CN110511081A - A kind of compound fertilizer and preparation method thereof improving soil texture - Google Patents
A kind of compound fertilizer and preparation method thereof improving soil texture Download PDFInfo
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- CN110511081A CN110511081A CN201910818731.XA CN201910818731A CN110511081A CN 110511081 A CN110511081 A CN 110511081A CN 201910818731 A CN201910818731 A CN 201910818731A CN 110511081 A CN110511081 A CN 110511081A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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Abstract
The present invention provides a kind of compound fertilizers and preparation method thereof for improving soil texture, it is related to fertilizer field, constituent including following parts by weight: 15-20 parts of turf, 40-60 parts of peanut shell powder of charing, 5-10 parts of starch-acrylate graft copolymer, 10-14 parts of ammonium sulfate, 6-9 parts of potassium sulfate, 20-25 parts of quick lime, 3-7 parts of potassium chloride, 8-12 parts of ferrous sulfate, 1-3 parts of asparagus amino-acid calcium, 2-4 parts of aluminium water-retaining agent of complexing, 5-10 parts of sodium lignin sulfonate, 2-5 parts of stabilizer, 30-40 parts of wood vinegar, compound fertilizer of the present invention is for promoting Tomato Quality, improving yield has good effect, starch-acrylate graft copolymer therein, aluminium water-retaining agent is complexed for promoting fertilizer fertility, promote Tomato Quality, yield has and its positive Effect.
Description
Technical field
The present invention relates to fertilizer fields, and in particular to a kind of compound fertilizer and preparation method thereof for improving soil texture.
Background technique
Chemical fertilizer plays very important effect to Agriculture Production in the history of China's existing over half a century.China
It is a large agricultural country, ratio of the chemical fertilizer in productive investment in agriculture accounts for about 50%, but the utilization rate of China's fertilizer is but
Only 30%, it thereby results in the huge waste on economical energy resources and has caused various environmental problems.If not applying chemical fertilizer,
The grain yield of China will reduce the even more yield of one third.But with the increasingly increase that chemical fertilizer is put into, negative shadow
Sound also gradually shows especially out.Currently, since agriculturally a large amount of application chemical fertilizer cause soil acidification aggravation, soil depletion and plate for a long time
Knot, and there is a series of problems, such as soil environment, water environment pollution, this realizes that sustainable development forms sternness to Chinese agriculture
Challenge, therefore it is extremely urgent to improve soil quality.
Soil quality is the material base of agricultural production, and soil physical properties and chemical property are the important sets of soil quality
At keeping soil, suitable physical property is to improve one of the premise of agricultural production.How to improve soil texture, is crop root
The emphasis of a more comfortable growing environment and agriculturist's following work is built, product of the present invention has good
Water-retaining property and adequately dispersibility, effectively improve and improve the function of topsoil soils structure while protecting water storage fertilizer.
Drought and water shortage is an important factor for restricting China's agricultural development and accelerate desertification of land, to improve Farmland Water and utilize
The Farmland Water utilization rate of rate especially Arid&semi-arid area becomes one of the central task of China's agricultural.Agricultural water-loss reducer tool
There is drought-resistant water-preserving, heat preservation, sustained-release synergistic, improve the effects of soil texture, soil water evaporation can be inhibited, improve soil saturation
Water content, reduction can leaching nutrient leaching loss, improve utilization rate of fertilizer, while can reduce the soil weight, improve soil
Earth structure and water and heat condition.Water-retaining agent although water-absorbing-retaining effect with super strength, but do not have fertilizer nutrient, and nutrient is then
Production estimation and the necessary nutritional condition of vegetation growth, meanwhile, water-retaining agent and fertilizer are applied time-consuming respectively, are also unfavorable for
The performance of water-fertilizer interaction and liquid manure effect.
