CN110408240A - A kind of mica powder and preparation method thereof that nano inorganic-is organic coated - Google Patents
A kind of mica powder and preparation method thereof that nano inorganic-is organic coated Download PDFInfo
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- CN110408240A CN110408240A CN201910586961.8A CN201910586961A CN110408240A CN 110408240 A CN110408240 A CN 110408240A CN 201910586961 A CN201910586961 A CN 201910586961A CN 110408240 A CN110408240 A CN 110408240A
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- acid
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- mica powder
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- 229910052618 mica group Inorganic materials 0.000 title claims abstract description 98
- 239000010445 mica Substances 0.000 title claims abstract description 97
- 239000000843 powder Substances 0.000 title claims abstract description 68
- 238000002360 preparation method Methods 0.000 title claims description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- 239000011248 coating agent Substances 0.000 claims abstract description 44
- 238000000576 coating method Methods 0.000 claims abstract description 44
- 239000000126 substance Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 119
- -1 carbonate compound Chemical class 0.000 claims description 62
- 229910052629 lepidolite Inorganic materials 0.000 claims description 30
- 229910052626 biotite Inorganic materials 0.000 claims description 27
- 238000000227 grinding Methods 0.000 claims description 25
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 claims description 23
- 229910052628 phlogopite Inorganic materials 0.000 claims description 23
- 238000005520 cutting process Methods 0.000 claims description 22
- 229910052627 muscovite Inorganic materials 0.000 claims description 22
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 13
- 229910000077 silane Inorganic materials 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 229920002545 silicone oil Polymers 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 9
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002202 Polyethylene glycol Chemical group 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 8
- 239000010955 niobium Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Chemical group 0.000 claims description 8
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 5
- 229920002125 Sokalan® Chemical group 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229920000180 alkyd Polymers 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 235000010233 benzoic acid Nutrition 0.000 claims description 5
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 5
- 229940008099 dimethicone Drugs 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 229940049964 oleate Drugs 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920000058 polyacrylate Chemical group 0.000 claims description 5
- 239000004584 polyacrylic acid Chemical group 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910052712 strontium Inorganic materials 0.000 claims description 5
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 150000003866 tertiary ammonium salts Chemical class 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229920006243 acrylic copolymer Chemical group 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052762 osmium Inorganic materials 0.000 claims description 4
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 150000005846 sugar alcohols Chemical group 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Chemical group 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical group 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 150000002222 fluorine compounds Chemical class 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002497 iodine compounds Chemical class 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Chemical group 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 2
- 230000035939 shock Effects 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052713 technetium Inorganic materials 0.000 claims description 2
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 239000002537 cosmetic Substances 0.000 abstract description 5
- 239000000919 ceramic Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 description 20
- 238000012544 monitoring process Methods 0.000 description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000000945 filler Substances 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 6
- QPBYLOWPSRZOFX-UHFFFAOYSA-J tin(iv) iodide Chemical compound I[Sn](I)(I)I QPBYLOWPSRZOFX-UHFFFAOYSA-J 0.000 description 6
- 241000790917 Dioxys <bee> Species 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 125000004423 acyloxy group Chemical group 0.000 description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 description 3
- 229910021630 Antimony pentafluoride Inorganic materials 0.000 description 3
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 239000005751 Copper oxide Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 3
- 239000004110 Zinc silicate Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 description 3
- DNWNZRZGKVWORZ-UHFFFAOYSA-N calcium oxido(dioxo)vanadium Chemical compound [Ca+2].[O-][V](=O)=O.[O-][V](=O)=O DNWNZRZGKVWORZ-UHFFFAOYSA-N 0.000 description 3
- 235000012241 calcium silicate Nutrition 0.000 description 3
- BIOOACNPATUQFW-UHFFFAOYSA-N calcium;dioxido(dioxo)molybdenum Chemical compound [Ca+2].[O-][Mo]([O-])(=O)=O BIOOACNPATUQFW-UHFFFAOYSA-N 0.000 description 3
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 3
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 3
- 229910000431 copper oxide Inorganic materials 0.000 description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
- ZOIVSVWBENBHNT-UHFFFAOYSA-N dizinc;silicate Chemical compound [Zn+2].[Zn+2].[O-][Si]([O-])([O-])[O-] ZOIVSVWBENBHNT-UHFFFAOYSA-N 0.000 description 3
- 229910000373 gallium sulfate Inorganic materials 0.000 description 3
- SBDRYJMIQMDXRH-UHFFFAOYSA-N gallium;sulfuric acid Chemical compound [Ga].OS(O)(=O)=O SBDRYJMIQMDXRH-UHFFFAOYSA-N 0.000 description 3
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 3
- DFIPXJGORSQQQD-UHFFFAOYSA-N hafnium;tetrahydrate Chemical compound O.O.O.O.[Hf] DFIPXJGORSQQQD-UHFFFAOYSA-N 0.000 description 3
- 229910003437 indium oxide Inorganic materials 0.000 description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical class [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 3
- IUJMNDNTFMJNEL-UHFFFAOYSA-K iridium(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[Ir+3] IUJMNDNTFMJNEL-UHFFFAOYSA-K 0.000 description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 229940099596 manganese sulfate Drugs 0.000 description 3
