CN110442178A - Experiment mentions lithium powersupply system with salt lake - Google Patents

Experiment mentions lithium powersupply system with salt lake Download PDF

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Publication number
CN110442178A
CN110442178A CN201910778044.XA CN201910778044A CN110442178A CN 110442178 A CN110442178 A CN 110442178A CN 201910778044 A CN201910778044 A CN 201910778044A CN 110442178 A CN110442178 A CN 110442178A
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China
Prior art keywords
voltage
controller
current
salt lake
output
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CN201910778044.XA
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CN110442178B (en
Inventor
李卫荣
闫东豪
王瑞金
冯韶辉
韩强
卢春雷
张治奎
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Hebei Weixin Electronic Technology Co Ltd
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Hebei Weixin Electronic Technology Co Ltd
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    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05FSYSTEMS FOR REGULATING ELECTRIC OR MAGNETIC VARIABLES
    • G05F1/00Automatic systems in which deviations of an electric quantity from one or more predetermined values are detected at the output of the system and fed back to a device within the system to restore the detected quantity to its predetermined value or values, i.e. retroactive systems
    • G05F1/10Regulating voltage or current
    • G05F1/46Regulating voltage or current wherein the variable actually regulated by the final control device is dc
    • G05F1/56Regulating voltage or current wherein the variable actually regulated by the final control device is dc using semiconductor devices in series with the load as final control devices
    • G05F1/561Voltage to current converters
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/0063Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries with circuits adapted for supplying loads from the battery

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Radar, Positioning & Navigation (AREA)
  • Automation & Control Theory (AREA)
  • Power Engineering (AREA)
  • Charge And Discharge Circuits For Batteries Or The Like (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Mentioning lithium powersupply system with salt lake this application involves a kind of experiment includes controller, Switching Power Supply, electronic commutating device, electrolytic cell and acquisition module;Controller is connect with electronic commutating device and acquisition module respectively, according to the acquisition parameter control electronic commutating device switch and/or commutation action of acquisition module output;Switching Power Supply is connect with electronic commutating device, changes Switching Power Supply out-put supply polarity by electronic commutating device;Acquisition module from electrolytic cell for obtaining acquisition parameter.The application is not required to additionally add mechanical switch structure to realize the adjustment to electrode voltage, therefore the working efficiency and reliability of system can be improved, and, it is connect by controller with sample circuit, it realizes the reversed constant current constant voltage output of power-supply system, proposes lithium experiment for salt lake and more stable power-supply system is provided.

Description

Experiment mentions lithium powersupply system with salt lake
Technical field
This application involves power system technologies field, especially a kind of experiment mentions lithium powersupply system with salt lake.
Background technique
Lithium metal be it is current it is found that most light metal, it is widely used in the fields such as the energy, chemical industry, metallurgy. With becoming increasingly conspicuous for energy problem, lithium ion battery is able to fast development, lithium and its compound in occupation of irreplaceable ground Position.In nature, lithium mainly exists in the form of ore and two kinds of brine, and most of lithium resource is present in brine especially salt lake halogen In water, reserves account for 80% or more of whole lithium resource reserves.With the growth of the market demand, mineral lithium resource seems for not It should ask, and cost of winning is high, people start the lithium resource developed in salt lake bittern.Salt lake needs power supply system during mentioning lithium System supports, and proposes power-supply system in lithium for the salt lake of electrochemistry deintercalation method and needs to carry out positive process, commutation and reverse procedure Three processes:
Positive process: it is added in supporting electrolyte side (lithium deviates from rich lithium liquid side) in anode, cathode is added in brine side (lithium ion It is embedded in side), under the action of an external electric field, start positive constant-current charge process, in side of the positive electrode, lithium ion starts from iron phosphate lithium positive pole (one or more of lithium iron phosphate positive material LiFePO4, LixMeyFePO4, LiFexMeyPO4's is mixed for adsorbent material Close object.Me is the mixing of one or more of Mg, Al, Ti, Ni, Co, Mn, Mo, Nb.0 < x <, 1,0 < y < 1) in abjection Into rich lithium liquid;In negative side, lithium ion is embedded into monophosphate monophosphate iron ion sieve adsorbent material (ferric phosphate ion sieve from brine For the mixture of one or more of FePO4, MexFeyPO4;Me be one of Mg, Al, Ti, Ni, Co, Mn, Mo, Nb or Several mixing;0 < x <, 1,0 < y < 1) in, by an electrolytic process, load can not meet constant current conditions, change into constant pressure Charging, until electric current is less than setting value, positive electrolytic process terminates, i.e., for anode-side, lithium abjection process terminates;For yin Pole, lithium telescopiny terminate.Entire forward direction process is first constant current constant pressure again.
