-BETA-Alanyl-L-histidine, D-Carnosine, N-BETA-Alanyl-L-histidine and its derivative (such as anserine), carotenoid, carrotene (such as α-carrot Element, beta carotene, lycopene) and its derivative, lipoic acid and its derivative (such as dihydrolipoic acid), aurothioglucose, Propylthiouracil and other thio-compounds (such as thioglycerol, thiosorbitol, thioglycolic acid, thioredoxin (thioredoxin), glutathione, cysteine, cystine, cystamine and its glycosyl, N- acetyl group, methyl, ethyl, propyl, Amyl, butyl, lauryl, palmityl, oil base, γ-Asia oil base, cholesteryl and glyceryl ester) and its salt, thio-2 acid Dilauryl, distearyl thiodipropionate, thio-2 acid and its derivative (ester, ether, peptide, lipid, nucleotide, nucleosides And salt) and with low-down tolerance dose (such as sulphoxide imine compound (such as the fourth sulphur ammonia of pmol/kg to pmol/kg) Sour sulphoxide imine, homocysteine sulphoxide imine, fourth methyllanthionine sulfone, five thionine sulphoxide imines, six thionine sulphoxide imines, seven sulphur Violet sulphoxide imine), there are also metal-chelators (such as alpha-hydroxy fatty acid, EDTA, EGTA, phytic acid, lactoferrin), 'alpha '-hydroxy acids (such as citric acid, lactic acid, malic acid), humic acid, bile acid, bile extract, gallate (such as propyl gallate Ester, octyl gallate and dodecyl gallate), flavones, catechuic acid, bilirubin, biliverdin and its derivative, no Saturated fatty acid and its derivative (such as gamma-Linolenic acid, linolenic acid, arachidonic acid, oleic acid), folic acid and its derivative, hydrogen Quinone and its derivative (such as arbutin), ubiquinone and panthenol and its derivative, vitamin C and its derivative (such as ascorbic acid Palmitate, Vitamin C dipalmitate, ascorbic acid acetic acid esters, magnesium ascorbyl phosphate, resists ascorbyl stearate Bad hematic acid sodium and Magnesium ascorbate, ascorbic acid disodium hydrogen phosphate and ascorbic acid disodium sulfate, ascorbyl tocopheryl potassium phosphate, Chitosan-acid ascorbyl ester), arabo-ascorbic acid and its derivative, tocopherol and its derivative (such as tocopherol acetate, life Educate phenol linoleate, vitamin E oleate and tocopherol succinate, tocopherol -5, tocopherol -10, tocopherol -12, fertility Phenol -18, tocopherol -50, tocofersolan (tocophersolan)), vitamin A and derivative (such as vitamin A palmitinic acid Ester), the coniferyl benzoate of benzoin resin, rutin sophorin, rue thuja acid and its derivative, two disodium sulfate of rutin sophorin, cortex cinnamomi Acid and its derivative (such as ferulic acid, ferulic acid ethyl ester, caffeeic acid), kojic acid, chitosan ethyl glycolate and chitosan Salicylate, butylated hydroxytoluene, butylated hydroxy anisole, nordihydroguaiaretic acid (nordihydroguaiacic Acid), first hydroxyl guaiaretic acid (nordihydroguaiaretic acid), THBP 2,4,5 trihydroxybutyrophenone are removed (trihydroxybutyrophenone), uric acid and its derivative, sweet dew carbohydrates and their derivative, selenium and selenium derivative (such as selenium For methionine), talan and diphenyl ethylene derivatives (such as talan oxide, trans stilbene oxide). According to the invention, it is possible to use suitable derivative (salt, ester, sugar, nucleotide, nucleosides, peptide and rouge comprising these antioxidants Matter) and these particular actives ingredients or plant extracts (such as tea oil, Rosmarinus officinalis extract and Rosmarinic acid) is mixed Close object.Antioxidant is that business manufactures, and can get by various companies.