- 239000011702 manganese sulphate Substances 0.000 description 3
- 235000007079 manganese sulphate Nutrition 0.000 description 3
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- WPCMRGJTLPITMF-UHFFFAOYSA-I niobium(5+);pentahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[Nb+5] WPCMRGJTLPITMF-UHFFFAOYSA-I 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- DYRWWVFQQONJJK-UHFFFAOYSA-K scandium(3+);phosphate Chemical compound [Sc+3].[O-]P([O-])([O-])=O DYRWWVFQQONJJK-UHFFFAOYSA-K 0.000 description 3
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 3
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 3
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 3
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 3
- 229910052917 strontium silicate Inorganic materials 0.000 description 3
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 3
- ZIRLXLUNCURZTP-UHFFFAOYSA-I tantalum(5+);pentahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[Ta+5] ZIRLXLUNCURZTP-UHFFFAOYSA-I 0.000 description 3
- IOWOAQVVLHHFTL-UHFFFAOYSA-N technetium(vii) oxide Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Tc+7].[Tc+7] IOWOAQVVLHHFTL-UHFFFAOYSA-N 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 3
- 235000019352 zinc silicate Nutrition 0.000 description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- XSXHWVKGUXMUQE-UHFFFAOYSA-N dioxoosmium Chemical compound O=[Os]=O XSXHWVKGUXMUQE-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910000018 strontium carbonate Inorganic materials 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GATXPHDUDVSRCV-UHFFFAOYSA-N [Cl].[Cd] Chemical compound [Cl].[Cd] GATXPHDUDVSRCV-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- UKCFNZXJZBAZFS-UHFFFAOYSA-N carbonic acid;strontium Chemical compound [Sr].OC(O)=O UKCFNZXJZBAZFS-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000010423 industrial mineral Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 150000002736 metal compounds Chemical group 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical compound [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000037394 skin elasticity Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/405—Compounds of aluminium containing combined silica, e.g. mica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The present invention relates to a kind of mica powders that nano inorganic-is organic coated, in the substance, mica is core, nano metal chemical combination object is middle layer, the organic surface modifying agent of nano thickness is shell, the quality of the nano-oxide is the 0.01-2% of mica quality, and the quality of the organic surface modifying agent is the 0.01-2% of mica quality.The raw powder's production technology are as follows: put into mica in coating reaction unit, coating reaction first is carried out together with the nano-inorganic substance that partial size is 20-200nm as underlying carrier, again with organic surface modifying agent carry out it is membrane wrapping modified and control membrane wrapping thickness 20-200nm to get.The present invention improves its heat resistance, chemical resistance, dispersibility and other performances by membrane wrapping modified to mica, enables to be applied to the industries such as rubber plastic, coating, ceramics, cosmetics, and improve respective material performance.
Description
Technical field
The present invention relates to chemical fields, and in particular to a kind of mica powder that nano inorganic-is organic coated and its preparation side
Method.
Background technique
Mica is a kind of rock-forming mineral, generally in false six sides or plate, sheet, the column crystalline form of diamond shape.Mica Group Minerals
In the most common mineral have biotite, muscovite, phlogopite, lepidolite, sericite etc..The chemical general formula of Mica Group is X { Y2-3
[Z4O10](OH)2, wherein X group cation is mainly K+Ion has Na sometimes+、Ca2+、Ba2+Ion etc., Y group cation are main
It is Al, Fe, Mg, Z group cation is mainly situated in the Si and Al of oxygen-octahedron layer, and general Al: Si=1: 3, there are Fe, Cr sometimes
Substitution.Mica has the good characteristics such as gloss, heat-resisting, corrosion-resistant, insulation, physical and chemical performance stabilization, is widely used in rubber plastic
The industries such as material, ceramics, coating, papermaking, paint, electrical isolation, cosmetics.
In rubber industry, mica has preferable performance in terms of product lubrication and demoulding；The mica in gum filler
It is that other substances cannot compare with reinforcing effect.In plastics industry, mica has increment and modifying function, can mention
The heat-resisting of high product, acid and alkali-resistance, weatherability electrical insulating property, anti-aging and impermeabilisation reduce shrinking percentage and warpage.In coating work
In industry, mica can make coating improve dispersibility as pigments and fillers, reduce settleability, improve storage stability and brushing performance, together
When also there is certain thickening and thixotropic transformation.Mica is added in cosmetics, have increase skin elasticity, it is sun-proof, brighten, drop
The effect of low cost.Characteristic and application field based on mica, mica has broad application prospects and market potential, is novel
One of multi-functional industrial mineral.
In the relevant public technology report of existing mica, Chinese patent CN1765805A provides a kind of conductive sericite powder
Preparation method, its main feature is that sericite in powder surface coat semiconductor material, to have the function that antistatic；Chinese patent
CN10120117A provides a kind of sericite/TiO with pigmentary titanium dioxide property2Composite material and preparation method makes
It is packet core matrix with GOOD TASTE sericite powder, crystallizes TiO2Tool is thus prepared in wet ultra-fine grinding system for coating object
There is sericite/TiO of pigmentary titanium dioxide property2Composite material；
Inventor has found in working practices in the relevant experiment of mica, production and application test etc., mica it is resistance to
Hot, stability, dispersion performance, which are applied to performance, important influence, and the present invention provides a kind of pair of mica powder and carries out nanometer
The Thoughts of inorganic-organic bilayer coating, the organic coated mica powder of the nano inorganic-of acquisition, are applied in rubber, coating
The industrial circles such as ink, ceramics, cosmetics significantly improve related application performance.