Commutation: the polarity reversing for the voltage for being added in electrode, it may be assumed that original plus forward voltage electrode becomes this moment plus negative sense Voltage;Original plus negative voltage electrode becomes this moment plus forward voltage.Trade-off is realized in external solution cooperation simultaneously.
Reverse procedure (for relatively positive process): being added in supporting electrolyte side in anode (being cathode before commutation), (lithium is de- Rich lithium liquid side out), cathode (being anode before commutation) is added in brine side (lithium ion insertion side), under the action of an external electric field, starts just To constant-current charge process, in side of the positive electrode, lithium ion starts to deviate from from LiFePO4 adsorbent material into rich lithium liquid, in cathode Side, lithium ion in brine from being embedded into ferrous phosphate adsorbent material, and by an electrolytic process, load can not meet constant current item Part changes into constant-voltage charge, and until electric current is less than setting value, negative sense electrolytic process terminates, or says that, for anode-side, lithium deviates from process Terminate;For cathode, lithium telescopiny terminates, and therefore, entire reverse procedure is also first constant current constant voltage process again.
Existing power-supply device can generally meet positive first constant current constant-voltage charge process again, can only be into for reverse procedure Row constant-current discharge, constant-resistance discharge, invariable power electric discharge, in other words can only reversed constant-current charge, constant-resistance charging, invariable power charging.Cause This cannot accomplish the process of first constant current constant pressure again in reverse procedure.
In the related technology, it is realized using outside addition mechanical switch structure to electrode electricity when carrying out salt lake and proposing lithium experiment The adjustment of pressure, but the technical solution of mechanical switch structure is added in the application that electrochemistry deintercalation method salt lake proposes lithium technology in outside, It will increase contact resistance and influence the working efficiency of system, and the volume of whole system can be obviously increased, it is mechanical due to increasing Switch also increases fault point to reduce the reliability of system, also, is unfavorable for automation control.
Summary of the invention
It is mechanical using external addition when carrying out salt lake and proposing lithium experiment to overcome at least to a certain extent in the related technology Construction of switch realizes the adjustment to electrode voltage, but the technical solution of external addition mechanical switch structure is in electrochemistry deintercalation method Salt lake mentions in the application of lithium technology, will increase contact resistance and influences the working efficiency of system, and can obviously increase entire system The volume of system also increases fault point due to increasing mechanical switch to reduce the reliability of system, also, is unfavorable for automating The problem of control, the application provide a kind of experiment and mention lithium powersupply system with salt lake, comprising:
Controller, Switching Power Supply, electronic commutating device, electrolytic cell and acquisition module;
The controller is connect with the electronic commutating device and acquisition module respectively, according to acquisition module output Acquisition parameter controls the electronic commutating device switch and/or commutation action;
The Switching Power Supply is connect with the electronic commutating device, changes the switch electricity by the electronic commutating device Source out-put supply polarity;
The acquisition module is for obtaining acquisition parameter from the electrolytic cell.
Further, the electronic commutating device includes: the switch element of two single-pole double throws.
Further, the electronic commutating device includes: the electronic switching element of four composition bridge-types connection.
Further, the electronic commutating device further includes control port, and the control port is connect with the controller.
Further, the system also includes power supply, the power supply provides input electricity for the Switching Power Supply Pressure.
Further, the system also includes rectification filtering module, the input terminal of the rectification filtering module and the confessions Power supply connection, the output end of the rectification filtering module are connect with the Switching Power Supply.
Further, the system also includes: output filter module, the input terminal of the output filter module are opened with described Powered-down source connection, the output end of the output filter module are connect with the acquisition module.
