CN110397913A - A kind of furfural dregs Denitration in Boiler system effectively improving denitration efficiency - Google Patents

A kind of furfural dregs Denitration in Boiler system effectively improving denitration efficiency Download PDF

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Publication number
CN110397913A
CN110397913A CN201910719625.6A CN201910719625A CN110397913A CN 110397913 A CN110397913 A CN 110397913A CN 201910719625 A CN201910719625 A CN 201910719625A CN 110397913 A CN110397913 A CN 110397913A
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CN
China
Prior art keywords
boiler
denitration
furfural dregs
belt machine
charging belt
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Pending
Application number
CN201910719625.6A
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Chinese (zh)
Inventor
范子久
王培晓
王新法
杜习军
王辉
***
徐煜中
张永宾
张建军
王力保
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Xinxiang Huineng Yuyuan Power Generation Co Ltd
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Xinxiang Huineng Yuyuan Power Generation Co Ltd
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Priority to CN201910719625.6A priority Critical patent/CN110397913A/en
Publication of CN110397913A publication Critical patent/CN110397913A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C10/00Fluidised bed combustion apparatus
    • F23C10/18Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J7/00Arrangement of devices for supplying chemicals to fire
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • F23J2215/101Nitrous oxide (N2O)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)

Abstract

The invention discloses the furfural dregs Denitration in Boiler systems that one kind can effectively improve denitration efficiency, including blanking funnel, boiler charging belt machine, boiler, spray purification tower, ammonia water tank and control cabinet, the transmission initial end top of boiler charging belt machine is arranged in blanking funnel, the transmission end of boiler charging belt machine is connect with boiler feeding end, and the upper end of boiler is equipped with smoke exhaust pipe.The adjustment that the present invention passes through the working of a furnaces such as test adjustment one Secondary Air proportion, to improve denitration efficiency, after a series of behaves such as addition inert material firing optimization, finally realize the minimum discharge of online NOx, reach 30mg/nm3 or less, by increasing inert material and scraper stirring, complete the reaction of partial denitrification ammonia nitrogen early period, in denitration workshop section, by repetition test, 150 titres also are reduced to by 210 titres in the use of ammonium hydroxide, greatly reduce cost, SO2 has also been down to minimum discharge standard in flue gas simultaneously, eliminates the costs such as the calcium oxide of desulfurization.

