CN110421777A - A kind of PDCPT bumper face-piece processing technology - Google Patents

A kind of PDCPT bumper face-piece processing technology Download PDF

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Publication number
CN110421777A
CN110421777A CN201910722830.8A CN201910722830A CN110421777A CN 110421777 A CN110421777 A CN 110421777A CN 201910722830 A CN201910722830 A CN 201910722830A CN 110421777 A CN110421777 A CN 110421777A
Authority
CN
China
Prior art keywords
pdcpt
dcpt
monomer
material temperature
bumper face
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910722830.8A
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Chinese (zh)
Inventor
陶智
韩德良
徐家骥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Dongsheng New Energy Automobile Co Ltd
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Hefei Dongsheng New Energy Automobile Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Dongsheng New Energy Automobile Co Ltd filed Critical Hefei Dongsheng New Energy Automobile Co Ltd
Priority to CN201910722830.8A priority Critical patent/CN110421777A/en
Publication of CN110421777A publication Critical patent/CN110421777A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2045/00Use of polymers of unsaturated cyclic compounds having no unsaturated aliphatic groups in a side-chain, e.g. coumarone-indene resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/30Vehicles, e.g. ships or aircraft, or body parts thereof
    • B29L2031/3044Bumpers

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)

Abstract

The invention discloses a kind of PDCPT bumper face-piece processing technologys, include the following steps, S1, DCPT monomer (dicyclopentadiene) and major catalyst are added in material temperature machine A and DCPT monomer and co-catalyst are added in material temperature machine B;S2, pass through constant displacement pump simultaneously to mold injection after internal DCPT monomer is adequately stirred and heated by material temperature machine A and material temperature machine B;S3, in injection moulding process, mixing head hits the DCPT monomer in die cavity repeatedly, formed PDCPT (polydicyclopentadiene);S4, cooled down by die heater to mold, PDCPT is demoulded after mould inside cooling and shaping by pulling equipment;S5, molding bumper face-piece surface is polished.The technique is formed using the PDCPD Material injection polymerization reaction of high tenacity, it is able to achieve the consistency of product, reduces own wt, shorten the process-cycle, improve resistance to deformation cracking, avoid the functions such as corrosion and durable aging.

