CN110483208A - A kind of organic water-soluble chitosan multi-Functional Fertilizers - Google Patents

A kind of organic water-soluble chitosan multi-Functional Fertilizers Download PDF

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Publication number
CN110483208A
CN110483208A CN201910729346.8A CN201910729346A CN110483208A CN 110483208 A CN110483208 A CN 110483208A CN 201910729346 A CN201910729346 A CN 201910729346A CN 110483208 A CN110483208 A CN 110483208A
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China
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parts
water
organic
soluble
mixture
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CN201910729346.8A
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Chinese (zh)
Inventor
张继
张舒婷
惠军涛
刘喆
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Shaanxi Haider Biotechnology Co Ltd
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Shaanxi Haider Biotechnology Co Ltd
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Priority to CN201910729346.8A priority Critical patent/CN110483208A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of organic water-soluble chitosan multi-Functional Fertilizers, fertilizer component includes 80-100 parts of organic fertilizer in parts by weight, 20-30 parts of potassium pyrophosphate, 10-20 parts of potassium dihydrogen phosphate, 10-20 parts of copper sulphate, 4-12 parts of organic carbon of nanometer, 5-10 parts of chelated iron, water-soluble 3-9 parts of coal base mineral resources sodium humate, 4-10 parts of sodium alginate, 3-10 parts of ferrous sulfate, 5-15 parts of potassium formate, 2-4 parts of microbial bacterial agent, 1-3 parts of fungicide, 15-25 parts of chitosan, 10-20 parts of polyglutamic acid, 70-80 parts of water, preparation method of the present invention is simple, fertilizer obtained can be improved soil fertility, improve the structure of soil, and reduce the pollution to soil, it can be improved crop yield simultaneously.

