CN110396281A - A kind of fishing rod of light-high-strength and preparation method thereof - Google Patents
A kind of fishing rod of light-high-strength and preparation method thereof Download PDFInfo
- Publication number
- CN110396281A CN110396281A CN201910815211.3A CN201910815211A CN110396281A CN 110396281 A CN110396281 A CN 110396281A CN 201910815211 A CN201910815211 A CN 201910815211A CN 110396281 A CN110396281 A CN 110396281A
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- fishing rod
- parts
- titanium alloy
- powder
- coating
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 49
- 239000000843 powder Substances 0.000 claims abstract description 47
- 239000000463 material Substances 0.000 claims abstract description 34
- 239000002775 capsule Substances 0.000 claims abstract description 24
- 239000003292 glue Substances 0.000 claims abstract description 23
- 239000004744 fabric Substances 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003822 epoxy resin Substances 0.000 claims abstract description 18
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 18
- 230000002787 reinforcement Effects 0.000 claims abstract description 18
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 13
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 10
- 239000011737 fluorine Substances 0.000 claims abstract description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 10
- 239000011858 nanopowder Substances 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 239000012745 toughening agent Substances 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 9
- 230000007797 corrosion Effects 0.000 claims abstract description 9
- 238000005260 corrosion Methods 0.000 claims abstract description 9
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims abstract description 9
- 238000007711 solidification Methods 0.000 claims abstract description 6
- 230000008023 solidification Effects 0.000 claims abstract description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 5
- 239000013078 crystal Substances 0.000 claims abstract description 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 64
- 239000011248 coating agent Substances 0.000 claims description 58
- 238000010422 painting Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 10
- 239000000706 filtrate Substances 0.000 claims description 10
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000002788 crimping Methods 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 229960004756 ethanol Drugs 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 229920002521 macromolecule Polymers 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920001187 thermosetting polymer Polymers 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 238000005259 measurement Methods 0.000 claims description 4
- 239000003094 microcapsule Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 150000004982 aromatic amines Chemical class 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000012779 reinforcing material Substances 0.000 claims 1
- 238000005829 trimerization reaction Methods 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010936 titanium Substances 0.000 abstract description 5
- 229910052719 titanium Inorganic materials 0.000 abstract description 5
- CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011162 core material Substances 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000007792 addition Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K87/00—Fishing rods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C13/00—Means for manipulating or holding work, e.g. for separate articles
- B05C13/02—Means for manipulating or holding work, e.g. for separate articles for particular articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/12—Hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/08—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Inorganic Chemistry (AREA)
- Fishing Rods (AREA)
Abstract
The invention discloses fishing rods of a kind of light-high-strength and preparation method thereof, the fishing rod is prepared by the material of following weight parts: 15-18 parts of fibrous reinforcements, 10-14 parts of fluorine-containing surfactant, 6-10 parts of capsule of nano powder, 2-3 parts of potassium titanate crystal whisker, 3-5 parts of aluminium triphosphate, 6-12 parts of aerosil, 1-4 parts of toughener, 3-5 parts of nigrosine, 1-2 parts of titanium alloy powder, calcium powder 5-10 parts of hydrogenation, 20-25 parts of dehydrated alcohol, glue crosslinking agent 15-18 parts of solidification, epoxy resin capsule powder and titanium alloy wire are added in prepreg of the invention, so that the binding force in fishing rod material obtained between carbon cloth enhances, the material of titanium alloy wire, which is arranged, simultaneously brings intensity height to fishing rod, corrosion resistance is good, the high advantage of heat resistance, and And the titanium alloy wire calcine with calcium hydride by titanium alloy powder, greatly reduces the oxygen content in Titanium base, reduces the formation of titanium oxide, so that fishing rod has the characteristics that light-high-strength.
Description
Technical field
The present invention relates to fishing rod preparation fields, and in particular to a kind of fishing rod of light-high-strength and preparation method thereof.