Description

A kind of PDCPT bumper face-piece processing technology
Technical field
The invention belongs to auto parts technical field of producing, and in particular to a kind of PDCPT bumper face-piece processing work Skill.
Background technique
Polydicyclopentadiene PDCPD is the homopolymer or copolymer of dicyclopentadiene (DCPD).For a kind of cross-linked three D net Shape Structural Engineering plastics.Density 1.03g/cm3,120 DEG C of heat distortion temperature.In -40 DEG C of timeinvariances.It is resistance to general acid, alkali, organic Solvent, but intolerant to aromatic hydrocarbons and halogenated hydrocarbons.1790~2070MPa of bending modulus.Tensile strength 34MPa.Glass transition temperature 185.5 ℃.Izod notched impact strength 427J/m.In the presence of the catalyst that tungsten hexachloride and aluminium diethyl monochloride form, by bicyclic Pentadiene ring opening metathesis polymerization is made.Various products can be made of reaction injection molding.And currently, Domestic Insurance thick stick face-piece is Metal plate punching, injection structure, SMC molding and FRP realize, product be easily deformed or be broken after being impacted exist simultaneously it is durable The defects of aging, corrosion.Prior art mold investment is big, and manufacturing procedure is more, and product own wt is larger, so needing a kind of new Processing technology come into operation and solve the above problems.
Summary of the invention
The purpose of the present invention is to provide a kind of PDCPT bumper face-piece processing technologys to come into operation, to solve above-mentioned back The problem of being proposed in scape technology.
To achieve the above object, the invention provides the following technical scheme: a kind of PDCPT bumper face-piece processing technology, packet Include following steps,
S1, DCPT monomer (dicyclopentadiene) and major catalyst are added in material temperature machine A and is added in material temperature machine B DCPT monomer and co-catalyst;
S2, pass through after internal DCPT monomer is adequately stirred and heated by material temperature machine A and material temperature machine B and determine Amount pump is simultaneously to mold injection;
S3, in injection moulding process, mixing head hits the DCPT monomer in die cavity repeatedly, formed PDCPT (poly bis ring Pentadiene);
S4, cooled down by die heater to mold, PDCPT is carried out after mould inside cooling and shaping by pulling equipment Demoulding;
S5, molding bumper face-piece surface is polished.
Preferably, the major catalyst is tungsten hexachloride, and the co-catalyst is aluminium diethyl monochloride.
Preferably, material temperature machine guarantees that DCPT monomer is in temperature constant state, and die heater control in the injection moulding process of step S3 Molding jig is in temperature constant state.
Preferably, one end of the mixing head penetrates the inside of die cavity by the through-hole opened up on mold, and mixing head and Sealing ring is provided between through-hole.
Preferably, the sealing ring is nitrile rubber or fluorubber material.
Technical effect and advantage of the invention: the PDCPT bumper face-piece processing technology, by material temperature machine to two parts of DCPT Monomer is pre-processed, and is input in the die cavity of mold through mixing head impingement mix, accelerates to generate PDCPT material, And in in-mold molding, formed using the PDCPD Material injection polymerization reaction of high tenacity, it be able to achieve product consistency, It reduces own wt, shorten the process-cycle, improve production efficiency, improve resistance to deformation cracking, avoid the function such as corrosion and durable aging Energy.
Detailed description of the invention
Fig. 1 is real work schematic diagram of the present invention;
In figure: 1, material temperature machine A;2, material temperature machine B;3, mold;4, mixing head;5, sealing ring;6, through-hole.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The present invention provides a kind of PDCPT bumper face-piece processing technologys as shown in Figure 1, include the following steps,
S1, DCPT monomer (dicyclopentadiene) and major catalyst are added in material temperature machine A1 and is added in material temperature machine B2 DCPT monomer and co-catalyst;
S2, pass through after internal DCPT monomer is adequately stirred and heated by material temperature machine A1 and material temperature machine B2 Constant displacement pump is molded to mold 3 simultaneously;Two parts of DCPT monomer materials are located in advance respectively by material temperature machine A1 and material temperature machine B2 Reason is heated and controls suitable temperature, guarantees that DCPT monomer can quickly be reacted when entering in mold 3.
S3, in injection moulding process, mixing head 4 hits the DCPT monomer in die cavity repeatedly, formed PDCPT it is (poly bis Cyclopentadiene);
S4, cooled down by die heater to mold 3, PDCPT be cooled and shaped inside the mold 3 after by pulling equipment into Row demoulding;Impingement mix is carried out to the DCPT monomer being injected into 3 die cavity of mold by mixing head 4, mixed liquor is very short It is chemically reacted in time, net high-polymer polymer can be formed, die sinking is detached from product after cured, further speeds up The formation efficiency of PDCPT, to accelerate production efficiency.
S5, molding bumper face-piece surface is polished.
The major catalyst is tungsten hexachloride, and the co-catalyst is aluminium diethyl monochloride, is urged by major catalyst and helping The cooperation of agent promotes the ring-opening metathesis reaction of DCPT, accelerates the generation of PDCPT.
Material temperature machine guarantees that DCPT monomer is in temperature constant state in the injection moulding process of step S3, and die heater controls mold 3 In temperature constant state, guarantee that DCPT monomer and mold 3 keep constant temperature, to guarantee that DCPT monomer can quick comprehensive open loop discrimination Change reaction and generates PDCPT.
One end of the mixing head 4 penetrates the inside of die cavity, and mixing head 4 and through-hole by the through-hole 6 opened up on mold 3 It is provided with sealing ring 5 between 6, guarantees the leakproofness between mixing head 4 and 3 through-hole 6 of mold, the mixed liquor in die cavity is avoided to let out Leakage.
The sealing ring 5 is nitrile rubber or fluorubber material, guarantees the heat resistance of sealing ring 5, to guarantee its use Service life.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (5)