Therefore, the material of water retaining function is combined with fertilizer, preparation can delay the function that controlled release nutrients have water conservation, drought resisting again
The research of energy diversification fertilizer will become fertilizer and research and produce the new hot spot in field.
The moisture-retention sustained adjustable soil moisture surplus and deficiency of release and release control fertilizer improves liquid manure interaction, improves water, fertilizer utilizes effect
Rate reduces fertilizer nutrient leaching shifting, fixed or volatilization loss, mitigates environmental pollution.Therefore, by fertilizer and water-retaining agent composite integrated
Change, have complementary advantages, before the moisture-retention sustained release and release control fertilizer that manufacturing, there is water retaining function and nutrient to delay control-release function becomes fertilizer research
Edge and direction meet water-saving and dry farming production actual needs.
Summary of the invention
The object of the present invention is to provide a kind of compound fertilizers and preparation method thereof for improving soil texture.
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
15-20 parts of turf, charing 40-60 parts of peanut shell powder, 5-10 parts of starch-acrylate graft copolymer, ammonium sulfate 10-14
Part, 6-9 parts of potassium sulfate, 20-25 parts of quick lime, 3-7 parts of potassium chloride, 8-12 parts of ferrous sulfate, 1-3 parts of asparagus amino-acid calcium, network
Close 2-4 parts of aluminium water-retaining agent, 5-10 parts of sodium lignin sulfonate, 2-5 parts of stabilizer, 30-40 parts of wood vinegar.
Further, above-mentioned compound fertilizer includes the constituent of following parts by weight:
16 parts of turf, charing 50 parts of peanut shell powder, 7 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 6 parts of potassium chloride, 10 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, complexing 3 parts of aluminium water-retaining agent, sulfomethylated lignin
10 parts of sour sodium, 5 parts of stabilizer, 32 parts of wood vinegar.
Further, the charing peanut shell is that the peanut shell after drying carbonizes 1-5h at 460-480 DEG C, and ground
800 mesh screens are obtained, pH value 9.8-10.2, organic carbon content 420-480g/kg.
Further, the starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80-90 DEG C of water-bath gelatinization 20-40min, is passed through nitrogen, is cooled to 40-50
DEG C, be added potassium peroxydisulfate, stirring 5-10min sodium hydrogensulfite is added again, continue stir 5-10min, by acrylic acid be added dropwise into
Enter, react 30-50min, with ammonia water conditioning system pH to neutrality, methanol is added dropwise after being cooled to room temperature, stands 5-15h and filter, filter
Ground 800 mesh screen is dried after the washing of cake methanol.
Further, starch, acrylic acid, distilled water mass ratio be 1:1-1.5:10-20.
Further, it is described complexing aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, after being warming up to 40-45 DEG C of stirring 20-30min, after stirring 5-10min after potassium peroxydisulfate is added, by aluminum sulfate
Potassium solution, humic acid solution are added, and take out after being warming up to 80-85 DEG C of reaction 1-3h, crush drying.
Further, the mass concentration of aluminum potassium sulfate solution is 0.1-0.5%, and the mass concentration of humic acid solution is 2-8%.
Further, the stabilizer is the mixture of 1,2- butanediol, hydroxycarboxylic acid mass ratio 1-3:1-3.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
(1) by turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent,
Sodium lignin sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 10-20h passes through granulation
Machine is granulated to obtain compound fertilizer idiosome；
(2) charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasonic vibration 5-10min in distilled water and obtained
To suspension；
(3) by spraying device by suspension spray on compound fertilizer idiosome surface, after aeration-drying to water content is lower than 10%,
The fast dewatering 10-15min at 80-85 DEG C；
(4) it is dispensed after low temperature drying 10-15h at 40-50 DEG C.