Description

A kind of furfural dregs Denitration in Boiler system effectively improving denitration efficiency
Technical field
The present invention relates to technical field of waste gas treatment, specially a kind of furfural dregs boiler that can effectively improve denitration efficiency is de- Nitre system.
Background technique
Furfural dregs are remaining solid waste after adding sulphuric acid hydrolysis by corncob, and furfural dregs are as biomass water solution preocess The waste of middle generation, salt content is high, is in acidity, and bulk deposition can generate pollution to atmosphere, soil, river, therefore Existing technology is that furfural dregs are carried out burning processing mostly.
But existing technical disadvantages:
1, existing furfural dregs humidity is larger, and direct burning boiler load is larger, and furfural dregs easily bond, and easily makes pot by burning Furnace is unstable and flue easily blocks.
2, existing furfural dregs are remaining solid waste after adding sulphuric acid hydrolysis by corncob, contain portion in furfural dregs Divide sulfuric acid, easily causes sulfur dioxide emissioning concentration higher after furfural dregs burning, 35mg/m3 cannot be reached hereinafter, being unable to flue gas The index request of online minimum discharge.
3, furfural dregs directly burn because furfural dregs moisture content is higher, cause water content in flue gas higher, in denitrating system When spraying ammonium hydroxide, ammonium hydroxide titre is made to require index higher, but cannot be reacted completely again after being contacted with water content, causes the wave of ammonium hydroxide Take, while nitrogen oxides in effluent content is higher, cannot reach and meet the needs of environmentally friendly 50mg/m3.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides the furfural dregs Denitration in Boiler systems that one kind can effectively improve denitration efficiency System solves the problem of furfural dregs combustion denitration low efficiency, smoke evacuation is unable to reach the technology of environmental requirement.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme: a kind of furfural dregs boiler that can effectively improve denitration efficiency Denitrating system, including blanking funnel, boiler charging belt machine, boiler, spray purification tower, ammonia water tank and control cabinet, blanking funnel The transmission initial end top of boiler charging belt machine is set, and the transmission end and boiler feeding end of boiler charging belt machine connect It connects, the upper end of boiler is equipped with smoke exhaust pipe, and the other end of smoke exhaust pipe is connect with the spray purification tower that boiler side is arranged in, spray The other side of purifying column is provided with ammonia water tank, and ammonia water pipe is equipped between ammonia water tank and spray purification tower, is equipped on ammonia water pipe Aqua ammonia pump, the top of boiler charging belt machine along boiler charging belt machine transmission direction be disposed with boiler ash setting gauge and Agstone setting gauge, boiler ash setting gauge and agstone setting gauge include U-shaped material toggling storehouse, supporting leg, rotating roller, center Axis, material toggling motor, material stirring disc and discharge port, the bottom end in U-shaped material toggling storehouse are welded with supporting leg, and the inside in U-shaped material toggling storehouse, which is equipped with, to be turned Dynamic roller, the centre of rotating roller are plugged with central axis, one end of central axis and the material toggling machine shaft for being mounted on U-shaped material toggling storehouse outer end It is fixedly connected, the outer end equal part of rotating roller is provided with material stirring disc, and the bottom end in U-shaped material toggling storehouse offers discharge port, the bottom of boiler It is connected with primary air fan, the side of boiler is connected with secondary air fan, and the bottom of boiler charging belt machine is arranged in control cabinet, control Case is electrically connected with boiler ash setting gauge and agstone setting gauge, primary air fan, secondary air fan and aqua ammonia pump respectively.
Preferably, spray purification tower includes tower body and the wet scrubber that is arranged in inside tower body.
Preferably, the inside of boiler is being respectively arranged with the first blast cap and second with primary air fan and secondary air fan junction Blast cap.
Preferably, furfural dregs and biomass fuel are provided in blanking funnel.
Preferably, the bottom of boiler is provided with vulcanization bed on the top of the first blast cap.
Preferably, one end of ammonia water pipe is inserted into the inside of spray purification tower, and is inserted into inside spray purification tower Spray apertures are offered on ammonia water pipe.
(3) beneficial effect
The present invention provides one kind can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, have it is following the utility model has the advantages that
(1) present invention tests the influence to denitration efficiency by adding the inert material of different proportion, passes through fuel structure Optimization, guarantee of ammonium hydroxide supply that optimization, air quantity are adjusted etc. reach optimum proportioning, and produce load reaches at full capacity, realize NOx row It is unconventional and unrestrained to discharge 10-15mg/m3 to 30mg/nm3 or less, SO2, meet national minimum discharge standard.