Further, the output filter module includes two groups of electrolytic capacitors, and the cathode of two groups of electrolytic capacitors is connected.
Further, the controller includes voltage controller and current controller, and the acquisition module includes that voltage is adopted Sample circuit and current sampling circuit;The voltage controller is connect with the voltage sampling circuit;The current controller and institute State current sampling circuit connection;
Predeterminated voltage reference value in the voltage controller, predetermined current reference value in the current controller, when described When voltage sampling circuit collects voltage and reaches the voltage reference value, voltage controller adjusts the electric current ginseng in current controller Value is examined, the current reference value by controlling current controller changes output electric current to control constant voltage output;
When the current sampling circuit collects electric current and reaches the current reference value, current controller adjusts voltage control Voltage reference value in device, the voltage reference value by controlling voltage controller change output voltage to control constant current output.
Further, the system also includes display interactive module, the display interactive module is connect with the controller, The display interactive module is for being locally displayed each course of work and statistical data that salt lake mentions lithium, and/or each work of setting The operating condition and parameter of process.
The technical solution that embodiments herein provides can include the following benefits:
The application is connect with electronic commutating device and acquisition module respectively by controller, according to adopting for acquisition module output Collect state modulator electronic commutating device switch and/or commutation action;It is not required to additionally add mechanical switch structure to realize to electrode The adjustment of voltage, therefore the working efficiency and reliability of system can be improved, also, not will increase system bulk, facilitate progress Experiment.
It should be understood that above general description and following detailed description be only it is exemplary and explanatory, not The application can be limited.
Detailed description of the invention
The drawings herein are incorporated into the specification and forms part of this specification, and shows the implementation for meeting the application Example, and together with specification it is used to explain the principle of the application.
Fig. 1 is the module map that a kind of experiment that the application one embodiment provides mentions lithium powersupply system with salt lake.
Fig. 2 is the module map that a kind of experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
Fig. 3 is the partial circuit that a kind of experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake Figure.
Fig. 4 is the module map that a kind of experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
Fig. 5 is the partial circuit that a kind of experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake Figure.
Fig. 6 is the partial circuit that another experiment that the application one embodiment provides mentions lithium powersupply system with salt lake Figure.
Specific embodiment
The present invention is described in detail below with reference to the accompanying drawings and embodiments.
Fig. 1 is the module map that the experiment that the application one embodiment provides mentions lithium powersupply system with salt lake.
As shown in Figure 1, experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
Controller 1, Switching Power Supply 2, electronic commutating device 3, electrolytic cell 4 and acquisition module 5;
Controller 1 is connect with electronic commutating device 3 and acquisition module 5 respectively, the acquisition parameter exported according to acquisition module 5 Control the switch of electronic commutating device 3 and/or commutation action;
Switching Power Supply 2 is connect with electronic commutating device 3, changes 2 out-put supply of Switching Power Supply by electronic commutating device 3 Polarity;
Acquisition module 5 is for obtaining acquisition parameter from electrolytic cell 4.
Salt lake mentions in lithium experiment and is often used electrochemistry deintercalation method salt lake and proposes lithium technology, the experiment based on electrochemistry deintercalation method Lithium powersupply system is mentioned with salt lake need to meet and carry out the functional requirement of automatic reverse to the polarity of voltage of electrolytic tank electrode, with reality Now automatic positive constant current, constant-voltage charge, reversed constant current, constant-voltage charge, positive constant current, constant-voltage charge, reversed constant current, constant pressure are filled Electricity ... week and operation repeatedly.