The invention has the following advantages:
With the use of fertilizer, soil hardening will cause, salt content increases, and gas permeability decline causes crop failure, the present invention is multiple
Not only nutrient is abundant for Hefei material, but also can be effectively improved soil texture, and the charing peanut shell powder in the present invention is rich in
Porous structure, good permeability, and fertilizer can be stored up with water storage, make fertilizer efficiency slow release, be unlikely to burn seedlings, with complexing aluminium water-retaining agent one
Play water-retaining agent, complexing aluminium water-retaining agent contains a large amount of amides and carboxylated hydrophilic group, inside water-retaining agent Al ion and
Osmotic pressure and polyelectrolyte that the difference of the concentration of amide and carboxylated hydrophilic group and aqueous solution Related Component generates and water
Affinity and can largely absorb water.And due to the addition of aluminum aluminum sulfate and humic acid, the water-retaining agent inner molecular structure degree of cross linking is got over
Height, elastic force is stronger, and water absorption is bigger, and water retention property is splendid, and starch-acrylate graft copolymer water absorption is big, is that biological can drop
The environment-friendly products of solution, and starch-acrylate graft copolymer prepared by the present invention purity is high, preparation method is simple, water absorption
Greatly, by test it is found that the soil items physicochemical property after application compound fertilizer of the present invention is substantially without larger change, wherein quick-acting
Nitrogen content, quick-acting potassium content are also promoted, and illustrate to improve for ASI systematic approach, and soluble-salt concentration
EC, pH are without large change, and soil can also be planted after illustrating harvest, and compound fertilizer of the present invention is for promoting tomato product
Matter, improving yield has a good effect, and starch-acrylate graft copolymer therein, complexing aluminium water-retaining agent are for promoting fertilizer fertilizer
Power promotes Tomato Quality, yield plays the role of and its positive.
Detailed description of the invention
Fig. 1 is the preparation method flow chart of compound fertilizer of the present invention.
Specific embodiment
Embodiment 1:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
16 parts of turf, charing 50 parts of peanut shell powder, 7 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 6 parts of potassium chloride, 10 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, complexing 3 parts of aluminium water-retaining agent, sulfomethylated lignin
32 parts of 5 parts of stabilizer, the wood vinegar that 10 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 2:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 5h, and ground 800 mesh screen gained at 465 DEG C
It arrives, pH value 10.2, organic carbon content 450g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80 DEG C of water-bath gelatinization 30min, is passed through nitrogen, is cooled to 45 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 8min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1.2:15, reacts 40min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature,
It stands 10h to filter, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.2% by mass concentration after stirring 5min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 25min
Aluminum potassium sulfate solution, mass concentration be 6% humic acid solution be added, taken out after being warming up to 80 DEG C of reaction 2h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 18h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 10min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 14min at 80 DEG C；It is dispensed after low temperature drying 15h at 40 DEG C.
Embodiment 2:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
18 parts of turf, charing 50 parts of peanut shell powder, 6 parts of starch-acrylate graft copolymer, 10 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 5 parts of potassium chloride, 10 parts of ferrous sulfate, 2 parts of asparagus amino-acid calcium, complexing 4 parts of aluminium water-retaining agent, sulfomethylated lignin
35 parts of 4 parts of stabilizer, the wood vinegar that 8 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 2:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 2h, and ground 800 mesh screen gained at 480 DEG C
It arrives, pH value 9.8, organic carbon content 480g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 88 DEG C of water-bath gelatinization 40min, is passed through nitrogen, is cooled to 42 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 10min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1:20, reacts 40min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature, quiet
12h suction filtration is set, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.3% by mass concentration after stirring 10min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 25min
Aluminum potassium sulfate solution, mass concentration be 4% humic acid solution be added, taken out after being warming up to 85 DEG C of reaction 3h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 20h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 5min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 12min at 85 DEG C；It is dispensed after low temperature drying 12h at 50 DEG C.
