CN110467904A - A kind of rubber oil and preparation method thereof for producing modified asphalt waterproof coiled material - Google Patents

A kind of rubber oil and preparation method thereof for producing modified asphalt waterproof coiled material Download PDF

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CN110467904A
CN110467904A CN201910750443.5A CN201910750443A CN110467904A CN 110467904 A CN110467904 A CN 110467904A CN 201910750443 A CN201910750443 A CN 201910750443A CN 110467904 A CN110467904 A CN 110467904A
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mass parts
oil
rubber
coiled material
modified asphalt
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CN110467904B (en
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王楚皓
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Huizhou Wanhong Jiuding Petroleum Technology Co.,Ltd.
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Guangdong Wanhong Jiuding Petroleum Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to waterproofing membrane production fields, provide a kind of rubber oil and preparation method thereof for producing modified asphalt waterproof coiled material, for solving the problems, such as that modified asphalt waterproof coiled material material is poor.It is provided by the invention a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 30 ~ 50 mass parts of aromatic naphtha, 30 ~ 50 mass parts of naphthenic oil, 5 ~ 10 mass parts of paraffin oil, 2 ~ 5 mass parts of tackifier, 0.2 ~ 0.5 mass parts of rubber accelerator, 0.2 ~ 0.5 mass parts of antioxidant.The quality that waterproof roll can significantly be improved reduces cost, and rubber oil production process is environmentally protective, safe and reliable;Pour point is low, flash-point is high, adhesive property is strong, and the bond effect that can be improved the peel strength of waterproof roll, hold viscosity, cement basic layer keeps the waterproof performance of coiled material more excellent, and waterproof effect is more persistently reliable.