Background technique
Have become a kind of important amusement of people, stress-relieving activity with the continuous improvement of people's living standards, fishing, it is competing
Skill fishing is also frequently carried out in high gear, and essential one kind fishing gear is fishing rod in whiffing process, in whiffing process
In play very important effect, the material of existing fishing rod itself has glass fibre and two kinds of carbon fiber, main at present to use
The material arrived is carbon fiber；
Chinese patent (CN106426975B) proposes a kind of preparation process of compound fishing rod simultaneously, steps are as follows:
(1) composite material is sent into fusion apparatus, heating fusing obtains melt；(2) non-woven fabrics is cut by being sized, and
The non-woven fabrics cut is immersed in melt, makes melt in conjunction with non-woven fabrics；(3) nonwoven fabric roll for being soaked with melt is wound on core material
On, it is sent into curing apparatus and carries out curing process, remove core material after the completion, japanning is dry；Present invention process step is simple, work
Skill is controllable, make made of fishing rod surface it is smooth closely knit, and have excellent mechanical property, but fishing rod made from the invention with
The problem that there are still intensity is poor for fishing rod in the prior art, quality is larger, and its painting process is frequently with artificial japanning, greatly
It increases and adds the labor intensity of staff.
Summary of the invention
In order to solve the above technical problems, the purpose of the present invention is to provide a kind of fishing rod of light-high-strength and its systems
Preparation Method.
The technical problems to be solved by the invention are as follows:
(1) it is added with epoxy resin capsule powder and titanium alloy wire in prepreg of the invention, greatly enhances fishing rod
Intensity makes fishing rod have the characteristics that light-high-strength under the raw material of carbon cloth, with solve existing fishing rod intensity compared with
Poor or larger quality problem；
(2) painting device of the invention cooperates conveying lever by being provided with the feeding warehouse of transfer block, may be implemented to fishing
Automatic charging in fishing rod coating process, then cooperate external telescoping mechanism to control conveying lever and do telescopic movable inside through-hole,
The labor intensity that staff can be substantially reduced may be implemented by the delivery wheel of setting in fishing rod coating process
Automatic conveying carries out coating to the single side of entire fishing rod, to solve existing fishing rod in the case where avoiding mobile coating head
Using the problem that artificial coating is time-consuming and laborious in coating process.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of fishing rod of light-high-strength, the fishing rod are prepared by the material of following weight parts: fibrous reinforcements
15-18 parts, 10-14 parts of fluorine-containing surfactant, 6-10 parts of capsule of nano powder, 2-3 parts of potassium titanate crystal whisker, aluminium triphosphate 3-
5 parts, 6-12 parts of aerosil, 1-4 parts of toughener, 3-5 parts of nigrosine, 1-2 parts of titanium alloy powder, hydrogenation calcium powder 5-
10 parts, 20-25 parts of dehydrated alcohol, glue crosslinking agent 15-18 parts of solidification；
The fishing rod is prepared by the following method to obtain, specifically:
S1: according to the parts by weight, capsule of nano powder, macromolecule thermosetting property high-intensity resin and anhydrous second are weighed
Alcohol carries out ultrasonic disperse after mixing, is then filtered under vacuum conditions, stops taking out when there is no ethyl alcohol drips
Filter takes out much filtrate, is placed in baking oven, is successively dried and preheated, and epoxy resin capsule is made in the material after taking out preheating
Powder, it is spare；
S2: according to the parts by weight, titanium alloy powder and hydrogenation calcium powder are weighed, in the closing gas with corrosion protection component
It is mixed under body environment, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then by pre- titanium alloy
Ultrasonic impact is first carried out, silk is finally pressed into and drying while successively being calcined, being cooled down under nitrogen protection, cooling is taken out
Titanium alloy wire is made in material afterwards, spare；
S3: according to the parts by weight, epoxy resin micro-capsule powder made from fluorine-containing surfactant, S1 is successively weighed
Titanium alloy wire, aluminium triphosphate, aerosil, toughener and nigrosine made from end, S2, are dissolved in organic molten
It carries out being mixed and stirred in agent uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, fibrous reinforcements are then dipped in the glue one
The section time, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain hair
Base, blank is ground, coating and assembly, are made fishing rod.
Further, the fibrous reinforcements are carbon cloth, and it is 3:7's that the cure-crosslinking agent, which is by mass ratio,
Fat polyamine and arylamine blend.