Embodiment 3:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
20 parts of turf, charing 55 parts of peanut shell powder, 8 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 5 parts of potassium chloride, 10 parts of ferrous sulfate, 2 parts of asparagus amino-acid calcium, complexing 4 parts of aluminium water-retaining agent, sulfomethylated lignin
40 parts of 4 parts of stabilizer, the wood vinegar that 8 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 2:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 2h, and ground 800 mesh screen gained at 480 DEG C
It arrives, pH value 10, organic carbon content 433g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80 DEG C of water-bath gelatinization 40min, is passed through nitrogen, is cooled to 50 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 8min, continues to stir 10min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1.2:18, reacts 40min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature,
It stands 10h to filter, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.2% by mass concentration after stirring 10min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 25min
Aluminum potassium sulfate solution, mass concentration be 3% humic acid solution be added, taken out after being warming up to 85 DEG C of reaction 2h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 20h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 6min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 12min at 80 DEG C；It is dispensed after low temperature drying 15h at 50 DEG C.
Embodiment 4:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
18 parts of turf, charing 60 parts of peanut shell powder, 8 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 9
Part, 24 parts of quick lime, 6 parts of potassium chloride, 10 parts of ferrous sulfate, 2 parts of asparagus amino-acid calcium, complexing 4 parts of aluminium water-retaining agent, sulfomethylated lignin
40 parts of 5 parts of stabilizer, the wood vinegar that 8 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 3:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 4h, and ground 800 mesh screen gained at 460 DEG C
It arrives, pH value 9.8, organic carbon content 450g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 90 DEG C of water-bath gelatinization 22min, is passed through nitrogen, is cooled to 50 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 10min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1.5:18, reacts 50min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature,
It stands 15h to filter, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.2% by mass concentration after stirring 10min after potassium peroxydisulfate is added after being warming up to 40 DEG C of stirring 22min
Aluminum potassium sulfate solution, mass concentration be 7% humic acid solution be added, taken out after being warming up to 80 DEG C of reaction 2h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 20h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 5min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 12min at 85 DEG C；It is dispensed after low temperature drying 12h at 50 DEG C.
Embodiment 5:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
15 parts of turf, charing 40 parts of peanut shell powder, 5 parts of starch-acrylate graft copolymer, 10 parts of ammonium sulfate, potassium sulfate 6
Part, 20 parts of quick lime, 3 parts of potassium chloride, 8 parts of ferrous sulfate, 1 part of asparagus amino-acid calcium, complexing 2 parts of aluminium water-retaining agent, sulfomethylated lignin
30 parts of 2 parts of stabilizer, the wood vinegar that 5 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 1:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 1h, and ground 800 mesh screen gained at 460 DEG C
It arrives, pH value 9.8, organic carbon content 420g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80 DEG C of water-bath gelatinization 20min, is passed through nitrogen, is cooled to 40 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 5min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1:10, reacts 30min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature, quiet
5h suction filtration is set, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.1% by mass concentration after stirring 5min after potassium peroxydisulfate is added after being warming up to 40 DEG C of stirring 20min
Aluminum potassium sulfate solution, mass concentration be 2% humic acid solution be added, taken out after being warming up to 80 DEG C of reaction 1h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 10h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 5min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 10min at 80 DEG C；It is dispensed after low temperature drying 10h at 40 DEG C.
Embodiment 6:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
20 parts of turf, charing 60 parts of peanut shell powder, 10 parts of starch-acrylate graft copolymer, 14 parts of ammonium sulfate, potassium sulfate 9
Part, 25 parts of quick lime, 7 parts of potassium chloride, 12 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, complexing 4 parts of aluminium water-retaining agent, sulfomethylated lignin
40 parts of 5 parts of stabilizer, the wood vinegar that 10 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 3:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 5h, and ground 800 mesh screen gained at 480 DEG C
It arrives, pH value 10.2, organic carbon content 480g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 90 DEG C of water-bath gelatinization 40min, is passed through nitrogen, is cooled to 50 DEG C, over cure is added
Sour potassium, stirring 10min sodium hydrogensulfite is added again, continue stir 10min, by acrylic acid be added dropwise enter, starch, acrylic acid,
The mass ratio of distilled water is 1:1.5:20, reacts 50min with ammonia water conditioning system pH to neutrality and first is added dropwise after being cooled to room temperature
Alcohol stands 15h and filters, and dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.5% by mass concentration after stirring 10min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 30min
Aluminum potassium sulfate solution, mass concentration be 8% humic acid solution be added, taken out after being warming up to 85 DEG C of reaction 3h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 20h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 10min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 15min at 85 DEG C；It is dispensed after low temperature drying 15h at 50 DEG C.
