CN110426325A - The method for carrying inert particle using micro-nano motor cluster - Google Patents

The method for carrying inert particle using micro-nano motor cluster Download PDF

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Publication number
CN110426325A
CN110426325A CN201910700867.0A CN201910700867A CN110426325A CN 110426325 A CN110426325 A CN 110426325A CN 201910700867 A CN201910700867 A CN 201910700867A CN 110426325 A CN110426325 A CN 110426325A
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micro
nano
cluster
motor cluster
light source
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官建国
张健华
牟方志
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Wuhan University of Technology WUT
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Wuhan University of Technology WUT
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N15/10Investigating individual particles
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume, or surface-area of porous materials
    • G01N2015/0003Determining electric mobility, velocity profile, average speed or velocity of a plurality of particles
    • G01N2015/1027

Abstract

The invention discloses a kind of methods for carrying inert particle using micro-nano motor cluster.By anatase TiO2Micro-and nano-particles dispersion is made into suspension in deionized water, stands 1-5min after being added drop-wise on glass substrate and obtains micro-nano motor cluster;Hydrogen peroxide is added as fuel, the movement of micro-nano motor cluster is controlled by control light source switch, light source direction, the intensity of light source, light application time, sweeps along target noble particle and realizes the carrying to inert particle.The present invention can control accurate crawl, transport and release of the motor cluster to inert particle by control direction of illumination, intensity of illumination, light application time, it is expected to push micro-nano motor in microcell space exploration, sensing and collaborative crawling, transport and the practical application for assembling field.