(2) present invention adjusts the adjustment of the working of a furnaces such as Secondary Air proportion by test, and Lai Tigao denitration efficiency passes through addition After a series of behaves such as inert material firing optimization, flue gas minimum discharge is not only realized, but also also by 210 drops in the use of ammonium hydroxide Degree is reduced to 130 titres, greatly reduces cost, and SO2 is also down to the concentration of emission of 10-15mg/m3 in flue gas, eliminates The costs such as the calcium oxide of desulfurization.
(3) after Boiler Mixed Burning inert material, desulfurization eliminates the dosage of calcium oxide and has opened two circulating pumps less, in conjunction with de- Nitre reduces ammonium hydroxide titre, saves the operation of four aqua ammonia pumps, saves production cost.
Detailed description of the invention
Fig. 1 is process flow chart of the invention;
Fig. 2 is the schematic diagram of internal structure of setting gauge of the present invention;
Fig. 3 is the schematic diagram of internal structure of spray purification tower of the present invention.
Appended drawing reference in figure are as follows: 1, blanking funnel;2, boiler charging belt machine;3, boiler;4, smoke exhaust pipe;5, spray cleaning Tower;6, ammonia water tank;7, boiler ash setting gauge;8, agstone setting gauge;9, primary air fan;10, secondary air fan;11, vulcanize Bed;12, the first blast cap;13, the second blast cap;14, tower body;15, wet scrubber;16, U-shaped material toggling storehouse;17, supporting leg;18, it rotates Roller;19, central axis;20, material toggling motor;21, material stirring disc;22, discharge port;23, ammonia water pipe;24, aqua ammonia pump;25, control cabinet.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
As shown in Figure 1-3, the present invention provides a kind of technical solution: one kind can effectively improve the furfural dregs boiler of denitration efficiency Denitrating system, including blanking funnel 1, boiler charging belt machine 2, boiler 3, spray purification tower 5, ammonia water tank 6 and control cabinet 25, fall The transmission initial end top of boiler charging belt machine 2, the transmission end of boiler charging belt machine 2 and boiler 3 is arranged in funnel 1 Feeding end connection, the upper end of boiler 3 are equipped with smoke exhaust pipe 4, and the other end of smoke exhaust pipe 4 and the spray that 3 side of boiler is arranged in are net Change tower 5 to connect, the other side of spray purification tower 5 is provided with ammonia water tank 6, is equipped with ammonium hydroxide between ammonia water tank 6 and spray purification tower 5 Pipe 23 is equipped with aqua ammonia pump 24 on ammonia water pipe 23, and the top of boiler charging belt machine 2 is along 2 transmission direction of boiler charging belt machine It is disposed with boiler ash setting gauge 7 and agstone setting gauge 8, boiler ash setting gauge 7 and agstone setting gauge 8 are equal Including U-shaped material toggling storehouse 16, supporting leg 17, rotating roller 18, central axis 19, material toggling motor 20, material stirring disc 21 and discharge port 22, U-shaped group The bottom end of feed bin 16 is welded with supporting leg 17, and the inside in U-shaped material toggling storehouse 16 is equipped with rotating roller 18, and the centre of rotating roller 18 is plugged with Central axis 19, one end of central axis 19 are fixedly connected with 20 shaft of material toggling motor for being mounted on U-shaped 16 outer end of material toggling storehouse, rotating roller 18 outer end equal part is provided with material stirring disc 21, and the bottom end in U-shaped material toggling storehouse 16 offers discharge port 22, and the bottom of boiler 3 is connected with Primary air fan 9, the side of boiler 3 are connected with secondary air fan 10, and the bottom of boiler charging belt machine 2 is arranged in control cabinet 25, control Case 25 processed is electric with boiler ash setting gauge 7 and agstone setting gauge 8, primary air fan 9, secondary air fan 10 and aqua ammonia pump 24 respectively Property connection, 25 model S7-200 of control cabinet, spray purification tower 5 includes tower body 14 and the wet dust removal that is arranged in inside tower body 14 The inside of device 15, boiler 3 is being respectively arranged with the first blast cap 12 and the second blast cap with primary air fan 9 and 10 junction of secondary air fan 13, furfural dregs and biomass fuel are provided in blanking funnel 1, and the bottom of boiler 3 is provided with sulphur on the top of the first blast cap 12 Change bed 11, one end of ammonia water pipe 23 is inserted into the inside of spray purification tower 5, and is inserted into the ammonium hydroxide inside spray purification tower 5 Spray apertures are offered on pipe 23.
Working principle;In use, first adding the alkaline biomass fuel of furfural dregs and moisture less than 10% in blanking funnel 1 Material, biomass fuel is preferably peanut shell, cotton frame, capsicum branch, then in the boiler ash on 2 top of boiler charging belt machine Ashes and agstone are added respectively in setting gauge 7 and agstone setting gauge 8, then to biomass fuel, furfural dregs, lime Mountain flour, ashes carry out adjusting test in proportion;Biomass fuel is pressed the interval time of deslagging by the shovel number calculating of forklift, furfural dregs It calculates, agstone and ashes are calculated by feeding port material toggling speed (subject to motor speed) is newly established;
At test initial stage, furfural dregs: biomass fuel: agstone: ashes=20min:2 shovel: 8r/min:20r/min passes through examination It tests, the flue gas nitrogen oxide content of boiler 3 can reach 45mg/m3 or so;When testing again, the ratio of a propellant composition is adjusted, By furfural dregs: biomass fuel: agstone: ashes=24min:3.5 is shoveled: 12r/min:18r/min, in final 3 flue gas of boiler Exhaust nitrogen oxides content can reach 40mg/m3 hereinafter, still less stable;It finally adjusts each boiler 3 and enters furnace component ratio, by chaff Aldehyde slag: biomass fuel: agstone: ashes=26.7min:3 shovel: 12r/min:24r/min, it is final to realize in 3 flue gas of boiler Exhaust nitrogen oxides content 30mg/m3 and stabilization;
