CN110438837A - A kind of preparation method that can quickly take off target and protect black aluminized paper - Google Patents
A kind of preparation method that can quickly take off target and protect black aluminized paper Download PDFInfo
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- CN110438837A CN110438837A CN201910595028.7A CN201910595028A CN110438837A CN 110438837 A CN110438837 A CN 110438837A CN 201910595028 A CN201910595028 A CN 201910595028A CN 110438837 A CN110438837 A CN 110438837A
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- acrylic emulsion
- aluminized paper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/02—Metal coatings
- D21H19/08—Metal coatings applied as vapour, e.g. in vacuum
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/84—Paper comprising more than one coating on both sides of the substrate
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
Abstract
Present disclose provides one kind can quickly take off the preparation method that target protects black aluminized paper, the method is the innovation of used primary coat, face painting and back-coating, the constituent of the bottom-coating are as follows: acrylic emulsion A, acrylic emulsion B, alcohol, deionized water, wetting agent, levelling agent and defoaming agent, the constituent of painting coating are as follows: waterborne polyurethane resin, acrylic emulsion B, alcohol, deionized water, wetting agent, levelling agent and defoaming agent, the constituent of back-coating are as follows: alkali soluble resins, polyvinyl alcohol, modification infusorial earth and deionized water.The not film-formable Alkali-resistant resin of the acrylic emulsion B of the method middle addition on coating, so that the prepared target that can quickly take off protects black aluminized paper close to osmotic effect same as common aluminized paper, and intermolecular active force can be formed by H key with carboxyl, amino, the hydroxyl in coating components, a three-dimensional netted skeleton is provided, to improve the resident effect of ink.
Description
Technical field
The disclosure belongs to functional paper technology field, and in particular to one kind can quickly take off the preparation that target protects black aluminized paper
Method.
Background technique
Aluminized paper is that a kind of surface in common magma paper (substrate) carries out process, the formation such as vacuum is aluminium-plated and answers
Combined paper material.It is widely used in a variety of industries such as label printing, food packaging, the application especially in beer label, by beer
Beer producers are usually and beer bottle are placed in NaOH aqueous solution to carry out de- mark processing when tag processes, common aluminized paper
Primary coat, face painting alkali resistance are poor, therefore in buck when wash bottle, the ink layer easily caused on label falls off, not only dirty in this way
The ink for having contaminated lye, and having fallen off can flow into washer bottle, cause secondary pollution to bottle.
101864692 A of patent CN " a kind of preparation method for aluminized paper of supporting ink well " be using dual-component coating production and
At the service life of coating is limited, vulnerable." there is one kind 201732516 U of patent CN ink to be resident free of contamination papery
Beer label " without reference to the specific wash bottle time, the alkali resistance that primary coat, face apply is good, and the seepage velocity of buck is naturally slow, washes
The bottle time is than usually longer than common aluminized paper.201732516 A of patent CN " it is a kind of can the resident aqueous environment protection of ink it is straight
Plate beer label bottom surface coating " face dual-component coating when applying, and the wash bottle time is longer, greater than the 180s of common aluminized paper.
Summary of the invention
Purpose of this disclosure is to provide one kind can quickly take off the preparation method that target protects black aluminized paper, to reach resident oil
Black, quick de- target purpose.
To achieve the above object, technical solution is as follows:
A kind of black aluminized paper bottom-coating of guarantor, the constituent of the coating are as follows: acrylic emulsion A, acrylic emulsion B,
Alcohol, deionized water, wetting agent, levelling agent and defoaming agent.
Each constituent additive amount of bottom-coating are as follows: 30-60 parts of acrylic emulsion A, acrylic emulsion B 20-40
Part, 25-40 parts of alcohol, 40-60 parts of deionized water, 0.1-0.5 parts of wetting agent, 0.1-0.3 parts of levelling agent and defoaming agent 0.01-
0.05 part, each constituent additive amount is further are as follows: 35-50 parts of acrylic emulsion A, 20-35 parts of acrylic emulsion B, alcohol
25-40 parts, 40-50 parts of deionized water, 0.1-0.3 parts of wetting agent, 0.1-0.2 parts of levelling agent and 0.01-0.03 parts of defoaming agent.
A kind of black aluminized paper painting coating of guarantor, the constituent of the coating are as follows: waterborne polyurethane resin, acrylic emulsion
B, alcohol, deionized water, wetting agent, levelling agent and defoaming agent.