Switching Power Supply 2 is connected to electrolytic cell 4 in the power-supply system, and electronic commutating device 3 connect with Switching Power Supply 2 and can cut The polarity of voltage being applied on electrolytic cell 4 is changed, acquisition module 5 is on the line between electronic commutating device 3 and electrolytic cell 4, acquisition Voltage, the current parameters of electrolytic cell 4, acquisition module 5 are connected by control line with controller 1, and controller 1 is read by control line 5 acquisition parameter data of acquisition module.Acquisition parameter is, for example, voltage parameter and current parameters, and controller 1 is by reading acquisition mould The voltage on electrolytic cell 4 that block 5 acquires, current data, reach to control after preset reference value and open in voltage, the electric current of electrolytic cell 4 Powered-down source 2 exports, and realizes that electrochemistry deintercalation method salt lake mentions first positive constant-current charge, then the positive mistake of constant-voltage charge in lithium application Journey, after positive process, control electronic commutating device 3 switches Switching Power Supply 2 and switches the voltage pole being applied on electrolytic cell 4 Property, subsequently into the reverse procedure of reversed constant-current charge, then constant-voltage charge, electronic commutating device 3 is controlled after reverse procedure Switching Switching Power Supply 2 is applied to the polarity of voltage on electrolytic cell 4 again, then starts positive process, so week and operation repeatedly, To guarantee that the salt lake of electrochemistry deintercalation method proposes lithium system trouble-free operation.
In the present embodiment, it is connect respectively with electronic commutating device and acquisition module by controller, it is defeated according to acquisition module Acquisition parameter control electronic commutating device switch and commutation action out;It is not required to additionally add mechanical switch structure to realize to electricity The adjustment of pole tension, therefore the working efficiency and reliability of system can be improved, also, connect by controller and sample circuit It connects, realizes the reversed constant current constant voltage output of power-supply system, propose lithium experiment for salt lake and more stable power-supply system is provided.
Fig. 2 is the module map that the experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
As shown in Fig. 2, experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
As optional a kind of implementation of the invention, the system also includes power supply 6, power supply 6 is switch Power supply 2 provides input voltage.
As a kind of implementation of the invention optional, the system also includes: rectification filtering module 7, rectifying and wave-filtering mould The input terminal of block 7 is connect with power supply 6, and the output end of rectification filtering module 7 is connect with Switching Power Supply 2.
By carrying out rectifying and wave-filtering to power supply 6, to guarantee the stabilized input voltage of Switching Power Supply 2.
As a kind of implementation of the invention optional, the system also includes: output filter module 7, output filtering mould The input terminal of block 7 is connect with Switching Power Supply 2, and the output end of output filter module 8 is connect with acquisition module 5.
As a kind of implementation of the invention optional, output filter module 8 includes two groups of electrolytic capacitors (C1, C2), and two The cathode of group electrolytic capacitor is connected.Output filter module 8 uses common cathode concatenated electrolytic capacitor C1, C2 to adapt to output stage The change of property.
It is not known it should be noted that output filter module 8 can also adapt to output polarity using non-polar condenser Characteristic.
In the present embodiment, rectifying and wave-filtering is carried out to power supply by rectification filtering module, to guarantee the defeated of Switching Power Supply Enter voltage stabilization;The output of Switching Power Supply is filtered by output filter module, to guarantee the input voltage of acquisition module Stablize.
Fig. 3 is the partial circuit diagram that the experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
As shown in figure 3, experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
Electronic commutating device 3 uses electronic switching device, can switch the polarity of output voltage, according to condition to meet salt lake Propose the demand in lithium technology application to voltage polarity switching on electrolytic cell is applied to.The switching device that electronic commutating device 3 uses It can be the electricity that single channel or multi-channel parallel metal-oxide-semiconductor, solid-state relay, mechanical relay or triode etc. have switching function Sub- device.The control signal adjustment Switching Power Supply 2 that the device can be exported according to controller 1 is applied to the voltage on electrolytic cell Polarity.
As optional a kind of implementation of the invention, electronic commutating device 3 includes: the switch member of two single-pole double throws Part.
1,2 Wiring ports of electronic commutating device 3 pass through the output end of cable connection switch power supply 41,3,6 Wiring ports It connects together, an electrode of electrolytic cell 4 is connected by cable, 4,5 Wiring ports, which are connected together, connects electricity by cable Solve another electrode of slot 4.Controller 1 switches the switch state of electronic commutating device 3 by control line, is applied to realize The conversion of polarity of voltage on electrolytic cell 4.When the switch that controller 1 controls electronic commutating device 3 is in 1 and 3 conductings, 2 and 5 are led When logical, electrolytic cell both ends apply forward voltage;When the switch of electronic commutating device 3 is connected in 1 and 4 conductings, 2 and 6, electrolysis 4 both ends of slot apply backward voltage.