According to embodiment, antioxidant exists with by weight 0.01% to 60% concentration range of total composition.
According to embodiment, composition can also include pH adjusting agent or buffer or neutralizer.PH buffer or neutralization Agent may include both bronsted lowry acids and bases bronsted lowries of organic origin or inorganic origin.According to embodiment, pH buffer or neutralizer include but It is not limited to organic acid, inorganic acid and alkali metal compound or salt.Organic acid can include but is not limited to one of following or more It is a variety of: citric acid, malic acid, adipic acid, cinnamic acid, fumaric acid, maleic acid, succinic acid and tartaric acid or its salt or derivative, And single basic salt, two basic salt or three basic salt of these acid or derivatives thereof.The suitable salt of these acid can be solvable Or be fusible salt, and including one of them or more acid proton by cationic such as sodium, potassium, calcium, magnesium and ammonium and Those of its mixture replacing salt.Alkali metal compound may include the hydroxide such as sodium hydroxide and hydroxide of alkali metal Potassium, the carbonate of alkali metal such as sodium carbonate, magnesium carbonate and potassium carbonate, the bicarbonate of alkali metal such as sodium bicarbonate and alkali gold Belong to phosphate such as sodium phosphate and its mixture.According to embodiment, the salt of inorganic acid includes but is not limited to one of following Or more: alkali metal salt such as lithium chloride, sodium chloride, potassium chloride, lithium nitrate, sodium nitrate, potassium nitrate, lithium sulfate, sodium sulphate, Potassium sulfate, disodium-hydrogen, potassium phosphate,monobasic, sodium dihydrogen phosphate, potassium dihydrogen phosphate etc.;Alkali salt such as magnesium chloride, chlorine Change calcium, ammonium sulfate, monoammonium phosphate, ammonium dihydrogen phosphate etc..
According to another embodiment, the invention further relates to the techniques for preparing stable particulate composition.The technique includes At least one agricultural chemical activity object ingredient and at least one heat stabilized polymer are mixed and blended to obtain mixture, Middle agricultural chemically-reactive substance includes at least one of water-soluble active ingredient or water sensitivity active ingredient.To mixture The middle filler and surfactant that premix is blended.Then by active matter, plasticizer, filler and surfactant, disintegrating agent Whole mixt be suitable for melting the temperature heating of heat stabilized polymer or plasticizer in oil bath.Then by fusing Mixture is squeezed out by middle pressure extruder, to provide stable agriculture chemistry particulate composition;So that particulate composition is with small In 20 minutes wetabilitys.
Careful management technique condition is needed, to provide final granular product, which has desired disintegration Time, wetability, the property of dispersibility and floatability.Those skilled in the art can use proper amount of pressure during extrusion Desired composition is provided.
Embodiment:
Prepare embodiment:
Following example illustrate the basic skills of composition of the invention and multifunctionalities.
1. including the particulate composition of 6% hydrochloric acid cartap (Cartap hydrochloride)
Table 1:
Also 65 parts by weight of hydrochloric acid cartap is sufficiently mixed with 22 parts by weight of citric acid, to be mixed Object A.713 parts by weight of filler is added into the mixture, the filler includes dolomite, diatomite, perlite And WitconateTM(sodium alklyarylsulfonate), and be sufficiently mixed.Additionally incorporate 200 parts by weight of PEG 4000.So Mixture is heated afterwards and squeezes out and cools down, to obtain the particulate composition of 6.5% hydrochloric acid cartap.
2. including the particulate composition of 4% hydrochloric acid cartap and 72.5% sulphur
Table 2:
67 parts by 765 parts by weight of sulphur active ingredient and by weight include dolomite, diatomite, perlite And WitconateTMThe δ filler of (sodium alklyarylsulfonate) is sufficiently mixed to obtain mixture A.Also by 45 parts by weight Hydrochloric acid cartap is mixed with 20 parts by weight of citric acid, to obtain mixture B.Then mixture A and mixture B is merged Together, and into the consolidated material 100 parts by weight of PEG 4000 is added.Then mixture is heated and squeeze out with it is cold But, with the particulate composition of acquisition 76.5% sulphur and 4.5% hydrochloric acid cartap.