A kind of preparation method of the fishing rod of light-high-strength, this method includes the following steps:
S1: according to the parts by weight of fishing rod material, capsule of nano powder, macromolecule thermosetting property high-intensity resin and nothing are weighed
Water-ethanol carries out ultrasonic disperse after mixing, is then filtered under vacuum conditions, stopped when there is no ethyl alcohol drips
It filters, takes out much filtrate, be placed in baking oven, successively dried and preheated, epoxide-resin glue is made in the material after taking out preheating
Capsule powder, it is spare；
S2: according to the parts by weight, titanium alloy powder and hydrogenation calcium powder are weighed, in the closing gas with corrosion protection component
It is mixed under body environment, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then by pre- titanium alloy
Ultrasonic impact is first carried out, silk is finally pressed into and drying while successively being calcined, being cooled down under nitrogen protection, cooling is taken out
Titanium alloy wire is made in material afterwards, spare；
S3: according to the parts by weight, epoxy resin micro-capsule powder made from fluorine-containing surfactant, S1 is successively weighed
Titanium alloy wire, aluminium triphosphate, aerosil, toughener and nigrosine made from end, S2, are dissolved in organic molten
It carries out being mixed and stirred in agent uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, fibrous reinforcements are then dipped in the glue one
The section time, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain hair
Base obtains crude fishing rod for blank is polished, coating is carried out to crude fishing rod by painting device, by the crude fish after coating
Pole assembly, is made fishing rod；
Wherein, in step S1 the drying temperature of much filtrate and time be respectively 25 DEG C and 4h, preheating temperature and time difference
For 55 DEG C and 15min.
Further, the painting device includes first support and pedestal, and the upper end outer surface of the first support is fixed
Feeding warehouse is installed, the two sides of the feeding warehouse offer through-hole, and it is flat that the inside of the feeding warehouse is fixedly installed with several
The inner wall of the transfer block that row is placed, through-hole described in side is movably installed with conveying lever；
The upper end outer surface of the pedestal is fixedly installed with second support and two third brackets, the second support position
Position between two third brackets, the outer surface of the second support are fixedly installed with coating head, the third bracket
Upper end outer surface is fixedly installed with station, the upper end outer surface of the station be provided with two groups of motors, two groups of placement racks with
And sliding rail, the quantity of motor described in every group and placement rack is two, and the outer surface of one of them placement rack is fixed
Sliding shoe is installed, the sliding shoe is located at the inside of sliding rail, and the internal activity of the placement rack is equipped with delivery wheel, institute
The output shaft end for stating motor is fixedly mounted by connecting shaft, and one end of the connecting shaft is fixedly plugged in the inside of delivery wheel, described
The inside of sliding rail is additionally provided with lead screw and lead screw base, and the lead screw and lead screw base are mutual cooperation structure, the sliding
The lower end outer surface of block is fixedly mounted on the outer surface of lead screw, and one end of the lead screw is fixedly installed with handle.
Further, the outer surface of the transfer block is provided with ladder-like fixture block, and the inner wall of the feeding warehouse is fixedly mounted
There is hang plate, the transfer block is located at the upper end outer surface of hang plate.
Further, the upper end outer surface of the third bracket is also fixedly installed with convex block, the upper surface of the convex block with
Two sides are respectively provided with opening.
Further, the specifically used method of the painting device are as follows:
S1: diameter and record of the measurement to coating fishing rod rotate handle, and lead screw is driven to do rotation fortune inside lead screw base
Dynamic, while the rotary motion of lead screw is converted to the linear motion of sliding shoe, sliding shoe is in the internal slide of sliding rail at this time, until
When spacing between two delivery wheels is less than the diameter of fishing rod, stop operating handle；
S2: will be sequentially placed into the transfer block of feeding warehouse to coating fishing rod, starting motor and coating equipment power supply, and utilization is defeated
The fishing rod for sending bar to push bottom is in contact to through hole and with delivery wheel, at this time under the rotary drive effect of delivery wheel, fish
Pole moves from left to right, and coating head directly carries out coating to the outer surface of fishing rod, until removing simultaneously after the completion of the coating of fishing rod outer surface
It standing, when wherein the fishing rod of bottom removes feeding warehouse, fishing rod adjacent thereto falls to bottom, continue aforesaid operations, to
After all fishing rods are completed coating and stood, overturning fishing rod continues aforesaid operations, completes the coating of entire fishing rod outer surface.