Embodiment 7:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
15 parts of turf, charing 60 parts of peanut shell powder, 5 parts of starch-acrylate graft copolymer, 14 parts of ammonium sulfate, potassium sulfate 6
Part, 25 parts of quick lime, 3 parts of potassium chloride, 12 parts of ferrous sulfate, 1 part of asparagus amino-acid calcium, complexing 4 parts of aluminium water-retaining agent, sulfomethylated lignin
30 parts of 5 parts of stabilizer, the wood vinegar that 5 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 3:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 1h, and ground 800 mesh screen gained at 480 DEG C
It arrives, pH value 10.2, organic carbon content 420g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 90 DEG C of water-bath gelatinization 20min, is passed through nitrogen, is cooled to 50 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 5min, continues to stir 10min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1:20, reacts 30min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature, quiet
15h suction filtration is set, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.5% by mass concentration after stirring 5min after potassium peroxydisulfate is added after being warming up to 40 DEG C of stirring 30min
Aluminum potassium sulfate solution, mass concentration be 2% humic acid solution be added, taken out after being warming up to 85 DEG C of reaction 1h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 20h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 5min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 10min at 85 DEG C；It is dispensed after low temperature drying 10h at 50 DEG C.
Embodiment 8:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
20 parts of turf, charing 40 parts of peanut shell powder, 10 parts of starch-acrylate graft copolymer, 10 parts of ammonium sulfate, potassium sulfate 9
Part, 20 parts of quick lime, 7 parts of potassium chloride, 8 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, complexing 2 parts of aluminium water-retaining agent, sulfomethylated lignin
40 parts of 2 parts of stabilizer, the wood vinegar that 10 parts of sour sodium, 1,2- butanediol, hydroxycarboxylic acid 1:3 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 5h, and ground 800 mesh screen gained at 460 DEG C
It arrives, pH value 9.8, organic carbon content 480g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80 DEG C of water-bath gelatinization 40min, is passed through nitrogen, is cooled to 40 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 10min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1.5:10, reacts 50min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature,
It stands 5h to filter, dries ground 800 mesh screen after the washing of filter cake methanol.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.1% by mass concentration after stirring 10min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 20min
Aluminum potassium sulfate solution, mass concentration be 8% humic acid solution be added, taken out after being warming up to 80 DEG C of reaction 3h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 10h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasound shake in distilled water
It swings 10min and obtains suspension；By spraying device by suspension spray in compound fertilizer idiosome surface, aeration-drying to water content
After 10%, the fast dewatering 10min at 85 DEG C；It is dispensed after low temperature drying 15h at 50 DEG C.
Comparative example 1:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
16 parts of turf, charing 50 parts of peanut shell powder, 12 parts of ammonium sulfate, 8 parts of potassium sulfate, 24 parts of quick lime, 6 parts of potassium chloride, sulphur
Sour 10 parts ferrous, 3 parts of asparagus amino-acid calcium, complexing 3 parts of aluminium water-retaining agent, 10 parts of sodium lignin sulfonate, 1,2- butanediol, hydroxyl carboxylic
32 parts of 5 parts of stabilizer, the wood vinegar that acid 2:1 in mass ratio is mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 5h, and ground 800 mesh screen gained at 465 DEG C
It arrives, pH value 10.2, organic carbon content 450g/kg.