Summary of the invention
In view of the above-mentioned defects in the prior art and insufficient, the present invention provides a kind of mica powder that nano inorganic-is organic coated
Body and preparation method thereof, by being modified using nano inorganic-is organic coated to mica, to improve the heat resistance, steady of mica
Qualitative, dispersion performance and other application performances enable to be applied to the industry such as coating and printing ink, rubber, catalyst, polishing agent
In, and improve respective material performance.The object of the present invention is achieved by the following technical solutions:
A kind of mica powder that nano inorganic-is organic coated, in the powder, mica is core, nano metal chemical combination object
For middle layer, the organic surface modifying agent of nano thickness is shell, and the quality of the nano-oxide is the 0.01- of mica quality
2%, the quality of the organic acid is the 0.01-2% of mica quality.
The mica is biotite, phlogopite, muscovite, lepidolite, sericite, euchlorite, one in zinnwaldite
Kind or more than one mixture.
The nano metal chemical combination object be magnesium, aluminium, calcium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, germanium,
Strontium, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, palladium, silver, cadmium, indium, tin, antimony, barium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, lead, bismuth chemical combination
One of object or more than one mixture.
The nano metal compound form is simple substance, oxide, hydroxide, fluorine compounds, chlorine compound, bromination
Close object, iodine compound, sulphate, carbonate compound, nitrate compound, phosphate cpd, silicate compound, aluminic acid chemical combination
One of object, vanadic acid compound, molybdic acid compound, ferrous acid compound, chromic acid compound or a variety of mixing.
The organic surface modifying agent is titanate esters, Aluminate, amino silane, epoxy radicals silicone hydride, sulfenyl silane, ethoxy
It is base silane, methyl-propyl acyloxy silane, silanol, stearic acid, stearate, sulfonate, sulphonic acid ester, alkyl benzene sulphonate, advanced
Phosphate ester salt, primary amine salt, secondary amine salt, tertiary ammonium salt, quaternary amine, polyethylene glycol, polyalcohol, polyacrylic acid, polyacrylate, poly- third
Olefin(e) acid copolymer, polyvinyl alcohol, poly, dimethicone, methyl-silicone oil, hydroxy silicon oil, containing hydrogen silicone oil, unsaturation poly- third
Alkene, polyethylene wax, epoxy resin, alkyd resin, ethyl orthosilicate, acrylic acid, methacrylic acid, butenoic acid, maleic acid, chlorine third
Olefin(e) acid, oleic acid, oleate, benzoic acid, phthalic acid, phthalic acid ester, phthalandione, phthalate ester, isophathalic acid, isophthalic ester,
One of 1-hydroxy ethylidene-1,1-diphosphonic acid or more than one mixture.
The preparation method is the following steps are included: the nanometer for being first 20-200nm with partial size as underlying carrier using mica
Inorganic matter carries out coating reaction together, then carries out membrane wrapping modified with organic surface modifying agent and control membrane wrapping thickness in 20-
Mica powder 200nm organic coated to get nano inorganic-.
The temperature of coating reaction twice is between -80 DEG C to 300 DEG C in the coating device, and the time is 2-480
Minute.
The coating reaction unit is ball mill, rod mill, Raymond mill, vibromill, mechanical shock formula grinding machine, stirring
Mill, sand mill, overhang roll mill, pressure roller mill, colloid mill, nanometer mill, eddy mill, airslide disintegrating mill, grinding machine for cutting charge into pieces in one
Kind.
The invention has the benefit that
By carrying out the double-deck coating to mica using nanometer empty and organic modifiers, to be modified to mica, eliminate
Drawbacks described above disperses it easily, improves its anti-corrosive properties, chemical resistance, prolongs its service life, and overcomes the prior art not
Foot.Nano-inorganic substance is capable of providing good anti-corrosive properties and stronger chemical-resistance as middle layer, and nano thickness is organic
Modifying agent enables to powder to have better dispersibility, convenient for merge with major ingredient in practical applications, is easy to disperse and not
Lamination can occur.The present inventor passes through lot of experiments, so that mica can be applied to above-mentioned material, to mention
The performances such as anti-corrosion, thermostabilization, the weather-proof, service life of high respective material.The organic coated mica of nano inorganic-and non-coating
Comparative experimental data is as follows: mica in practical applications
Specific embodiment
The present invention is further illustrated below by embodiment.It should be understood that the embodiment of the present invention is for illustrating
The present invention is rather than limiting the invention.The simple modifications that essence according to the present invention carries out the present invention belong to the present invention
Claimed range.
Embodiment 1
In a kind of organic coated mica powder of nano inorganic-of the present invention, lepidolite is core, strontium hydroxide, hydrogen
The mixture of calcium oxide is middle layer, the ethyl orthosilicate of nano thickness, silanol mixture be shell, the strontium hydroxide,
The quality of the mixture of calcium hydroxide is the 0.55% of the quality of lepidolite, the mixture of the ethyl orthosilicate, silanol
Quality is the 0.36% of lepidolite quality.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg lepidolite is put into grinding machine for cutting charge into pieces, as the strontium hydroxide that underlying carrier and 0.55kg partial size are 40nm,
The mixture of calcium hydroxide carries out coating reaction, and the temperature of reaction is 80 DEG C, and the time is 110 minutes, then puts into 0.36kg just
The mixture of silester, silanol, the reaction time 150 minutes, the temperature of reaction was 105 DEG C, film thickness monitoring 55nm to get.