Description

A kind of organic water-soluble chitosan multi-Functional Fertilizers
Technical field
The present invention relates to multi-Functional Fertilizers manufacture technology field, specially a kind of organic water-soluble chitosan multi-Functional Fertilizers.
Background technique
Demand of the biological growth to nutrient is a spontaneous process, and biological medicated fertilizer is the most important life of agricultural production One of production data is maximum substance investment in the material base and agricultural production of agricultural sustainable development, it is all raw to account for about it The 50% of production property expenditure.It is counted according to FAO (Food and Agriculture Organization of the United Nation), in the volume increase of developing country's grain, 55% work from fertilizer With industrial crops are also such case.
Instantly crust fertilizer, chitosan fertilizer are much on the market, but most of is all to do pin with this theory It sells, with chitin, chitosan has not a particle of a relationship or even some so-called crust fertilizers, chitosan fertilizer were using Occur the injury to crops in journey, was the good product that can release phytotoxicity fertilizer damage originally, instead at the member of injury crops Act of violence, conscientiously being investigated just discovery later is to use amino acid entirely, and humic acid adds some hormones and plant growth regulator, in the short time See blade edge, common people have been taken as product, they really have ignored just genuine chitin, the property of chitosan in fact Can, therefore, it is necessary to be improved to existing fertilizer.
Summary of the invention
The purpose of the present invention is to provide a kind of organic water-soluble chitosan multi-Functional Fertilizers, to solve in above-mentioned background technique The problem of proposition.
To achieve the above object, the invention provides the following technical scheme: a kind of organic water-soluble chitosan multi-Functional Fertilizers, fertilizer Expect that component includes 80-100 parts of organic fertilizer, 20-30 parts of potassium pyrophosphate, 10-20 parts of potassium dihydrogen phosphate, copper sulphate in parts by weight 10-20 parts, 4-12 parts of nanometer organic carbon, 5-10 parts of chelated iron, water-soluble 3-9 parts of coal base mineral resources sodium humate, sodium alginate 4- 10 parts, it is 3-10 parts of ferrous sulfate, 5-15 parts of potassium formate, 2-4 parts of microbial bacterial agent, 1-3 parts of fungicide, 15-25 parts of chitosan, poly- 10-20 parts of glutamic acid, 70-80 parts of water.
Preferably, the preferred composition proportion of fertilizer component includes 90 parts of organic fertilizer, 25 parts of potassium pyrophosphate, potassium dihydrogen phosphate 15 Part, 8 parts of 15 part, nanometer organic carbon of copper sulphate, 8 parts of chelated iron, water-soluble 6 parts of coal base mineral resources sodium humate, 7 parts of sodium alginate, 7 parts of ferrous sulfate, 10 parts of potassium formate, 3 parts of microbial bacterial agent, 2 parts of fungicide, 20 parts of chitosan, 15 parts of polyglutamic acid, water 75 Part.
Preferably, the microbial bacterial agent uses one of bacillus licheniformis, bacillus subtilis, lactobacillus acidophilus Or a variety of mixtures.
Preferably, the fungicide using one of amino-oligosaccharide, Zhongshengmycin, polyoxin or more than one Mixture.
Preferably, preparation method includes the following steps:
A, blender is added after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid Middle stirring obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, it is sufficiently mixed It is stirred at 60 DEG C after conjunction, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic force after being sufficiently mixed It is stirred in blender, obtains organic water-soluble fertilizer.
Preferably, stirring rate is 500-800 revs/min in the step C, time 15min-25min.
Preferably, the magnetic stirrer revolving speed is 800-1200 revs/min, time 10min-20min.
Compared with prior art, the beneficial effects of the present invention are: preparation method of the present invention is simple, fertilizer obtained can be mentioned High soil fertility, improves the structure of soil, and reduce the pollution to soil, while can be improved crop yield; Wherein, the microbial bacterial agent added in the present invention can inhibit and reduce soil surface characters, improve and eliminate soil hardening and micro- life State environment;The fungicide of addition can induce crop to the resistance of disease;The first that the chitosan of addition can activate its exclusive Chitinase, promotes well developed root system, cauline leaf sturdy at the Mechanism of Physiological and Biochemical for enhancing plant, and plant is made to absorb and utilize the energy of liquid manure Power and photosynthesis etc. are all enhanced.20%-40% or more can be increased production for fruits and vegetables sprinkling irrigation etc..Fruit does sth. in advance maturation 3-7 days.Cucumber production promoting is up to 50%.Kidney bean, soybean yield-increasing 20%-35%.Energy is protected with extremely strong rootability and root Power;Plant is promoted to have superpower disease resistance;With extremely strong double regulation control ability.Chitosan is taking into account insecticide, fungicide While the characteristics of being used in mixed way with organic fertilizer, giving full play to its biodegradability and compatibility, to pesticide and chemistry fertilizer Material has synergistic effect.Special biochemical method makes the organic macromolecule in chitin become the small molecule for being easy to plant absorption, A variety of organic nutrient collaborations play a role.Unique chelating technology keeps its sufficiently stable, to promote plant to nitrogen, phosphorus, potassium It absorbs, strong plant part, shortens plant growing cycle, enhancing plant disease-resistant ability has remarkable result, hence it is evident that improves plant Quality and yield, in addition, the preparation method that the present invention uses is easy to operate, it can be ensured that each material component is sufficiently mixed, into One step improves fertilizer effect.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
The invention provides the following technical scheme: a kind of organic water-soluble chitosan multi-Functional Fertilizers, fertilizer component is by weight Number includes organic fertilizer 80-100 parts, 20-30 parts of potassium pyrophosphate, 10-20 parts of potassium dihydrogen phosphate, 10-20 parts of copper sulphate, nanometer are organic 4-12 parts of carbon, 5-10 parts of chelated iron, water-soluble 3-9 parts of coal base mineral resources sodium humate, 4-10 parts of sodium alginate, ferrous sulfate 3-10 Part, 5-15 parts of potassium formate, 2-4 parts of microbial bacterial agent, 1-3 parts of fungicide, 15-25 parts of chitosan, 10-20 parts of polyglutamic acid, water 70-80 parts.
Embodiment one:
Fertilizer component includes 80 parts of organic fertilizer, 20 parts of potassium pyrophosphate, 10 parts of potassium dihydrogen phosphate, copper sulphate 10 in parts by weight Part, 4 parts of nanometer organic carbon, 5 parts of chelated iron, water-soluble 3 parts of coal base mineral resources sodium humate, 4 parts of sodium alginate, 3 parts of ferrous sulfate, 5 parts of potassium formate, 2 parts of microbial bacterial agent, 1 part of fungicide, 15 parts of chitosan, 10 parts of polyglutamic acid, 70 parts of water.