1. a kind of PDCPT bumper face-piece processing technology, it is characterised in that: include the following steps,
S1, DCPT monomer (dicyclopentadiene) and major catalyst are added in material temperature machine A and addition DCPT is mono- in material temperature machine B Body and co-catalyst;
S2, pass through constant displacement pump after internal DCPT monomer is adequately stirred and heated by material temperature machine A and material temperature machine B Simultaneously to mold injection;
S3, in injection moulding process, mixing head hits the DCPT monomer in die cavity repeatedly, formed PDCPT (poly bis ring penta 2 Alkene);
S4, cooled down by die heater to mold, PDCPT is taken off after mould inside cooling and shaping by pulling equipment Mould;
S5, molding bumper face-piece surface is polished.
2. a kind of PDCPT bumper face-piece processing technology according to claim 1, it is characterised in that: the major catalyst For tungsten hexachloride, the co-catalyst is aluminium diethyl monochloride.
3. a kind of PDCPT bumper face-piece processing technology according to claim 1, it is characterised in that: in the note of step S3 Material temperature machine guarantees that DCPT monomer is in temperature constant state during modeling, and die heater control mold is in temperature constant state.
4. a kind of PDCPT bumper face-piece processing technology according to claim 1, it is characterised in that: the mixing head One end penetrates the inside of die cavity by the through-hole opened up on mold, and sealing ring is provided between mixing head and through-hole.
5. a kind of PDCPT bumper face-piece processing technology according to claim 4, it is characterised in that: the sealing ring is Ding Qing Rubber or fluorubber material.
CN201910722830.8A 2019-08-06 2019-08-06 A kind of PDCPT bumper face-piece processing technology Pending CN110421777A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910722830.8A CN110421777A (en) 2019-08-06 2019-08-06 A kind of PDCPT bumper face-piece processing technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910722830.8A CN110421777A (en) 2019-08-06 2019-08-06 A kind of PDCPT bumper face-piece processing technology

Publications (1)

Publication Number Publication Date
CN110421777A true CN110421777A (en) 2019-11-08

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Citations (12)

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CN101352911A (en) * 2008-09-27 2009-01-28 中国蓝星(集团)总公司 Method for preparing chemical industry pipeline
CN101537685A (en) * 2009-04-28 2009-09-23 中国蓝星(集团)股份有限公司 Screw cap and preparation method thereof
CN201473856U (en) * 2009-07-27 2010-05-19 卓越(福建)机械制造发展有限公司 Road curb vibration device
CN102814921A (en) * 2011-12-31 2012-12-12 洛阳智颢工程塑料有限公司 High-pressure reaction injection moulding device
CN104250330A (en) * 2013-06-27 2014-12-31 蓝星(北京)特种纤维技术研发中心有限公司 Dicyclopentadiene and carbon fiber cloth composite manhole cover and manufacturing method thereof
CN106273209A (en) * 2016-08-31 2017-01-04 湖南华强电气股份有限公司 The preparation method of car air-conditioner DCPD composite cover plate
CN106380578A (en) * 2016-08-31 2017-02-08 湖南华强电气股份有限公司 Vehicle air conditioner DCPD composite material pedestals
CN106608026A (en) * 2017-01-24 2017-05-03 常州轻工职业技术学院 Injection mold feed port structure based on CAE technology
CN106827406A (en) * 2017-02-13 2017-06-13 长沙金镂机械科技有限公司 For the auto parts and components mould and forming method of PDCPD reaction shapings
CN108044871A (en) * 2017-12-20 2018-05-18 嘉丰工业科技(惠州)有限公司 A kind of Shooting Technique
CN207808003U (en) * 2018-01-17 2018-09-04 福建省东浦科技实业有限公司 A kind of vibrating material-distributing device
CN108659169A (en) * 2018-06-06 2018-10-16 全椒祥瑞塑胶有限公司 A kind of heat-resistant high impact-resistant hits the preparation method of bumper material

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CN101352911A (en) * 2008-09-27 2009-01-28 中国蓝星(集团)总公司 Method for preparing chemical industry pipeline
CN101537685A (en) * 2009-04-28 2009-09-23 中国蓝星(集团)股份有限公司 Screw cap and preparation method thereof
CN201473856U (en) * 2009-07-27 2010-05-19 卓越(福建)机械制造发展有限公司 Road curb vibration device
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CN106273209A (en) * 2016-08-31 2017-01-04 湖南华强电气股份有限公司 The preparation method of car air-conditioner DCPD composite cover plate
CN106380578A (en) * 2016-08-31 2017-02-08 湖南华强电气股份有限公司 Vehicle air conditioner DCPD composite material pedestals
CN106608026A (en) * 2017-01-24 2017-05-03 常州轻工职业技术学院 Injection mold feed port structure based on CAE technology
CN106827406A (en) * 2017-02-13 2017-06-13 长沙金镂机械科技有限公司 For the auto parts and components mould and forming method of PDCPD reaction shapings
CN108044871A (en) * 2017-12-20 2018-05-18 嘉丰工业科技(惠州)有限公司 A kind of Shooting Technique
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Application publication date: 20191108