CN110467349A - The method that mineral material containing coloring oxide recycles - Google Patents
The method that mineral material containing coloring oxide recycles Download PDFInfo
- Publication number
- CN110467349A CN110467349A CN201910807680.0A CN201910807680A CN110467349A CN 110467349 A CN110467349 A CN 110467349A CN 201910807680 A CN201910807680 A CN 201910807680A CN 110467349 A CN110467349 A CN 110467349A
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- CN
- China
- Prior art keywords
- containing coloring
- mineral material
- oxide
- finished product
- coloring oxide
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention belongs to scrap concrete processing technology fields, more particularly to a kind of method that the mineral material containing coloring oxide recycles, the following steps are included: (1) is calcined after mixing the mineral material containing coloring oxide, and after the completion of calcining, material after being calcined；(2) 200 meshes are crossed after the calcining for obtaining step (1) after crushing material, extracting screen underflow obtains the powder of 200 mesh；(3) powder for 200 mesh that step (2) obtains is crossed into 325 meshes, obtains plus sieve material finished product and minus sieve material finished product.Effective component in mineral material containing coloring oxide can be recycled by the present invention, realize the recycling of resource, solve the problems, such as that environment is polluted in the wasting of resources, the ceramic paint and glaze that the finished product of preparation can replace the chemical industry metal oxide of currently employed high-purity to manufacture, material cost can reduce by 20% or more.
Description
Technical field
The invention belongs to scrap concrete processing technology fields, and in particular to a kind of mineral material containing coloring oxide time
Receive the method utilized.
Background technique
The ornament materials (pigment and glaze) that current ceramic uses, the overwhelming majority use the chemical industry metal oxygen of high-purity
Compound, the metal oxide of high-purity are non-renewable resources, while having a large amount of (cobalt, iron, chromium containing coloring oxide in the market
Deng) mineral material and residue of chemical industry material heap put, majority without any processing, be unfavorable for wasting money while environmental protection
Source.
Containing largely recyclable material in mineral material containing coloring oxide, typically contain cobalt oxide, iron oxide with
And nickel oxide etc., equal recoverable.
Summary of the invention
The technical problem to be solved by the present invention is overcoming the deficiencies of the prior art and provide a kind of mine containing coloring oxide
Effective component in mineral material containing coloring oxide is recycled by the method for object MAT'L recycling, realizes money
The recycling in source solves the problems, such as that environment is polluted in the wasting of resources.
The method that mineral material of the present invention containing coloring oxide recycles, comprising the following steps:
(1) by the mineral material containing coloring oxide using stainless steel batch mixer mix 20~after forty minutes, after mixing
Mineral material be fitted into saggar and calcined, calcination temperature is 1000~1200 DEG C, and calcination time is 8~12 hours, calcining
The flue gas of generation is handled by desulfuring and denitrifying apparatus, after the completion of calcining, material after being calcined；
(2) material uses super fine machine and airflow milling to carry out pulverization process to material after the calcining for obtaining step (1),
200 mesh screen residue 0.3wt% are smashed it through hereinafter, extracting screen underflow, obtains the powder of 200 mesh；
(3) powder for 200 mesh that step (2) obtains is crossed into 325 mesh all-pass, obtains plus sieve material finished product and minus sieve material
Finished product, the product of two kinds of specifications.
Preferably, the mineral material containing coloring oxide described in step (1) includes the following components'mass percentage: oxygen
Change cobalt 2~8%, iron oxide 22~28%, nickel oxide 22~28%.
The water content of the product of plus sieve material finished product and minus sieve material two kinds of specifications of finished product prepared by the present invention is both needed to be less than
0.1wt% is controlled within ± 0.3 with the Δ E of the color difference of standard colorimetric, and plus sieve material finished product can be used for conventional screen printed ceramic
Porcelain pigment, minus sieve material finished product are used for roller ceramic paint.
Compared with prior art, beneficial effects of the present invention are as follows:
1, the ceramic paint that finished product prepared by the present invention can replace the chemical industry metal oxide of currently employed high-purity to manufacture
And glaze, material cost can reduce by 20% or more.
2. the effective component in the mineral material containing coloring oxide can be recycled by the present invention, resource is realized
Recycling, solve the problems, such as the wasting of resources pollute environment.