In the present embodiment, microbial bacterial agent uses bacillus licheniformis.
In the present embodiment, fungicide uses amino-oligosaccharide.
The preparation method of the present embodiment the following steps are included:
A, blender is added after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid Middle stirring obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, it is sufficiently mixed It is stirred at 60 DEG C after conjunction, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic force after being sufficiently mixed It is stirred in blender, obtains organic water-soluble fertilizer.
In the present embodiment, stirring rate is 500 revs/min in step C, time 15min.
In the present embodiment, magnetic stirrer revolving speed is 800 revs/min, time 10min.
Embodiment two:
Fertilizer component includes 100 parts of organic fertilizer, 30 parts of potassium pyrophosphate, 20 parts of potassium dihydrogen phosphate, copper sulphate in parts by weight 20 12 parts of part, nanometer organic carbons, 10 parts of chelated iron, water-soluble 9 parts of coal base mineral resources sodium humate, 10 parts of sodium alginate, sulfuric acid are sub- 10 parts of iron, 15 parts of potassium formate, 4 parts of microbial bacterial agent, 3 parts of fungicide, 25 parts of chitosan, 20 parts of polyglutamic acid, 80 parts of water.
In the present embodiment, microbial bacterial agent uses bacillus subtilis.
In the present embodiment, fungicide uses Zhongshengmycin.
The preparation method of the present embodiment the following steps are included:
A, blender is added after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid Middle stirring obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, it is sufficiently mixed It is stirred at 60 DEG C after conjunction, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic force after being sufficiently mixed It is stirred in blender, obtains organic water-soluble fertilizer.
In the present embodiment, stirring rate is 800 revs/min in step C, time 25min.
In the present embodiment, magnetic stirrer revolving speed is 1200 revs/min, time 20min.
Embodiment three:
Fertilizer component includes 95 parts of organic fertilizer, 24 parts of potassium pyrophosphate, 16 parts of potassium dihydrogen phosphate, copper sulphate 14 in parts by weight Part, 10 parts of nanometer organic carbon, 7 parts of chelated iron, water-soluble 5 parts of coal base mineral resources sodium humate, 8 parts of sodium alginate, ferrous sulfate 5 Part, 12 parts of potassium formate, 2 parts of microbial bacterial agent, 3 parts of fungicide, 22 parts of chitosan, 17 parts of polyglutamic acid, 77 parts of water.
In the present embodiment, microbial bacterial agent uses bacillus licheniformis, bacillus subtilis mixture.
In the present embodiment, fungicide uses amino-oligosaccharide, Zhongshengmycin mixture.
The preparation method of the present embodiment the following steps are included:
A, blender is added after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid Middle stirring obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, it is sufficiently mixed It is stirred at 60 DEG C after conjunction, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic force after being sufficiently mixed It is stirred in blender, obtains organic water-soluble fertilizer.
In the present embodiment, stirring rate is 600 revs/min in step C, time 18min.
In the present embodiment, magnetic stirrer revolving speed is 900 revs/min, time 14min.
Example IV:
Fertilizer component includes 90 parts of organic fertilizer, 25 parts of potassium pyrophosphate, 15 parts of potassium dihydrogen phosphate, copper sulphate 15 in parts by weight Part, 8 parts of nanometer organic carbon, 8 parts of chelated iron, water-soluble 6 parts of coal base mineral resources sodium humate, 7 parts of sodium alginate, 7 parts of ferrous sulfate, 10 parts of potassium formate, 3 parts of microbial bacterial agent, 2 parts of fungicide, 20 parts of chitosan, 15 parts of polyglutamic acid, 75 parts of water.
In the present embodiment, microbial bacterial agent uses bacillus licheniformis, bacillus subtilis, lactobacillus acidophilus mixture.
In the present embodiment, fungicide uses amino-oligosaccharide, Zhongshengmycin, polyoxin mixture.
The preparation method of the present embodiment the following steps are included:
A, blender is added after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid Middle stirring obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, it is sufficiently mixed It is stirred at 60 DEG C after conjunction, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic force after being sufficiently mixed It is stirred in blender, obtains organic water-soluble fertilizer.
In the present embodiment, stirring rate is 650 revs/min in step C, time 20min.
In the present embodiment, magnetic stirrer revolving speed is 1000 revs/min, time 15min.
Preparation method of the present invention is simple, and fertilizer obtained can be improved soil fertility, improves the structure of soil, and Reduce the pollution to soil, while can be improved crop yield;Wherein, the microbial bacterial agent added in the present invention can inhibit With reduction soil surface characters, improve and eliminate soil hardening and micro-ecological environment;The fungicide of addition can induce crop to disease Harmful resistance;The Mechanism of Physiological and Biochemical of chitinase, enhancing plant that the chitosan of addition can activate its exclusive promotes root System is flourishing, cauline leaf is sturdy, and plant is made to absorb and all be enhanced using the ability of liquid manure and photosynthesis etc..It is sprayed for fruits and vegetables Filling etc. can increase production 20%-40% or more.Fruit is done sth. in advance 3-7 days mature.Cucumber production promoting is up to 50%.Kidney bean, soybean yield-increasing 20%-35%.With extremely strong rootability and root protective capability;Plant is promoted to have superpower disease resistance;With extremely strong Double regulation control ability.Chitosan is used in mixed way while taking into account insecticide, fungicide with organic fertilizer, gives full play to its life The characteristics of Biodegradable and compatibility, has synergistic effect to pesticide and chemical fertilizer.Special biochemical method makes chitin In organic macromolecule become the small molecule for being easy to plant absorption, a variety of organic nutrients collaborations play a role.Unique chelating skill Art keeps its sufficiently stable, and to absorption of the plant to nitrogen, phosphorus, potassium is promoted, strong plant part shortens plant growing cycle, increases Strong plant disease-resistant ability has remarkable result, hence it is evident that the quality and yield of plant is improved, in addition, the preparation method that the present invention uses It is easy to operate, it can be ensured that each material component is sufficiently mixed, and further improves fertilizer effect.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (7)