The painting coating each component additive amount are as follows: 40-60 parts of waterborne polyurethane resin, 15-20 parts of acrylic emulsion B,
20-40 parts of alcohol, 30-50 parts of deionized water, 0.1-0.5 parts of wetting agent, 0.1-0.3 parts of levelling agent and defoaming agent 0.01-0.03
Part, each constituent additive amount is further are as follows: 30-45 parts of waterborne polyurethane resin, 15-18 parts of acrylic emulsion B, alcohol 25-
40 parts, 25-40 parts of deionized water, 0.1-0.3 parts of wetting agent, 0.1-0.2 parts of levelling agent and 0.01-0.02 parts of defoaming agent.
One kind can quickly take off target aluminized paper back-coating, which is characterized in that the constituent of the coating are as follows: alkali solubility
Resin, polyvinyl alcohol, modification infusorial earth and deionized water.
The back-coating each component additive amount are as follows: 15-25 parts of alkali soluble resins, 20-30 parts of polyvinyl alcohol, modified diatom
Native 0.05-0.5 parts and deionized water 60-100 parts, each component additive amount advanced optimizes are as follows: 15-20 parts of alkali soluble resins gathers
17-25 parts of vinyl alcohol, 0.1-0.3 parts of modification infusorial earth and 65-90 parts of deionized water.
The acrylic emulsion A is the strong alkaline-resisting acrylic emulsion of large arch dam using compound emulsifying agent preparation, solid content
For 45-50, partial size 60-100nm, softening point is 25-60 DEG C.
The acrylic emulsion B is the not film-formable large arch dam alkali of resistance to type styrene-acrylic emulsion by force, solid content 45-50, softening
Point is 90-120 DEG C.
The wetting agent is Siloxane-Oxyalkylene Copolymers, fluorin modified crylic acid ester polymer, polyoxyethylene alkyl ether, acetylene
The one or more of ethylene glycol or polyoxyethylene glycol Arrcostab.
The levelling agent is silicone oil, dimethyl silicone polymer, polyether polyester azo polyether polyeste, alkyl-modified organosilicon
The one or more of oxygen alkane.
The defoaming agent is selected from one of modified polyorganosiloxane, modified silicon ketone compounds or interfacial agent or several
Kind.
The aqueous polyurethane is alkali resistant resin.
A kind of preparation method that can quickly take off target and protect black aluminized paper, which is characterized in that the bottom-coating of the aluminized paper
For above-mentioned guarantor's ink aluminized paper bottom-coating, the painting coating of the aluminized paper is above-mentioned guarantor's ink aluminized paper painting coating, the plating
The back-coating of aluminium paper can quickly take off target aluminized paper back-coating to be above-mentioned.
The beneficial effect of the disclosure is: providing a kind of preparation method that can quickly take off target and protect black aluminized paper, the side
The not film-formable Alkali-resistant resin of the acrylic emulsion B of method middle addition on coating, is uniformly dispersed in coating, utilizes it
Can not film forming mechanism, so that coating surface is will appear gap, even generate cracking, promote the faster permeation coating of buck, connect
Osmotic effect closely same as common aluminized paper applies carboxyl, amino, hydroxyl in component additionally, due to primary coat component and face and passes through
H key forms intermolecular active force, provides a three-dimensional netted skeleton, to achieve the effect that ink is resident, and effect
Excellent, ink retention rate is up to 90% or more.
The alkali soluble resins added in back-coating can make back coating also quickly react molten while contacting buck
Solution allows the glue of patch bottle to be rapidly separated with the paper sheet label back side, further promotes falling off for label, and the de- mark time is less than
180s。
Specific embodiment
Following steps are only to illustrate the technical solution of the disclosure, rather than its limitations；Although referring to These steps
The disclosure is described in detail, but those skilled in the art should understand that: it still can be to aforementioned each step
Technical solution documented by rapid is modified, or equivalent substitution of some or all of the technical features；And these
It modifies or replaces, the range of each step technique scheme of the disclosure that it does not separate the essence of the corresponding technical solution.
Embodiment 1
A kind of preparation method that can quickly take off target and protect black aluminized paper, the specific steps are that: this hair is used on coating machine
Bright bottom-coating carries out primary coat to the smooth surface of wet strong base stock (substrate), carries out vacuum in primary coat coating surface with vacuum aluminum-plating machine
It is aluminium-plated, then using face of the present invention apply and back be coated on coating machine carry out the painting of line face and back apply process, finally use damping machine,
The equipment such as cutting machine, packing machine such as get damp again to aluminized paper, are cut, being packed at the rear process processing.