Description

The method for carrying inert particle using micro-nano motor cluster
Technical field
Micro-nano motor cluster, which is particularly related to, the invention belongs to micro-nano motor technical field carries inert particle Method.
Background technique
There are a large amount of biologies in nature, they only have limited perception and ability to act as individual, but pass through part The biological cluster that self-organizing reciprocation is formed but tends to show the group behavior and synergistic function that individual does not have, complete Carries at cooperation, migrate, look for food, nest, resist the enemy etc. the team tasks of complexity.Micro-nano motor is a kind of size in micro-nano Meter level is other, and the energy (such as chemical energy) of other forms in environment can be converted into the micro-nano machine of itself kinetic energy (Nanoscale 2014,6,7175;Nanoscale 2013,5,4696;ACS Appl.Mater.Interfaces 2014, 6,9897;Small 2014,10,4154;Chem.Rev.2015,115,8704).It is similar with organism, some micro-nano motors Various physiochemical signals can be discharged into environment, and are interacted and self-organizing shape with other micro-nano motors generation near it At micro-nano motor cluster (Acc.Chem.Res.2015,48,1938).For example, Pennsylvania State Univ-Univ Park USA Sen and Mallouk seminar (Angew.Chem.Int.Ed.2009,48,3308;J.Am.Chem.Soc.2013,135,1280; Adv.Funct.Mater.2010,20,1568) it is interacted using the diffusiophoresis between colloidal particle, develop AgCl, Ag3PO4 And SiO2/TiO2Micron motor cluster.Solovev et al. (Nanoscale 2013,5,1284) utilizes capillary force interaction structure Bubble driving tubulose engine cluster is built.California, USA university, branch school, San Diego Wang seminar (Nano Lett.2015,15, 4814) effect that Xiang Bojie (or antinode) assembles in standing-wave sound field using particle has developed from driving metal bar shape nanometer Motor cluster changes the position of stationary field node and antinode by adjusting supersonic frequency, can regulate and control the position of nano-motor cluster And movement.Since micro-nano motor cluster has good fault-tolerance, redundancy and adaptivity, thus it is expected their energy The synergistic function that individual micro-nano motor does not have enough is shown, is expected to as programmable micro-nano machine in micro-nano-scale The cooperation of lower completion cargo carries, micro-nano device assemble in situ and processing, micro- aerospace telemetry, drug conveying and it is micro- perform the operation etc. it is complicated Task brings change property application technology to the fields such as bio-medical, environmental monitoring and improvement, micro-nano process engineering.But so far These micro-nano motor clusters of development otherwise be only able to achieve aggregation, divergent function or mass motion direction are difficult to control.It Can not all plan or the control on demand direction of motion and track in real time and also to rarely have micro-nano motor cluster application at present in advance The relevant report of aspect.Recently, Hong Kong Chinese University Zhang Li seminar (Nat.Commun.2018,9,3260) utilizes oscillating magnetic flux Realize magnetic cluster free extension deformation and directed movement in complex fluid environment in field;He Qiang seminar, Harbin Institute of Technology (Sci.Robot.2019,4, eaav8006) using vortex motor cluster realizes its directed movement and to large cargo polyphenyl The carrying of ethylene microballoon.However it is seriously constrained to the dependence of 3 D complex oscillating magnetic field can operational readiness and practical application.Cause This, development constructs a kind of direction of motion controllable precise, without specific complicated outfield, and can carry out cooperation carrying to " large cargo " Micro-nano motor cluster be one of this field urgent problem to be solved.
Summary of the invention
It is an object of that present invention to provide a kind of methods for accurately controlling micro-nano motor collective motion direction and track simultaneously Realize that cluster delivers the bionical cooperation of inert particle.
To achieve the above object, as follows using technical solution:
The method for carrying inert particle using micro-nano motor cluster, comprising the following steps:
By anatase TiO2Micro-and nano-particles dispersion is made into suspension in deionized water, quiet after being added drop-wise on glass substrate It sets 1-5min and obtains micro-nano motor cluster;
Hydrogen peroxide is added as fuel, is controlled by control light source switch, light source direction, the intensity of light source, light application time micro- The movement of nano-motor cluster sweeps along target noble particle and realizes the carrying to inert particle.
According to the above scheme, the anatase TiO2The particle size range of micro-and nano-particles is 0.025-20 μm.
According to the above scheme, the particle size range of the inert particle is at 10 μm or less.
According to the above scheme, the light source is wavelength in 400nm light below.
According to the above scheme, the angle of the light source and horizontal plane normal is θ, and 0 °≤θ < 90 °.
According to the above scheme, the light source output power is in 0.06W or more.
According to the above scheme, hydrogen peroxide concentration in system is 0.005wt% or more.
According to the above scheme, it by the control to micro-and nano-particles concentration, realizes to micro-nano motor cluster cohesive size Control;With the increase of concentration, increase tendency is presented in the size under micro-nano motor cluster coherent condition.
