CN110484382A - A kind of protein fruits and vegetables cleaning agent and preparation method thereof - Google Patents
A kind of protein fruits and vegetables cleaning agent and preparation method thereof Download PDFInfo
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- CN110484382A CN110484382A CN201910836951.5A CN201910836951A CN110484382A CN 110484382 A CN110484382 A CN 110484382A CN 201910836951 A CN201910836951 A CN 201910836951A CN 110484382 A CN110484382 A CN 110484382A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Preparation Of Fruits And Vegetables (AREA)
Abstract
The present invention relates to a kind of protein fruits and vegetables cleaning agents and preparation method thereof, belong to food processing field.Protein-cerium compound will be obtained by washing centrifugation after protein and ammonium ceric nitrate in proportion hybrid reaction, fruits and vegetables cleaning agent is made after compounding in proportion.The formula of fruits and vegetables cleaning agent is mainly as follows: protein-cerium compound 10%-20%, alkyl-glucoside 5%-10%, potassium citrate 5%-10%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium carboxymethylcellulose 2%-4%, sodium bicarbonate 2%-5%, deionized water 51%-74%, the sum of each component are 100%.Prepared by the method fruits and vegetables cleaning agent materials safety is without chemical contamination, with green, degradable, the processing is simple, mild non-stimulated, it is without secondary pollution the features such as, remove the high-efficient of pesticide, residual rate is extremely low, can effectively solve pesticide residue excessive problem in fruits and vegetables.
Description
Technical field
The present invention relates to food processing fields, and in particular to a kind of protein fruits and vegetables cleaning agent and preparation method thereof.
Background technique
In recent years, China's agricultural development was rapid, and the use scope of pesticide expands increasingly, usage amount in year by year it is increased become
Gesture.In order to improve the yield of fruits and vegetables and guarantee its yield and quality, will use in fruits and vegetables growth course fungicide and
Insecticide, common insecticide include organic phosphates, carbamates and quasi- chrysanthemum ester insecticide.In order to guarantee the peace of fruits and vegetables
Quan Xing, using suitable cleaning way to fruits and vegetables is essential step.Common fruits and vegetables cleaning agent has many limitations,
Most cleaning agents belong to the synthesis material based on cheap sodium alkyl benzene sulfonate, and safety is not high.Currently, most detergent institute
The surfactant contained may remain on fruit and vegetable surfaces, easily cause secondary pollution, and long-term intake may generate murder by poisoning to human body
Accumulation.
Patent of invention (application publication number: 102513055 B of CN, data of publication of application: 2013.08.14) is open to report topic
To be a kind of for adsorbing the magnetic material preparation method of enrichment organophosphorus pesticide, although organic phosphorus agriculture can be effectively made in this method
Medicine adsorbent material, but since the solution type of preparation is more, using a large amount of chemical raw material, certain pollution is caused to environment,
And this method requires high, complex procedures there are technique, it is at high cost the problems such as.Patent of invention (application publication number: CN
108841454 A, data of publication of application: 2018.11.20) preparation method for reporting a kind of entitled fruits and vegetables cleaning agent, the fruit are disclosed
Vegetable cleaning agent has good cleaning effect, but the raw material used is mostly chemical synthesis agent, can not only cause to environment centainly
Pollution, can also generate safety problem.Patent of invention (application publication number: 109225167 A of CN, data of publication of application:
2019.01.18 it) discloses and reports a kind of entitled pesticide in vegetable adsorbent, and the removal pesticide residue based on adsorption function
There are the defects such as time-consuming, and energy consumption is high, and adsorption efficiency is low in the adsorbent of vegetables processing method, this method preparation, make in face of promoting
Huge challenge.
Currently, detergent majority in the market is by components such as salt, surfactant or extracts, there are constituent phases
To the defects of single, pesticide residue rate is high, and safety is poor.Cerium ion has the ability of preferable degrading pesticide, and cerium ion is answered
For to there is significant realistic meaning in fruits and vegetables cleaning.It is low to develop a kind of green, mild, degradable, safety, pesticide residue rate
Fruits and vegetables cleaning agent, it is most important for reducing pesticide residue.