In test, discovery biomass fuel is not enough, and 3 fluid effect of boiler is not satisfactory, then adjusts primary air fan 9, two The frequency of secondary blower 10 is to guarantee completely burned and boiler 3 fluidizes well, blocking of not agglomerating, 9 frequency of final result primary air fan 50HZ is increased to by 39HZ, 10 frequency of secondary air fan is adjusted downward to 39HZ by 45HZ, realizes 3 completely burned of boiler and flue gas is up to standard The purpose of discharge.
It can to sum up obtain, the present invention adjusts the adjustment of the working of a furnaces such as Secondary Air proportion by test, and Lai Tigao denitration efficiency leads to After crossing a series of behaves such as addition inert material firing optimization, finally realize the minimum discharge of online NOx, reach 30mg/nm3 with Under, it is stirred by increasing inert material and scraper, the reaction of partial denitrification ammonia nitrogen is completed early period, in denitration workshop section, by repeatedly Test, is also reduced to 150 titres by 210 titres in the use of ammonium hydroxide, greatly reduces cost, while SO2 also drops in flue gas To minimum discharge standard, the costs such as the calcium oxide of desulfurization are eliminated.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. one kind can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, including blanking funnel (1), boiler charging belt Machine (2), boiler (3), spray purification tower (5), ammonia water tank (6) and control cabinet (25), it is characterised in that: blanking funnel (1) setting On the transmission initial end top of boiler charging belt machine (2), the transmission end of boiler charging belt machine (2) and boiler (3) pan feeding End connection, the upper end of boiler (3) are equipped with smoke exhaust pipe (4), spray of the other end of smoke exhaust pipe (4) with setting in boiler (3) side Purifying column (5) connection is drenched, the other side of spray purification tower (5) is provided with ammonia water tank (6), ammonia water tank (6) and spray purification tower (5) Between be equipped with ammonia water pipe (23), be equipped on ammonia water pipe (23) aqua ammonia pump (24), the top of boiler charging belt machine (2) is along pot Furnace charging belt machine (2) transmission direction is disposed with boiler ash setting gauge (7) and agstone setting gauge (8), Boiler Furnace Grey setting gauge (7) and agstone setting gauge (8) include U-shaped material toggling storehouse (16), supporting leg (17), rotating roller (18), central axis (19), the bottom end of material toggling motor (20), material stirring disc (21) and discharge port (22), U-shaped material toggling storehouse (16) is welded with supporting leg (17), U The inside in type material toggling storehouse (16) is equipped with rotating roller (18), and the centre of rotating roller (18) is plugged with central axis (19), central axis (19) one end is fixedly connected with material toggling motor (20) shaft for being mounted on U-shaped material toggling storehouse (16) outer end, outside rotating roller (18) End equal part is provided with material stirring disc (21), and the bottom end of U-shaped material toggling storehouse (16) offers discharge port (22), the bottom connection of boiler (3) Once blower (9), the side of boiler (3) are connected with secondary air fan (10), and control cabinet (25) is arranged in boiler charging belt machine (2) bottom, control cabinet (25) respectively with boiler ash setting gauge (7) and agstone setting gauge (8), primary air fan (9), two Secondary blower (10) and aqua ammonia pump (24) are electrically connected.
2. one kind according to claim 1 can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, feature exists In: spray purification tower (5) includes the wet scrubber (15) of tower body (14) and setting in tower body (14) inside.
3. one kind according to claim 1 can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, feature exists In: the inside of boiler (3) is being respectively arranged with the first blast cap (12) and with primary air fan (9) and secondary air fan (10) junction Two blast caps (13).
4. one kind according to claim 1 can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, feature exists In: furfural dregs and biomass fuel are provided in blanking funnel (1).
5. one kind according to claim 1 can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, feature exists In: the bottom of boiler (3) is provided with vulcanization bed (11) on the top of the first blast cap (12).
6. one kind according to claim 1 can effectively improve the furfural dregs Denitration in Boiler system of denitration efficiency, feature exists In: one end of ammonia water pipe (23) is inserted into the inside of spray purification tower (5), and is inserted into the internal ammonia of spray purification tower (5) Water pipe offers spray apertures on (23).
CN201910719625.6A 2019-08-06 2019-08-06 A kind of furfural dregs Denitration in Boiler system effectively improving denitration efficiency Pending CN110397913A (en)

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中国重型机械工业协会: "《中国重型机械选型手册-物料搬运机械》", pages: 337 - 339 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114646067A (en) * 2022-03-28 2022-06-21 北京奥科瑞丰新能源股份有限公司 Desulfurization treatment process for combustion application of furfural residues

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