In the present embodiment, Switching Power Supply does not have the adjustment polar function of output voltage, the output of Switching Power Supply and electronics Reversing arrangement is connected, and electronic commutating device uses the closing element structure of two single-pole double throws, the control exported according to controller Signal shift switch state adjusts the polarity of voltage being applied on electrolytic cell.Controller is opened by the way that electronic commutating device is controllable Powered-down source opens, stops, and switches constant current or constant voltage output state.
Fig. 4 is the partial circuit diagram that the experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
As shown in figure 4, experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
As optional a kind of implementation of the invention, electronic commutating device 3 includes: the electronic cutting of four composition bridge-types connection Close element.
1,2 Wiring ports of electronic commutating device 3 are connected by cable with the output of Switching Power Supply 41, and 3,4 Wiring ports are logical Cable is crossed to be connected with 4 pole plate of electrolytic cell.It is controlled by controller 1, switch S1, S4 closure conducting, electrolytic cell 4 when S2, S3 are disconnected Both ends apply forward voltage;Switch S1, S4 are disconnected, and 4 both ends of electrolytic cell apply backward voltage when S2, S3 closure are connected.
In the present embodiment, the electronic switching element that electronic commutating device is connected using four composition bridge-types is defeated according to controller Control signal shift switch state out adjusts the polarity of voltage being applied on electrolytic cell.Controller passes through electronic commutating device Controllable switch power supply opens, stops, and switches constant current or constant voltage output state.
Fig. 5 is the module map that the experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
As shown in figure 5, a kind of experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
As optional a kind of implementation of the invention, controller 1 includes voltage controller 11 and current controller 12, is adopted Collecting module 5 includes voltage sampling circuit 51 and current sampling circuit 52;Voltage controller 11 is connect with voltage sampling circuit 51; Current controller 12 is connect with current sampling circuit 52;
Predeterminated voltage reference value in voltage controller 11, predetermined current reference value in current controller 71, works as voltage sample When circuit 51 collects voltage and reaches the voltage reference value, voltage controller 11 adjusts the current reference in current controller 12 Value, the current reference value by controlling current controller 12 change output electric current to control constant voltage output;
When current sampling circuit 52 collects electric current and reaches current reference value, current controller 12 adjusts voltage controller 11 Interior voltage reference value, the voltage reference value by controlling voltage controller 11 change output voltage to control constant current output.
Current sampling circuit 52 is coil-induced detection circuit, Hall current detection circuit and direct current current divider detection circuit One of, it should be noted that current sampling circuit 52 can be set in any position that can detect operating current, can be with It is set on the total outlet line of electrolytic cell 4, also can be set on the route of each branch of electrolytic cell 4.
By carrying out electric current output, current sample after output filtering after the output to electronic commutating device 3 of current controller 12 The electric current of the acquisition output of circuit 52 carries out current feedback to current controller 12, and the output of voltage controller 11 to electronic commutation fills By carrying out voltage output after output filtering after setting 3, the voltage of the acquisition output of voltage sampling circuit 51 carries out Voltage Feedback extremely Voltage controller 11 forms closed-loop control.
In the present embodiment, using voltage controller 11 and current controller 12 cyclic system in parallel, Switching Power Supply 2 is always Forward direction output, the polarity of voltage for being applied to 3 both ends of electrolytic cell is adjusted, by electronic commutating device 3 to adapt to 3 liang of electrolyser The case where section polarity of voltage adjustment, the sample circuit of feedback loop, which is used, to be cut by electronic switching element according to output voltage polarity The polar scheme of sampled signal input sampling circuit is changed, so that sampled signal is always with positive polarity input sampling circuit, from And the polarity of voltage no matter realization applies on electrolytic cell is forward direction or reversed, which can reach in output voltage Pwm modulator is adjusted by voltage controller when setting reference value Vref and realizes pressure stabilizing output, reaches setting ginseng in output electric current Current stabilization output is realized by current controller 11 when examining value Iref.