According to the above scheme, it by the control to light application time, the intensity of light source or hydrogen peroxide concentration, realizes to micro-nano motor The control of the real-time size of cluster and movement rate;With the increase of light application time, the intensity of light source and hydrogen peroxide concentration, micro-nano horse Increase tendency is presented in real-time size and movement velocity up to cluster.
According to the above scheme, by the control to light source incidence direction, the control to micro-nano motor collective motion direction is realized System;When light source is from non-perpendicular to slide direction directive micro-nano motor cluster, micro-nano motor cluster can be towards light source incidence Direction movement, increases the size of itself simultaneously because particle scatters, and when changing light source direction, micro-nano motor cluster The direction of motion also changes correspondingly immediately;Light source shows the increase of size and does not have perpendicular to slide direction, micro-nano motor cluster Directional movement.
The present invention has the beneficial effect that:
The method that the present invention can accurately control micro-nano motor collective motion direction and track has easy to operate, behaviour Control the features such as precision is high, applied widely.
The size of inert particle of the present invention is much larger than the size of single micron motor, can not be moved by single-motor; The cluster can be loaded, transport and discharge to the cargo of different surfaces performance, different number.
The present invention can control motor cluster to inert particle by control direction of illumination, intensity of illumination, light application time It is accurate crawl, transport and release, be expected to push micro-nano motor microcell space exploration, sensing and collaborative crawling, transport With the practical application in assembling field.
Detailed description of the invention
Fig. 1: cluster structure figures under the scanning electron microscope (SEM) photograph (A) of 1 isotropism titanium dioxide micrometer particle of embodiment, microscope (B), XRD diffraction pattern (C) and TG-DSC analysis chart (D).
Fig. 2: (B) cluster formational situation under natural light (A) and dark condition.
Fig. 3: cluster size and mass motion speed are respectively with the change of intensity of illumination (A, B, C) and fuel concentration (D, E, F) Change trend.
Fig. 4: light irradiation apparatus schematic diagram.
Fig. 5: the time diagram of cycling switch ultraviolet lamp.
Fig. 6: light guide isotropism TiO2The directed movement trajectory diagram of micron motor cluster.
Fig. 7: the adaptability deformation of micron motor cluster.
Fig. 8: light guide controls the cooperation of titanium dioxide micrometer motor and carries the trajectory diagram that inert particle realizes directed movement.
Fig. 9: the light-operated titanium dioxide micrometer motor realizes the unloading to inert particle.
Figure 10: different-grain diameter TiO 2 particles assemble the micrograph for forming cluster in aqueous solution.
Figure 11: the cluster micrograph that titanium dioxide micrometer motor is formed under the conditions of different particle concentrations.
Figure 12: titanium dioxide micrometer motor cluster carries the timing diagram of different surfaces performance cargo, (A) amino PS ball;(B) Carboxyl PS ball.
Figure 13: the relationship between the average movement velocity and entrained quantity of goods of titanium dioxide micrometer motor cluster.
Specific embodiment
Following embodiment further illustrates technical solution of the present invention, but not as limiting the scope of the invention.
Embodiment 1
One kind being based on isotropism TiO2The cluster building of micron motor and phototaxis motion control method:
Take isotropic anatase TiO2Spherical micro particles, are scattered in deionized water solution and are configured to The particle suspension of 0.35mg/ml.A small amount of particle suspension is taken to be dispersed to certain density hydrogen peroxide as fuel (0.25wt.%) In, 1-5min or so is waited, the micron motor cluster of self aggregation formation can be obtained.Build illumination platform, setting light and level Face angle is β (0 °≤0<90 °), sets light source output power as P (>0.06W), is by control illumination switch, direction of illumination Accurately control TiO2The direction of motion of micron motor cluster and track.
Utilize scanning electron microscope (SEM, S-4800, Hitachi Co., Ltd., Japan), inverted fluorescence microscope (Leica DM 3000B), X-ray diffraction analysis instrument (XRD Bruker D8 Advance X-ray diffractometer) Microstructure characterization is carried out to taken titanium dioxide micrometer particle with thermogravimetric analyzer (NETZSEC, STA-449C, Germany) It is mutually characterized with object, as a result as shown in figure 1 shown in A, B, C, D.Figure 1A illustrates that this structural motif for being used to construct motor cluster is 1.2 μm or so of spheroidal particle;Figure 1B explanation independently can assemble to form cluster in aqueous solution;Fig. 1 C and D show this particle In contain anatase TiO2With hydration TiO2
Isotropism TiO2The performance test of micron motor cluster:
1) natural light tests the influence that cluster is formed
By the mixed liquor of 1 gained micron motor cluster of embodiment and hydrogen peroxide be placed individually into natural light and dark In environmental system, TiO is observed using fluorescence microscope (Leica DM 3000B)2The case where micron motor forms cluster.Such as Fig. 2 Shown in middle A, B, show that motor can self-assemble formation cluster under natural light or dark surrounds.