Beneficial effects of the present invention:
(1) epoxy resin capsule powder and titanium alloy wire are added in prepreg of the invention, so that fishing rod obtained
In use if clashed, capsule powder will rupture, and join it as the epoxy resin and solidification glue of core material
Agent reaction, enhances the binding force between carbon cloth, avoids falling off, while the material of titanium alloy wire is arranged and brings intensity to fishing rod
The advantage high, corrosion resistance is good, heat resistance is high, and the titanium alloy wire calcine with calcium hydride by titanium alloy powder, greatly
The oxygen content in Titanium base is reduced greatly, the formation of titanium oxide is reduced, to improve the mechanical property of titanium or titanium alloy material, greatly
The intensity of big enhancing fishing rod, makes fishing rod have the characteristics that light-high-strength under the raw material of carbon cloth；
(2) painting device of the invention cooperates conveying lever by being provided with the feeding warehouse of transfer block, may be implemented to fishing
Automatic charging in fishing rod coating process, then cooperate external telescoping mechanism to control conveying lever and do telescopic movable inside through-hole,
The labor intensity that staff can be substantially reduced may be implemented by the delivery wheel of setting in fishing rod coating process
Automatic conveying carries out coating to the single side of entire fishing rod, structure is simple, uses effect in the case where avoiding mobile coating head
Fruit is more excellent, in use, by being sequentially placed into the transfer block of feeding warehouse to coating fishing rod, starting motor and coating equipment electricity
Source pushes the fishing rod of bottom to be in contact to through hole and with delivery wheel, at this time in the rotary drive of delivery wheel using conveying lever
Under effect, fishing rod moves from left to right, and coating head directly carries out coating to the outer surface of fishing rod, until the coating of fishing rod outer surface is completed
After remove and stand, when wherein the fishing rod of bottom removes feeding warehouse, fishing rod adjacent thereto falls to bottom, continues above-mentioned
Operation, after all fishing rods are completed coating and stood, overturning fishing rod continues aforesaid operations, completes the painting of entire fishing rod outer surface
Dress；
(3) painting device of the invention cooperates sliding shoe by the lead screw of setting, may be implemented between adjacent conveyor wheel
The practicability of device is greatly improved so that single painting device adapts to the fishing rod of different-thickness specification away from adjusting, is used
When, the diameter and record to coating fishing rod are measured, handle is rotated, drives lead screw to make rotating motion inside lead screw base, while silk
The rotary motion of thick stick is converted to the linear motion of sliding shoe, and sliding shoe is in the internal slide of sliding rail at this time, until two conveyings
When spacing between wheel is less than the diameter of fishing rod, stop operating handle.
Detailed description of the invention
The present invention will be further described below with reference to the drawings.
Fig. 1 is the overall structure diagram of painting device of the invention；
Fig. 2 is that the station of painting device of the invention, placement rack and motor combine view；
Fig. 3 is that the first support of painting device of the invention combines view with feeding warehouse；
Fig. 4 is enlarged view at A in Fig. 3.
In figure: 1, first support；11, feeding warehouse；12, conveying lever；13, hang plate；14, through-hole；15, transfer block；2, bottom
Seat；3, second support；4, coating head；5, third bracket；51, convex block；52, delivery wheel；53, motor；54, connecting shaft；55, it places
Seat；56, station；6, sliding rail；61, lead screw；62, lead screw base；63, handle；64, sliding shoe.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts all other
Embodiment shall fall within the protection scope of the present invention.
A kind of fishing rod of light-high-strength is present embodiments provided, which is prepared by the material of following weight parts:
15-18 parts of fibrous reinforcements, 10-14 parts of fluorine-containing surfactant, 6-10 parts of capsule of nano powder, potassium titanate crystal whisker 2-3
Part, 3-5 parts of aluminium triphosphate, 6-12 parts of aerosil, 1-4 parts of toughener, 3-5 parts of nigrosine, titanium alloy powder 1-2
Part, calcium powder 5-10 parts of hydrogenation, 20-25 parts of dehydrated alcohol, glue crosslinking agent 15-18 parts of solidification；
The fishing rod is prepared by the following method to obtain, specifically:
S1: according to the parts by weight of fishing rod material, capsule of nano powder, macromolecule thermosetting property high-intensity resin and nothing are weighed
Water-ethanol carries out ultrasonic disperse after mixing, is then filtered under vacuum conditions, stopped when there is no ethyl alcohol drips
It filters, takes out much filtrate, be placed in baking oven, successively dried and preheated, epoxide-resin glue is made in the material after taking out preheating
Capsule powder, it is spare；
S2: according to the parts by weight of fishing rod material, titanium alloy powder and hydrogenation calcium powder are weighed, with corrosion protection component
It is mixed under confining gas environment, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then will be pre-
Titanium alloy first carries out ultrasonic impact, is finally pressed into silk and drying while successively being calcined, being cooled down under nitrogen protection, takes
Titanium alloy wire is made in material after cooling out, spare；
S3: according to the parts by weight of fishing rod material, the micro- glue of epoxy resin made from fluorine-containing surfactant, S1 is successively weighed
Titanium alloy wire made from capsule powder, S2, aluminium triphosphate, aerosil, toughener and nigrosine, have been dissolved in
It carries out being mixed and stirred in solvent uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, fibrous reinforcements are then dipped in the glue one
The section time, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain hair
Base, blank is ground, coating and assembly, are made fishing rod.