Be complexed aluminium water-retaining agent the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, and is 0.2% by mass concentration after stirring 5min after potassium peroxydisulfate is added after being warming up to 45 DEG C of stirring 25min
Aluminum potassium sulfate solution, mass concentration be 6% humic acid solution be added, taken out after being warming up to 80 DEG C of reaction 2h, crush dry is
It can.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent, wood
Quality sodium sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 18h is made by pelletizer
Grain obtains compound fertilizer idiosome；Charing peanut shell powder is added to ultrasonic vibration 10min in distilled water and obtains suspension；Pass through
Spraying device by suspension spray on compound fertilizer idiosome surface, it is fast at 80 DEG C after aeration-drying to water content is lower than 10%
Speed dehydration 14min；It is dispensed after low temperature drying 15h at 40 DEG C.
Comparative example 1 is substantially the same manner as Example 1, and difference is, is added without starch-acrylate graft copolymer.
Comparative example 2:
A kind of compound fertilizer that can be effectively improved soil texture, the constituent including following parts by weight:
16 parts of turf, charing 50 parts of peanut shell powder, 7 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 6 parts of potassium chloride, 10 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, 10 parts of sodium lignin sulfonate, 1,2- fourth
32 parts of 5 parts of stabilizer, the wood vinegar that glycol, hydroxycarboxylic acid 2:1 in mass ratio are mixed.
Wherein, charing peanut shell is that the peanut shell after drying carbonizes 5h, and ground 800 mesh screen gained at 465 DEG C
It arrives, pH value 10.2, organic carbon content 450g/kg.
Starch-acrylate graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80 DEG C of water-bath gelatinization 30min, is passed through nitrogen, is cooled to 45 DEG C, over cure is added
Sodium hydrogensulfite is added again by sour potassium, stirring 8min, continues to stir 5min, acrylic acid is added dropwise and is entered, starch, acrylic acid, steaming
The mass ratio of distilled water is 1:1.2:15, reacts 40min with ammonia water conditioning system pH to neutrality and methanol is added dropwise after being cooled to room temperature,
It stands 10h to filter, dries ground 800 mesh screen after the washing of filter cake methanol.
The above-mentioned compound fertilizer that can be effectively improved soil texture the preparation method is as follows:
By turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, sodium lignin sulfonate, steady
Determine agent, wood vinegar is added in mixer, machinery is puddled uniformly, and mixing time 18h is granulated to obtain compound fertilizer by pelletizer
Idiosome；Charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasonic vibration 10min in distilled water and are hanged
Supernatant liquid；By spraying device by suspension spray on compound fertilizer idiosome surface, after aeration-drying to water content is lower than 10%, in
Fast dewatering 14min at 80 DEG C；It is dispensed after low temperature drying 15h at 40 DEG C.
Comparative example 2 is substantially the same manner as Example 1, and difference is, is added without complexing aluminium water-retaining agent.
Planting experiment:
Test site: the Prevalence In Qixia District, Nanjing City village Shang Ba, test variety: tomato wins auspicious 39.