2) micron motor cluster size and mass motion speed are surveyed with the variation of light application time, intensity of illumination, fuel concentration Examination
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, utilizes external UV emitting device (365nm) is irradiated it, changes light application time, intensity of illumination and fuel concentration, using fluorescence microscope (Leica DM 3000B) observe TiO2The variation of micron motor cluster size and movement velocity.As shown in Fig. 3 A, B, C, D, E, F, with illumination Increase tendency is presented in the increase of time, intensity of illumination and fuel concentration, the size and movement velocity of cluster.
3) the phototaxis movenent performance test of micron motor cluster
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, builds illumination platform as shown in Figure 4, The switch of ultraviolet lamp is controlled with program as shown in Figure 5, wherein A figure is the time diagram of cycling switch Y direction ultraviolet lamp;B figure For the time diagram of cycling switch X-direction ultraviolet lamp.TiO is observed using fluorescence microscope (Leica DM 3000B)2Micron horse Up to the variation of cluster position.Light intensity is 1W/cm in experiment2, hydrogen peroxide concentration 0.25wt.%.As a result as shown in fig. 6, showing Light can accurately control the direction of motion and the track of cluster.
4) aptitude tests that micron motor cluster is deformed according to environment self-adaption
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, with illumination platform as shown in Figure 4 behaviour Control cluster.Long-time illumination (> 1min) is carried out to cluster, as a result as shown in Figure 7 A, one big cluster can disintegrate to form 18 Small cluster, and big cluster may finally be reassembled into.When in environmental system there are when barrier or narrow pipeline, Cluster is manipulated with illumination platform as shown in Figure 4, TiO is observed using fluorescence microscope (Leica DM 3000B)2Micron motor Flock behaviour change in location shows that this micron of motor cluster, can be with when encountering barrier and pipeline as a result as shown in Fig. 7 B, C The form for adjusting itself carrys out across obstacle and across narrow pipeline.
5) performance test of inert particle is carried in the bionical cooperation of micron motor cluster
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, is added 0.01mg/ml's into system SiO2Particle (10 μm), with the direction of motion of illumination platform as shown in Figure 4 manipulation cluster and track.Using fluorescence microscope (Leica DM 3000B) observes TiO2Micron motor cluster and SiO2Interaction between particle, experimental result such as Fig. 8 and figure Shown in 9.Show TiO2Micron motor cluster can carry out bionical cooperation carrying to large-scale inert particle, be precisely accomplished determining for cargo Point transport and release.
Embodiment 2
The TiO of cluster will be constructed in embodiment 12Micro particles change P25 (25nm) nano-TiO into respectively2With utilize microemulsion The large scale TiO of method preparation2Micro particles (5-20 μm), disperse the two in deionized water solution respectively be configured to it is certain dense The particle suspension of degree.A small amount of particle suspension is taken to be added dropwise on glass substrate, using fluorescence microscope (Leica DM 3000B) particle buildup situation is characterized.The results are shown in Figure 10
Embodiment 3
Particle suspension concentration in embodiment 1 is adjusted separately to 0.15,0.5,0.75mg/ml, above embodiments 1 are repeated The step of, obtain TiO2Micron motor cluster carries out particle buildup situation using fluorescence microscope (Leica DM 3000B) Characterization illustrates that the different cluster of size can be obtained when particle concentration is higher than 0.15mg/ml, particle concentration is got over as shown in figure 11 Height, obtained cluster size are bigger.
Embodiment 4
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, is added 0.01mg/ml's into system NH4- PS ball and COOH-PS spherolite are sub (10 μm), with the direction of motion of illumination platform as shown in Figure 4 manipulation cluster and track. TiO is observed using fluorescence microscope (Leica DM 3000B)2Micron motor cluster and NH4- PS ball and COOH-PS spherolite Between interaction, experimental result is as shown in figure 12.Show that this micron of motor cluster can carry the cargo of different surfaces modification Particle, adaptability are extensive.
Embodiment 5
With the TiO obtained in Figure 1B of embodiment 12Micron motor cluster is object, is added 0.1mg/ml's into system SiO2Particle (10 μm), with the direction of motion of illumination platform as shown in Figure 4 manipulation cluster and track.Using fluorescence microscope (Leica DM 3000B) observes TiO2Micron motor cluster and multiple SiO2Interaction between particle calculates quantity of goods To the affecting laws of travelling speed, as a result as shown in figure 13.Show that this micron of motor cluster can carry multiple inertia grains simultaneously Son, and its travelling speed is reduced with the increase of quantity of goods.
The present invention relates to cluster building behavior, particle concentration (motor and cargo), particle size (cargo), illumination it is strong Parameters, the section values such as degree, light application time, direction of illumination variation and fuel concentration can realize the present invention, herein not one by one Enumerate embodiment.