Specific embodiment
The present invention is further described below with reference to embodiment.
Embodiment 1
The method that the mineral material containing coloring oxide recycles, comprising the following steps:
(1) mineral material containing coloring oxide is mixed using stainless steel batch mixer after twenty minutes, by mixed mine
Object material, which is fitted into saggar, to be calcined, and calcination temperature is 1000 DEG C, and calcination time is 12 hours, and the flue gas for calcining generation passes through
Desulfuring and denitrifying apparatus processing, after the completion of calcining, material after being calcined；
(2) material uses super fine machine and airflow milling to carry out pulverization process to material after the calcining for obtaining step (1),
200 mesh screen residue 0.3wt% are smashed it through hereinafter, extracting screen underflow, obtains the powder of 200 mesh；
(3) powder for 200 mesh that step (2) obtains is crossed into 325 mesh all-pass, obtains plus sieve material finished product and minus sieve material
The product of two kinds of specifications of finished product.
The water content of finished product of two kinds of specifications of preparation is respectively less than 0.1wt%, with the Δ E of the color difference of standard colorimetric ±
Within 0.3.
Embodiment 2
The method that the mineral material containing coloring oxide recycles, comprising the following steps:
(1) after mixing the mineral material containing coloring oxide 30 minutes using stainless steel batch mixer, by mixed mine
Object material, which is fitted into saggar, to be calcined, and calcination temperature is 1100 DEG C, and calcination time is 10 hours, and the flue gas for calcining generation passes through
Desulfuring and denitrifying apparatus processing, after the completion of calcining, material after being calcined；
(2) material uses super fine machine and airflow milling to carry out pulverization process to material after the calcining for obtaining step (1),
200 mesh screen residue 0.3wt% are smashed it through hereinafter, extracting screen underflow, obtains the powder of 200 mesh；
(3) powder for 200 mesh that step (2) obtains is crossed into 325 mesh all-pass, obtains plus sieve material finished product and minus sieve material
The product of two kinds of specifications of finished product.
The water content of finished product of two kinds of specifications of preparation is respectively less than 0.1wt%, with the Δ E of the color difference of standard colorimetric ±
Within 0.3.
Embodiment 3
The method that the mineral material containing coloring oxide recycles, comprising the following steps:
(1) mineral material containing coloring oxide is mixed using stainless steel batch mixer after forty minutes, by mixed mine
Object material, which is fitted into saggar, to be calcined, and calcination temperature is 1200 DEG C, and calcination time is 8 hours, and the flue gas for calcining generation passes through
Desulfuring and denitrifying apparatus processing, after the completion of calcining, material after being calcined；
(2) material uses super fine machine and airflow milling to carry out pulverization process to material after the calcining for obtaining step (1),
200 mesh screen residue 0.3wt% are smashed it through hereinafter, extracting screen underflow, obtains the powder of 200 mesh；
(3) powder for 200 mesh that step (2) obtains is crossed into 325 mesh all-pass, obtains plus sieve material finished product and minus sieve material
The product of two kinds of specifications of finished product.
The water content of finished product of two kinds of specifications of preparation is respectively less than 0.1wt%, with the Δ E of the color difference of standard colorimetric ±
Within 0.3.
Mineral material raw material containing coloring oxide used by above-described embodiment 1-3 is detected, included in
Constituent content is as shown in table 1.
Constituent content included in mineral material raw material of the table 1 containing coloring oxide
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Cobalt oxide (%) | 3 | 6 | 3 |
| Iron oxide (%) | 25 | 26 | 24 |
| Nickel oxide (%) | 25 | 28 | 25 |
Certainly, above content is only presently preferred embodiments of the present invention, be should not be construed as limiting to implementation of the invention
Example range.The present invention is also not limited to the example above, and those skilled in the art are in essential scope of the invention
Interior made all the changes and improvements etc., should all belong in patent covering scope of the invention.
Claims (6)
1. a kind of method that the mineral material containing coloring oxide recycles, it is characterised in that: the following steps are included:
(1) it is calcined after mixing the mineral material containing coloring oxide, after the completion of calcining, material after being calcined；
(2) 200 meshes are crossed after the calcining for obtaining step (1) after crushing material, extracting screen underflow obtains the powder of 200 mesh；
(3) powder for 200 mesh that step (2) obtains is crossed into 325 meshes, obtains plus sieve material finished product and minus sieve material finished product.