It is colonized on August 12nd, 2018, uproots plants after their edible portions have been harvested on 2 1st, 2019.It is cultivated, line-spacing 50cm, spacing in the rows 40cm, is tried using duplicate rows
6 pieces of ground is tested, it is unified to apply base fertilizer cow dung 0.5kg/m2, wherein experimental group 1 applies the compound fertilizer of the embodiment of the present invention 1, control
Group 1,2 applies the compound fertilizer of reference examples 1,2 of the present invention respectively, and control group 3 applies commercially available compound fertilizer (brand name: prosperous
It is female), unified to carry out water and fertilizer management, test result is as follows:
Table 1 is soil physico-chemical property variation comparing result before and after planting experiment:
Table 1:
| Physicochemical property | Soil physico-chemical property before testing | Experimental group 1 | Control group 1 | Control group 2 | Control group 3 |
| Quick-acting nitrogen contents (mg/kg) | 18.12 | 19.05 | 17.36 | 17.76 | 9.85 |
| Available phosphorus contents (mg/kg) | 34.65 | 33.28 | 26.46 | 24.93 | 15.26 |
| Quick-acting potassium content (mg/kg) | 88.21 | 90.74 | 79.95 | 81.45 | 55.60 |
| The content of organic matter (g/kg) | 54.66 | 64.31 | 47.61 | 50.64 | 21.18 |
| Total nitrogen content (g/kg) | 1.37 | 1.43 | 0.82 | 0.95 | 0.38 |
| EC/(mS/cm) | 0.44 | 0.45 | 0.65 | 0.83 | 1.22 |
| Soil moisture (%) | 26.3 | 24.2 | 23.9 | 17.3 | 9.49 |
| pH | 7.53 | 7.45 | 7.06 | 7.08 | 6.11 |
Find out as shown in Table 1, the soil items physicochemical property after applying compound fertilizer of the present invention is substantially without larger change, middling speed
Effect nitrogen content, quick-acting potassium content are also promoted, and illustrate to improve for ASI systematic approach, and soluble-salt concentration
EC, pH are without large change, and soil can also be planted after illustrating harvest.
Table 2 is the influence that different fertilizer harvests situation to tomato:
Table 2:
| Project | Experimental group 1 | Control group 1 | Control group 2 | Control group 3 |
| Per plant number (a) | 23.5 | 21.0 | 21.4 | 16.8 |
| Single fruit average weight (g) | 73.10 | 69.28 | 70.51 | 66.9 |
| Per mu yield (kg) | 3381 | 3125 | 3091 | 2896 |
Find out as shown in Table 2, for compound fertilizer of the present invention for promoting Tomato Quality, improving yield has good effect, and passes through
Comparative test it can be concluded that, the present invention in starch-acrylate graft copolymer, complexing aluminium water-retaining agent for promoted fertilizer fertility,
Promote Tomato Quality, yield plays the role of and its positive.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to
Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment
Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
Invention is explained in detail, those skilled in the art should understand that: it still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features；And these modification or
Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.
Claims (9)
1. the compound fertilizer that one kind can be effectively improved soil texture, which is characterized in that the composition including following parts by weight at
Point:
15-20 parts of turf, charing 40-60 parts of peanut shell powder, 5-10 parts of starch-acrylate graft copolymer, ammonium sulfate 10-14
Part, 6-9 parts of potassium sulfate, 20-25 parts of quick lime, 3-7 parts of potassium chloride, 8-12 parts of ferrous sulfate, 1-3 parts of asparagus amino-acid calcium, network
Close 2-4 parts of aluminium water-retaining agent, 5-10 parts of sodium lignin sulfonate, 2-5 parts of stabilizer, 30-40 parts of wood vinegar.
2. the compound fertilizer of soil texture can be effectively improved as described in claim 1, which is characterized in that including following weight
The constituent of number:
16 parts of turf, charing 50 parts of peanut shell powder, 7 parts of starch-acrylate graft copolymer, 12 parts of ammonium sulfate, potassium sulfate 8
Part, 24 parts of quick lime, 6 parts of potassium chloride, 10 parts of ferrous sulfate, 3 parts of asparagus amino-acid calcium, complexing 3 parts of aluminium water-retaining agent, sulfomethylated lignin
10 parts of sour sodium, 5 parts of stabilizer, 32 parts of wood vinegar.
3. the compound fertilizer of soil texture can be effectively improved as described in claim 1, which is characterized in that the charing peanut
Shell is that the peanut shell after drying carbonizes 1-5h at 460-480 DEG C, and ground 800 mesh screen is obtained, pH value 9.8-
10.2, organic carbon content 420-480g/kg.
