CN110465252A - The system that a kind of pair of vapor for preparing potassium fluoride generation is recycled - Google Patents

The system that a kind of pair of vapor for preparing potassium fluoride generation is recycled Download PDF

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Publication number
CN110465252A
CN110465252A CN201910868503.3A CN201910868503A CN110465252A CN 110465252 A CN110465252 A CN 110465252A CN 201910868503 A CN201910868503 A CN 201910868503A CN 110465252 A CN110465252 A CN 110465252A
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CN
China
Prior art keywords
vapor
potassium fluoride
recycled
solenoid valve
pipe
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Application number
CN201910868503.3A
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Chinese (zh)
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CN110465252B (en
Inventor
胡明辉
胡作军
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Inner Mongolia Xinghan Fluorine Chemical Co Ltd
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Inner Mongolia Xinghan Fluorine Chemical Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28BSTEAM OR VAPOUR CONDENSERS
    • F28B5/00Condensers employing a combination of the methods covered by main groups F28B1/00 and F28B3/00; Other condensers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

The invention discloses a kind of systems recycled to the vapor for preparing potassium fluoride generation, including reacting can body, exhaust pipe on the reaction can body is connected with connecting tube, the connecting tube is equipped with solenoid valve four, pacifying shape in the connecting tube has aspiration pump, the system recycled to the vapor for preparing potassium fluoride generation passes through drainer, semiconductor chilling plate, spiral cold-finger and gas-liquid separating pipe be convenient for in vapor gas and liquid condense and separate, the temperature of condensed vapor is observed by thermometer, so that user judges whether the liquid in vapor liquefies completely, it is convenient for being filtered the liquid separated in vapor by filter, and it is conveniently replaceable filter screen, it is convenient for storing the liquid separated in vapor by holding vessel, being convenient for by multiple drainpipes of setting will Treated, and liquid supply distinct device is carried out using practicability is stronger.