The comparison of physical property:
Biological effect result:
Embodiment 1: the biological effect of the hydrochloric acid cartap particle of embodiment according to the present invention:
Field trial is carried out to rice in India's Haryana state area Hissar, to assess implementation according to the present invention The hydrochloric acid cartap particle of scheme preparation and the sulphur of embodiment according to the present invention add the validity of hydrochloric acid cartap particle. Experiment is also using the individual sulphur 90%WG and individual hydrochloric acid of the reference substance and untreated control being used as comparing Cartap 4% particle carries out.Processing further includes killing snout moth's larva according to the sulphur 70%+ hydrochloric acid of the embodiment of 251/MUM/2011 preparation The composition of red 4%WP.Processing further includes the combination according to the embodiment of EP1882414, EP2460408 and US6703350B Object, these patents disclose the particulate composition of cartap.
Processing is carried out according to randomized block design, and keeps all agronomic practices consistent all processing.Work as sight When observing every leaf has a large amount of snout moth's larvas (yellow rice borer (Scirpophaga incertulas) Walker) group, application processing. All agronomic practices all bases are proposed with.
The young of yellow rice borer Walker leads to heart death during vegetative growth phase, and leads during reproductive phase Cause Bai Ertou.If dead heart infection is no more than 10%, rice plants can be compensated, however, the loss of white ear is can not It repairs.Observe the % of white ear head infection, and 5 plants of plant injuries due to caused by leaflet.Table 1A and table 1B are respectively represented Observation result about white ear head infection and leaflet.
Processing is carried out by sowing composition twice within the 30th day after rice transplantation and the 60th day.In order to avoid processing Mixing, is prepared for the false dike boundary of about 20cm to 30cm thickness around the plot with particle insecticide treatment.It is assessed to answer With both with effect.
Applied processing is as shown in the table:
Table 1A: the effect of about white ear head
Note: the number of days after DAT- transplanting
It is noted that with according to the preparation of the embodiment of EP1882414, EP 2460408 and US6703350 and with aobvious Cartap 4%, the cartap 6% for writing higher application dose application are compared with the processing 6 of 8% particle of cartap with processing 7, are used 4% hydrochloric acid cartap particle of the composition that embodiment according to the present invention is applied with significantly reduced application dose and 6% The application of processing 1 and both the processing 2 of hydrochloric acid cartap particle, obtains excellent effect in terms of controlling white ear head.
In addition, with the sulphur 50%+ hydrochloric acid cartap 7.5%GR according to the embodiment of 251/MUM/2011 with per hectare The processing 5 of 10000+1500g.a.i. compare and with to compared to processing 3 and handle 4 much higher dosage sulphur is used alone It compares with the processing 8 of cartap with processing 9, is killed after the transfer with the sulphur 75%+ hydrochloric acid of per hectare 7500+400g.a.i. within 75 days Snout moth's larva pellet 4%GR (processing 3) and sulphur 75%+ hydrochloric acid cartap 6%GR (processing 4) dialogue ear with per hectare 7500+600g.a.i. Head infection, which provides, preferably to be controlled.
Table 1B: the effect of about leaflet
Note: the number of days after DAT- transplanting
Such as from table 1B it is observed that compared with the independent processing with sulphur (processing 9) and cartap (processing 10), and With with according to the embodiment of EP1882414, EP 2460408 and US6703350 prepare and with significantly higher application dose Cartap 4%, the cartap 6% of application are compared with the processing 6 of 8% particle of cartap, processing 7 with processing 8, for according to this The processing 1 of composition prepared by the embodiment of invention, with the application of significantly reduced application dose is (with 4% hydrochloric acid cartap Particle), 2 (with 6% hydrochloric acid cartap particle) of processing, processing 3 (use 4% particle of sulphur 75%+ hydrochloric acid cartap) and handle 4 (use 6% particle of sulphur 75%+ hydrochloric acid cartap), the control to the plant injury due to caused by leaflet is excellent.