Description

A kind of rubber oil and preparation method thereof for producing modified asphalt waterproof coiled material
Technical field
The present invention relates to waterproofing membrane production fields, and in particular to a kind of for producing the rubber of modified asphalt waterproof coiled material Oil and preparation method thereof.
Background technique
In waterproofing industry, modified pitch used in waterproof roll needs to be added the oils of a certain amount of (5-15%), allows Modified pitch system has more processing performance, while improving the adhesive property and anti-severe cold effect etc. of coiled material.But the oil being added If class does not choose, it is unqualified that the modified asphalt waterproof coiled material made will appear the indexs such as peel strength, permeability, construction Bond it is insecure, the problems such as loss of properties on aging, so as to cause the waterproof layer leak of building.At present in waterproofing industry, still There are some enterprises to produce waterproof roll using the used oil or residual oil of dangerous waste, this to the quality of environmental protection, waterproof roll, The effect of waterproof all plays negative impact.
Summary of the invention
Present invention solves the technical problem that providing one kind to solve the problems, such as that modified asphalt waterproof coiled material material is poor and being used for Produce the rubber oil and preparation method thereof of modified asphalt waterproof coiled material.
In order to solve the above technical problem, the present invention provides technical solution are as follows:
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 30 ~ 50 mass parts of aromatic naphtha, 30 ~ 50 matter of naphthenic oil Measure part, 5 ~ 10 mass parts of paraffin oil, 2 ~ 5 mass parts of tackifier, 0.2 ~ 0.5 mass parts of rubber accelerator, antioxidant 0.2 ~ 0.5 Mass parts.
Aromatic naphtha may make allotted rubber oil and the good compatibility of pitch, naphthenic oil that the low temperature of product can be improved Flexibility, paraffin oil can allow in modified pitch the high molecular polymer modifying agent being added to have better solution rate and effect are blended Fruit, and tackifier can make the peel strength of waterproof roll and construction bond effect be significantly improved, rubber accelerator has Help the production and storage of product.
The quality that waterproof roll can significantly be improved reduces cost, and rubber oil production process is environmentally protective, and use is safe Reliably;Pour point is low, flash-point is high, adhesive property is strong, can improve the peel strength of waterproof roll, hold viscosity, the bonding of cement basic layer Effect keeps the waterproof performance of coiled material more excellent, and waterproof effect is more persistently reliable.
Preferably, including 40 ~ 50 mass parts of aromatic naphtha, 40 ~ 50 mass parts of naphthenic oil, 7 ~ 10 mass parts of paraffin oil viscosify 3 ~ 5 mass parts of agent, 0.4 ~ 0.5 mass parts of rubber accelerator, 0.4 ~ 0.5 mass parts of antioxidant.
Preferably, including 40 mass parts of aromatic naphtha, 40 mass parts of naphthenic oil, 7 mass parts of paraffin oil, 3 mass parts of tackifier, 0.4 mass parts of rubber accelerator, 0.4 mass parts of antioxidant.
Preferably, the aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber accelerator, the flash-point of antioxidant are high In 220 degrees Celsius.Flash-point is high, and safety is good.
Preferably, aryl content > 80% ,+20 DEG C of the pour point < of the aromatic naphtha, 100 DEG C of kinematic viscosity are 10- 20mm2/s。
Preferably, the naphthenic base content > 60% of the naphthenic oil, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5- 15mm2/s。
Preferably, the linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5- 10mm2/s。
It is a kind of for producing the preparation method of the rubber oil of modified asphalt waterproof coiled material, comprising:
S11. naphthenic oil and paraffin oil are mixed, tackifier, rubber accelerator and antioxidant, stirring or air blowing 30min is added;
S12. aromatic naphtha, stirring or air blowing 2h is added to complete miscibility.
Compared with prior art, the device have the advantages that are as follows: can significantly improve the quality of waterproof roll, drop Low cost, rubber oil production process is environmentally protective, safe and reliable;Pour point is low, flash-point is high, adhesive property is strong, can improve anti- The peel strength of water coiled material, the bond effect for holding viscosity, cement basic layer, keep the waterproof performance of coiled material more excellent, waterproof effect It is more persistently reliable;< -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 10-20mm2/ s, density < 1.00g/mL, flash-point > 220 DEG C, moisture-free.
Specific embodiment
Following implementation column is to further explanation of the invention, is not limitation of the present invention.
Embodiment 1
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 40 mass parts of aromatic naphtha, 40 mass parts of naphthenic oil, 7 mass parts of paraffin oil, 3 mass parts of tackifier, 0.4 mass parts of rubber accelerator, 0.4 mass parts of antioxidant.The aromatic naphtha, Naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aromatic naphtha Aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base of the naphthenic oil contains > 60% is measured, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Aromatic naphtha may make allotted rubber oil and the good compatibility of pitch, naphthenic oil that the low temperature of product can be improved Flexibility, paraffin oil can allow in modified pitch the high molecular polymer modifying agent being added to have better solution rate and effect are blended Fruit, and tackifier can make the peel strength of waterproof roll and construction bond effect be significantly improved, rubber accelerator has Help the production and storage of product.The quality that waterproof roll can significantly be improved reduces cost, rubber oil production process green Environmental protection, it is safe and reliable;Pour point is low, flash-point is high, adhesive property is strong, can improve the peel strength of waterproof roll, hold viscosity, water The bond effect of mud base keeps the waterproof performance of coiled material more excellent, and waterproof effect is more persistently reliable.Flash-point is high, safety It is good.
It is a kind of for producing the preparation method of the rubber oil of modified asphalt waterproof coiled material, comprising: S11. is by naphthenic oil and stone Wax oil mixing, is added tackifier, rubber accelerator and antioxidant, stirs 30min;
S12. aromatic naphtha, stirring 2h to complete miscibility is added.
Embodiment 2
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 30 mass parts of aromatic naphtha, 30 mass parts of naphthenic oil, 5 mass parts of paraffin oil, 2 mass parts of tackifier, 0.2 mass parts of rubber accelerator, 0.2 mass parts of antioxidant.The aromatic naphtha, Naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aromatic naphtha Aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base of the naphthenic oil contains > 60% is measured, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
It is a kind of for producing the preparation method of the rubber oil of modified asphalt waterproof coiled material, comprising: S11. is by naphthenic oil and stone Wax oil mixing, is added tackifier, rubber accelerator and antioxidant, air blowing 30min;