Claims (10)

1. the method for carrying inert particle using micro-nano motor cluster, it is characterised in that the following steps are included:
By anatase TiO2Micro-and nano-particles dispersion is made into suspension in deionized water, stands 1- after being added drop-wise on glass substrate 5min obtains micro-nano motor cluster;
Hydrogen peroxide is added as fuel, is controlled by control light source switch, light source direction, the intensity of light source, light application time micro-nano The movement of motor cluster sweeps along target noble particle and realizes the carrying to inert particle.
2. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the rutile titania Mine TiO2The particle size range of micro-and nano-particles is 0.025-20 μm.
3. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the inertia The particle size range of particle is at 20 μm or less.
4. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the light source It is wavelength in 400nm light below.
5. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the light source Angle with horizontal plane normal is θ, and 0 °≤θ < 90 °.
6. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the light source Output power is in 0.06 W or more.
7. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that the dioxygen Water concentration in system is 0.005wt% or more.
8. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that by micro- The control to micro-nano motor cluster cohesive size is realized in the control of nanoparticle concentration;With the increase of concentration, micro-nano horse Increase tendency is presented up to the size under cluster coherent condition.
9. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that by light According to the control of time, the intensity of light source or hydrogen peroxide concentration, the control to the real-time size of micro-nano motor cluster and movement rate is realized System;With the increase of light application time, the intensity of light source and hydrogen peroxide concentration, the real-time size and movement velocity of micro-nano motor cluster Increase tendency is presented.
10. the method for carrying inert particle using micro-nano motor cluster as described in claim 1, it is characterised in that by light The control to micro-nano motor collective motion direction is realized in the control of source incident direction;When light source is from non-perpendicular to slide direction When directive micro-nano motor cluster, micro-nano motor cluster can be moved towards light source incidence direction, simultaneously because particle, which scatters, to be made The size of itself increases, and when changing light source direction, the direction of motion of micro-nano motor cluster also changes correspondingly immediately;Light source Perpendicular to slide direction, micro-nano motor cluster shows the increase of size without directional motion.
CN201910700867.0A 2019-07-31 2019-07-31 The method for carrying inert particle using micro-nano motor cluster Pending CN110426325A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106448794A (en) * 2016-10-14 2017-02-22 武汉理工大学 Semiconductor micro-nano particle oriented motion control method
CN107098384A (en) * 2017-04-06 2017-08-29 武汉理工大学 One kind is based on TiO2The light-operated micron motor of twin crystal phase micro particles and its preparation and control
CN108233774A (en) * 2018-01-12 2018-06-29 武汉理工大学 A kind of dynamic control method of micro-nano motor cluster
CN108462407A (en) * 2018-03-13 2018-08-28 武汉理工大学 The method for guiding micro-nano motor using magnetic responsiveness topology track
CN109647311A (en) * 2018-12-17 2019-04-19 武汉理工大学 A kind of magnetic liquid hoodle and its light control method
CN110059427A (en) * 2019-04-24 2019-07-26 杭州电子科技大学 The novel micro-nano motor transport system of driving certainly, transportation resources and analogy method
CN110181060A (en) * 2019-05-20 2019-08-30 武汉理工大学 The experimental method of electric pulse regulation laser direct forming beta-titanium alloy crystallite dimension

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106448794A (en) * 2016-10-14 2017-02-22 武汉理工大学 Semiconductor micro-nano particle oriented motion control method
CN107098384A (en) * 2017-04-06 2017-08-29 武汉理工大学 One kind is based on TiO2The light-operated micron motor of twin crystal phase micro particles and its preparation and control
CN108233774A (en) * 2018-01-12 2018-06-29 武汉理工大学 A kind of dynamic control method of micro-nano motor cluster
CN108462407A (en) * 2018-03-13 2018-08-28 武汉理工大学 The method for guiding micro-nano motor using magnetic responsiveness topology track
CN109647311A (en) * 2018-12-17 2019-04-19 武汉理工大学 A kind of magnetic liquid hoodle and its light control method
CN110059427A (en) * 2019-04-24 2019-07-26 杭州电子科技大学 The novel micro-nano motor transport system of driving certainly, transportation resources and analogy method
CN110181060A (en) * 2019-05-20 2019-08-30 武汉理工大学 The experimental method of electric pulse regulation laser direct forming beta-titanium alloy crystallite dimension

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
NAN LIU: "A review on TiO2-based nanotubes synthesized via hydrothermalmethod:Formation mechanism, structure modification, andphotocatalytic applications", 《CATALYSIS TODAY》 *
孔磊: "自驱动微纳米马达的设计原理与结构简化方法", 《科学通报》 *

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