Embodiment 2
In a kind of organic coated mica powder of nano inorganic-of the present invention, zinnwalditum, phlogopite are core, chlorine
Cadmium, stannic iodide, copper oxide mixture be middle layer, the titanate esters of nano thickness, polyacrylate, unsaturated polypropylene mixing
Object is shell, the caddy, stannic iodide, copper oxide mixture quality be zinnwalditum, phlogopite quality
1.38%, the titanate esters, polyacrylate, unsaturated polyacrylic mixture quality be zinnwalditum, phlogopite matter
The 0.8% of amount.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
It is 190nm as underlying carrier and 1.38kg partial size by 100kg zinnwalditum, phlogopite investment grinding machine for cutting charge into pieces
Caddy, stannic iodide, copper oxide mixture carry out coating reaction, the temperature of reaction is -80 DEG C, and the time is 30 minutes, then
The titanate esters of investment 0.01kg, polyacrylate, unsaturated polyacrylic mixture, the reaction time 455 minutes, the temperature of reaction
Be 25 DEG C, film thickness monitoring 165nm to get.
Embodiment 3
In a kind of organic coated mica powder of nano inorganic-of the present invention, euchlorite, sericite, biotite are
Core, pucherite, silver chlorate, strontium titanates mixture be middle layer, the advanced phosphate ester salt of nano thickness, the mixture of quaternary ammonium salt are
Shell, the pucherite, silver chlorate, strontium titanates mixture quality be euchlorite, sericite, biotite quality
2%, the advanced phosphate ester salt, quaternary ammonium salt the quality of mixture be euchlorite, sericite, biotite quality
0.59%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg euchlorite, sericite, biotite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 2kg partial size
The mixture progress coating reaction of the pucherite, silver chlorate, strontium titanates of 180nm, the temperature of reaction is 300 DEG C, and the time is 2 points
Clock, then the mixture of the advanced phosphate ester salt of 0.59kg, quaternary ammonium salt is put into, the reaction time 315 minutes, the temperature of reaction was 0 DEG C,
Film thickness monitoring 175nm to get.
Embodiment 4
In a kind of organic coated mica powder of nano inorganic-of the present invention, sericite is core, zinc molybdate, dioxy
The mixture of SiClx is middle layer, and the phthalic acid of nano thickness, the mixture of alkyl benzene sulphonate are shell, the molybdic acid
Zinc, silica mixture quality be sericite quality 0.85%, the phthalic acid, alkyl benzene sulphonate
The quality of mixture is the 1.1% of quality of sericite.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg sericite is put into grinding machine for cutting charge into pieces, is the zinc molybdate of 60nm, two as underlying carrier and 0.85kg partial size
The mixture of silica carries out coating reaction, and the temperature of reaction is 120 DEG C, and the time is 135 minutes, then puts into the adjacent benzene of 1.1kg
The mixture of dioctyl phthalate, alkyl benzene sulphonate, the reaction time 100 minutes, the temperature of reaction was 95 DEG C, and film thickness monitoring is in 40nm, i.e.,
.
Embodiment 5
In a kind of organic coated mica powder of nano inorganic-of the present invention, muscovite, lepidolite are core, phosphoric acid
Zinc, magnesium hydroxide, aluminum oxide mixture be middle layer, the phthalic acid ester of nano thickness, benzoic acid, polyethylene glycol
Mixture is shell, the trbasic zinc phosphate, magnesium hydroxide, aluminum oxide the quality of mixture be muscovite, lepidolite
The 0.85% of quality, the phthalic acid ester, benzoic acid, polyethylene glycol mixture quality be muscovite, lepidolite
The 1.1% of quality.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg muscovite, lepidolite investment grinding machine for cutting charge into pieces, the phosphorus for being 90nm as underlying carrier and 0.85kg partial size
The mixture progress coating reaction of sour zinc, magnesium hydroxide, aluminum oxide, the temperature of reaction is 100 DEG C, and the time is 180 minutes,
Put into the mixture of the phthalic acid ester of 1.1kg, benzoic acid, polyethylene glycol again, the reaction time 270 minutes, the temperature of reaction
Be 125 DEG C, film thickness monitoring 95nm to get.
Embodiment 6
In a kind of organic coated mica powder of nano inorganic-of the present invention, biotite is core, nickel nitrate, chlorination
Barium, ruthenium powder, niobium (Nb) pentafluoride mixture be middle layer, the epoxy radicals silicone hydride of nano thickness, stearate, oleic acid mixture be outer
Shell, the nickel nitrate, barium chloride, ruthenium powder, niobium (Nb) pentafluoride mixture quality be biotite quality 0.01%, it is described
Epoxy radicals silicone hydride, stearate, oleic acid mixture quality be biotite matrix amount 1.64%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg biotite is put into grinding machine for cutting charge into pieces, as the nickel nitrate that underlying carrier and 0.01kg partial size are 200nm,
The mixture progress coating reaction of barium chloride, ruthenium powder, niobium (Nb) pentafluoride, the temperature of reaction is -60 DEG C, and the time is 55 minutes, then is thrown
Entering the mixture of the epoxy radicals silicone hydride of 1.64kg, stearate, oleic acid, the reaction time 480 minutes, the temperature of reaction was -80 DEG C,
Film thickness monitoring 190nm to get.
Embodiment 7
In a kind of organic coated mica powder of nano inorganic-of the present invention, muscovite is core, zirconium oxide, carbonic acid
Strontium, titanium tetrachloride, manganese sulfate mixture be middle layer, the 1-hydroxy ethylidene-1,1-diphosphonic acid of nano thickness, poly, primary amine salt it is mixed
Conjunction object is shell, the zirconium oxide, strontium carbonate, titanium tetrachloride, manganese sulfate mixture quality be muscovite quality
0.63%, the 1-hydroxy ethylidene-1,1-diphosphonic acid, poly, primary amine salt the quality of mixture be muscovite quality
0.27%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg muscovite is put into grinding machine for cutting charge into pieces, as the zirconium oxide that underlying carrier and 0.63kg partial size are 105nm,
The mixture progress coating reaction of strontium carbonate, titanium tetrachloride, manganese sulfate, the temperature of reaction is 60 DEG C, and the time is 240 minutes, then
Put into the 1-hydroxy ethylidene-1,1-diphosphonic acid of 0.27kg, poly, primary amine salt mixture, the reaction time 120 minutes, the temperature of reaction
Be 170 DEG C, film thickness monitoring 85nm to get.