4. the compound fertilizer of soil texture can be effectively improved as described in claim 1, which is characterized in that the starch-the third
Olefin(e) acid graft copolymer the preparation method is as follows:
Starch is added in distilled water, is kept the temperature after 80-90 DEG C of water-bath gelatinization 20-40min, is passed through nitrogen, is cooled to 40-50
DEG C, be added potassium peroxydisulfate, stirring 5-10min sodium hydrogensulfite is added again, continue stir 5-10min, by acrylic acid be added dropwise into
Enter, react 30-50min, with ammonia water conditioning system pH to neutrality, methanol is added dropwise after being cooled to room temperature, stands 5-15h and filter, filter
Ground 800 mesh screen is dried after the washing of cake methanol.
5. the compound fertilizer of soil texture can be effectively improved as claimed in claim 4, which is characterized in that starch, acrylic acid,
The mass ratio of distilled water is 1:1-1.5:10-20.
6. the compound fertilizer of soil texture can be effectively improved as described in claim 1, which is characterized in that the complexing aluminium is protected
Aqua the preparation method is as follows:
Agar, sodium acrylate, acrylamide, silicon powder are added to after being stirred and evenly mixed in distilled water, by N, N-di-2-ethylhexylphosphine oxide third
Acrylamide is added, after being warming up to 40-45 DEG C of stirring 20-30min, after stirring 5-10min after potassium peroxydisulfate is added, by aluminum sulfate
Potassium solution, humic acid solution are added, and take out after being warming up to 80-85 DEG C of reaction 1-3h, crush drying.
7. the compound fertilizer of soil texture can be effectively improved as claimed in claim 6, which is characterized in that aluminum potassium sulfate solution
Mass concentration be 0.1-0.5%, the mass concentration of humic acid solution is 2-8%.
8. the compound fertilizer of soil texture can be effectively improved as described in claim 1, which is characterized in that the stabilizer is
The mixture of 1,2- butanediol, hydroxycarboxylic acid mass ratio 1-3:1-3.
9. such as the preparation method of the compound fertilizer of any of claims 1-8 that can be effectively improved soil texture,
It is characterized in that, specific as follows:
(1) by turf, ammonium sulfate, potassium sulfate, quick lime, potassium chloride, ferrous sulfate, asparagus amino-acid calcium, complexing aluminium water-retaining agent,
Sodium lignin sulfonate, stabilizer, wood vinegar are added in mixer, and machinery is puddled uniformly, and mixing time 10-20h passes through granulation
Machine is granulated to obtain compound fertilizer idiosome；
(2) charing peanut shell powder, starch-acrylate graft copolymer are added to ultrasonic vibration 5-10min in distilled water and obtained
To suspension；
(3) by spraying device by suspension spray on compound fertilizer idiosome surface, after aeration-drying to water content is lower than 10%,
The fast dewatering 10-15min at 80-85 DEG C；
(4) it is dispensed after low temperature drying 10-15h at 40-50 DEG C.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300430A (en) * | 2020-10-23 | 2021-02-02 | 东莞市东森光电科技有限公司 | Antistatic scratch-resistant toughened film |
| CN115745705A (en) * | 2022-11-30 | 2023-03-07 | 河北萌帮生物科技有限公司 | Fertilizer for reducing soil hardening rate and preparation method thereof |
-
2019
- 2019-08-30 CN CN201910818731.XA patent/CN110511081A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300430A (en) * | 2020-10-23 | 2021-02-02 | 东莞市东森光电科技有限公司 | Antistatic scratch-resistant toughened film |
| CN112300430B (en) * | 2020-10-23 | 2023-01-24 | 东莞市东森光电科技有限公司 | Antistatic scratch-resistant toughened film |
| CN115745705A (en) * | 2022-11-30 | 2023-03-07 | 河北萌帮生物科技有限公司 | Fertilizer for reducing soil hardening rate and preparation method thereof |
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Application publication date: 20191129 |