Description

The system that a kind of pair of vapor for preparing potassium fluoride generation is recycled
Technical field
It is specially a kind of that the vapor for preparing potassium fluoride generation is returned the present invention relates to potassium fluoride production technical field The system of receipts.
Background technique
Potassium fluoride is a kind of salt, so being called the fluoride salt of potassium, white monoclinic crystal or crystalline powder, taste is salty, is easily inhaled It is wet, be dissolved in water, do not dissolve in ethyl alcohol, aqueous solution in alkalinity, can etching glass and porcelain, relative density 2.454,858 DEG C of fusing point, Medium poison, median lethal dose (rat, oral) 245mg/kg is irritant, in the production process of potassium fluoride, when neutralization reaction More waste heat can be generated, in the production technology of existing potassium fluoride, the water generated when there is no to production potassium fluoride steams Gas carries out secondary use, and potassium fluoride in the production process, is needed the obtained potassium fluoride of potassium fluoride aqueous solution dehydration, and potassium fluoride water Solution alkaline, and contain a small amount of solid impurity, so when being recycled to the vapor for preparing potassium fluoride generation, Need to condense the gas being discharged when preparing potassium fluoride, filter and pH value adjust.
Summary of the invention
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of water steaming to potassium fluoride generation is prepared The system that gas is recycled, convenient for the gas being discharged when preparing potassium fluoride is condensed, is filtered and pH value adjust, be convenient for To treated, aqueous solution is stored to utilize again, and use is more convenient, can effectively solve asking in background technique Topic.
To achieve the above object, the invention provides the following technical scheme: it is a kind of to prepare potassium fluoride generation vapor into The system of row recycling, including reaction can body, the exhaust pipe on the reaction can body is connected with connecting tube, in the connecting tube Pacifying shape equipped with solenoid valve four, in the connecting tube has aspiration pump, and the outlet side of the aspiration pump is connected with for cooling production fluorine The drainer of vapor generated when changing potassium is connected with gas-liquid separation pipe on the drainer, and the gas-liquid separation pipe is equipped with Thermometer, the gas-liquid separation pipe are equipped with the exhaust pipe being arranged upward, and the exhaust pipe is equipped with solenoid valve one, the gas-liquid The end of separating pipe is connected with filter, and the drain pipe one of the filter is connected with pH value adjustment tank, the pH value adjustment tank Drain pipe two be equipped with solenoid valve six, the drain pipe two of the pH value adjustment tank is connected with holding vessel.
As a preferred technical solution of the present invention, spiral cold-finger is equipped in the drainer, the drainer Bottom is equipped with semiconductor chilling plate.
As a preferred technical solution of the present invention, solenoid valve two, the filtering are connected on the gas-liquid separation pipe The drain pipe one of device is equipped with solenoid valve three.
As a preferred technical solution of the present invention, the filter includes the connection for being connected to gas-liquid separation tube end Lid, the inner thread of the connection cover are connected with filter housing, and the inner wall of the filter housing is equipped with link slot, sets on the link slot There is tubular filter screen, the bottom of the tubular filter screen is equipped with circular filter net.
As a preferred technical solution of the present invention, the axial plane inner wall of the pH value adjustment tank is connected with drive rod, institute The circumferential surface for stating drive rod is evenly distributed with stirring rod, and the end of the stirring rod is equipped with connecting plate, the upper surface of the connecting plate It is evenly distributed with stirrer gear, the end of the stirring rod is connected with the motor on pH value adjustment tank.
As a preferred technical solution of the present invention, the circumferential surface of the pH value adjustment tank is equipped with the addition being arranged upward Agent feed pipe, the additive feed pipe are equipped with solenoid valve seven.
As a preferred technical solution of the present invention, the pH value adjustment tank is equipped with pH value tester.
As a preferred technical solution of the present invention, the circumferential surface of the holding vessel is equipped with observation window, the observation window It is equipped with transparent panel.
It is equipped at the position of bottom as a preferred technical solution of the present invention, on the holding vessel circumferential surface multiple Drainpipe, the drainpipe are equipped with solenoid valve five.
Compared with prior art, the beneficial effects of the present invention are: passing through drainer, semiconductor chilling plate, spiral cold-finger With gas-liquid separating pipe be convenient for in vapor gas and liquid condense and separate, by thermometer convenient for observe it is condensed The temperature of vapor is convenient for by filter to vapor so that user judges whether the liquid in vapor liquefies completely In the liquid separated be filtered, and be conveniently replaceable filter screen, separated by pH value adjustment tank convenient for adjusting in vapor The pH value of liquid out is convenient for the liquid that will be separated in vapor by holding vessel in order to utilize liquids recovery Body is stored, by multiple drainpipes of setting convenient for by treated, liquid supply distinct device carries out using practicability It is relatively strong.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention;
Fig. 2 is drainer schematic diagram of internal structure of the present invention;
Fig. 3 is filter interior structural schematic diagram of the present invention;
Fig. 4 is pH value adjustment tank schematic diagram of internal structure of the present invention.
In figure: 1 reaction can body, 2 aspiration pumps, 3 connecting tubes, 4 drainers, 5 semiconductor chilling plates, 6 exhaust pipes, 7 electromagnetism Valve one, 8 thermometers, 9 gas-liquid separation pipes, 10 solenoid valves two, 11 filters, 12 solenoid valves three, 13 pH value adjustment tanks, 14 motors, 15 solenoid valves four, 16 drainpipes, 17 observation windows, 18 holding vessels, 19 connecting plates, 20 spiral cold-fingers, 21 solenoid valves five, 22 electromagnetism Valve six, 23 drive rods, 24 solenoid valves seven, 25 additive feed pipes, 26 connection covers, 27 tubular filter screens, 28 filter housings, 29 connections Slot, 30 stirrer gears, 31 stirring rods, 32PH value tester.