In S1 the drying temperature of much filtrate and time be respectively 25 DEG C and 4h, preheating temperature and time be respectively 55 DEG C and
15min。
Fibrous reinforcements are carbon cloth, and cure-crosslinking agent is the fat polyamine and fragrance for being 3:7 by mass ratio
Amine blends.
A kind of preparation method of the fishing rod of light-high-strength, this method includes the following steps:
S1: according to the parts by weight of fishing rod material, capsule of nano powder, macromolecule thermosetting property high-intensity resin and nothing are weighed
Water-ethanol carries out ultrasonic disperse after mixing, is then filtered under vacuum conditions, stopped when there is no ethyl alcohol drips
It filters, takes out much filtrate, be placed in baking oven, successively dried and preheated, epoxide-resin glue is made in the material after taking out preheating
Capsule powder, it is spare；
S2: according to the parts by weight of fishing rod material, titanium alloy powder and hydrogenation calcium powder are weighed, with corrosion protection component
It is mixed under confining gas environment, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then will be pre-
Titanium alloy first carries out ultrasonic impact, is finally pressed into silk and drying while successively being calcined, being cooled down under nitrogen protection, takes
Titanium alloy wire is made in material after cooling out, spare；
S3: according to the parts by weight of fishing rod material, the micro- glue of epoxy resin made from fluorine-containing surfactant, S1 is successively weighed
Titanium alloy wire made from capsule powder, S2, aluminium triphosphate, aerosil, toughener and nigrosine, have been dissolved in
It carries out being mixed and stirred in solvent uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, fibrous reinforcements are then dipped in the glue one
The section time, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain hair
Base obtains crude fishing rod for blank is polished, coating is carried out to crude fishing rod by painting device, by the crude fish after coating
Pole assembly, is made fishing rod；
Wherein, in step S1 the drying temperature of much filtrate and time be respectively 25 DEG C and 4h, preheating temperature and time difference
For 55 DEG C and 15min.
It please refers to shown in Fig. 1-4, painting device includes first support 1 and pedestal 2, and the upper end outer surface of first support 1 is solid
Dingan County is equipped with feeding warehouse 11, and the two sides of feeding warehouse 11 offer through-hole 14, and the inside of feeding warehouse 11 is fixedly installed with several
The inner wall of the transfer block 15 being placed in parallel, a side through hole 14 is movably installed with conveying lever 12；
The upper end outer surface of pedestal 2 is fixedly installed with second support 3 and two third brackets 5, and second support 3 is located at two
Position between a third bracket 5, the outer surface of second support 3 are fixedly installed with coating head 4, the upper end appearance of third bracket 5
Face is fixedly installed with station 56, and the upper end outer surface of station 56 is provided with two groups of motors, 53, two groups of placement racks 55 and slides
The quantity of dynamic rail road 6, every group of motor 53 and placement rack 55 is two, and the outer surface of one of placement rack 55 is fixedly installed with
Sliding shoe 64, sliding shoe 64 are located at the inside of sliding rail 6, and the internal activity of placement rack 55 is equipped with delivery wheel 52, motor 53
Output shaft end be fixedly mounted by connecting shaft 54, one end of connecting shaft 54 is fixedly plugged in the inside of delivery wheel 52, sliding rail 6
Inside be additionally provided with lead screw 61 and lead screw base 62, lead screw 61 and lead screw base 62 are mutual cooperation structure, under sliding shoe 64
End outer surface is fixedly mounted on the outer surface of lead screw 61, and one end of lead screw 61 is fixedly installed with handle 63.