Embodiment 8
In a kind of organic coated mica powder of nano inorganic-of the present invention, sericite, biotite, lepidolite are
Core, iron aluminate could, strontium silicate, zinc ferrite, three indium oxides mixture be middle layer, the containing hydrogen silicone oil of nano thickness, butenoic acid it is mixed
Conjunction object be shell, the iron aluminate could, strontium silicate, zinc ferrite, three indium oxides mixture quality be sericite, biotite,
The 1.91% of the quality of lepidolite, the containing hydrogen silicone oil, butenoic acid mixture quality be sericite, biotite, lithium cloud
The 2% of matrix amount.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg sericite, biotite, lepidolite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 1.91kg partial size
The mixture progress coating reaction of the iron aluminate could, strontium silicate, zinc ferrite, three indium oxides of 170nm, the temperature of reaction is -40 DEG C, when
Between be 265 minutes, then put into the mixture of the containing hydrogen silicone oil of 2kg, butenoic acid, the reaction time 2 minutes, the temperature of reaction was -70
DEG C, film thickness monitoring 200nm to get.
Embodiment 9
In a kind of organic coated mica powder of nano inorganic-of the present invention, euchlorite is core, pucherite, dioxy
Change titanium, plumbous chromate, cobalt hydroxide mixture be middle layer, the methyl-propyl acyloxy silane of nano thickness is shell, described
Pucherite, titanium dioxide, plumbous chromate, cobalt hydroxide mixture quality be euchlorite quality 0.13%, the first
The quality of base propyl acyloxy silane is the 1.75% of euchlorite quality.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg euchlorite is put into grinding machine for cutting charge into pieces, is the pucherite of 20nm, two as underlying carrier and 0.13kg partial size
The mixture progress coating reaction of titanium oxide, plumbous chromate, cobalt hydroxide, the temperature of reaction is 0 DEG C, and the time is 480 minutes, then is thrown
Enter the methyl-propyl acyloxy silane of 1.75kg, the reaction time 25 minutes, the temperature of reaction was -40 DEG C, and film thickness monitoring exists
145nm to get.
Embodiment 10
In a kind of organic coated mica powder of nano inorganic-of the present invention, zinnwaldite, biotite, muscovite
For core, calcium aluminate, iron oxide, titanyl sulfate, platinum chloride mixture be middle layer, the epoxy resin of nano thickness, chloracrylic acid,
Tertiary ammonium salt, sulfonate mixture be shell, the calcium aluminate, iron oxide, titanyl sulfate, platinum chloride mixture quality
It is the 1.8% of the quality of zinnwaldite, biotite, muscovite, the epoxy resin, chloracrylic acid, tertiary ammonium salt, sulfonate
The quality of mixture be zinnwaldite, biotite, muscovite quality 0.15%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg zinnwaldite, biotite, muscovite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 1.8kg partial size
The mixture progress coating reaction of the calcium aluminate, iron oxide, titanyl sulfate, platinum chloride of 160nm, the temperature of reaction is -20 DEG C, when
Between be 460 minutes, then put into the mixture of the epoxy resin of 0.15kg, chloracrylic acid, tertiary ammonium salt, sulfonate, reaction time 50
Minute, the temperature of reaction is 300 DEG C, film thickness monitoring 140nm to get.
Embodiment 11
In a kind of organic coated mica powder of nano inorganic-of the present invention, lepidolite, sericite are core, carbonic acid
Calcium, gallium sulfate, tungstic acid mixture be middle layer, methyl-silicone oil, alkyd resin, the polyvinyl paraffin wax mixture of nano thickness
For shell, the calcium carbonate, gallium sulfate, tungstic acid mixture quality be lepidolite, sericite quality
0.25%, the methyl-silicone oil, alkyd resin, polyvinyl paraffin wax the quality of mixture be lepidolite, quality of sericite
1.55%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg lepidolite, sericite investment grinding machine for cutting charge into pieces, the carbon for being 30nm as underlying carrier and 0.25kg partial size
The mixture progress coating reaction of sour calcium, gallium sulfate, tungstic acid, the temperature of reaction is 200 DEG C, and the time is 440 minutes, then is thrown
Enter the mixture of the methyl-silicone oil of 1.55kg, alkyd resin, polyvinyl paraffin wax, the reaction time 235 minutes, the temperature of reaction was
285 DEG C, film thickness monitoring 150nm to get.
Embodiment 12
In a kind of organic coated mica powder of nano inorganic-of the present invention, biotite, phlogopite, euchlorite are
Core, magnesium silicate, calcium vanadate, cobalt chloride mixture be middle layer, the polyalcohol of nano thickness, sulphonic acid ester, Ethoxysilane it is mixed
Conjunction object be shell, the magnesium silicate, calcium vanadate, cobalt chloride mixture quality be biotite, phlogopite, euchlorite matter
Amount 1.74%, the polyalcohol, sulphonic acid ester, Ethoxysilane mixture quality be biotite, phlogopite, euchlorite
The 1.87% of quality.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg biotite, phlogopite, euchlorite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 1.74kg partial size
The mixture progress coating reaction of the magnesium silicate, calcium vanadate, cobalt chloride of 50nm, the temperature of reaction is 140 DEG C, and the time is 210 points
Clock, then the mixture of the ethyl orthosilicate of 1.87kg, silanol is put into, the reaction time 295 minutes, the temperature of reaction was 140 DEG C, film
Thickness control 60nm to get.