1. a kind of organic water-soluble chitosan multi-Functional Fertilizers, it is characterised in that: fertilizer component includes organic fertilizer 80- in parts by weight 100 parts, 20-30 parts of potassium pyrophosphate, 10-20 parts of potassium dihydrogen phosphate, 10-20 parts of copper sulphate, 4-12 parts of nanometer organic carbon, chelated iron 5-10 parts, water-soluble 3-9 parts of coal base mineral resources sodium humate, 4-10 parts of sodium alginate, 3-10 parts of ferrous sulfate, potassium formate 5-15 Part, 2-4 parts of microbial bacterial agent, 1-3 parts of fungicide, 15-25 parts of chitosan, 10-20 parts of polyglutamic acid, 70-80 parts of water.
2. a kind of organic water-soluble chitosan multi-Functional Fertilizers according to claim 1, it is characterised in that: fertilizer component is preferred Composition proportion include 90 parts of organic fertilizer, 25 parts of potassium pyrophosphate, 15 parts of potassium dihydrogen phosphate, 15 part, nanometer organic carbon 8 of copper sulphate It is part, 8 parts of chelated iron, water-soluble 6 parts of coal base mineral resources sodium humate, 7 parts of sodium alginate, 7 parts of ferrous sulfate, 10 parts of potassium formate, micro- 3 parts of bacteria agent, 2 parts of fungicide, 20 parts of chitosan, 15 parts of polyglutamic acid, 75 parts of water.
3. a kind of organic water-soluble chitosan multi-Functional Fertilizers according to claim 1, it is characterised in that: the microbial bacteria Agent uses one of bacillus licheniformis, bacillus subtilis, lactobacillus acidophilus or a variety of mixtures.
4. a kind of organic water-soluble chitosan multi-Functional Fertilizers according to claim 1, it is characterised in that: the fungicide is adopted With one of amino-oligosaccharide, Zhongshengmycin, polyoxin or more than one mixture.
5. realizing a kind of preparation method of organic water-soluble chitosan multi-Functional Fertilizers described in claim 1, it is characterised in that: its Preparation method the following steps are included:
A, it is added in blender and stirs after mixing nanometer organic carbon, chelated iron, water-soluble coal base mineral resources sodium humate, polyglutamic acid It mixes, obtains mixture A;
B, ball milling in ball mill is added after mixing copper sulphate, sodium alginate, ferrous sulfate, potassium formate, obtains mixture B;
C, mixture A, mixture B, organic fertilizer, potassium pyrophosphate, potassium dihydrogen phosphate are sequentially added in blender, after being sufficiently mixed It is stirred at 60 DEG C, obtains mixture C;
D, microbial bacterial agent, fungicide, chitosan are added in mixture C, feeds the mixture into magnetic agitation after being sufficiently mixed It is stirred in machine, obtains organic water-soluble fertilizer.
6. a kind of preparation method of organic water-soluble chitosan multi-Functional Fertilizers according to claim 5, it is characterised in that: institute Stating stirring rate in step C is 500-800 revs/min, time 15min-25min.
7. a kind of preparation method of organic water-soluble chitosan multi-Functional Fertilizers according to claim 5, it is characterised in that: institute Stating magnetic stirrer revolving speed is 800-1200 revs/min, time 10min-20min.
CN201910729346.8A 2019-08-08 2019-08-08 A kind of organic water-soluble chitosan multi-Functional Fertilizers Pending CN110483208A (en)

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WO2021118426A1 (en) * 2019-12-11 2021-06-17 Perstorp Ab Method for increasing the starch content in agricultural crops
CN113880665A (en) * 2021-11-19 2022-01-04 塔里木大学 Processing technology of chitosan liquid fertilizer

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Publication number Priority date Publication date Assignee Title
WO2021118426A1 (en) * 2019-12-11 2021-06-17 Perstorp Ab Method for increasing the starch content in agricultural crops
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Application publication date: 20191122