S12. aromatic naphtha, air blowing 2h to complete miscibility is added.
Embodiment 3
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 50 mass parts of aromatic naphtha, 50 mass parts of naphthenic oil, 10 mass parts of paraffin oil, 5 mass parts of tackifier, 0.5 mass parts of rubber accelerator, 0.5 mass parts of antioxidant.The aromatic hydrocarbons Oil, naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aromatic naphtha Aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base of the naphthenic oil Content > 60%, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > of the paraffin oil 60%, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
It is a kind of for producing the preparation method of the rubber oil of modified asphalt waterproof coiled material, comprising:
S11. naphthenic oil and paraffin oil are mixed, tackifier, rubber accelerator and antioxidant is added, stir 30min;
S12. aromatic naphtha, stirring 2h to complete miscibility is added.
Comparative example 1
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 43 mass parts of aromatic naphtha, 44 mass parts of naphthenic oil, 3 mass parts of tackifier, 0.4 mass parts of rubber accelerator, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, Tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aryl content > of the aromatic naphtha 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base content > 60% of the naphthenic oil, pour point < -30 DEG C, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Comparative example 2
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 40 mass parts of naphthenic oil, 47 mass parts of paraffin oil, 3 mass parts of tackifier, 0.4 mass parts of rubber accelerator, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, Tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aryl content > of the aromatic naphtha 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The linear paraffin content > 60% of the paraffin oil, inclines < -20 DEG C of point, 100 DEG C of kinematic viscosity are 5-10mm2/s.The linear paraffin content > 60% of the paraffin oil, pour point < -20 DEG C, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Comparative example 3
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 40 mass parts of aromatic naphtha, 47 mass parts of paraffin oil, 3 mass parts of tackifier, 0.4 mass parts of rubber accelerator, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, Tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aryl content > of the aromatic naphtha 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base content > 60% of the naphthenic oil, pour point < -30 DEG C, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Comparative example 4
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 87 mass parts of aromatic naphtha, 3 mass parts of tackifier, rubber 0.4 mass parts of promoter for rubber, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber promote Agent, antioxidant flash-point be above 220 degrees Celsius.Aryl content > 80% ,+20 DEG C of the pour point < of the aromatic naphtha, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base content > 60% of the naphthenic oil, < -30 DEG C of pour point, 100 DEG C of movements Viscosity is 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5- 10mm2/s。
Comparative example 5
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 87 mass parts of naphthenic oil, 3 mass parts of tackifier, rubber 0.4 mass parts of promoter for rubber, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber promote Agent, antioxidant flash-point be above 220 degrees Celsius.Aryl content > 80% ,+20 DEG C of the pour point < of the aromatic naphtha, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base content > 60% of the naphthenic oil, < -30 DEG C of pour point, 100 DEG C of movements Viscosity is 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5- 10mm2/s。
Comparative example 6
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 87 mass parts of paraffin oil, 3 mass parts of tackifier, rubber 0.4 mass parts of promoter for rubber, 0.4 mass parts of antioxidant.The aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber promote Agent, antioxidant flash-point be above 220 degrees Celsius.Aryl content > 80% ,+20 DEG C of the pour point < of the aromatic naphtha, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base content > 60% of the naphthenic oil, < -30 DEG C of pour point, 100 DEG C of movements Viscosity is 5-15mm2/s.The linear paraffin content > 60% of the paraffin oil, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5- 10mm2/s。
Comparative example 7
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 60 mass parts of aromatic naphtha, 20 mass parts of naphthenic oil, 3 mass parts of paraffin oil, 2 ~ 5 mass parts of tackifier, 0.2 ~ 0.5 mass parts of rubber accelerator, 0.2 ~ 0.5 mass parts of antioxidant. The aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.It is described Aromatic naphtha aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic oil Naphthenic base content > 60%, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin of the paraffin oil Content > 60%, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Comparative example 8
It is a kind of for producing the rubber oil of modified asphalt waterproof coiled material, including 20 mass parts of aromatic naphtha, 60 mass parts of naphthenic oil, 15 mass parts of paraffin oil, 5 mass parts of tackifier, 0.5 mass parts of rubber accelerator, 0.5 mass parts of antioxidant.The aromatic hydrocarbons Oil, naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.The aromatic naphtha Aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s.The naphthenic base of the naphthenic oil Content > 60%, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s.The linear paraffin content > of the paraffin oil 60%, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
Experimental example
Modified asphalt waterproof coiled material is produced using the rubber oil prepared in embodiment and comparative example, tests the technical indicator of coiled material, As shown in the table.
The technical indicator for the coiled material that table 1 is prepared using the rubber oil in embodiment and comparative example
As known from Table 1, the same cement of coiled material of modified asphalt waterproof coiled material is used for after aromatic naphtha, naphthenic oil and three kinds of paraffin oil compoundings The peel strength of mortar is effectively improved, while coiled material has also obtained certain raising with the peel strength between coiled material, Holding viscosity and being also used alone compared with any two compoundings or any oil has comparable raising.
Comparative example 1 ~ 3 is the compounding of any two oil, is shown containing only there are two types of the rubber oils of oil can not significantly improve coiled material Performance;A kind of oil is contained only in comparative example 4 ~ 6, effect is poor;In comparative example 7 and 8 three kinds of oily ratios with embodiment not Together, effect is also poor, shows that only there are three types of could improve volume in the production for being applied to coiled material after oil according to a certain percentage compounding The quality of material.
Above-listed detailed description is illustrating for possible embodiments of the present invention, and above embodiments are not to limit this The scope of the patents of invention, all equivalence enforcements or change without departing from carried out by the present invention, is intended to be limited solely by the scope of the patents of this case.