The wherein component and additive amount of the bottom-coating are as follows: (hundred million companies provide acrylic emulsion A for Xi'an day, model
For 35 parts of TY-504), 20 parts of acrylic emulsion B (being provided for Xi'an day hundred million companies, model TY-506), 25 parts of alcohol, go from
40 parts of sub- water, 0.1 part of fluorin modified crylic acid ester polymer, 0.1 part of dimethyl silicone polymer and modified silicon ketone compounds 0.01
Part.
The component and additive amount of the painting coating are as follows: 30 parts of waterborne polyurethane resin, acrylic emulsion B are (for Xi'an day
Hundred million companies provide, model TY-506) 15 parts, 25 parts of alcohol, 25 parts of deionized water, 0.1 part of acetylene ethylene glycol, alkyl-modified have
0.1 part and 0.01 part of interfacial agent of organic siloxane.
The component and additive amount of the back-coating are as follows: 15 parts of alkali soluble resins, 17 parts of polyvinyl alcohol, modification infusorial earth
0.1 part and 65 parts of deionized water.
Embodiment 2
A kind of preparation method that can quickly take off target and protect black aluminized paper, the specific steps are that: on coating machine specially using this
Sharp bottom-coating carries out primary coat to the smooth surface of wet strong base stock (substrate), carries out vacuum in primary coat coating surface with vacuum aluminum-plating machine
It is aluminium-plated, then using this patent face apply and back be coated on coating machine carry out the painting of line face and back apply process, finally with damping machine,
The equipment such as cutting machine, packing machine such as get damp again to aluminized paper, are cut, being packed at the rear process processing.
The wherein component and additive amount of the bottom-coating are as follows: (hundred million companies provide acrylic emulsion A for Xi'an day, model
For 50 parts of TY-504), 35 parts of acrylic emulsion B (being provided for Xi'an day hundred million companies, model TY-506), 40 parts of alcohol, go from
50 parts of sub- water, 0.3 part of Siloxane-Oxyalkylene Copolymers, 0.2 part of silicone oil and 0.03 part of modified polyorganosiloxane.
The component and additive amount of the painting coating are as follows: 45 parts of waterborne polyurethane resin, acrylic emulsion B are (for Xi'an day
Hundred million companies provide, model TY-506) 18 parts, 40 parts of alcohol, 40 parts of deionized water, 0.3 part of fluorin modified crylic acid ester polymer,
0.2 part and 0.02 part of modified polyorganosiloxane agent of dimethyl silicone polymer.
The component and additive amount of the back-coating are as follows: 20 parts of alkali soluble resins, 25 parts of polyvinyl alcohol, modification infusorial earth
0.3 part and 90 parts of deionized water.
Claims (10)
1. a kind of black aluminized paper bottom-coating of guarantor, which is characterized in that the constituent of the coating are as follows: acrylic emulsion A, propylene
Yogurt liquid B, alcohol, deionized water, wetting agent, levelling agent and defoaming agent.
2. according to guarantor's ink aluminized paper bottom-coating described in claims 1, which is characterized in that each constituent additive amount
Are as follows: 30-60 parts of acrylic emulsion A, 20-40 parts of acrylic emulsion B, 25-40 parts of alcohol, 40-60 parts of deionized water, wetting agent
0.1-0.5 parts, 0.1-0.3 parts of levelling agent and 0.01-0.05 parts of defoaming agent, each constituent additive amount is further are as follows: acrylic acid
35-50 parts of latex A, 20-35 parts of acrylic emulsion B, 25-40 parts of alcohol, 40-50 parts of deionized water, wetting agent 0.1-0.3
Part, 0.1-0.2 parts of levelling agent and 0.01-0.03 parts of defoaming agent.
3. according to guarantor's ink aluminized paper bottom-coating described in claims 1, which is characterized in that the acrylic emulsion A is
The strong alkaline-resisting acrylic emulsion of large arch dam, solid content 45-50, partial size 60-100nm, softening point are 25-60 DEG C；Preferably
Acrylic emulsion B is the not film-formable large arch dam alkali of resistance to type styrene-acrylic emulsion by force, and solid content 45-50, softening point is 90-120 DEG C.