2. the method that the mineral material according to claim 1 containing coloring oxide recycles, it is characterised in that: step
(1) mineral material containing coloring oxide described in includes the following components'mass percentage: cobalt oxide 2~8%, iron oxide 22
~28%, nickel oxide 22~28%.
3. the method that the mineral material according to claim 1 containing coloring oxide recycles, it is characterised in that: step
(1) being mixed into described in is mixed 20~40 minutes using stainless steel batch mixer.
4. the method that the mineral material according to claim 1 containing coloring oxide recycles, it is characterised in that: step
(1) calcination temperature described in is 1000~1200 DEG C, and calcination time is 8~12 hours.
5. the method recycled according to the mineral material according to claim 1 containing coloring oxide, it is characterised in that:
Plus sieve material finished product described in step (3) is used for conventional screen stamp ceramic paint.
6. the method recycled according to the mineral material according to claim 1 containing coloring oxide, it is characterised in that:
Minus sieve material finished product described in step (3) is used for roller ceramic paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910807680.0A CN110467349A (en) | 2019-08-29 | 2019-08-29 | The method that mineral material containing coloring oxide recycles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910807680.0A CN110467349A (en) | 2019-08-29 | 2019-08-29 | The method that mineral material containing coloring oxide recycles |
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| Publication Number | Publication Date |
|---|---|
| CN110467349A true CN110467349A (en) | 2019-11-19 |
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ID=68513962
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910807680.0A Pending CN110467349A (en) | 2019-08-29 | 2019-08-29 | The method that mineral material containing coloring oxide recycles |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044638A (en) * | 1989-01-31 | 1990-08-15 | 林承焕 | The production method of deep dark color glaze stocks and correlated product thereof |
| JPH1149560A (en) * | 1997-06-04 | 1999-02-23 | Koyo Seiko Co Ltd | Coloring agent, color developing clay and glaze for ceramic products as well as production of coloring agent and glaze |
| CN101219910A (en) * | 2007-12-24 | 2008-07-16 | 钟旭东 | Method for producing color blank glaze archaizing brick by using iron mine tailing |
| CN102617188A (en) * | 2012-03-28 | 2012-08-01 | 陕西科技大学 | Method for preparing split-phase black fancy glaze by utilizing industrial slag |
| CN103086748A (en) * | 2013-02-06 | 2013-05-08 | 陕西科技大学 | Preparation method of slag bicrystal gold fancy glaze |
| CN103922807A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature black glaze by utilizing iron-ore slag |
| CN107056052A (en) * | 2017-05-21 | 2017-08-18 | 景德镇陶瓷大学 | A kind of high additive ferrochrome waste residue brown ceramic glaze and its application process |
-
2019
- 2019-08-29 CN CN201910807680.0A patent/CN110467349A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044638A (en) * | 1989-01-31 | 1990-08-15 | 林承焕 | The production method of deep dark color glaze stocks and correlated product thereof |
| JPH1149560A (en) * | 1997-06-04 | 1999-02-23 | Koyo Seiko Co Ltd | Coloring agent, color developing clay and glaze for ceramic products as well as production of coloring agent and glaze |
| CN101219910A (en) * | 2007-12-24 | 2008-07-16 | 钟旭东 | Method for producing color blank glaze archaizing brick by using iron mine tailing |
| CN102617188A (en) * | 2012-03-28 | 2012-08-01 | 陕西科技大学 | Method for preparing split-phase black fancy glaze by utilizing industrial slag |
| CN103086748A (en) * | 2013-02-06 | 2013-05-08 | 陕西科技大学 | Preparation method of slag bicrystal gold fancy glaze |
| CN103922807A (en) * | 2014-04-09 | 2014-07-16 | 陕西科技大学 | Method for preparing low temperature black glaze by utilizing iron-ore slag |
| CN107056052A (en) * | 2017-05-21 | 2017-08-18 | 景德镇陶瓷大学 | A kind of high additive ferrochrome waste residue brown ceramic glaze and its application process |
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