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Fig. 1-4 is please referred to, the present invention provides a kind of technical solution: a kind of to return to the vapor for preparing potassium fluoride generation The system of receipts, including reaction can body 1 react the exhaust pipe on can body 1 and are connected with connecting tube 3, and connecting tube 3 is equipped with electromagnetism Valve 4 15, peace shape has an aspiration pump 2 in connecting tube 3, the outlet side of aspiration pump 2 be connected with for it is cooling produce potassium fluoride when generate The drainer 4 of vapor, gas-liquid separation pipe 9 is connected on drainer 4, and gas-liquid separation pipe 9 is equipped with thermometer 8, gas-liquid separation Pipe 9 is equipped with the exhaust pipe 6 being arranged upward, and exhaust pipe 6 is equipped with solenoid valve 1, and the end of gas-liquid separation pipe 9 was connected with Filter 11, the drain pipe one of filter 11 are connected with pH value adjustment tank 13, and the drain pipe two of pH value adjustment tank 13 is equipped with electromagnetism Valve 6 22, the drain pipe two of pH value adjustment tank 13 are connected with holding vessel 18, are equipped with spiral cold-finger 20, drainer 4 in drainer 4 Bottom be equipped with semiconductor chilling plate 5, be connected with solenoid valve 2 10 on gas-liquid separation pipe 9, set on the drain pipe one of filter 11 There is solenoid valve 3 12, filter 11 includes the connection cover 26 for being connected to 9 end of gas-liquid separation pipe, and the inner thread of connection cover 26 connects It is connected to filter housing 28, replaces filter screen convenient for opening connection cover 26, to keep its filter effect, the inner wall of filter housing 33 is set There is link slot 29, link slot 29 is equipped with tubular filter screen 27, and the bottom of tubular filter screen 27 is equipped with circular filter net, pH value The axial plane inner wall for adjusting tank 13 is connected with drive rod 23, and the circumferential surface of drive rod 23 is evenly distributed with stirring rod 31, stirring rod 31 End is equipped with connecting plate 19, and the upper surface of connecting plate 19 is evenly distributed with stirrer gear 30, and the end of stirring rod 31, which is connected with, to be located at Motor 14 on pH value adjustment tank 13, the circumferential surface that PH value adjusts tank 13 are equipped with the additive feed pipe 25 being arranged upward, addition Agent feed pipe 25 is equipped with solenoid valve 7 24, and pH value adjustment tank 13 is equipped with pH value tester 32, sets on the circumferential surface of holding vessel 18 There is an observation window 17, observation window 17 is equipped with transparent panel, and transparent panel can be with acrylic board or transparent glass, on 18 circumferential surface of holding vessel Multiple drainpipes 16 are equipped at the position of bottom, drainpipe 16 is equipped with solenoid valve 5 21.
Aspiration pump 2, semiconductor chilling plate 5, solenoid valve 1, solenoid valve 2 10, solenoid valve 3 12, motor 14, solenoid valve four 15, solenoid valve 5 21, solenoid valve six, solenoid valve 7 24 and pH value tester are connect with peripheral control unit, peripheral control unit control Aspiration pump 2 processed, semiconductor chilling plate 5, solenoid valve 1, solenoid valve 2 10, solenoid valve 3 12, motor 14, solenoid valve 4 15, electricity Magnet valve 5 21, solenoid valve six, solenoid valve 7 24 and pH value tester method be common method in the prior art, outside control Device, aspiration pump 2, semiconductor chilling plate 5, solenoid valve 1, solenoid valve 2 10, solenoid valve 3 12, motor 14, solenoid valve 4 15, electricity Magnet valve 5 21, solenoid valve six, solenoid valve 7 24 and pH value tester 32 are all made of model common on the market, peripheral control unit Model such as North China industry control PPC-3310, the Roots vaccum pump of the model of aspiration pump 2 such as Jiangsu Tian Feng vacuum pump Co., Ltd, The model of semiconductor chilling plate 5 is for example happy to think way semiconductor chilling plate, solenoid valve 1, solenoid valve 2 10, solenoid valve 3 12, electricity Magnet valve 4 15, solenoid valve 5 21, solenoid valve six, solenoid valve 7 24 the serial pilot diaphragm solenoid valve of model such as power allusion quotation 52, PH The PH controller MIK-PH160 of the model of value tester 32 such as U.S. control.
When in use: being extracted into drainer 4 by aspiration pump 2 by the vapor being discharged in can body 1 is reacted, by partly leading Body cooling piece 5 cools down to the inner cavity of drainer 4, flows through the vapor liquefaction in spiral cold-finger 26, passes through temperature Meter 8 can observe the temperature after vapor liquefaction, the gas in vapor is discharged by exhaust pipe 6, liquid runs down gas-liquid Separating pipe 9 enters in filter 11 by tubular filter screen 27 and circular filter net, is flowed into pH value adjustment tank 13, passes through Regulator is added to adjust the pH value of liquid in additive feed pipe 25, drives stirrer gear 30 and 31 turns of stirring rod by motor 14 Dynamic, the quick mixing of accelerating liquid and regulator observes the pH value of liquid by pH value tester 32, after adjusting Liquid, which enters in holding vessel 18, to be stored, and the amount of storage of liquid in holding vessel 18 can be observed by observation window 17, by more Liquid transporting is carried out secondary use to different equipment by a drainpipe 16.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of system recycled to the vapor for preparing potassium fluoride generation, including reaction can body (1), feature exists In: the exhaust pipe on reaction can body (1) is connected with connecting tube (3), and the connecting tube (3) is equipped with solenoid valve four (15), pacifying shape on the connecting tube (3) has aspiration pump (2), and the outlet side of the aspiration pump (2) is connected with for cooling production fluorine The drainer (4) of vapor generated when changing potassium is connected with gas-liquid separation pipe (9), the gas-liquid separation on the drainer (4) It manages (9) and is equipped with thermometer (8), the gas-liquid separation pipe (9) is equipped with the exhaust pipe (6) being arranged upward, the exhaust pipe (6) It is equipped with solenoid valve one (7), the end of the gas-liquid separation pipe (9) is connected with filter (11), the row of the filter (11) Liquid pipe one is connected with pH value adjustment tank (13), and the drain pipe two of the pH value adjustment tank (13) is equipped with solenoid valve six (22), institute The drain pipe two for stating pH value adjustment tank (13) is connected with holding vessel (18).
2. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute It states in drainer (4) and is equipped with spiral cold-finger (20), the bottom of the drainer (4) is equipped with semiconductor chilling plate (5).
3. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute It states and is connected with solenoid valve two (10) on gas-liquid separation pipe (9), the drain pipe one of the filter (11) is equipped with solenoid valve three (12)。
4. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute Stating filter (11) includes the connection cover (26) for being connected to gas-liquid separation pipe (9) end, the inner thread of the connection cover (26) It is connected with filter housing (28), the inner wall of the filter housing (33) is equipped with link slot (29), and the link slot (29) is equipped with tubular The bottom of filter screen (27), the tubular filter screen (27) is equipped with circular filter net.
5. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute The axial plane inner wall for stating pH value adjustment tank (13) is connected with drive rod (23), and the circumferential surface of the drive rod (23) is evenly distributed with stirring The end of bar (31), the stirring rod (31) is equipped with connecting plate (19), and the upper surface of the connecting plate (19), which is evenly distributed with, to be stirred Teeth (30), the end of the stirring rod (31) are connected with the motor (14) on pH value adjustment tank (13).
6. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute The circumferential surface for stating pH value adjustment tank (13) is equipped with the additive feed pipe (25) that is arranged upward, on the additive feed pipe (25) Equipped with solenoid valve seven (24).
7. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute PH value adjustment tank (13) are stated equipped with pH value tester (32).
8. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute The circumferential surface for stating holding vessel (18) is equipped with observation window (17), and the observation window (17) is equipped with transparent panel.
9. the system according to claim 1 recycled to the vapor for preparing potassium fluoride generation, it is characterised in that: institute It states and is equipped with multiple drainpipes (16) at the position of bottom on holding vessel (18) circumferential surface, the drainpipe (16) is equipped with electromagnetism Valve five (21).
CN201910868503.3A 2019-09-12 2019-09-12 System for retrieve vapor that potassium fluoride produced is prepared Active CN110465252B (en)