The outer surface of transfer block 15 is provided with ladder-like fixture block, and the inner wall of feeding warehouse 11 is fixedly installed with hang plate 13, defeated
The upper end outer surface for sending block 15 to be located at hang plate 13.
The upper end outer surface of third bracket 5 is also fixedly installed with convex block 51, and upper surface and the two sides of convex block 51 are respectively provided with
Opening.
The specifically used method of painting device are as follows:
S1: diameter and record of the measurement to coating fishing rod rotate handle 63, drive lead screw 61 to do inside lead screw base 62 and revolve
Transhipment is dynamic, while the rotary motion of lead screw 61 is converted to the linear motion of sliding shoe 64, and sliding shoe 64 is in sliding rail 6 at this time
Internal slide, until stop operating handle 63 when the spacing between two delivery wheels 52 is less than the diameter of fishing rod；
S2: will be sequentially placed into the transfer block 15 of feeding warehouse 11 to coating fishing rod, starting motor 53 and coating equipment power supply,
It is pushed at the fishing rod to through-hole 14 of bottom using conveying lever 12 and is in contact with delivery wheel 52, at this time in the rotation of delivery wheel 52
Under transmission effect, fishing rod moves from left to right, and coating head 4 directly carries out coating to the outer surface of fishing rod, until fishing rod outer surface applies
It removes and stands after the completion of dress, when wherein the fishing rod of bottom removes feeding warehouse 11, fishing rod adjacent thereto falls to bottom,
Continue aforesaid operations, after all fishing rods are completed coating and stood, overturning fishing rod continues aforesaid operations, completes outside entire fishing rod
The coating on surface.
(1) epoxy resin capsule powder and titanium alloy wire are added in prepreg of the invention, so that fishing rod obtained
In use if clashed, capsule powder will rupture, and join it as the epoxy resin and solidification glue of core material
Agent reaction, enhances the binding force between carbon cloth, avoids falling off, while the material of titanium alloy wire is arranged and brings intensity to fishing rod
The advantage high, corrosion resistance is good, heat resistance is high, and the titanium alloy wire calcine with calcium hydride by titanium alloy powder, greatly
The oxygen content in Titanium base is reduced greatly, the formation of titanium oxide is reduced, to improve the mechanical property of titanium or titanium alloy material, greatly
The intensity of big enhancing fishing rod, makes fishing rod have the characteristics that light-high-strength under the raw material of carbon cloth；
(2) painting device of the invention cooperates conveying lever 12, Ke Yishi by being provided with the feeding warehouse 11 of transfer block 15
Now to the automatic charging in fishing rod coating process, then cooperates external telescoping mechanism to control conveying lever 12 and done inside through-hole 14
Telescopic movable can substantially reduce the labor intensity of staff, by the delivery wheel 52 of setting, may be implemented to apply fishing rod
Automatic conveying during dress carries out coating, structure to the single side of entire fishing rod in the case where avoiding mobile coating head 4
Simply, using effect is more excellent, in use, by being sequentially placed into coating fishing rod in the transfer block 15 of feeding warehouse 11, starting electricity
Machine 53 and coating equipment power supply are pushed at the fishing rod to through-hole 14 of bottom using conveying lever 12 and are in contact with delivery wheel 52,
At this time under the rotary drive effect of delivery wheel 52, fishing rod moves from left to right, and coating head 4 directly carries out the outer surface of fishing rod
Coating, until remove and stand after the completion of the coating of fishing rod outer surface, it is adjacent thereto when wherein the fishing rod of bottom removes feeding warehouse 11
Fishing rod fall to bottom, continue aforesaid operations, after all fishing rods are completed coating and stood, overturning fishing rod continues above-mentioned
Operation, completes the coating of entire fishing rod outer surface；
(3) painting device of the invention cooperates sliding shoe 64 by the lead screw 61 of setting, may be implemented to adjacent conveyor wheel
52 spacing is adjusted, so that single painting device adapts to the fishing rod of different-thickness specification, greatly improves the practicability of device,
In use, diameter and record of the measurement to coating fishing rod, rotate handle 63, lead screw 61 is driven to do rotation fortune inside lead screw base 62
It is dynamic, while the rotary motion of lead screw 61 is converted to the linear motion of sliding shoe 64, sliding shoe 64 is in the inside of sliding rail 6 at this time
Sliding, until stop operating handle 63 when the spacing between two delivery wheels 52 is less than the diameter of fishing rod.