Summary of the invention
The object of the present invention is to provide it is a kind of using protein and cerium ion cooperation method, thus obtain it is a kind of can be effective
Adsorb the fruits and vegetables cleaning agent of pesticide.This method is simple and effective, does not need complicated and expensive equipment, and the raw material peace used
It is complete reliable, it is nontoxic, it is degradable, it is a kind of environmentally protective fruits and vegetables cleaning agent well.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of protein fruits and vegetables cleaning agent production method, steps are as follows:
(1) dissolution of raw material: accurately weighing a certain amount of protein in distilled water, and adjusting pH dissolves it sufficiently.
(2) cross-linking reaction: the ammonium ceric nitrate for adding different proportion is dissolved in protein solution, adjusts reaction pH and reaction temperature
Degree controls the reaction time, to be cooled to room temperature after reaction, obtains protein-cerium complex precipitate.
(3) once washing: protein-cerium compound is sufficiently washed using acetone/ethanol solution (1:1), is passed through after washing
Centrifugation removal supernatant, centrifugal rotational speed 5000-8000r/min, centrifugation time 10-30min take precipitating spare, leave after centrifugation
Layer precipitating is spare.
(4) secondary washing: carrying out secondary washing to the precipitating obtained after centrifugation with deionized water, be centrifuged after washing, removal
Remaining acetone and ethanol solution in precipitating, centrifugal rotational speed 5000-8000r/min, centrifugation time 10-30min, it is heavy to take after centrifugation
It forms sediment spare.
(5) dry: protein-cerium complex precipitate being dried using vacuum freeze drier.
(6) ingredient: take it is dry after protein-cerium compound 10%-20%, alkyl-glucoside 5%-10%, lemon
Sour potassium 5%-10%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium carboxymethylcellulose 2%-4%, sodium bicarbonate 2%-
5%, deionized water 51%-74%, the sum of each component are 100%.Raw material, which is stirred, is uniformly mixed it, obtains after dissolution
Fruits and vegetables cleaning agent.
Further, step (1) described raw material includes rice bran protein, soybean protein isolate, peanut protein, wheat gluten etc.
Phytoprotein.
Further, the ratio of step (2) the addition protein and ammonium ceric nitrate is 1:1-10:1, and bath temperature is
25-55 DEG C, pH value of solution 3.0-8.0, reaction time 8-28h.
Beneficial effects of the present invention
The present invention relates to a kind of protein fruits and vegetables cleaning agents and preparation method thereof, using protein-cerium compound to fruits and vegetables
Surface pesticide residue is adsorbed, and harm of the pesticide residue to human health, the native protein that raw material uses, peace are substantially reduced
Completely without murder by poisoning, have the characteristics that green, degradable, the processing is simple, mild non-stimulated, dirt-removing power is strong, can effectively solve fruits and vegetables
The residual excessive problem of middle pesticide.
Detailed description of the invention
In order to facilitate the understanding of those skilled in the art, the present invention will be further described below with reference to the drawings.
Fig. 1 is a kind of process flow chart of protein fruits and vegetables cleaning agent and preparation method thereof;
Fig. 2 is that the different fruits and vegetables cleaning agents recorded in embodiment compare the persticide residue of omethoate pesticide cleaning front and back
Figure.
Specific embodiment
It describes the specific embodiments of the present invention in detail below with reference to the accompanying drawings.
In order to be more clear the objectives, technical solutions, and advantages of the present invention, below with reference to embodiment, the present invention is carried out
It is further described.It should be appreciated that described herein, the specific embodiments are only for explaining the present invention, is not used to limit this
Invention.