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CN201910868503.3A CN110465252B (en) 2019-09-12 2019-09-12 System for retrieve vapor that potassium fluoride produced is prepared

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CN201910868503.3A CN110465252B (en) 2019-09-12 2019-09-12 System for retrieve vapor that potassium fluoride produced is prepared

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CN110465252B CN110465252B (en) 2024-04-09

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005191587A (en) * 1996-01-12 2005-07-14 Tadahiro Omi Cleaning method
CN101376509A (en) * 2007-08-31 2009-03-04 多氟多化工股份有限公司 Method for preparing potassium fluoride
CN204429265U (en) * 2015-02-03 2015-07-01 台夕市 The exothermic reaction device of condensed water can be reclaimed
CN205672597U (en) * 2016-06-21 2016-11-09 山东豪迈机械制造有限公司 A kind of heat exchange condensate disposal systems
KR101815586B1 (en) * 2016-08-08 2018-01-05 황경자 The condensate tanks of steam emissions controls
CN207413398U (en) * 2017-10-28 2018-05-29 宿迁市万和泰化工有限公司 A kind of chemical industry effectively hydrolyzing reaction kettle
CN108351098A (en) * 2015-11-05 2018-07-31 株式会社东芝 Vapor recovery method in vapor recovery system, thermal power generation system and power generation exhaust gas in power generation exhaust gas
CN211864954U (en) * 2019-09-12 2020-11-06 内蒙古星汉氟都化工有限公司 System for recovering vapor generated in potassium fluoride preparation

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005191587A (en) * 1996-01-12 2005-07-14 Tadahiro Omi Cleaning method
CN101376509A (en) * 2007-08-31 2009-03-04 多氟多化工股份有限公司 Method for preparing potassium fluoride
CN204429265U (en) * 2015-02-03 2015-07-01 台夕市 The exothermic reaction device of condensed water can be reclaimed
CN108351098A (en) * 2015-11-05 2018-07-31 株式会社东芝 Vapor recovery method in vapor recovery system, thermal power generation system and power generation exhaust gas in power generation exhaust gas
CN205672597U (en) * 2016-06-21 2016-11-09 山东豪迈机械制造有限公司 A kind of heat exchange condensate disposal systems
KR101815586B1 (en) * 2016-08-08 2018-01-05 황경자 The condensate tanks of steam emissions controls
CN207413398U (en) * 2017-10-28 2018-05-29 宿迁市万和泰化工有限公司 A kind of chemical industry effectively hydrolyzing reaction kettle
CN211864954U (en) * 2019-09-12 2020-11-06 内蒙古星汉氟都化工有限公司 System for recovering vapor generated in potassium fluoride preparation

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Address after: 750336 Bayin Aobao Industrial Park, Lashan Economic Development Zone, Alxa League, Inner Mongolia Autonomous Region

Applicant after: Inner Mongolia Xinghan New Materials Co.,Ltd.

Address before: 750336 Bayin OBO Industrial Park, Alxa Economic Development Zone, Alxa League, Inner Mongolia Autonomous Region

Applicant before: Inner Mongolia Xinghan Fluorine Chemical Co.,Ltd.

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