4. according to guarantor's ink aluminized paper bottom-coating described in claims 1, which is characterized in that the wetting agent changes for polyethers
Property polysiloxanes, fluorin modified crylic acid ester polymer, polyoxyethylene alkyl ether, acetylene ethylene glycol or polyoxyethylene glycol alkyl
The one or more of ester；Preferred levelling agent is silicone oil, dimethyl silicone polymer, polyether polyester azo polyether polyeste, alkyl
The one or more of azo polyether polyeste；Preferred defoaming agent is modified polyorganosiloxane, modified silicon ketone compounds or interface
One or more of activating agent.
5. a kind of black aluminized paper painting coating of guarantor, which is characterized in that the constituent of the coating are as follows: waterborne polyurethane resin,
Acrylic emulsion B, alcohol, deionized water, wetting agent, levelling agent and defoaming agent.
6. according to guarantor's ink aluminized paper painting coating described in claims 5, which is characterized in that each component additive amount are as follows: water
Property 40-60 parts of polyurethane resin, 15-20 parts of acrylic emulsion B, 20-40 parts of alcohol, 30-50 parts of deionized water, wetting agent
0.1-0.5 parts, 0.1-0.3 parts of levelling agent and 0.01-0.03 parts of defoaming agent, each constituent additive amount is further are as follows: aqueous poly-
30-45 parts of urethane resin, 15-18 parts of acrylic emulsion B, 25-40 parts of alcohol, 25-40 parts of deionized water, wetting agent 0.1-0.3
Part, 0.1-0.2 parts of levelling agent and 0.01-0.02 parts of defoaming agent.
7. according to guarantor's ink aluminized paper painting coating described in claims 5, which is characterized in that the aqueous polyurethane is resistance to
Alkaline resin；Preferred acrylic emulsion B is the not film-formable large arch dam alkali of resistance to type styrene-acrylic emulsion by force, solid content 45-50, soft
Changing point is 90-120 DEG C；Preferred wetting agent is Siloxane-Oxyalkylene Copolymers, fluorin modified crylic acid ester polymer, polyoxyethylene alkane
The one or more of base ether, acetylene ethylene glycol or polyoxyethylene glycol Arrcostab；Preferred levelling agent is silicone oil, poly dimethyl
Siloxanes, polyether polyester azo polyether polyeste, the one or more of alkyl-modified organosiloxane；Preferably defoaming agent is excellent is
One or more of modified polyorganosiloxane, modified silicon ketone compounds or interfacial agent.
8. one kind can quickly take off target aluminized paper back-coating, which is characterized in that the constituent of the coating are as follows: alkali solubility tree
Rouge, polyvinyl alcohol, modification infusorial earth and deionized water.
9. can quickly take off target aluminized paper back-coating according to claims 8, which is characterized in that each component addition
Amount are as follows: 15-25 parts of alkali soluble resins, 20-30 parts of polyvinyl alcohol, 0.05-0.5 parts of modification infusorial earth and deionized water 60-100
Part, each component additive amount advanced optimizes are as follows: 15-20 parts of alkali soluble resins, 17-25 parts of polyvinyl alcohol, modification infusorial earth 0.1-
0.3 part and deionized water 65-90 parts.
10. one kind can quickly take off the preparation method that target protects black aluminized paper, which is characterized in that the bottom-coating of the aluminized paper is
Guarantor's ink aluminized paper bottom-coating described in any one of claim 1-4, the painting coating of the aluminized paper are that right seeks 5-7
Any one of described in guarantor's ink aluminized paper painting coating, the back-coating of the aluminized paper is described in claim 8 or 9
Target aluminized paper back-coating can quickly be taken off.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910595028.7A CN110438837B (en) | 2019-07-03 | 2019-07-03 | Preparation method of ink-preserving aluminized paper capable of quickly removing labels |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910595028.7A CN110438837B (en) | 2019-07-03 | 2019-07-03 | Preparation method of ink-preserving aluminized paper capable of quickly removing labels |
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| CN110438837A true CN110438837A (en) | 2019-11-12 |
| CN110438837B CN110438837B (en) | 2021-08-31 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110846931A (en) * | 2019-11-13 | 2020-02-28 | 烟台博源科技材料股份有限公司 | Novel environment-friendly high-barrier direct plating paper and preparation process thereof |
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