Process flow of the invention referring to Fig. 1, the embodiment of the present invention includes:
Embodiment 1
Peanut protein 8g is accurately weighed, is put into beaker, 100ml distilled water is added and is stirred, using 0.1M hydrochloric acid tune
Section pH value of solution sufficiently dissolves peanut protein to 9.0, and addition 8g ammonium ceric nitrate is dissolved in protein solution, heating water bath to 40
DEG C, magnetic agitation is carried out, and adjust reaction pH to 6.0, reaction time 18h.Using acetone/ethanol (1: 1) mixed solution to flower
Raw albumen-cerium compound carries out once washing, is centrifuged after cleaning up using centrifuge, revolving speed 4000r/min, centrifugation time
10min removes supernatant, takes lower sediment spare.Then secondary washing is carried out to obtained precipitating with deionized water, removal is heavy
Acetone and ethyl alcohol Liquid Residue in shallow lake.Supernatant is removed using the method for centrifugation, by the freeze-dried processing standby of lower sediment
With wherein centrifuge speed is 4000r/min, centrifugation time 10min.Peanut protein-cerium compound 10g after taking drying, alkane
Base glucoside 5g, potassium citrate 5g, disodium ethylene diamine tetraacetate 0.1g, sodium carboxymethylcellulose 2g, sodium bicarbonate 2g add
Ionized water is settled to 100mL, is uniformly mixed it, and fruits and vegetables cleaning agent is obtained after dissolution.
Embodiment 2
Soybean protein isolate 8g is accurately weighed, is put into beaker, 100ml distilled water is added and is stirred, using 0.1M salt
Acid-conditioning solution pH to 9.0 sufficiently dissolves soybean protein isolate, and addition 8g ammonium ceric nitrate is dissolved in protein solution, and water-bath adds
Heat carries out magnetic agitation to 40 DEG C, and adjusts reaction pH to 6.0, reaction time 18h.It is mixed using acetone/ethanol (1: 1) molten
Liquid carries out once washing to soybean protein isolate-cerium compound, is centrifuged after cleaning up using centrifuge, revolving speed 4000r/
Min, centrifugation time 10min remove supernatant, take lower sediment spare.Then two are carried out to obtained precipitating with deionized water
Secondary washing removes acetone and ethyl alcohol Liquid Residue in precipitating.Supernatant is removed using the method for centrifugation, lower sediment is chilled
Spare after drying process, wherein centrifuge speed is 4000r/min, centrifugation time 10min.Soybean separation protein after taking drying
White-cerium compound 10g, alkyl-glucoside 5g, potassium citrate 5g, disodium ethylene diamine tetraacetate 0.1g, sodium carboxymethylcellulose
2g, sodium bicarbonate 2g, adds deionized water to be settled to 100mL, is uniformly mixed it, and fruits and vegetables cleaning agent is obtained after dissolution.
Embodiment 3
Rice bran protein 8g is accurately weighed, is put into beaker, 100ml distilled water is added and is stirred, using 0.1M hydrochloric acid tune
Section pH value of solution sufficiently dissolves rice bran protein to 9.0, and addition 8g ammonium ceric nitrate is dissolved in protein solution, heating water bath to 40
DEG C, magnetic agitation is carried out, and adjust reaction pH to 6.0, reaction time 18h.Using acetone/ethanol (1: 1) mixed solution to rice
Chaff albumen-cerium compound carries out once washing, is centrifuged after cleaning up using centrifuge, revolving speed 4000r/min, centrifugation time
10min removes supernatant, takes lower sediment spare.Then secondary washing is carried out to obtained precipitating with deionized water, removal is heavy
Acetone and ethyl alcohol Liquid Residue in shallow lake.Supernatant is removed using the method for centrifugation, by the freeze-dried processing standby of lower sediment
With wherein centrifuge speed is 4000r/min, centrifugation time 10min.Rice bran protein-cerium compound 10g after taking drying, alkane
Base glucoside 5g, potassium citrate 5g, disodium ethylene diamine tetraacetate 0.1g, sodium carboxymethylcellulose 2g, sodium bicarbonate 2g add
Ionized water is settled to 100mL, is uniformly mixed it, and fruits and vegetables cleaning agent is obtained after dissolution.