Above content is only to structure of the invention example and explanation, affiliated those skilled in the art couple
Described specific embodiment does various modifications or additions or is substituted in a similar manner, without departing from invention
Structure or beyond the scope defined by this claim, is within the scope of protection of the invention.
Claims (7)
1. a kind of fishing rod of light-high-strength, which is characterized in that the fishing rod is prepared by the material of following weight parts: threadiness
15-18 parts of reinforcing material, 10-14 parts of fluorine-containing surfactant, 6-10 parts of capsule of nano powder, 2-3 parts of potassium titanate crystal whisker, trimerization
3-5 parts of aluminum phosphate, 6-12 parts of aerosil, 1-4 parts of toughener, 3-5 parts of nigrosine, 1-2 parts of titanium alloy powder, hydrogenation
5-10 parts of calcium powder, 20-25 parts of dehydrated alcohol, glue crosslinking agent 15-18 parts of solidification；
The fishing rod is prepared by the following method to obtain, specifically:
S1: according to the parts by weight, weighing capsule of nano powder, macromolecule thermosetting property high-intensity resin and dehydrated alcohol, mixes
Ultrasonic disperse is carried out after conjunction, is then filtered under vacuum conditions, is stopped filtering when there is no ethyl alcohol drips, be taken out
Much filtrate is placed in baking oven, is successively dried and is preheated, the material after taking out preheating, and epoxy resin capsule powder is made, standby
With；
S2: according to the parts by weight, titanium alloy powder and hydrogenation calcium powder are weighed, in the confining gas ring with corrosion protection component
It is mixed under border, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then pre- titanium alloy is advanced
Row ultrasonic impact is finally pressed into silk and drying while successively being calcined, being cooled down under nitrogen protection, takes out after cooling
Titanium alloy wire is made in material, spare；
S3: according to the parts by weight, epoxy resin micro-capsule powder, S2 made from fluorine-containing surfactant, S1 are successively weighed
Titanium alloy wire, aluminium triphosphate, aerosil, toughener and nigrosine obtained, are dissolved in organic solvent
Be mixed and stirred for uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, when fibrous reinforcements being then dipped in one section of the glue
Between, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain blank, will
Blank is ground, coating and assembly, and fishing rod is made.
2. a kind of fishing rod of light-high-strength according to claim 1, which is characterized in that the fibrous reinforcements are
Carbon cloth, the cure-crosslinking agent are the fat polyamine and arylamine blend for being 3:7 by mass ratio.
3. a kind of preparation method of the fishing rod of light-high-strength according to claim 1, which is characterized in that this method includes
Following step:
S1: according to the parts by weight of fishing rod material, capsule of nano powder, macromolecule thermosetting property high-intensity resin and anhydrous second are weighed
Alcohol carries out ultrasonic disperse after mixing, is then filtered under vacuum conditions, stops taking out when there is no ethyl alcohol drips
Filter takes out much filtrate, is placed in baking oven, is successively dried and preheated, and epoxy resin capsule is made in the material after taking out preheating
Powder, it is spare；
S2: according to the parts by weight, titanium alloy powder and hydrogenation calcium powder are weighed, in the confining gas ring with corrosion protection component
It is mixed under border, then prepares pre- titanium alloy using laser synchronization powder feeding equipment and using simple scanning, then pre- titanium alloy is advanced
Row ultrasonic impact is finally pressed into silk and drying while successively being calcined, being cooled down under nitrogen protection, takes out after cooling
Titanium alloy wire is made in material, spare；
S3: according to the parts by weight, epoxy resin micro-capsule powder, S2 made from fluorine-containing surfactant, S1 are successively weighed
Titanium alloy wire, aluminium triphosphate, aerosil, toughener and nigrosine obtained, are dissolved in organic solvent
Be mixed and stirred for uniformly, prepreg solution being made；
S4: cure-crosslinking agent is added in prepreg solution and forms glue, when fibrous reinforcements being then dipped in one section of the glue
Between, finally fibrous reinforcements are taken out and dried, prepreg cloth is made, it is spare；
S5: by prepreg cloth successively through cutting out, hot pick, pipe crimping, tape wrap fastening, be heating and curing and demoulding handle, obtain blank, will
Blank is polished to obtain crude fishing rod, carries out coating to crude fishing rod by painting device, the crude fishing rod after coating is filled
Match, fishing rod is made；
Wherein, the drying temperature of much filtrate and time are respectively 25 DEG C in step S1 and 4h, preheating temperature and time are respectively 55
DEG C and 15min.