Embodiment 13
In a kind of organic coated mica powder of nano inorganic-of the present invention, zinnwaldite, muscovite, sericite
For core, strontium chromate, zinc silicate, calcium molybdate mixture be middle layer, Aluminate, amino silane, acrylic acid, the phthalandione of nano thickness
Mixture be shell, the strontium chromate, zinc silicate, calcium molybdate mixture quality be zinnwaldite, muscovite, thin,tough silk cloud
The 0.34% of female quality, the Aluminate, amino silane, acrylic acid, phthalandione mixture quality be zinnwaldite, it is white
The 1.16% of mica, quality of sericite.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg zinnwaldite, muscovite, sericite investment grinding machine for cutting charge into pieces, as underlying carrier and 0.34kg partial size
Coating reaction is carried out for the mixture of the strontium chromate of 140nm, zinc silicate, calcium molybdate, the temperature of reaction is 280 DEG C, the time 80
Minute, then the mixture of the Aluminate of 1.16kg, amino silane, acrylic acid, phthalandione is put into, the reaction time 425 minutes, reaction
Temperature be 50 DEG C, film thickness monitoring 20nm to get.
Embodiment 14
In a kind of organic coated mica powder of nano inorganic-of the present invention, phlogopite is core, scandium phosphate, zirconium list
Matter, calcium silicates mixture be middle layer, the stearic acid of nano thickness, sulfenyl silane, secondary amine salt, maleic acid mixture be outer
Shell, the scandium phosphate, zirconium simple substance, calcium silicates mixture quality be phlogopite quality 0.46%, the tristearin
Acid, sulfenyl silane, secondary amine salt, maleic acid mixture quality be phlogopite quality 0.65%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg phlogopite is put into grinding machine for cutting charge into pieces, scandium phosphate, the zirconium for being 70nm as underlying carrier and 0.46kg partial size
The mixture progress coating reaction of simple substance, calcium silicates, the temperature of reaction is 160 DEG C, and the time is 370 minutes, then puts into 0.65kg
Stearic acid, sulfenyl silane, secondary amine salt, maleic acid mixture, the reaction time 210 minutes, the temperature of reaction was -65 DEG C, film
Thickness control 130nm to get.
Embodiment 15
In a kind of organic coated mica powder of nano inorganic-of the present invention, lepidolite, sericite are core, dioxy
Change germanium, the mixture of palladium chloride is middle layer, the methacrylic acid of nano thickness, isophathalic acid mixture be shell, described two
Germanium oxide, palladium chloride mixture quality be lepidolite, sericite quality 1.61%, it is the methacrylic acid, different
The quality of the mixture of phthalandione be lepidolite, quality of sericite 1.25%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
It is 100nm's as underlying carrier and 1.61kg partial size by 100kg lepidolite, sericite investment grinding machine for cutting charge into pieces
The mixture progress coating reaction of germanium dioxide, palladium chloride, the temperature of reaction is 20 DEG C, and the time is 420 minutes, then is put into
The mixture of the methacrylic acid of 1.25kg, isophathalic acid, the reaction time 75 minutes, the temperature of reaction was 260 DEG C, and film thickness monitoring exists
125nm to get.
Embodiment 16
In a kind of organic coated mica powder of nano inorganic-of the present invention, lepidolite, phlogopite, euchlorite are
Core, hydroxide iridium, molybdenum trioxide, antimony pentafluoride mixture be middle layer, the polyacrylic acid of nano thickness, advanced phosphate ester salt,
The mixture of oleate be shell, the hydroxide iridium, molybdenum trioxide, antimony pentafluoride mixture quality be lepidolite,
The 0.78% of the quality of phlogopite, euchlorite, the polyacrylic acid, advanced phosphate ester salt, oleate mixture quality
For lepidolite, phlogopite, euchlorite quality 1.49%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg lepidolite, phlogopite, euchlorite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 0.78kg partial size
The hydroxide iridium of 80nm, molybdenum trioxide, antimony pentafluoride mixture carry out coating reaction, the temperature of reaction is 180 DEG C, and the time is
290 minutes, then the mixture of the polyacrylic acid of 1.49kg, advanced phosphate ester salt, oleate is put into, the reaction time 175 minutes, instead
The temperature answered be 245 DEG C, film thickness monitoring 70nm to get.
Embodiment 17
In a kind of organic coated mica powder of nano inorganic-of the present invention, zinnwaldite is core, chromium sulfate, five
V 2 O, yttrium nitrate mixture be middle layer, the acrylic copolymer of nano thickness, the mixture of dimethicone are outer
Shell, the chromium sulfate, vanadic anhydride, yttrium nitrate mixture quality be zinnwaldite quality 0.97%, it is described
Acrylic copolymer, dimethicone mixture quality be zinnwaldite quality 0.42%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg zinnwaldite is put into grinding machine for cutting charge into pieces, the sulfuric acid for being 150nm as underlying carrier and 0.97kg partial size
The mixture progress coating reaction of chromium, vanadic anhydride, yttrium nitrate, the temperature of reaction is 40 DEG C, and the time is 400 minutes, then is thrown
Enter the acrylic copolymer of 0.42kg, the mixture of dimethicone, the reaction time 190 minutes, the temperature of reaction was -15
DEG C, film thickness monitoring 25nm to get.