Voltage and current setting reference value is adjustable in voltage controller 11 and current controller 12, when output electric current reaches Current loop works when setting reference value, realizes constant current output, and when output voltage reaches setting reference value, voltage loop is risen Constant voltage output is realized in effect.Due to Switching Power Supply always positive output, electrolytic cell is applied to by electronic commutating device adjustment The polarity of voltage at both ends, to adapt to the case where two sections of polarity of voltages of electrolytic cell adjust, current loop makes by adjusting electric current output The polarity of voltage that no matter apply on electrolytic cell be it is positive or reversed, electric current outbound course is constant.When output voltage reaches When setting voltage reference value Vref, constant voltage output is realized by voltage controller 11, reaches setting electric current reference in output electric current When value Iref, constant current output is realized by current controller 12, thus can be according to setting when realizing forward and reverse output Reference value carries out constant pressure or constant current output.
In the present embodiment, using voltage, the loop control circuit of double current loop modulation, applied by electronic commutating device adjustment It is added in the polarity of voltage at electrolytic cell both ends, the power-supply system is realized can in positive process and reverse procedure and is joined according to setting Number realizes reliable and stable constant voltage output, constant current output.
Fig. 6 is the module map that the experiment that another embodiment of the application provides mentions lithium powersupply system with salt lake.
As shown in fig. 6, a kind of experiment provided in this embodiment mentions lithium powersupply system with salt lake, comprising:
As optional a kind of implementation of the invention, the system also includes display interactive modules 9, show interactive module 9 connect with controller 1, display interactive module 9 for being locally displayed each course of work and statistical data that salt lake mentions lithium, and/ Or the operating condition and parameter of each course of work of setting.
Show that interactive module 9 includes touch screen, touch screen is 7 cun of big touch screens, and display effect is clearly comprehensive, and the interface UI is set Meter is friendly, can be clearly in the operating condition and parameter for being locally displayed and setting each course of work.
Controller 1 further includes communication interface, and the long-range control of the realization that can be connected with background system switches constant pressure, constant current, perseverance Power mode output, the convenient other parts with application cooperate, and realize that electrochemistry salt lake mentions the automation control of lithium process.Control Device 1 processed judges the voltage and current state of electrolytic cell 4, according to each process of setting work item by reading 5 data of acquisition module Part controls the opening of power supply by Communication Control electronic commutating device 3, stops, the adjustment of voltage and current setting and output polarity Power-supply system first positive constant-current charge is realized in adjustment, is reached after condition constant-voltage charge again, is shut down after reaching condition, switching switch Power supply is applied to the polarity of voltage on electrolytic cell 4, starts reversed constant-current charge again after the completion of the exchanged solutions, reaches after condition again Constant-voltage charge is shut down after reaching condition, and reverse procedure terminates, then Switching power is applied to the polarity of voltage on electrolytic cell, then opens Begin positive process, so week and operation repeatedly.
The connection of controller 1 and electronic commutating device 3 can select RS485 communication connection, to guarantee controller to electronics The manipulation of reversing arrangement 3 is accurate and reliable.
In the present embodiment, controller with display interactive module connect, may be implemented display effect it is good, show clear data, The displaying scheme of interactive operation friendly interface can provide preferable manipulation experience, realize complicated technology control.
It is understood that same or similar part can mutually refer in the various embodiments described above, in some embodiments Unspecified content may refer to the same or similar content in other embodiments.
It should be noted that term " first ", " second " etc. are used for description purposes only in the description of the present application, without It can be interpreted as indication or suggestion relative importance.In addition, in the description of the present application, unless otherwise indicated, the meaning of " multiple " Refer at least two.
Any process described otherwise above or method description are construed as in flow chart or herein, and expression includes It is one or more for realizing specific logical function or process the step of executable instruction code module, segment or portion Point, and the range of the preferred embodiment of the application includes other realization, wherein can not press shown or discussed suitable Sequence, including according to related function by it is basic simultaneously in the way of or in the opposite order, Lai Zhihang function, this should be by the application Embodiment person of ordinary skill in the field understood.
It should be appreciated that each section of the application can be realized with hardware, software, firmware or their combination.Above-mentioned In embodiment, software that multiple steps or method can be executed in memory and by suitable instruction execution system with storage Or firmware is realized.It, and in another embodiment, can be under well known in the art for example, if realized with hardware Any one of column technology or their combination are realized: having a logic gates for realizing logic function to data-signal Discrete logic, with suitable combinational logic gate circuit specific integrated circuit, programmable gate array (PGA), scene Programmable gate array (FPGA) etc..