4. a kind of preparation method of the fishing rod material of light-high-strength according to claim 1, which is characterized in that the painting
Assembling device includes first support (1) and pedestal (2), and the upper end outer surface of the first support (1) is fixedly installed with feeding warehouse
(11), the two sides of the feeding warehouse (11) offer through-hole (14), and the inside of the feeding warehouse (11) is fixedly installed with several
The inner wall of a transfer block (15) being placed in parallel, through-hole (14) described in side is movably installed with conveying lever (12)；
The upper end outer surface of the pedestal (2) is fixedly installed with second support (3) and two third brackets (5), and described second
Bracket (3) is located at the position between two third brackets (5), and the outer surface of the second support (3) is fixedly installed with coating head
(4), the upper end outer surface of the third bracket (5) is fixedly installed with station (56), the upper end appearance of the station (56)
Face is provided with two groups of motors (53), two groups of placement racks (55) and sliding rail (6), motor described in every group (53) and placement rack
(55) quantity is two, and the outer surface of one of them placement rack (55) is fixedly installed with sliding shoe (64), the cunning
Motion block (64) is located at the inside of sliding rail (6), and the internal activity of the placement rack (55) is equipped with delivery wheel (52), the electricity
The output shaft end of machine (53) is fixedly mounted by connecting shaft (54), and one end of the connecting shaft (54) is fixedly plugged in delivery wheel (52)
Inside, the inside of the sliding rail (6) is additionally provided with lead screw (61) and lead screw base (62), the lead screw (61) and lead screw
Seat (62) is mutual cooperation structure, and the lower end outer surface of the sliding shoe (64) is fixedly mounted on the outer surface of lead screw (61), institute
The one end for stating lead screw (61) is fixedly installed with handle (63).
5. a kind of preparation method of the fishing rod material of light-high-strength according to claim 4, which is characterized in that described defeated
The outer surface of block (15) is sent to be provided with ladder-like fixture block, the inner wall of the feeding warehouse (11) is fixedly installed with hang plate (13), institute
State the upper end outer surface that transfer block (15) is located at hang plate (13).
6. a kind of preparation method of the fishing rod material of light-high-strength according to claim 4, which is characterized in that described
The upper end outer surface of three brackets (5) is also fixedly installed with convex block (51), and the upper surface of the convex block (51) is respectively provided with two sides
Opening.
7. a kind of preparation method of the fishing rod material of light-high-strength according to claim 4, which is characterized in that the painting
The specifically used method of assembling device are as follows:
S1: diameter and record of the measurement to coating fishing rod rotate handle (63), lead screw (61) are driven to do inside lead screw base (62)
Rotary motion, while the rotary motion of lead screw (61) is converted to the linear motion of sliding shoe (64), sliding shoe (64) is in cunning at this time
The internal slide in dynamic rail road (6), until stop operating handle when the spacing between two delivery wheels (52) is less than the diameter of fishing rod
(63)；
S2: will be sequentially placed into the transfer block (15) of feeding warehouse (11) to coating fishing rod, starting motor (53) and coating equipment electricity
Source is pushed at the fishing rod to through-hole (14) of bottom using conveying lever (12) and is in contact with delivery wheel (52), conveyed at this time
It takes turns under the rotary drive effect of (52), fishing rod moves from left to right, and coating head (4) directly carries out coating to the outer surface of fishing rod,
It removes and stands after the completion of to the coating of fishing rod outer surface, it is adjacent thereto when wherein the fishing rod of bottom removes feeding warehouse (11)
Fishing rod falls to bottom, continues aforesaid operations, and after all fishing rods are completed coating and stood, overturning fishing rod continues above-mentioned behaviour
Make, completes the coating of entire fishing rod outer surface.
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| CN201910815211.3A CN110396281A (en) | 2019-08-30 | 2019-08-30 | A kind of fishing rod of light-high-strength and preparation method thereof |
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| CN201910815211.3A CN110396281A (en) | 2019-08-30 | 2019-08-30 | A kind of fishing rod of light-high-strength and preparation method thereof |
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| CN110396281A true CN110396281A (en) | 2019-11-01 |
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Application publication date: 20191101 |