Absorption property of the invention is analyzed, chooses the omethoate of Shandong Dezhou great achievement pesticide Co., Ltd as control sample
Product, the initial concentration of omethoate are that 96.86%, Fig. 2 is shellfish parent, embodiment 1, embodiment 2, embodiment 3 cleaning front and back omethoate
The comparison diagram of content reacts 30min in isothermal vibration incubator respectively, measure its persticide residue be respectively 5.13%,
2.83%, 2.16%, 1.66%.According to the experimental results, protein cleaning agent absorption property prepared by the present invention is much higher than city
Common fruits and vegetables cleaning agent shellfish parent on face, experiment show to have using the protein fruits and vegetables cleaning agent of technology preparation excellent clear
Wash effect.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair
Equivalent structure or equivalent flow shift made by bright specification and accompanying drawing content is applied directly or indirectly in other relevant skills
Art field is included in scope of patent protection of the invention.
Claims (6)
1. a kind of protein fruits and vegetables cleaning agent, which is characterized in that the cleaning agent is prepared by the raw material of following mass percent:
Protein-cerium compound 10%-20%, alkyl-glucoside 5%-10%, potassium citrate 5%-10%, ethylenediamine tetra-acetic acid two
Sodium 0.1%-0.5%, sodium carboxymethylcellulose 2%-4%, sodium bicarbonate 2%-5%, deionized water 51%-74%, each component
The sum of be 100%.
2. a kind of preparation method of protein fruits and vegetables cleaning agent, which comprises the steps of:
(1) dissolution of raw material: accurately weighing a certain amount of protein in distilled water, and adjusting pH dissolves it sufficiently;
(2) cross-linking reaction: the ammonium ceric nitrate for adding different proportion is dissolved in protein solution, adjusts reaction pH and reaction temperature,
The reaction time is controlled, to be cooled to room temperature after reaction, obtains protein-cerium compound;
(3) once washing: sufficiently washing protein-cerium compound, removes supernatant through centrifugation after washing, and leaving layer precipitating is standby
With;
(4) secondary washing: the lower sediment of acquisition carries out secondary washing, and remaining acetone and ethanol solution in removal precipitating are washed
Protein-cerium complex precipitate is obtained through centrifugation after washing;
(5) dry: protein-cerium complex precipitate being dried using vacuum freeze drier;
(6) ingredient: take it is dry after protein-cerium compound 10%-20%, alkyl-glucoside 5%-10%, potassium citrate
5%-10%, disodium ethylene diamine tetraacetate 0.1%-0.5%, sodium carboxymethylcellulose 2%-4%, sodium bicarbonate 2%-5% are gone
Ionized water 51%-74%, the sum of each component are 100%;It is uniformly mixed it raw material stirring, fruits and vegetables cleaning is obtained after dissolution
Agent.
3. a kind of preparation method of protein fruits and vegetables cleaning agent according to claim 2, which is characterized in that step (1) institute
The raw material stated is rice bran protein, soybean protein isolate, peanut protein.
4. a kind of preparation method of protein fruits and vegetables cleaning agent according to claim 2, which is characterized in that step (2) institute
The ratio of the addition protein and ammonium ceric nitrate stated is 1:1-10:1, and bath temperature is 25-55 DEG C, pH value of solution 3.0-8.0, instead
It is 8-28h between seasonable.
5. a kind of preparation method of protein fruits and vegetables cleaning agent according to claim 2, which is characterized in that step (3) institute
That states carries out protein-cerium compound once washing using acetone/ethanol solution, and the ratio of acetone and ethyl alcohol is 1:1, washing
After be centrifuged, centrifugal rotational speed 5000-8000r/min, centrifugation time 10-30min, taken after centrifugation precipitating it is spare.
6. a kind of preparation method of protein fruits and vegetables cleaning agent according to claim 2, which is characterized in that step (4) institute
The secondary washing stated uses deionized water solution, is centrifuged after washing, centrifugal rotational speed 5000-8000r/min, centrifugation time 10-
30min takes precipitating spare after centrifugation.
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Cited By (1)
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CN111893002A (en) * | 2020-09-09 | 2020-11-06 | 邓文鹏 | Antibacterial fruit and vegetable cleaning agent for removing pesticides and preparation method thereof |
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