Other than the larva of control yellow rice borer category pest and leaflet, sulphur+hydrochloric acid of various concentration according to the present invention is killed The combination product of snout moth's larva pellet also shows that the valuable influence on physiologic factor, such as improved Rice Leaf (green) and tiller number The increase of (number of tillers), this facilitates higher yield.
Here is that the table of the yield of tiller number when indicating 60DAT (number of days after transplanting) is presented.
Table 1B:
In the case where the application of processing 2 with the sulphur 75%+ hydrochloric acid cartap 6%GR of per hectare 7500+600g.a.i., Observe maximum tiller number.The processing 1 of sulphur 75%+ hydrochloric acid cartap 4%GR to per hectare 7500+400g.a.i. Using also showing that dramatically increasing for the tiller number observed.
Since sulphur and hydrochloric acid cartap are with various concentration combined application, crop also shows increased chlorophyll and contains Amount.
In fact, combination of the above object with manage simultaneously folded by snout moth's larva and leaf caused by damage and plant growth just For the purpose of the demand of sulfur fertilizer material needed for phase, therefore compared with hydrochloric acid cartap or sulphur is used alone, so that the composition is to most Whole user is more economical and more beneficial.
Combination of the above object also limits the excessive loading of carrier such as sand, in individual hydrochloric acid cartap composition In, it is actually a kind of waste that carrier exists with up to 90% degree.
It was therefore concluded that compared with conventional formulation and the water-dispersible granule preparation of other prior arts, according to The water-dispersible particulate composition of embodiment of the present invention shows the biological effect significantly increased, even if applying agent in reduction Under amount, the lasts longer duration.
According to aforementioned, it will be observed that many modifications and variations may be implemented, without departing from the true of novel concept of the invention Real spirit and scope.It should be understood that the specific embodiment for shown in, it is not intended to or not should be inferred that any restrictions.

Claims (19)

1. a kind of stable agriculture chemistry particulate composition, includes:
I. at least one first agricultural chemical activity object ingredient, wherein the first agricultural chemical activity object includes water-soluble active At least one of object ingredient or water sensitivity active ingredient;
Ii. at least one heat-staple plasticizer, wherein the plasticizer, which has, is greater than 20 DEG C and the fusing point less than 150 DEG C;
Iii. acceptable excipient at least one agriculture chemistry;
Wherein the particulate composition has the wetability less than 20 minutes.
2. stable agriculture chemistry particulate composition as described in claim 1 is less than wherein the particulate composition has 99% floatability.
3. stable agriculture chemistry particulate composition as described in claim 1, wherein the particulate composition was at 10 minutes There is the floatability less than 99% in period.
4. stable agriculture chemistry particulate composition as described in claim 1, wherein the particulate composition has less than 30 The disintegration time of minute.
5. stable agriculture chemistry particulate composition as described in claim 1, wherein the composition, which has, is less than 1.5gms/ The bulk density of ml.
6. stable agriculture particulate composition as described in claim 1, wherein the composition at least 20% it is wear-resisting Property.
7. stable agriculture chemistry particulate composition as described in claim 1, wherein the water-soluble active ingredient is in water In have greater than every liter of water of 0.1mg solubility.
8. stable agriculture chemistry particulate composition as described in claim 1, wherein including in the particulate composition The decomposition of the active matter is under the conditions of accelerating storage less than 20%.