Embodiment 18
In a kind of organic coated mica powder of nano inorganic-of the present invention, sericite, lepidolite, biotite are
Core, technetium oxide, tantalum hydroxide, niobium hydroxide mixture be middle layer, the mixture of the hydroxy silicon oil of nano thickness, isophthalic ester
For shell, the technetium oxide, tantalum hydroxide, niobium hydroxide mixture quality be sericite, lepidolite, biotite matter
The 1.23% of amount, the hydroxy silicon oil, isophthalic ester the quality of mixture be sericite, lepidolite, biotite quality
0.95%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg sericite, lepidolite, biotite investment grinding machine for cutting charge into pieces, it is as underlying carrier and 1.23kg partial size
The technetium oxide of 130nm, tantalum hydroxide, niobium hydroxide mixture carry out coating reaction, the temperature of reaction is 260 DEG C, and the time is
150 minutes, then put into the mixture of the hydroxy silicon oil of 0.95kg, isophthalic ester, the reaction time 370 minutes, the temperature of reaction was
75 DEG C, film thickness monitoring 100nm to get.
Embodiment 19
In a kind of organic coated mica powder of nano inorganic-of the present invention, muscovite, phlogopite are core, dioxy
Change osmium, the mixture of copper chloride is middle layer, the sulphonic acid ester of nano thickness, polyethylene glycol mixture be shell, the dioxy
Change osmium, copper chloride mixture quality be muscovite, phlogopite quality 1.42%, the sulphonic acid ester, polyethylene glycol
Mixture quality be muscovite, phlogopite quality 0.73%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
It is 110nm's as underlying carrier and 1.42kg partial size by 100kg muscovite, phlogopite investment grinding machine for cutting charge into pieces
The mixture progress coating reaction of osmium dioxide, copper chloride, the temperature of reaction is 220 DEG C, and the time is 345 minutes, then is put into
The mixture of the sulphonic acid ester of 0.73kg, polyethylene glycol, the reaction time 340 minutes, the temperature of reaction was 195 DEG C, and film thickness monitoring exists
35nm to get.
Embodiment 20
In a kind of organic coated mica powder of nano inorganic-of the present invention, zinnwaldite, euchlorite are core, chlorine
Change gold, the mixture of hafnium hydroxide is middle layer, the silanol of nano thickness, alkyl benzene sulphonate, amino silane mixture be shell,
The quality of the mixture of the chlorauride, hafnium hydroxide be zinnwaldite, euchlorite quality 1.5%, the silanol,
Alkyl benzene sulphonate, amino silane mixture quality be zinnwaldite, euchlorite quality 1.32%.
The organic coated mica powder of nano inorganic-of the present invention, preparation method includes the following steps:
It is 120nm as underlying carrier and 1.23kg partial size by 100kg zinnwaldite, euchlorite investment grinding machine for cutting charge into pieces
Chlorauride, hafnium hydroxide mixture carry out coating reaction, the temperature of reaction is 240 DEG C, and the time is 320 minutes, then is put into
The silanol of 1.32kg, alkyl benzene sulphonate, amino silane mixture, the reaction time 400 minutes, the temperature of reaction was 220 DEG C, film
Thickness control 160nm to get.
Products application test:
Experimental example 1
1,3,9 products application of the embodiment of the present invention is applied in rubber in as filler material, dispersibility, compatibility are good,
The mica of non-coating is added in comparison, can significantly improve rubber UV resistant performance and ozone resistance.In accelerated test, rubber
Product UV resistant can extend 36 hours or more, and resistance to ozone can extend 36 hours or more.
Experimental example 2
2,4,18 products application of the embodiment of the present invention is applied in coating and printing ink in as filler material, it is evenly dispersed, easy
In toning, the mica of non-coating is added in comparison, resistance to 5% hydrochloric acid and the raising of 5% sodium hydroxide 36 hours or more.
Experimental example 3
By 7,11,13 products application of the embodiment of the present invention in as filler material be applied to ceramics in, it is evenly dispersed and other
Filler compatibility is good, and the mica of non-coating is added in comparison, and flexural strength improves 50MPa or more.
Experimental example 4
8,15,16 products application of the embodiment of the present invention is applied in cosmetics in as filler material, comparison addition is not wrapped
The mica of film, dispersibility, whiteness, covering power, glossiness are all significantly increased.
Although above having used general explanation, specific embodiment and test, the present invention is made to retouch in detail
State, but on the basis of the present invention, to it make it is some modify or improve, this is apparent to those skilled in the art
's.Therefore, without departing from spirit of that invention
On the basis of these modifications or improvements, fall within the scope of the claimed invention.
Claims (8)
1. a kind of mica powder that nano inorganic-is organic coated, it is characterised in that: in the powder, mica is core, nanogold
Category compound is middle layer, and the organic surface modifying agent of nano thickness is shell, and the quality of the nano-oxide is mica matter
The 0.01-2% of amount, the quality of the organic acid are the 0.01-2% of mica quality.
2. the organic coated mica powder of nano inorganic-according to claim 1, it is characterised in that: the mica is
One of biotite, phlogopite, muscovite, lepidolite, sericite, euchlorite, zinnwaldite or more than one mixture.
3. the organic coated mica powder of nano inorganic-according to claim 1, it is characterised in that: the nanogold
Category compound be magnesium, aluminium, calcium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, germanium, strontium, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium,
Palladium, silver, cadmium, indium, tin, antimony, barium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, lead, bismuth one of compound or more than one
Mixture.