Those skilled in the art are understood that realize all or part of step that above-described embodiment method carries It suddenly is that relevant hardware can be instructed to complete by program, the program can store in a kind of computer-readable storage medium In matter, which when being executed, includes the steps that one or a combination set of embodiment of the method.
It, can also be in addition, can integrate in a processing module in each functional unit in each embodiment of the application It is that each unit physically exists alone, can also be integrated in two or more units in a module.Above-mentioned integrated mould Block both can take the form of hardware realization, can also be realized in the form of software function module.The integrated module is such as Fruit is realized and when sold or used as an independent product in the form of software function module, also can store in a computer In read/write memory medium.
Storage medium mentioned above can be read-only memory, disk or CD etc..
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is contained at least one embodiment or example of the application.In the present specification, schematic expression of the above terms are not Centainly refer to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be any One or more embodiment or examples in can be combined in any suitable manner.
Although embodiments herein has been shown and described above, it is to be understood that above-described embodiment is example Property, it should not be understood as the limitation to the application, those skilled in the art within the scope of application can be to above-mentioned Embodiment is changed, modifies, replacement and variant.
It should be noted that the present invention is not limited to above-mentioned preferred forms, those skilled in the art are of the invention Other various forms of products can be all obtained under enlightenment, however, make any variation in its shape or structure, it is all have with The identical or similar technical solution of the application, is within the scope of the present invention.

Claims (10)

1. a kind of experiment mentions lithium powersupply system with salt lake characterized by comprising
Controller, Switching Power Supply, electronic commutating device, electrolytic cell and acquisition module;
The controller is connect with the electronic commutating device and acquisition module respectively, the acquisition exported according to the acquisition module The switch of electronic commutating device described in state modulator and/or commutation action;
The Switching Power Supply is connect with the electronic commutating device, and it is defeated to change the Switching Power Supply by the electronic commutating device Electric power polarity out;
The acquisition module is for obtaining acquisition parameter from the electrolytic cell.
2. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that the electronic commutation dress Set include: two single-pole double throws switch element.
3. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that the electronic commutation dress Set include: four composition bridge-types connection electronic switching element.
4. mentioning lithium powersupply system with salt lake according to the described in any item experiments of claim 4 or 5, which is characterized in that described Electronic commutating device further includes control port, and the control port is connect with the controller.
5. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that further include power supply electricity Source, the power supply provide input voltage for the Switching Power Supply.
6. experiment according to claim 5 mentions lithium powersupply system with salt lake, which is characterized in that the acquisition module packet Sample circuit and signal processing circuit are included, the sample circuit is connect with signal processing circuit, and the signal processing circuit is to institute The output result for stating sample circuit is handled, so that sample circuit output result is met the requirements.
7. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that further include: output filter Wave module, the input terminal of the output filter module are connect with the Switching Power Supply, the output end of the output filter module with The acquisition module connection.
8. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that the output filters mould Block includes two groups of electrolytic capacitors, and the cathode of two groups of electrolytic capacitors is connected.
9. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that the controller includes Voltage controller and current controller, the acquisition module include voltage sampling circuit and current sampling circuit;The voltage control Device processed is connect with the voltage sampling circuit;The current controller is connect with the current sampling circuit;
Predeterminated voltage reference value in the voltage controller, predetermined current reference value in the current controller, when the voltage When sample circuit collects voltage and reaches the voltage reference value, voltage controller adjusts the current reference in current controller Value, the current reference value by controlling current controller change output electric current to control constant voltage output;
When the current sampling circuit collects electric current and reaches the current reference value, current controller is adjusted in voltage controller Voltage reference value, by control voltage controller voltage reference value change output voltage to control constant current output.
10. experiment according to claim 1 mentions lithium powersupply system with salt lake, which is characterized in that further include that display is handed over Mutual module, the display interactive module are connect with the controller, and the display interactive module mentions lithium for salt lake to be locally displayed Each course of work and statistical data, and/or the operating condition and parameter of each course of work of setting.
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