9. stable agriculture chemistry particulate composition as described in claim 1, wherein the heat-staple plasticizer be selected from by One of following or more the group of composition: surfactant, polyethers, thermoplastic material, resin, lubricant, protecting colloid, Water soluble salt, water-soluble polymer, nitrogenous fertilizer, water solubility copolymer, block polymer, polyethers, complexing agent, carbohydrate spread out Biology.
10. stable agriculture chemistry particulate composition as described in claim 1, wherein the heat-staple plasticizer be selected from One of lower or more: polyoxyethylene oxide, vitamin E polyethylene glycol succinic acid ester, polyethylene glycol glycerol hydroxyl are hard Resin acid ester, polyethylene glycol, poloxamer (block copolymer of PULLRONIC F68), PULLRONIC F68 block Copolymer, 1- phenyl -1,2- ethylene glycol, poly- (ethylene) adipate ester, ethylene oxide/propylene oxide block copolymer, ethylene-second The poly- acetic acid second of vinyl acetate copolymer, the copolyvidone of vinyl pyrrolidone and vinyl acetate, Vinylcaprolactam homopolymer- Enester-polyethyleneglycol-graft copolymer, polyvinyl alcohol (PVA)-polyethylene glycol (PEG) graft copolymer and hydroxypropyl cellulose.
11. stable agriculture chemistry particulate composition as described in claim 1, wherein the first agricultural chemical activity object at Be selected from one of following or more: insecticide, fungicide, herbicide, plant growth regulator, nematicide, Acaricide, insect growth regulator, IGR, safener, herbicide or other pesticide activity objects mixed.
12. stable agriculture chemistry particulate composition as described in claim 1, wherein the first agricultural chemical activity object at It is selected from one of following or more: anabasine insecticide, oxygroup phenoxy group acid esters, cyclohexanedione oxime herbicide, sulphur Sulfonylurea compound, cloquintocet herbicide-safener, HPPD inhibit herbicide, Phenylpyrazole, nereistoxin similar to object insecticidal Agent and organophosphorus ester insecticide.
13. stable agriculture chemistry particulate composition as described in claim 1, wherein the first agricultural chemical activity object at Dividing is one of hydrochloric acid cartap, cartap and pinoxaden or more.
14. stable agriculture chemistry particulate composition as described in claim 1, wherein the second agricultural chemical activity object at Dividing is Fipronil.
15. stable agriculture chemistry particulate composition as described in claim 1, wherein the composition also includes in following It is one or more of: fertilizer, the second pesticide activity object ingredient, macronutrient and micronutrient.
16. the purposes of agriculture chemistry particulate composition as described in claim 1, wherein the composition be in following at least It is a kind of: fertilizer composition, nutrition composition, crop production compositions, composition pesticide, plant hardening agent composition, soil Conditioner composition and yield enhancer compositions.
17. a kind of technique for preparing stable particulate composition, the technique include:
A. at least one agricultural chemical activity object ingredient and at least one heat stabilized polymer are mixed and blended to be mixed Object is closed, wherein the agricultural chemical activity object includes at least one in water-soluble active ingredient or water sensitivity active ingredient Kind;
B. it heats and the cooling mixture is to obtain stable agriculture chemistry particulate composition;
Wherein the particulate composition has the wetability less than 20 minutes.
18. technique as claimed in claim 26, wherein the step that is mixed and blended further includes by one or more of agriculturals Chemical excipient is added in the mixture.
19. a kind of cover crop or the method for improving its health or yield, the method includes at stable particulate composition Manage at least one of plant, crop, plant propagation material, seed, seedling or surrounding soil, the stable particulate composition Include:
I. at least one agricultural chemical activity object ingredient, wherein the agricultural chemical activity object include water-soluble active ingredient or One of water sensitivity active ingredient or more;
Ii. at least one heat-staple plasticizer;With,
Iii. acceptable excipient at least one agriculture chemistry;Wherein the particulate composition has the profit less than 20 minutes It is moist.
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