4. the organic coated mica powder of nano inorganic-according to claim 3, it is characterised in that: the nanogold
Category compound form is simple substance, oxide, hydroxide, fluorine compounds, chlorine compound, bromine compounds, iodine compound, sulphation
Close object, carbonate compound, nitrate compound, phosphate cpd, silicate compound, aluminic acid compound, vanadic acid compound, Molybdated
Close one of object, ferrous acid compound, chromic acid compound or a variety of mixing.
5. the organic coated mica powder of nano inorganic-according to claim 1, it is characterised in that: organic table
Face modifying agent is titanate esters, Aluminate, amino silane, epoxy radicals silicone hydride, sulfenyl silane, Ethoxysilane, methyl-propyl acyl-oxygen
Base silane, silanol, stearic acid, stearate, sulfonate, sulphonic acid ester, alkyl benzene sulphonate, advanced phosphate ester salt, primary amine salt, secondary amine
Salt, tertiary ammonium salt, quaternary amine, polyethylene glycol, polyalcohol, polyacrylic acid, polyacrylate, acrylic copolymer, polyvinyl alcohol,
Poly, dimethicone, methyl-silicone oil, hydroxy silicon oil, containing hydrogen silicone oil, unsaturated polypropylene, polyethylene wax, asphalt mixtures modified by epoxy resin
Rouge, alkyd resin, ethyl orthosilicate, acrylic acid, methacrylic acid, butenoic acid, maleic acid, chloracrylic acid, oleic acid, oleate,
Benzoic acid, phthalic acid, phthalic acid ester, phthalandione, phthalate ester, isophathalic acid, isophthalic ester, in 1-hydroxy ethylidene-1,1-diphosphonic acid
One or more kinds of mixtures.
6. the organic coated mica powder of nano inorganic-according to claim 1-4, which is characterized in that it is made
Preparation Method using mica as underlying carrier together with the nano-inorganic substance that partial size is 20-200nm the following steps are included: first wrap
Film reaction, then carry out membrane wrapping modified with organic surface modifying agent and control membrane wrapping thickness and have in 20-200nm to get nano inorganic-
The mica powder of machine coating.
7. the organic coated mica powder of nano inorganic-according to claim 5, it is characterised in that: the coating dress
The temperature for setting coating reaction twice is between -80 DEG C to 300 DEG C, and the time is 2-480 minutes.
8. the organic coated mica powder of nano inorganic-according to claim 5, it is characterised in that: the coating is anti-
Answering device is ball mill, rod mill, Raymond mill, vibromill, mechanical shock formula grinding machine, Ball-stirring mill, sand mill, overhang roll mill, pressure roller
Mill, two roller mills, three-roll grinder, colloid mill, nanometer mill, eddy mill, airslide disintegrating mill, grinding machine for cutting charge into pieces in one
Kind.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113045911A (en) * | 2021-03-03 | 2021-06-29 | 滁州格锐矿业有限责任公司 | Processing method of sericite powder for rubber filler |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4084983A (en) * | 1974-06-21 | 1978-04-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Dyed lustrous pigments |
| CN101210117A (en) * | 2006-12-25 | 2008-07-02 | 中国地质大学（北京） | Sericite/TiO2 composite material with white pigment property |
| CN101679768A (en) * | 2007-05-02 | 2010-03-24 | 巴斯夫欧洲公司 | Reinforced metal oxide flakes for effect pigments |
| CN102015914A (en) * | 2008-05-09 | 2011-04-13 | 巴斯夫欧洲公司 | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
| CN102746716A (en) * | 2012-07-12 | 2012-10-24 | 杭州弗沃德精细化工有限公司 | Preparation process of superfine coloring mica pigment |
| CN105199147A (en) * | 2014-06-15 | 2015-12-30 | 成都棕通石油配件有限公司 | Preparation method of modified mica powder for rubber packing |
| CN106947297A (en) * | 2017-01-23 | 2017-07-14 | 广西新晶科技有限公司 | Poly aluminium phosphate powder of nano-oxide organic acid coating and preparation method thereof |
-
2019
- 2019-06-28 CN CN201910586961.8A patent/CN110408240A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4084983A (en) * | 1974-06-21 | 1978-04-18 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Dyed lustrous pigments |
| CN101210117A (en) * | 2006-12-25 | 2008-07-02 | 中国地质大学（北京） | Sericite/TiO2 composite material with white pigment property |
| CN101679768A (en) * | 2007-05-02 | 2010-03-24 | 巴斯夫欧洲公司 | Reinforced metal oxide flakes for effect pigments |
| CN102015914A (en) * | 2008-05-09 | 2011-04-13 | 巴斯夫欧洲公司 | Pearlescent pigments coated with a metal oxide/hydroxide layer and an acrylic copolymer |
| CN102746716A (en) * | 2012-07-12 | 2012-10-24 | 杭州弗沃德精细化工有限公司 | Preparation process of superfine coloring mica pigment |
| CN105199147A (en) * | 2014-06-15 | 2015-12-30 | 成都棕通石油配件有限公司 | Preparation method of modified mica powder for rubber packing |
| CN106947297A (en) * | 2017-01-23 | 2017-07-14 | 广西新晶科技有限公司 | Poly aluminium phosphate powder of nano-oxide organic acid coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113045911A (en) * | 2021-03-03 | 2021-06-29 | 滁州格锐矿业有限责任公司 | Processing method of sericite powder for rubber filler |
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