Claims (8)

1. a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that including 30 ~ 50 mass parts of aromatic naphtha, 30 ~ 50 mass parts of naphthenic oil, 5 ~ 10 mass parts of paraffin oil, 2 ~ 5 mass parts of tackifier, 0.2 ~ 0.5 mass parts of rubber accelerator resist 0.2 ~ 0.5 mass parts of oxidant.
2. according to claim 1 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that including 40 ~ 50 mass parts of aromatic naphtha, 40 ~ 50 mass parts of naphthenic oil, 7 ~ 10 mass parts of paraffin oil, 3 ~ 5 mass parts of tackifier, rubber promote 0.4 ~ 0.5 mass parts of agent, 0.4 ~ 0.5 mass parts of antioxidant.
3. according to claim 2 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that including 40 mass parts of aromatic naphtha, 40 mass parts of naphthenic oil, 7 mass parts of paraffin oil, 3 mass parts of tackifier, 0.4 mass of rubber accelerator Part, 0.4 mass parts of antioxidant.
4. according to claim 1 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that described Aromatic naphtha, naphthenic oil, paraffin oil, tackifier, rubber accelerator, antioxidant flash-point be above 220 degrees Celsius.
5. according to claim 1 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that described Aromatic naphtha aryl content > 80% ,+20 DEG C of pour point <, 100 DEG C of kinematic viscosity are 10-20mm2/s。
6. according to claim 1 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that described Naphthenic oil naphthenic base content > 60%, < -30 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-15mm2/s。
7. according to claim 1 a kind of for producing the rubber oil of modified asphalt waterproof coiled material, which is characterized in that described Paraffin oil linear paraffin content > 60%, < -20 DEG C of pour point, 100 DEG C of kinematic viscosity are 5-10mm2/s。
8. a kind of for producing the preparation method of the rubber oil of modified asphalt waterproof coiled material characterized by comprising
S11. naphthenic oil and paraffin oil are mixed, tackifier, rubber accelerator and antioxidant, stirring or air blowing 30min is added;
S12. aromatic naphtha, stirring or air blowing 2h is added to complete miscibility.
CN201910750443.5A 2019-08-14 2019-08-14 Rubber oil for producing modified asphalt waterproof coiled material and preparation method thereof Active CN110467904B (en)

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